A comparison study on structure-function relationship of polysaccharides obtained from sea buckthorn berries using different methods:antioxidant and bile acid-binding capacity

In this study,the structural characters,antioxidant activities and bile acid-binding ability of sea buckthorn polysaccharides(HRPs)obtained by the commonly used hot water(HRP-W),pressurized hot water(HRP-H),ultrasonic(HRP-U),acid(HRP-C)and alkali(HRP-A)assisted extraction methods were investigated.The results demonstrated that extraction methods had significant effects on extraction yield,monosaccharide composition,molecular weight,particle size,triple-helical structure,and surface morphology of HRPs except for the major linkage bands.Thermogravimetric analysis showed that HRP-U with filamentous reticular microstructure exhibited better thermal stability.The HRP-A with the lowest molecular weight and highest arabinose content possessed the best antioxidant activities.Moreover,the rheological analysis indicated that HRPs with higher galacturonic acid content and molecular weight showed higher viscosity and stronger crosslinking network(HRP-C,HRP-W and HRP-U),which exhibited stronger bile acid binding capacity.The present findings provide scientific evidence in the preparation technology of sea buckthorn polysaccharides with good antioxidant and bile acid binding capacity which are related to the structure affected by the extraction methods.

Structure Bearing Capacity Testing and Evaluation of Existing Bridges

The bearing capacity testing and evaluation of the existing bridge engineering structure is not only the key to clarify its structural quality and safety performance,but it also can lay a solid foundation for subsequent repairs and maintenance work.To ensure the bearing capacity,durability and reliability of existing bridges,this paper analyzes the importance and methods of testing and evaluation of structural bearing capacity of a bridge.This analysis aims to provide scientific reference for the quality assessment and subsequent repair and maintenance of existing bridge engineering structures.

Analysis of Bridge-Bearing Capacity Detection and Evaluation Technology

A bridge project is taken as an example to analyze the application of bearing capacity detection and evaluation.This article provides a basic overview of the project,the application of bearing capacity detection technology,and the bearing capacity assessment analysis.It is hoped that this analysis can provide a scientific reference for the load-bearing capacity detection and evaluation work in bridge engineering projects,thereby achieving a scientific assessment of the overall load-bearing capacity of the bridge engineering structure.

A Combination of N2 and CO2 Adsorption to Characterize Nanopore Structure of Organic-Rich Lower Silurian Shale in the Upper Yangtze Platform, South China： Implications for Shale Gas Sorption Capacity

The pores in shales are mainly of nanometer-scale, and their pore size distribution is very important for the preservation and exploitation of shale gas. This study focused on the organic-rich Lower Silurian black shale from four wells in the Upper Yangtze Platform, and their TOC, mineralogical composition and pore characterization were investigated. Low pressure N2 and CO2 adsorption were conducted at 77.35 K and 273.15 K, respectively, and the pore structures were characterized by modified Brunauer-Emmett-Teller （BET）, Dubinin-Radushkevich （DR）, t-plot, Barrett- Joyner-Halenda （BJH） and density functional theory （DFT） methods and then the relationship between pore structure and shale gas sorption capacity was discussed. The results indicate that （1） The Lower Silurian shale has high TOC content of 0.92%~96%, high quartz content of 30.6%-69.5%, and high clays content of 24.1%-51.2%. The total specific surface area varies from 7.56 m^2/g to 25.86 m^2/g. Both the total specific surface area and quartz content are positively associated with the TOC content. （2） Shale samples with higher TOC content have more micropores, which results in more complex nanopore structure. Micropore volumes/surface areas and non-micropore surface areas all increase with the increasing TOC content. （3） A combination of N2 and CO2 adsorption provides the most suitable detection range （~0.3-60 nm） and has high reliability and accuracy for nanopore structure characterization. （4） The TOC content is the key factor to control the gas sorption capacity of the Lower Silurian shale in the Upper Yangtze Platform.

