A hybrid material of carbon microspheres(CMSs) with Ag decoration(Ag/CMSs) was developed.Poly(3-hexylthiophene):Ag/CMSs composite film was prepared by spin-coating.Scanning electron microscopy,transmission elec...A hybrid material of carbon microspheres(CMSs) with Ag decoration(Ag/CMSs) was developed.Poly(3-hexylthiophene):Ag/CMSs composite film was prepared by spin-coating.Scanning electron microscopy,transmission electron microscopy,Fourier transform infrared spectrometry,X-ray diffraction,thermogravimetric analysis and cyclic voltammetry were employed to analyze the morphologies,structures,thermal properties and energy levels of Ag/CMSs.The optical property of the composite films was characterized by ultraviolet-visible spectrophotometry and fluorescent spectrometry.The results indicate that silver nanoparticles(AgNPs,d = 10-20 nm) are distributed on the surface of CMSs.LUMO and HOMO energy levels of Ag/CMSs are-3.97 and-5.52 e V,below the vacuum energy level,respectively,indicating that it is feasible to use Ag/CMSs as an electron acceptor.Ag NPs are blended into the active layer to trigger localized surface plasmon resonance,and consequently enhance light harvesting.The coupling of surface plasmons and excitons increased the probability of exciton dissociation.展开更多
A thermally tunable terahertz metamaterial absorber(MA) with InS b embedded in a metal-dielectric-metal structure is proposed. The transmission and tuning properties of the proposed metamaterial absorber are analyzed ...A thermally tunable terahertz metamaterial absorber(MA) with InS b embedded in a metal-dielectric-metal structure is proposed. The transmission and tuning properties of the proposed metamaterial absorber are analyzed for the temperature ranging from 160 K to 350 K. The simulated results show that the maximum absorption of the absorber is nearly 99.8% at a full-width at half-maximum(FWHM) of 38 GHz, and the absorption frequency can be dynamically tuned from 0.82 THz to 1.02 THz.展开更多
基金Funded by the National Natural Science Foundation of China(21176169)the Shanxi Provincial Key Innovative Research Team in Science and Technology(2012041011,2015013002-10)+1 种基金the International Science&Technology Cooperation Program of China(2012DFR50460)the Research Project Supported by Shanxi Scholarship Council of China(2012-038)
文摘A hybrid material of carbon microspheres(CMSs) with Ag decoration(Ag/CMSs) was developed.Poly(3-hexylthiophene):Ag/CMSs composite film was prepared by spin-coating.Scanning electron microscopy,transmission electron microscopy,Fourier transform infrared spectrometry,X-ray diffraction,thermogravimetric analysis and cyclic voltammetry were employed to analyze the morphologies,structures,thermal properties and energy levels of Ag/CMSs.The optical property of the composite films was characterized by ultraviolet-visible spectrophotometry and fluorescent spectrometry.The results indicate that silver nanoparticles(AgNPs,d = 10-20 nm) are distributed on the surface of CMSs.LUMO and HOMO energy levels of Ag/CMSs are-3.97 and-5.52 e V,below the vacuum energy level,respectively,indicating that it is feasible to use Ag/CMSs as an electron acceptor.Ag NPs are blended into the active layer to trigger localized surface plasmon resonance,and consequently enhance light harvesting.The coupling of surface plasmons and excitons increased the probability of exciton dissociation.
基金supported by the National Basic Research Program of China(No.2014CB339800)the National High Technology Research and Development Program of China(No.2011AA010205)the National Natural Science Foundation of China(Nos.61171027 and 10904076)
文摘A thermally tunable terahertz metamaterial absorber(MA) with InS b embedded in a metal-dielectric-metal structure is proposed. The transmission and tuning properties of the proposed metamaterial absorber are analyzed for the temperature ranging from 160 K to 350 K. The simulated results show that the maximum absorption of the absorber is nearly 99.8% at a full-width at half-maximum(FWHM) of 38 GHz, and the absorption frequency can be dynamically tuned from 0.82 THz to 1.02 THz.