Multifunctional alarm door locks developed and produced by the Shanghai Huxi Special Locks Factory are a product combining a safety lock with an alarm device and bell. All the technical data of the product have been e...Multifunctional alarm door locks developed and produced by the Shanghai Huxi Special Locks Factory are a product combining a safety lock with an alarm device and bell. All the technical data of the product have been examined and tested by the quality inspection展开更多
A comprehensive investigation was performed for repairing the different types of cracks appearing on the surface or inside the concrete lining at various depths.The mate- rial properties used in grouting and two metho...A comprehensive investigation was performed for repairing the different types of cracks appearing on the surface or inside the concrete lining at various depths.The mate- rial properties used in grouting and two methods for crack repair were discussed in details, and consequently reliable repair measures were proposed and implemented.It is a better choice to adopt the hole-drilling method for the relatively regular crack.The grouting pres- sure should not be too high and it is generally between 0.4~0.6 MPa.For the second time grouting,the pressure maybe increased to 0.8 MPa.Other method is the pasting nozzles method which is more suitable for irregular cracks such as cracks with intensive density and crossing cracks.Its grouting pressure is generally between 0.6~1.0 MPa.The in-situ tests in Three Gorges Project demonstrate favorably the feasibility and applicability of the proposed methods for crack repair within the lining concrete.展开更多
Permanent magnetic locks are a new high tech product manufactured by the Datang Industrial Corporation, Ltd. in the Jinan High Tech Development Zone. Instead of using mechanical springs, permanent magnetic locks featu...Permanent magnetic locks are a new high tech product manufactured by the Datang Industrial Corporation, Ltd. in the Jinan High Tech Development Zone. Instead of using mechanical springs, permanent magnetic locks feature alternating and equidifferent mono and multiple magnetic codes. The locks contain millions of codes. With no key hole or gears, permanent magnetic locks cannot be opened by a master key. The locks are damage proof, shock proof and drill proof, and easy to use. Permanent magnetic locks are used for safes, cars, motorcycles and bicycles.展开更多
Jindie (Golden Butterfly) Brand door locks are supergrade multifunctional locks developed by the Beijing City Building Locks Factory using imported advanced technology and equipment. Featuring security, reliability an...Jindie (Golden Butterfly) Brand door locks are supergrade multifunctional locks developed by the Beijing City Building Locks Factory using imported advanced technology and equipment. Featuring security, reliability and convenience, the products enjoy a good reputation in domestic and word markets. They include double, plug and ball-type locks, decorative locks and industrial locks. There are 36 varieties under five categories. The factory can also offer Jindie Brand electrical tools including hand and punch drills, automatic drills, rivet guns, electric scissors, stone cutting machines and diamond saw blades. The Beijing City Building Material Import and Export Corporation is sales agent for the products.展开更多
Silt deposition occurs in the downstream approach channel of the tidal lock as in a closed channel or excavated dock basin. It is often difficult to calculate or predict siltation because of complex flow and sediment ...Silt deposition occurs in the downstream approach channel of the tidal lock as in a closed channel or excavated dock basin. It is often difficult to calculate or predict siltation because of complex flow and sediment conditions and many other affecting factors. In this paper, the characteristics of flow movement in the approach channel (including its mouth) of the tidal lock are analyzed, the basic laws of sediment movement and siltation mechanism are investigated, the conditions for three types of siltation (circumfluence siltation, density flow siltation and slow flow siltation) are discussed, and corresponding calculating formulas are proposed. A practical example shows that the difference between measured and calculated results is small, indicating that the present calculating methods could be used in design and management of practical engineering projects.展开更多
A lock solution composed of gentamicin sulfate(5 mg/mL) and ethylenediaminetetraacetic acid disodium salt(EDTA-Na2, 30 mg/mL) could fully eradicate in vivo bacterial biofilms in totally implantable venous access ports...A lock solution composed of gentamicin sulfate(5 mg/mL) and ethylenediaminetetraacetic acid disodium salt(EDTA-Na2, 30 mg/mL) could fully eradicate in vivo bacterial biofilms in totally implantable venous access ports(TIVAP). In this study, fabrication, conditioning and sterilization processes of antimicrobial lock solution(ALS) were detailed and completed by a stability study. Stability of ALS was conducted for12 months in vial(25 °C 7 2 °C, 60% 7 5% relative humidity(RH), and at 40 °C 7 2 °C, RH 75% 7 5%)and for 24 h and 72 h in TIVAP(40 °C 7 2 °C, RH 75% 7 5%). A stability indicating HPLC assay with UV detection for simultaneous quantification of gentamicin sulfate and EDTA-Na2 was developed. ALS was assayed by ion-pairing high performance liquid chromatography(HPLC) needing gentamicin derivatization, EDTA-Na2 metallocomplexation of samples and gradient mobile phase. HPLC methods to separate four gentamicin components and EDTA-Na2 were validated. Efficiency of sterility procedure and conditioning of ALS was confirmed by bacterial endotoxins and sterility tests. Physicochemical stability of ALS was determined by visual inspection, osmolality, pH, and sub-visible particle counting. Results confirmed that the stability of ALS in vials was maintained for 12 months and 24 h and 72 h in TIVAP.展开更多