ULTIMATE LOAD-BEARING CAPACITY OF CYLINDER DERIVED FROM AUTOFRETTAGE UNDER IDEAL CONDITION

According to the basic theory on autofrettage and according to the 4th strength theory, several parameters and their relations are studied under ideal condition, including σej/σy, the equivalent stress of total stresses at elastoplastic juncture; σei/σy, the equivalent stress of total stresses at inside surface; σej＇/σy, the equivalent stress of residual stresses at elastoplastic juncture; σei＇/σy, the equivalent stress of residual stresses at inside surface; and p/σy, load-bearing capacity of an autofrettaged cylinder. By theoretical study on relations between the parameters, noticeable results and laws are achieved： to satisfy ｜σei＇｜=σy. the relation between kj and k is, k^2lnkj^2-k^2-kj^2＋2=0, when k→∞, kj = √e = 1.648 72, as based on the 3rd strength theory, where k is the outside/inside radius ratio of a cylinder, kj is the ratio of elastoplastic juncture radius to inside radius of a cylinder; If the plastic region covers the whole wall of a cylinder, for compressive yield not to occur after removing autofrettage pressure, the ultimate k is k=-2.218 46 as based on the 3rd strength theory; With k=2.218 46, a cylinder＇s ultimate load-bearing capacity equals its entire yield pressure, or p/σy=21nk/√3; The maximum and optimum load-bearing capacity of an autofrettaged cylinder is just 2 times the loading which an unautofrettaged cylinder can bear elastically, or p/σy=2（k^2-1）/√3 k^2, and the limit of the load-bearing capacity of an autofrettaged cylinder is also just 2 times that of an unautofrettaged cylinder. The conclusions are the same as based on the 3rd strength theory, but some equations are different from each other.

Effect of Optimum Plastic Depth on Stresses and Load-bearing Capacity of Autofrettaged Cylinder

Autofrettage is an effective measure to even distribution of stresses and raise load-bearing capacity for （ultra-）high pressure apparatus. Currently, the research on autofrettage has focused mostly on specific engineering problems, while general theoretical study is rarely done. To discover the general law contained in autofrettage theory, by the aid of the authors’ previous work and according to the third strength theory, theoretical problems about autofrettage are studied including residual stresses and their equivalent stress, total stresses and their equivalent stress, etc. Because of the equation of optimum depth of plastic zone which is presented in the authors’ previous work, the equations for the residual stresses and their equivalent stress as well as the total stress and their equivalent stress are simplified greatly. Thus the law of distribution of the residual stresses and their equivalent stress as well as the total stress and their equivalent stress and the varying tendency of these stresses are discovered. The relation among various parameters are revealed. The safe and optimum load-bearing conditions for cylinders are obtained. According to the results obtained by theoretical analysis, it is shown that if the two parameters, namely ratio of outside to inside radius, k, and depth of plastic zone, kj, meet the equation of optimum depth of plastic zone, when the pressure contained in an autofrettaged cylinder is lower than two times the initial yield pressure of the unautofrettaged cylinder, the equivalent residual stress and the equivalent total stress at the inside surface as well as the elastic-plastic juncture of a cylinder are lower than yield strength. When an autofrettaged cylinder is subjected to just two times the initial yield pressure of the unautofrettaged cylinder, the equivalent total stress within the whole plastic zone is just identically equal to the yield strength, or it is a constant. The proposed research theoretically depicts the stress state of ultra-）high pressure autofrettaged cylinder more accurately and more reasonably and provides the reference for design of （ultra-）high pressure apparatus.

