The Solid-liquid Transformation of Low-grade Solid Potash Deposit in Dalangtan Basin and the Simplification of the Liquid Phase System

We studied the solid-liquid transformation of low-grade solid potash deposit in Dalangtan Basin and simplified the liquid phase system.We did experiments to optimize conditions of the solid-liquid transformation.The Suitable

Effects of high-pressure heat treatment on the solid-state phase transformation and microstructures of Cu_(61.13)Zn_(33.94)Al_(4.93) alloys

The phase transformation activation energy of the Cu61.13Zn33.94A14.93 alloys, which were treated at 4 GPa and 700 ℃ for 15 minutes, was calculated by means of differential scanning calorimetry curves obtained at various heating and cooling rates. Then, the effects of high-pressure heat treatments on the solid-state phase transformation and the microstructures of Cu61.13Zn33.94A14.93 alloys were investigated. The results show that high-pressure heat treatments can refine the grains and can change the preferred orientation from （111） to （200） of α phase. Compared with the as-cast alloy, the sample with high-pressure heat treatment has finer grains, lower β＇→β and/β→β＇ transformation temperature and activation energy. Furthermore, we found that high cooling rate favours the formation of fine needle-like α phase in the range of 5-20℃/min.

SOLID-STATE PHASE TRANSFORMATION OF WELDED METAL IN CONTROL OF WELDING DISTORTION PROCESS

Based on the tests of a build-up welding at plate edge (BWPE) and amulti-layer build-up welding on plate (MBWP), the article studies on the solid-state phasetransformations which affect welding distortion process and on the influence rule of transformationstarting temperature (TST) of welded metal to the welding residual distortion. The weldingdistortion can be decreased or controlled by the transformation volume expansion caused bysolid-state phase transformation of welded metal during the cooling. The test results of BWPE showthat when TST is at about 190 deg C, the bending distortion of welded specimen is the smallest, andits displacements at free end are decreased to 58 percent and 67 percent compared with those ofconventional welding electrodes A102 and E5015, which TST are less than room temperature and equalto 758 deg C respectively. The test results of MBWP show that when TST were at 100 approx 250 deg C.the welded specimen would appear reversible bending distortion compared with those of A102 andE5015. The maximum deflection value of reversible bending distortion in 8 mm thick plate is -2.94 mmat about 170 deg C of TST. The test results provide a valuable method to decrease or to controlwelding residual distortion.

Effect of high Pressure on the Solid-State Phase Transformation Microstructure of Cu-Zn Alloy

The solid-state phase transformation microstructure of Cu-Zn alloy under different high pressure were investigated by means of SEM and XRD. The results show that the α phase with smaller grain size, different shape and random distribution appears in the Cu-Zn alloy, when the solid-state phase transformation generation in the Cu-Zn alloy under 25～750 ℃ and 3～6 GPa high pressure, and the volume fraction of transformation phase decreases with increasing pressure, under high pressure (6 GPa), the changes of microstructure of Cu-Zn alloy is not obvious. In addition, the effect of high pressure on the solid-state phase transformation microstructure of Cu-Zn alloy was discussed.

RESEARCH ON METHOD TO CALCULATE VELOCITIES OF SOLID PHASE AND LIQUID PHASE IN DEBRIS FLOW

Velocities of solid phase and liquid phase in debris flow are one key problem to research on impact and abrasion mechanism of banks and control structures under action of debris flow. Debris flow was simplified as two-phase liquid composed of solid phase with the same diameter particles and liquid phase with the same mechanical features. Assume debris flow was one-dimension two-phase liquid moving to one direction, then general equations of velocities of solid phase and liquid phase were founded in two-phase theory. Methods to calculate average pressures, volume forces and surface forces of debris flow control volume were established. Specially, surface forces were ascertained using Bingham＇s rheology equation of liquid phase and Bagnold＇s testing results about interaction between particles of solid phase. Proportional coefficient of velocities between liquid phase and solid phase was put forward, meanwhile, divergent coefficient between theoretical velocity and real velocity of solid phase was provided too. To state succinctly before, method to calculate velocities of solid phase and liquid phase was obtained through solution to general equations. The method is suitable for both viscous debris flow and thin debris flow. Additionally, velocities every phase can be identified through analyzing deposits in-situ after occurring of debris flow. It is obvious from engineering case the result in the method is consistent to that in real-time field observation.