This paper introduces a multi-granularity locking model (MGL) for concurrency control in object-oriented database system briefiy, and presents a MGL model formally. Four lockingscheduling algorithms for MGL are propos...This paper introduces a multi-granularity locking model (MGL) for concurrency control in object-oriented database system briefiy, and presents a MGL model formally. Four lockingscheduling algorithms for MGL are proposed in the paper. The ideas of single queue scheduling(SQS) and dual queue scheduling (DQS) are proposed and the algorithm and the performance evaluation for these two scheduling are presented in some paper. This paper describes a new idea of thescheduling for MGL, compatible requests first (CRF). Combining the new idea with SQS and DQS,we propose two new scheduling algorithms called CRFS and CRFD. After describing the simulationmodel, this paper illustrates the comparisons of the performance among these four algorithms. Asshown in the experiments, DQS has better performance than SQS, CRFD is better than DQS, CRFSperforms better than SQS, and CRFS is the best one of these four scheduling algorithms.展开更多
By employing the asymmetric end-group engineering,an asymmetric nonfused-ring electron acceptor(NFREA)was designed and synthesized.Compared with the symmetric analogs(NoCA-17 and NoCA-18),NoCA-19 possesses broader lig...By employing the asymmetric end-group engineering,an asymmetric nonfused-ring electron acceptor(NFREA)was designed and synthesized.Compared with the symmetric analogs(NoCA-17 and NoCA-18),NoCA-19 possesses broader light absorption range,more coplanarπ-conjugated backbone,and appropriate crystallinity according to the experimental and theoretical results.The organic solar cells based on J52:NoCA-19 exhibited a power conversion efficiency as high as 12.26%,which is much higher than those of J52:NoCA-17(9.50%)and J52:NoCA-18(11.77%),mainly due to more efficient exciton dissociation,better and balanced charge mobility,suppressed recombination loss,shorter charge extraction time,longer charge carrier lifetimes,and more favorable blend film morphology.These findings demonstrate the great potential of asymmetric end-group engineering in exploring low-cost and high-performance NFREAs.展开更多
Nonfused ring electron acceptors(NFREAs)have attracted much attention due to their concise synthetic routes and low cost.However,developing high-performance NFREAs with simple structure remains a great challenge.In th...Nonfused ring electron acceptors(NFREAs)have attracted much attention due to their concise synthetic routes and low cost.However,developing high-performance NFREAs with simple structure remains a great challenge.In this work,a simple building block(POBT)with noncovalently conformational locks(No CLs)was designed and synthesized.Single-crystal X-ray study indicated the presence of S…O NOCLs in POBT,thus enabling it to possess a coplanar conformation comparable to that of fused-ring CPT.Two novel NFREAs based on CPT and POBT were developed,namely TT-CPT and TT-POBT,respectively.Besides,TT-POBT possessed a smaller Stokes shift and a reduced reorganization energy compared with TT-CPT,indicating the introduction of S…O No CLs can enhance the molecular rigidity even if simplifying the molecular structure.As a result,the TT-POBT-based PSC device afforded an impressive power conversion efficiency of 11.15%,much higher than that of TT-CPT counterpart(7.03%),mainly resulting from the tighterπ-πstacking,improved and balanced charge transport,and more favorable film morphology.This work demonstrates the potential of the simple building block POBT with No CLs towards constructing low-cost and highperformance NFREAs.展开更多
Comprehensive Summary By employing thiazole and 4-chlorothiazole as the A′units,two A-D-A′-D-A type nonfused-ring electron acceptors(NFREAs)Tz-H and Tz-Cl were designed and synthesized.Replacing thiazole in Tz-H wit...Comprehensive Summary By employing thiazole and 4-chlorothiazole as the A′units,two A-D-A′-D-A type nonfused-ring electron acceptors(NFREAs)Tz-H and Tz-Cl were designed and synthesized.Replacing thiazole in Tz-H with 4-chlorothiazole can not only remarkably shorten the synthetic route through C—H direct arylation but also enhance molecular planarity with the simultaneous incorporation of S…N and S…Cl noncovalently conformational locks(NoCLs).The photovoltaic devices based on PM6:Tz-Cl exhibited a power conversion efficiency as high as 11.10%,much higher than that of PM6:Tz-H(6.41%),mainly due to more efficient exciton dissociation,better and more balanced carrier mobility,less charge recombination,and more favorable morphology.These findings demonstrate the great potential of NoCLs in achieving low-cost and high-performance NFREAs.展开更多