Hierarchical platinum–iridium neural electrodes structured by femtosecond laser for superwicking interface and superior charge storage capacity

The interfacial performance of implanted neural electrodes is crucial for stimulation safety and the recording quality of neuronal activity.This paper proposes a novel surface architecture and optimization strategy for the platinum–iridium(Pt–Ir)electrode to optimize electrochemical performance and wettability.A series of surface micro/nano structures were fabricated on Pt–Ir electrodes with different combinations of four adjustable laser-processing parameters.Subsequently,the electrodes were characterized by scanning electron microscopy,energy-dispersive X-ray spectroscopy,cyclic voltammetry,electrochemical impedance spectroscopy,and wetting behavior.The results show that electrode performance strongly depends on the surface morphology.Increasing scanning overlap along with moderate pulse energy and the right number of pulses leads to enriched surface micro/nano structures and improved electrode performance.It raises the maximum charge storage capacity to 128.2 mC/cm^(2) and the interface capacitance of electrodes to 3.0×10^(4)μF/cm^(2) for the geometric area,compared with 4.6 mC/cm^(2) and 443.1μF/cm2,respectively,for the smooth Pt–Ir electrode.The corresponding optimal results for the optically measured area are 111.8 mC/cm^(2) and 2.6×10^(4)μF/cm^(2),which indicate the contribution of fner structures to the ablation profle.The hierarchical structures formed by the femtosecond laser dramatically enhanced the wettability of the electrode interface,giving it superwicking properties.A wicking speed of approximately 80 mm/s was reached.Our optimization strategy,leading to superior performance of the superwicking Pt–Ir interface,is promising for use in new neural electrodes.

Mesh-like vertical structures enable both high areal capacity and excellent rate capability

In order to balance electrochemical kinetics with loading level for achieving efficient energy storage with high areal capacity and good rate capability simultaneously for wearable electronics,herein,2 D meshlike vertical structures(NiCo_2 S_4@Ni(OH)_2) with a high mass loading of 2.17 mg cm^(-2) and combined merits of both 1 D nanowires and 2 D nanosheets are designed for fabricating flexible hybrid supercapacitors.Particularly,the seamlessly interconnected NiCo_2 S_4 core not only provides high capacity of 287.5 μAh cm^(-2) but also functions as conductive skeleton for fast electron transport;Ni(OH)_2 sheath occupying the voids in NiCo_2 S_4 meshes contributes extra capacity of 248.4 μAh cm^(-2);the holey features guarantee rapid ion diffusion along and across NiCO_2 S_4@Ni(OH)_2 meshes.The resultant flexible electrode exhibits a high areal capacity of 535.9 μAh cm^(-2)(246.9 mAh g^(-1)) at 3 mA cm^(-2) and outstanding rate performance with 84.7% retention at 30 mA cm^(-2),suggesting efficient utilization of both NiCo_2 S_4 and Ni(OH)_2 with specific capacities approaching to their theoretical values.The flexible solid-state hybrid device based on NiCo_2 S_4@Ni(OH)_2 cathode and Fe_2 O_3 anode delivers a high energy density of 315 μWh cm^(-2) at the power density of 2.14 mW cm^(-2) with excellent electrochemical cycling stability.

Comparison of Gas Distribution Properties of Conventional and High Capacity Structured Packings

这份报纸论述用大规模设备执行在弄皱的表组织了收拾行李的一个高能力(Montz-pak B1-250M ) 的煤气的分发性质上观察几何学的效果并且把它与它的常规对应物(Montz-pak B1-250 ) 的作比较的试验性的研究的结果。尽管收拾行李的高能力展出显著地更低的全面压力落下，煤气的分发表演类似于常规收拾行李的，并且在两个盒子中一致地好的。

Analytical Framework Model for Capacity Needs Assessment and Strategic Capacity Development within the Local Government Structure in Tanzania

This is a methodological paper prepared by senior academicians, researchers and consultants from renowned universities in Tanzania. The paper provides insights as to how best development agents can approach the challenge of capacity needs assessment and development of capacity building programs in the context of the local government structure in Tanzania. The paper is of original nature and is based on author’s accumulated knowledge and practice in conducting capacity assessments and developing capacity building programs in Tanzania. The paper describes what can be considered to be best practices in conducting participatory capacity assessment through consultative processes which involves most of the key actors who would be engaged in implementing proposed interventions. The paper puts forward an analytical model for capacity assessment and program development in the Tanzanian context. The main features of the model can be summarized as participatory capacity assessment, strategic capacity building program development and complementarity through synergy building with like-minded stakeholders. The operational modality for utilizing the model in developing capacity building programs which among other components has monitoring and evaluation aspects is included. It is recommended that practitioners and development agents should test the model in their working environments to realize its potential benefits including program ownership by stakeholders.

