The electron paramagnetic resonance（EPR） spectra of trigonal Mn^（2＋） centers in Zn（ClO4）2·6（H2O） and Mg（ClO4）2·6（H2O） crystals were studied on the basis of the complete energy matrices for a d^5...The electron paramagnetic resonance（EPR） spectra of trigonal Mn^（2＋） centers in Zn（ClO4）2·6（H2O） and Mg（ClO4）2·6（H2O） crystals were studied on the basis of the complete energy matrices for a d^5 configuration ion in a trigonal ligand field. It was demonstrated that the local lattice structure around a trigonal Mn^（2＋） center has an compressed distortion along the crystalline c3 axis, and when Mn^（2＋） is doped in the Zn（ClO4）2·6（H2O） and Mg（ClO4）2·6（H2O） crystals, there is a similar local distortion. From the EPR calculation, the local lattice structure parameters R=2.183 2 ？, for Zn（ClO4）2·6（H2O）, R=2.130 2 ？, for Mg（ClO4）2·6（H2O） have been determined.展开更多
The electron paramagnetic spectra of trigonal Mn^(2+) centers in[Co(H_(2)O)_(6)]SiF6,[Co(H_(2)O)_(6)]SnF6,and[Co(H_(2)O)_(6)]PtCl6 crystals were studied on the basis of the complete energy matrices for a d5 configurat...The electron paramagnetic spectra of trigonal Mn^(2+) centers in[Co(H_(2)O)_(6)]SiF6,[Co(H_(2)O)_(6)]SnF6,and[Co(H_(2)O)_(6)]PtCl6 crystals were studied on the basis of the complete energy matrices for a d5 configuration ion in a trigonal ligand field.When Mn^(2+) is doped in the[Co(H_(2)O)_(6)]SiF6,[Co(H_(2)O)_(6)]SnF6,and[Co(H_(2)O)_(6)]PtCl6 crystals crystals,there is a similar local distortion.The experimental results show that the local lattice structure around a trigonal Mn^(2+) center has an elongation distortion along the crystalline C3 axis.From the EPR calculation,the local lattice structure parameters R=2.278A,θ=52.6406? for[Co(H_(2)O)_(6)]SiF6,R=2.280,θ=52.4936° for[Co(H_(2)O)_(6)]SnF6 and R=2.244A,θ=53.0616? for[Co(H_(2)O)_(6)]PtCl6 were determined.展开更多
基金Funded in Part by the National Natural Science Foundation of China(No.61601384)
文摘The electron paramagnetic resonance（EPR） spectra of trigonal Mn^（2＋） centers in Zn（ClO4）2·6（H2O） and Mg（ClO4）2·6（H2O） crystals were studied on the basis of the complete energy matrices for a d^5 configuration ion in a trigonal ligand field. It was demonstrated that the local lattice structure around a trigonal Mn^（2＋） center has an compressed distortion along the crystalline c3 axis, and when Mn^（2＋） is doped in the Zn（ClO4）2·6（H2O） and Mg（ClO4）2·6（H2O） crystals, there is a similar local distortion. From the EPR calculation, the local lattice structure parameters R=2.183 2 ？, for Zn（ClO4）2·6（H2O）, R=2.130 2 ？, for Mg（ClO4）2·6（H2O） have been determined.
基金Funded by the National Natural Science Foundation of China (Nos. 11804285 and 61601384)。
文摘The electron paramagnetic spectra of trigonal Mn^(2+) centers in[Co(H_(2)O)_(6)]SiF6,[Co(H_(2)O)_(6)]SnF6,and[Co(H_(2)O)_(6)]PtCl6 crystals were studied on the basis of the complete energy matrices for a d5 configuration ion in a trigonal ligand field.When Mn^(2+) is doped in the[Co(H_(2)O)_(6)]SiF6,[Co(H_(2)O)_(6)]SnF6,and[Co(H_(2)O)_(6)]PtCl6 crystals crystals,there is a similar local distortion.The experimental results show that the local lattice structure around a trigonal Mn^(2+) center has an elongation distortion along the crystalline C3 axis.From the EPR calculation,the local lattice structure parameters R=2.278A,θ=52.6406? for[Co(H_(2)O)_(6)]SiF6,R=2.280,θ=52.4936° for[Co(H_(2)O)_(6)]SnF6 and R=2.244A,θ=53.0616? for[Co(H_(2)O)_(6)]PtCl6 were determined.