Highly planar conformation is considered to be one of the most important properties for high performance organic semiconductors. Among all kinds strategies for designing highly performing materials, noncovalent confor...Highly planar conformation is considered to be one of the most important properties for high performance organic semiconductors. Among all kinds strategies for designing highly performing materials, noncovalent conformational locks (NCLs) have been widely used to increase the planarity and rigidity for x-conjugated systems. This review summarizes π-conjugated small molecules and polymers by employing various NCLs for controlling molecular conformation in the past two years. The optoelectronic properties of the conjugated materials, together with their applications on organic field-effect transistors (OFETs) and organic photovoltaics (OPVs) are discussed. Besides, the outlook and challenges in this field are also presented. It is obvious that NCLs play an important role in the design and synthesis of high-performance organic semiconductors.展开更多
Nyquist pulses have wide applications in many areas,from electronics to optics.Mode-locked lasers are ideal platforms to generate such pulses.However,how to generate high-quality Nyquist pulses in mode-locked lasers r...Nyquist pulses have wide applications in many areas,from electronics to optics.Mode-locked lasers are ideal platforms to generate such pulses.However,how to generate high-quality Nyquist pulses in mode-locked lasers remains elusive.We address this problem by managing different physical effects in mode-locked fiber lasers through extensive numerical simulations.We find that net dispersion,linear loss,gain and filter shaping can affect the quality of Nyquist pulses significantly.We also demonstrate that Nyquist pulses experience similariton shaping due to the nonlinear attractor effect in the gain medium.Our work may contribute to the design of Nyquist pulse sources and enrich the understanding of pulse shaping dynamics in mode-locked lasers.展开更多
Dissipative soliton resonance(DSR) was previously studied in separated mode-locked fiber lasers within different dispersion regimes including anomalous, near-zero and normal dispersion. Here we propose a method to stu...Dissipative soliton resonance(DSR) was previously studied in separated mode-locked fiber lasers within different dispersion regimes including anomalous, near-zero and normal dispersion. Here we propose a method to study DSR in a single mode-locked laser in these different dispersion regimes. This is achieved by virtue of a waveshaper which can control the laser dispersion readily using software, avoiding the usual tedious cutback method. We find that dispersion has a negligible effect on DSR since the pulse duration keeps constant while dispersion is varied. Moreover, we examine the dynamics of DSR on the parameters of the SA including modulation depth and saturation power, and find that the pulse duration can be changed in a large range when the saturation power is decreased. Our numerical simulations could be important to guide relative experimental studies.展开更多
Vertical cavity surface emitting lasers(VCSELs)have emerged as a versatile and promising platform for developing advanced integrated photonic devices and systems due to their low power consumption,high modulation band...Vertical cavity surface emitting lasers(VCSELs)have emerged as a versatile and promising platform for developing advanced integrated photonic devices and systems due to their low power consumption,high modulation bandwidth,small footprint,excellent scalability,and compatibility with monolithic integration.By combining these unique capabilities of VCSELs with the functionalities offered by micro/nano optical structures(e.g.metasurfaces),it enables various versatile energy-efficient integrated photonic devices and systems with compact size,enhanced performance,and improved reliability and functionality.This review provides a comprehensive overview of the stateof-the-art versatile integrated photonic devices/systems based on VCSELs,including photonic neural networks,vortex beam emitters,holographic devices,beam deflectors,atomic sensors,and biosensors.By leveraging the capabilities of VCSELs,these integrated photonic devices/systems open up new opportunities in various fields,including artificial intelligence,large-capacity optical communication,imaging,biosensing,and so on.Through this comprehensive review,we aim to provide a detailed understanding of the pivotal role played by VCSELs in integrated photonics and highlight their significance in advancing the feld towards effcient,compact,and versatile photonic solutions.展开更多