Rapid analysis of fifteen sulfonamide residues in pork and fish samples by automated on-line solid phase extraction coupled to liquid chromatography–tandem mass spectrometry

The aim of this work was to develop an automated on-line solid phase extraction(SPE)with liquid chromatography-tandem mass spectrometry method for the detection of fifteen sulfonamides in pork and fish samples.Samples were extracted with 0.2%formic acid acetonitrile solution,purified by on-line SPE device with HLB column,then separated by XBridge C18 column,using 0.1%formic acid solution and acetonitrile as the mobile phase.Mass spectrometric data was acquired under multiple reaction monitoring(MRM)mode using positive ionization electrospray.Internal standard method was used in the quantification,good linear relationship was got in range of 0.1–100 ng/mL and correlation coefficient was higher than 0.9990.The limits of detection were in the range of 0.125–2.00g/kg and the limits of quantitation were in the range of 0.250–5.00g/kg.Recoveries of the method were in range of 78.3%–99.3%,relative standard deviation were lower than 10%.The method was simple,sensitivity,and could be used for routine supervision and analysis of fifteen sulfonamides in pork and fish.

A Novel Technology for Synthesizing Pentasil Zeolites Based on Solid-Solid Mass Transformation Mechanism

A novel technology of preparing zeolites based on solid-solid mass transformation mechanism is developed for the first time. By employing this technology, three different types of highly crystallized pentasil zeolites, ZSM-35 (FER-type), Silicalite-1(MFI-type) and Mordenite(MOR-type), are successfully synthesized in the solid system. In terms of commercial production, the technology-could simplify synthesis procedure and make the continuous production of zeolites possible, so as to improve the productivity. Additionally, it is environmentally friendly because the crystallization occurs in solid phase where there exists no pollution caused by waste liquid. Therefore, this technique provides us with a new industrial process for the clean and continuous production of zeolites. The characteristics in synthesis chemistry and the crystallization mechanism involved in the technology are also discussed.

Effect of two-step solid solution on microstructure andδphase precipitation of Inconel 718 alloy

Inconel 718 is the most popular nickel-based superalloy and is extensively used in aerospace,automotive,and energy indus-tries owing to its extraordinary thermomechanical properties.The effects of different two-step solid solution treatments on microstructure andδphase precipitation of Inconel 718 alloy were studied,and the transformation mechanism fromγ″metastable phase toδphase was clarified.The precipitates were statistically analyzed by X-ray diffractometry.The results show that theδphase content firstly increased,and then decreased with the temperature of the second-step solid solution.The changes in microstructure andδphase were studied by scanning electron microscopy and transmission electron microscopy.An intragranularδphase formed in Inconel 718 alloy at the second-[100]_(δ)[011]γ step solid solution temperature of 925℃,and its orientation relationship withγmatrix was determined as//and(010)_(δ)//(111)γ.Furthermore,the Vickers hardness of different heat treatment samples was measured,and the sample treated by second-step solid solution at 1010℃ reached the maximum hardness of HV 446.84.

Determination of Sulfadimidine in Royal Jelly by C_(18)-functionalized Magnetic Silica Nanoparticles Solid Phase Extraction-High Performance Liquid Chromatography-Tandem Mass Spectrometry

[Objective] This study aimed to develop a method of C_18-functionalized magnetic silica nanoparticles solid phase extraction-high performance liquid chro- matography-tandem mass spectrometry for the determination of sulfadimidine in royal jelly. [Method] The royal jelly samples were pretreated by MCX SPE column and C_18-functionalized magnetic silica nanoparticles, and the purified samples were de- tected by HPLC-MS/MS. [Result] The detection method showed a good linear rela- tionship in the range of 5-80 ugkg （r=0.993 1）. The recovery ranges were between 93%- 104% with the relative standard deviations （RSD） below 11.3%. [Conclusion] Combined with automation equipment, the method is simple, fast, time-saving, and easy to real- ize the automation of sulfadimidine in the royal jelly samples before determination.