Electronic Band Structure and Heat Capacity Calculation of Some TlX (X = Sb, Bi) Compounds

The tight binding linear muffin-tin-orbital (TB-LMTO) method within the local density approximation (LDA) has been used to calculate structural and electronic properties of thallium pnictides TlX (X = Sb, Bi). As a function of volume, the total energy is evaluated. Apart from this, equilibrium lattice parameter, bulk modulus, first order derivative, electronic and lattice heat co-efficient, Debye temperature and Grüneisen constants, band structure and density of states are calculated. From energy band diagram, we observed metallic behaviour in TlSb and TlBi compounds. The equilibrium lattice constants agreed well with the available data.

Analysis and Modeling of k-regular and k-connected Protection Structure in Ultra-High Capacity Optical Networks

This paper proposes k-regular and k-connected(k&k) structure against multifaults in ultra-high capacity optical networks.Theoretical results show that pre-configured k&k structure can reach the lower bound on logical redundancy.The switching time of k&k protection structure is as quickly as ringbased protection in SDH network.It is the optimal protection structure in ultra-high capacity optical networks against multi-faults.We develop the linear programming model for k&k structure and propose a construction method for k&k structure design.Simulations are conducted for spare spectrum resources effi ciency of the pre-confi gured k&k structure under multi-faults on representative COST239 and NSFnet topologies.Numerical results show that the spare spectrum resources efficiency of k&k structure can reach the lower bound on logical redundancy in static networks.And it can largely improve spare spectrum resources effi ciency compared with p-cycles based protection structure without reducing protection effi ciency under dynamic traffi cs.

QSRR Study on the Relationship between the Chromatographic Capacity Factor and Lipophilicity and Structure Parameters of Halogenated Thiophenols

The capacity factors （k＇） of fourteen types ofhalogenated thiophenols in different phases of methanol-water eluent were determined by reversed phased high-performance liquid chromatography （RP-HPLC） and the relationships between the logarithm of capacity factor lgK＇ and methanol ratio ψ were analyzed. A fair linear relationship is found between lgK＇ and ψ, and the correlation coefficients R2 of the constructed linear equations are all greater than 0.990. Relationship between the chromatographic data lgKw＇ when extrapolated to pure water and n-octanol/water partition coefficient lgKow obtained by the group contribution method has shown a good linear correlation with R2= 0.956. The structure parameters of fourteen halogenated thiophenols were calculated by using DFT, and the correlation equation of lgKw＇ and structure parameters was obtained by using SPSS, lgKw＇ = -0.409 ＋ 0.039a and R2 = 0.981, meaning that lgKw＇ is mainly determined by the polarizability α.

A Bio-inspired Mutual-hook Strategy for the Soft Finger to Improve Load-bearing Capacity and Grasping Stability

Soft grippers have great potential applications in daily life,since they can compliantly grasp soft and delicate objects.However,the highly elastic fingers of most soft grippers are prone to separate from each other while grasping objects due to their low stiffness,thus reducing the grasping stability and load-bearing capacity.To tackle this problem,inspired from the venus flytrap plant,this work proposes a mutual-hook mechanism to restrain the separation and improve the grasping performance of soft fingers.The novel soft gripper design consists of three modules,a soft finger-cot,two Soft Hook Actuators(SHAs)and two sliding mechanisms.Here,the soft finger-cot covers on the soft finger,increasing the contact area with the target object,two SHAs are fixed to the left and right sides of the finger-cot,and the sliding mechanisms are designed to make SHAs stretch flexibly.Experiments demonstrate that the proposed design can restrain the separation of soft fingers substantially,and the soft fingers with the finger-cots can grasp objects three times heavier than the soft fingers without the proposed design.The proposed design can provide invaluable insights for soft fingers to restrain the separation while grasping,thus improving the grasping stability and the load-bearing capacity.