We demonstrated a scheme of phase-locked terahertz quantum cascade lasers(THz QCLs)array,with a single-mode pulse power of 108 mW at 13 K.The device utilizes a Talbot cavity to achieve phase locking among five ridge l...We demonstrated a scheme of phase-locked terahertz quantum cascade lasers(THz QCLs)array,with a single-mode pulse power of 108 mW at 13 K.The device utilizes a Talbot cavity to achieve phase locking among five ridge lasers with first-order buried distributed feedback(DFB)grating,resulting in nearly five times amplification of the single-mode power.Due to the optimum length of Talbot cavity depends on wavelength,the combination of Talbot cavity with the DFB grating leads to better power amplification than the combination with multimode Fabry-Perot(F-P)cavities.The Talbot cavity facet reflects light back to the ridge array direction and achieves self-imaging in the array,enabling phase-locked operation of ridges.We set the spacing between adjacent elements to be 220μm,much larger than the free-space wavelength,ensuring the operation of the fundamental supermode throughout the laser's dynamic range and obtaining a high-brightness far-field distribution.This scheme provides a new approach for enhancing the single-mode power of THz QCLs.展开更多
Mode locking can be effectively achieved by using the thermo-optic effects in the whispering gallery mode(WGM)optical microcavity,without the help of external equipment.Therefore,it has the advantages of small size,lo...Mode locking can be effectively achieved by using the thermo-optic effects in the whispering gallery mode(WGM)optical microcavity,without the help of external equipment.Therefore,it has the advantages of small size,low integration costs,and self-locking,which shows great potential for application.However,the conventional single-channel microcavity thermal-locking method that relies solely on internal thermal balance will inevitably be disturbed by the external environment.This limitation affects the locking time and stability.Therefore,in this paper,we propose a new method for closed-loop thermal locking of a dual-channel microcavity.The thermal locking of the signal laser and the thermal regulation of the control laser are carried out respectively by synchronously drawing a dual-path tapered fiber.The theoretical model of the thermal dynamics of the dual-channel microcavity system is established,and the influence of the control-laser power on the thermal locking of the signal laser is confirmed.The deviation between the locking voltage of the signal laser and the set point value is used as a closed-loop feedback parameter to achieve long-term and highly stable mode locking of the signal laser.The results show that in the 2.63 h thermal-locking test,the locking stability is an order of magnitude higher than that of the single tapered fiber.This solution addresses the issue of thermal locking being disrupted by the external environment,and offers new possibilities for important applications such as spectroscopy and micro-optical sensor devices.展开更多
Spin–momentum locking is a key feature of the topological surface state, which plays an important role in spintronics.The electrical detection of current-induced spin polarization protected by the spin–momentum lock...Spin–momentum locking is a key feature of the topological surface state, which plays an important role in spintronics.The electrical detection of current-induced spin polarization protected by the spin–momentum locking in nonmagnetic systems provides a new platform for developing spintronics, while previous studies were mostly based on magnetic materials.In this study, the spin transport measurement of Dirac semimetal Cd_(3)As_(2) was studied by three-terminal geometry, and a hysteresis loop signal with high resistance and low resistance state was observed. The hysteresis was reversed by reversing the current direction, which illustrates the spin–momentum locking feature of Cd_(3)As_(2). Furthermore, we realized the on–off states of the spin signals through electric modulation of the Fermi arc via the three-terminal configuration, which enables the great potential of Cd_(3)As_(2) in spin field-effect transistors.展开更多
The finite element method (FEM) plays a valuable role in computer modeling and is beneficial to the mechanicaldesign of various structural parts. However, the elements produced by conventional FEM are easily inaccurat...The finite element method (FEM) plays a valuable role in computer modeling and is beneficial to the mechanicaldesign of various structural parts. However, the elements produced by conventional FEM are easily inaccurate andunstable when applied. Therefore, developing new elements within the framework of the generalized variationalprinciple is of great significance. In this paper, an 8-node plane hybrid finite element with 15 parameters (PHQ8-15β) is developed for structural mechanics problems based on the Hellinger-Reissner variational principle.According to the design principle of Pian, 15 unknown parameters are adopted in the selection of stress modes toavoid the zero energy modes.Meanwhile, the stress functions within each element satisfy both the equilibrium andthe compatibility relations of plane stress problems. Subsequently, numerical examples are presented to illustrate theeffectiveness and robustness of the proposed finite element. Numerical results show that various common lockingbehaviors of plane elements can be overcome. The PH-Q8-15β element has excellent performance in all benchmarkproblems, especially for structures with varying cross sections. Furthermore, in bending problems, the reasonablemesh shape of the new element for curved edge structures is analyzed in detail, which can be a useful means toimprove numerical accuracy.展开更多