Numerical Simulation and Analysis of Solid-liquid Two-phase Flow in Centrifugal Pump

The flow with solid-liquid two-phase media inside centrifugal pumps is very complicated and the relevant method for the hydraulic design is still immature so far. There exist two main problems in the operation of the two-phase flow pumps, i.e., low overall efficiency and severe abrasion. In this study, the three-dimensional, steady, incompressible, and turbulent solid-liquid two-phase flows in a low-specific-speed centrifugal pump are numerically simulated and analyzed by using a computational fluid dynamics （CFD） code based on the mixture model of the two-phase flow and the RNG k-~ two-equation turbulence model, in which the influences of rotation and curvature are fully taken into account. The coupling between impeller and volute is implemented by means of the frozen rotor method. The simulation results predicted indicate that the solid phase properties in two-phase flow, especially the concentration, the particle diameter and the density, have strong effects on the hydraulic performance of the pump. Both the pump head and the efficiency are reduced with increasing particle diameter or concentration. However, the effect of particle density on the performance is relatively minor. An obvious jet-wake flow structure is presented near the volute tongue and becomes more remarkable with increasing solid phase concentration. The suction side of the blade is subject to much more severe abrasion than the pressure side. The obtained results preliminarily reveal the characteristics of solid-liquid two-phase flow in the centrifugal pump, and are helpful for improvement and empirical correction in the hydraulic design of centrifugal pumps.

Simultaneous Determination of Bisphenols and Alkylphenols in Water by Solid Phase Extraction and Ultra Performance Liquid Chromatography-tandem Mass Spectrometry

To establish an analytical method for determination of four bisphenols （BPA, BPB, BPF, and BPS） and two alkylphenols （4-n-OP, 4-n-NP） in water by ultra performance liquid chromatography- tandem mass spectrometry （UPLC/MS/MS）. The water samples were extracted and condensed with solid-phase extraction （SPE） using C18 cartridges and eluted by acetonitrile. Separation was carried out with Acquity BEH C8 column and detection were performed by UPLC/MS/MS. Quantification was calculated by using the internal standard BPA-d16 and 4-n-NP-d8. The linear correlation coefficients of these compounds in the range of 1.0-100.0μg/L were all over 0.999. The minimum detectable concentrations were 0.75-1.0 ng/L, and the recoveries ranged from 87.0% to 106.9%.

Phase Transformation of Nanosized Zirconia

The nanosized zirconia was synthesized via solid state reaction in the presence of surfactant. The results indicate that crystal phase of zirconia can be controlled by tuning the synthesis parameters such as OH^-/Zr molar ratio, crystallizing temperature and time. It can be transformed among amorphous, tetragonal and monoclinic phases. The transformation is driven by particle size. The research shows the nanocrystalline zirconia possesses the higher thermal stability compared with amorphous framework. The ＂glow exotherm＂ can be observed for the amorphous samples. Otherwise, it is in the absence for nanocrystalline samples. Herein, the reason for retention of tetragonal zirconia is demonstrated.

Computational Analysis of Centrifugal Pump Delivering Solid-liquid Two-phase Flow during Startup Period