Development of Maritime Mix-Type Structures

Mixed-type structures combining the advantages of pile constructions(low material consumption and possibility to erect on weak soils)and gravity walls(high bearing capacity and stability,good reliability and durability)are considered and improved.The sphere of application,main peculiarities,and practical technological aspects of these structures’implementation are analyzed.

Effects of Pit-Sand on Resistance Capacities of Reinforced Concrete Space Framed Structures

This paper used the existing formulae in estimating resistance parameter of reinforced concrete structure to assess the effect of concrete produced from pit-sand in Akure metropolis, on the resistance parameters of a collapsed building in Oba-Ile, Akure. Site inspections were carried out on the collapsed building, and concrete samples were taken. Both destructive and non-destructive methods were used to determine the structure’s concrete strength. The number of reinforcements in each structural element was determined by exposing them. Resistance parameters such as moments of resistance for slab (MRS), for beam (MRB) and shear capacity (VC) of the structural elements were estimated using existing formulae and, compare the results with the structure’s actual resistance parameters. The average concrete strength was 8.5 N/mm2 which was less than 20 N/mm2, the prescribed concrete strength for construction of the building. The estimated resistance parameters MRS, MRB and VC based on 8.5 N/mm2 concrete strength are 18.2 kN·m, 46.3 kN·m and 64.4 kN respectively. Also the estimated resistance parameters MRS, MRB and VC based on 20 N/mm2 concrete strength are 20.6 kN·m, 54.1 kN·m and 90.73 kN respectively. The actual MRS, MRB and VC at collapse were 6.67 kN·m, 13.6 kN·m and 18.88 kN respectively. The existing formulae for predicting resistance parameters did not give accurate resistance parameters for the building at collapse. The collapse of the building was by shear failure, since shear failure capacity will be reached first before any of the other resistance parameters.

The Effect of Bone Loss Pattern on the Structural Capacity of the Proximal Femur

The effect of age-related bone loss on the structural capacity of the proximal femur were investigated by Finite Element Analysis (FEA). Four bone loss patterns were considered. These were "uniform cortical bone loss", "neck cortical bone loss", "intertrochanteric cortical bone loss" and "uniform trabecular bone loss". The results show that the two "non-uniform cortical bone loss" patterns are more dangerous than the "uniform cortical bone loss" pattern, and that the cortical bone loss in intertrochanteric region is associated with a greater reduction in cortical failure load than the cortical bone loss in the femoral neck. The trabecular bone loss causes a limited decrease in both cortical failure and trabecular failure loads. This research should be helpful to the clinical assessment of femur fracture risk due to age-related bone loss.

China's Excess Oil Refining Production Capacity in the Background of the Supply Side Structural Reform

Through analysis of the current situation and newly-increased production capacity-of the oil refining industry of China, this Paper discusses both the continuous expansion trend and the serious excess of production capacity of the oil refining industry of China. Due to the entry of the Chinese economy into the new normal,the accelerated substitution of old energy by new energy and rigid restrictions composed of low carbon and environmental protection requirements, the oil demand of China will continue to increase overall, but the growth will obviously slow down. At the same time, the newly-increased production capacity in Shandong and coastal region will continuously expand, the supply and demand contradiction will intensify, and the structural excess production capacity of the oil refining industry of China will be prominent. It is suggested that the government should attach great importance to the production capacity of the oil refining industry at the macro level, and deeply carry forward the supply side structural reform, and that enterprises should speed up technical innovation,enhance regional and layout optimization, adapt to market changes and adjust product structure, control oil refining but increase chemical engineering, improve product quality and production efficiency, and constantly promote the international competitiveness of the Chinese petrochemical industry.