The transient behavior of centrifugal pumps during transient operating periods, such as startup and stopping, has drawn more and more attention recently because of urgent needs in engineering. Up to now, almost all the existing studies on this behavior are limited to using water as working fluid. The study on the transient behavior related to solid-liquid two-phase flow has not been seen yet. In order to explore the transient characteristics of a high specific-speed centrifugal pump during startup period delivering the pure water and solid-liquid two-phase flow, the transient flows inside the pump are numerically simulated using the dynamic mesh method. The variable rotational speed and flow rate with time obtained from experiment are best fitted as the function of time, and are written into computational fluid dynamics （CFD） code-FLUENT by using a user defined function. The predicted heads are compared with experimental results when pumping pure water. The results show that the difference in the transient performance during startup period is very obvious between water and solid-liquid two-phase flow during the later stage of startup process. Moreover, the time for the solid-liquid two-phase flow to achieve a stable condition is longer than that for water. The solid-liquid two-phase flow results in a higher impeller shaft power, a larger dynamic reaction force, a more violent fluctuation in pressure and a reduced stable pressure rise comparing with water. The research may be useful to tmderstanding on the transient behavior of a centrifugal pump under a solid-liquid two-phase flow during startup period.

Uncertainty Evaluation of Determination of Microcystin MC-LR in Environmental Samples by Solid Phase Extraction-Ultra Performance Liquid Chromatography-Tandem Mass Spectrometry

To assess uncertainty of determination of MC-LR in environmental samples by solid phase extraction- ultra performance liquid chromatography- tandem mass spectrometry,the sources of the uncertainty were evaluated firstly,and the expanded uncertainty was calculated finally.The results show that when MC-LR concentration in the water samples was 0.50 μg/L,the expanded uncertainty was 0.00628 μg/L(k=2).

Development of a Rapid and Efficient Liquid Chromatography Method for Determination of Gibberellin A4 in Plant Tissue, with Solid Phase Extraction for Purification and Quantification

A new, rapid and efficient reverse phase Liquid Chromatography (RP-LC) method was developed for determination of Gibberellin A4 (GA4) in samples of flower stalk of Dasylirion cedrosanum and vegetative tissue of Epithelantha micromeris. Purification of GA4 was carried out by solid phase extraction (SPE), in Epithelantha micromeris. In the chromatography method was obtaining a retention time of 2.1 min, using Hypersil GOLD C-18 column (100 × 4.6 mm dim and size particle 5 μ), mobile phase 50/50 acetonitrile/water and a flow 1.0 ml/min. Detection was carried out by a UV detector set at 205 nm, and a quantization limit of 0.4 mg/L. The obtained correlation coefficient was 0.995.

Stability analysis of unsaturated soil slope during rainfall infiltration using coupled liquid-gas-solid three-phase model

Generally, most soil slope failures are induced by rainfall infiltration, a process that involves interactions between the liquid phase, gas phase,and solid skeleton in an unsaturated soil slope. In this study, a loosely coupled liquid-gas-solid three-phase model, linking two numerical codes,TOUGH2/EOS3, which is used for water-air two-phase flow analysis, and FLAC^(3D), which is used for mechanical analysis, was established. The model was validated through a documented water drainage experiment over a sandy column and a comparison of the results with measured data and simulated results from other researchers. The proposed model was used to investigate the features of water-air two-phase flow and stress fields in an unsaturated soil slope during rainfall infiltration. The slope stability analysis was then performed based on the simulated water-air two-phase seepage and stress fields on a given slip surface. The results show that the safety factor for the given slip surface decreases first, then increases, and later decreases until the rainfall stops. Subsequently, a sudden rise occurs. After that, the safety factor decreases continually and reaches its lowest value, and then increases slowly to a steady value. The lowest value does not occur when the rainfall stops, indicating a delayed effect of the safety factor. The variations of the safety factor for the given slip surface are therefore caused by a combination of pore-air pressure, matric suction, normal stress, and net normal stress.

Numerical simulation of predicting and reducing solid particle erosion of solid-liquid two-phase flow in a choke

Chokes are one of the most important components of downhole flow-control equipment. The particle erosion mathematical model, which considers particle-particle interaction, was established and used to simulate solid particle movement as well as particle erosion characteristics of the solid-liquid two-phase flow in a choke. The corresponding erosion reduction approach by setting ribs on the inner wall of the choke was advanced. This mathematical model includes three parts： the flow field simulation of the continuous carrier fluid by an Eulerian approach, the particle interaction simulation using the discrete particle hard sphere model by a Lagrangian approach and calculation of erosion rate using semiempirical correlations. The results show that particles accumulated in a narrow region from inlet to outlet of the choke and the dominating factor affecting particle motion is the fluid drag force. As a result, the optimization of rib geometrical parameters indicates that good anti-erosion performance can be achieved by four ribs, each of them with a height （H） of 3 mm and a width （B） of 5 mm equaling the interval between ribs （L）.

Flux vector splitting solutions for coupling hydraulic transient of gas-liquid-solid three-phase flow in pipelines

The gas-liquid-solid three-phase mixed flow is the most general in multiphase mixed transportation. It is significant to exactly solve the coupling hydraulic transient problems of this type of multiphase mixed flow in pipelines. Presently, the method of characteristics is widely used to solve classical hydraulic transient problems. However, when it is used to solve coupling hydraulic transient problems, excessive interpolation errors may be introduced into the results due to unavoidable multiwave interpolated calculations. To deal with the problem, a finite difference scheme based on the Steger- Warming flux vector splitting is proposed. A flux vector splitting scheme is established for the coupling hydraulic transient model of gas-liquid-solid three-phase mixed flow in the pipelines. The flux subvectors are then discretized by the Lax-Wendroff central difference scheme and the Warming-Beam upwind difference scheme with second-order precision in both time and space. Under the Rankine-Hugoniot conditions and the corresponding boundary conditions, an effective solution to those points located at the boundaries is developed, which can avoid the problem beyond the calculation region directly induced by the second-order discrete technique. Numerical and experimental verifications indicate that the proposed scheme has several desirable advantages including high calculation precision, excellent shock wave capture capability without false numerical oscillation, low sensitivity to the Courant number, and good stability.

Comparison of liquid-liquid extraction-thin layer chromatography with solid-phase extraction-high-performance thin layer chromatography in detection of urinary morphine

Liquid-liquid extraction-thin layer chromatography （LLE-TLC） has been a common and routine combined method for detection of drugs in biological materials. Solid-phase extraction （SPE） is gradually replacing the tra- ditional LLE method. High performance thin layer chromatography （HPTLC） has several advantages over TLC. The present work studied the higher efficiency of a new SPE-HPTLC method over that of a routine LLE-TLC method, in extraction and detection of urinary morphine. Fifty-eight urine samples, primarily identified as mor- phine-positive samples by a strip test, ＇were re-screened by LLE-TLC and SPE-HPTLC. The results of LLE-TLC and SPE-HPTLC were then compared with each other. The results showed that the SPE-HPTLC detected 74% of total samples as morphine-positive samples whereas the LLE-TLC detected 48% of the same samples. We further discussed the effect of codeine abuse on TLC analysis of urinary morphine. Regarding the importance of morphine detection in urine, the present combined SPE-HPTLC method is suggested as a replacement method for detection of urinary morphine by many reference laboratories.

Microstructural Evolution and Phase Transformations of Mechanically Stirred Non-dendritic ZA27 Alloy during Partial Remelting

The microstructural evolution and phase transformations of mechanically stirred non-dendritic ZA27 alloy during partial remelting were studied by using scanning electron microscopy and X-ray diffraction technique.The partial remelting temperature was 460℃ and lower than the stirring temperature of 465℃.So the microstructure with globular grains needed for semi-solid forming can not be obtained and the starting primary non-dendritic grains change in turn to connect non-dendritic grains, long chain-like structures and finally to coarsen connect grains.However,the small near-equiaxed grains between the primary non-dendritic grains are evolved into small globular grains gradually,some of which are also attached to the primary non-dendritic grains during the subsequent heating.The X-ray diffraction results show that a series of phase transformations, α+η+ε→β,η+β→L,β→α′+L,α+η+ε→α′ and α′→L, occur successively during this process.The main reason why the starting primary non-dendritic grains do not separate into the needed independent globular grains is that the reactions of η+β→L and α′→L do not occur or occurr incompletely in the layers used to connect the primary non-dendritic grains.