BACKGROUND This article presents a rare case of a complex hip fracture involving the ipsilateral femoral neck,trochanter,and femoral head,that was accompanied by hip dislocation.Currently,there is no established stand...BACKGROUND This article presents a rare case of a complex hip fracture involving the ipsilateral femoral neck,trochanter,and femoral head,that was accompanied by hip dislocation.Currently,there is no established standard treatment method for this specific type of fracture.Therefore,it is crucial to comprehensively consider factors such as patient age,fracture type,and degree of displacement to achieve a successful outcome.CASE SUMMARY A 38-year-old man sustained a comminuted fracture of his right hip as a result of a car accident.The injuries included a fracture of the femoral head,a fracture of the femoral neck,an intertrochanteric fracture of the femur,and a posterior dislocation of the hip on the same side.We opted for a treatment approach combining the use of a proximal femoral locking plate,cannulated screws,and Kirschner wires.Following the surgery,we developed an individualized rehabil-itation program to restore patient limb function.CONCLUSION For this complex fracture,we selected appropriate internal fixation and for-mulated individualized rehabilitation,which ultimately achieved good results.展开更多
文摘Multifunctional alarm door locks developed and produced by the Shanghai Huxi Special Locks Factory are a product combining a safety lock with an alarm device and bell. All the technical data of the product have been examined and tested by the quality inspection
基金the National Natural Science Foundation of China(10602049)
文摘A comprehensive investigation was performed for repairing the different types of cracks appearing on the surface or inside the concrete lining at various depths.The mate- rial properties used in grouting and two methods for crack repair were discussed in details, and consequently reliable repair measures were proposed and implemented.It is a better choice to adopt the hole-drilling method for the relatively regular crack.The grouting pres- sure should not be too high and it is generally between 0.4~0.6 MPa.For the second time grouting,the pressure maybe increased to 0.8 MPa.Other method is the pasting nozzles method which is more suitable for irregular cracks such as cracks with intensive density and crossing cracks.Its grouting pressure is generally between 0.6~1.0 MPa.The in-situ tests in Three Gorges Project demonstrate favorably the feasibility and applicability of the proposed methods for crack repair within the lining concrete.
文摘Permanent magnetic locks are a new high tech product manufactured by the Datang Industrial Corporation, Ltd. in the Jinan High Tech Development Zone. Instead of using mechanical springs, permanent magnetic locks feature alternating and equidifferent mono and multiple magnetic codes. The locks contain millions of codes. With no key hole or gears, permanent magnetic locks cannot be opened by a master key. The locks are damage proof, shock proof and drill proof, and easy to use. Permanent magnetic locks are used for safes, cars, motorcycles and bicycles.
文摘Jindie (Golden Butterfly) Brand door locks are supergrade multifunctional locks developed by the Beijing City Building Locks Factory using imported advanced technology and equipment. Featuring security, reliability and convenience, the products enjoy a good reputation in domestic and word markets. They include double, plug and ball-type locks, decorative locks and industrial locks. There are 36 varieties under five categories. The factory can also offer Jindie Brand electrical tools including hand and punch drills, automatic drills, rivet guns, electric scissors, stone cutting machines and diamond saw blades. The Beijing City Building Material Import and Export Corporation is sales agent for the products.
文摘Silt deposition occurs in the downstream approach channel of the tidal lock as in a closed channel or excavated dock basin. It is often difficult to calculate or predict siltation because of complex flow and sediment conditions and many other affecting factors. In this paper, the characteristics of flow movement in the approach channel (including its mouth) of the tidal lock are analyzed, the basic laws of sediment movement and siltation mechanism are investigated, the conditions for three types of siltation (circumfluence siltation, density flow siltation and slow flow siltation) are discussed, and corresponding calculating formulas are proposed. A practical example shows that the difference between measured and calculated results is small, indicating that the present calculating methods could be used in design and management of practical engineering projects.
基金supported by Centre de Recherche Translationnelle de I'Institut Pasteur, grant Number S- PI15007-02Asupported by the French Government's Investissement d'Avenir program:Laboratoire d'Excellence ‘Integrative Biology of Emerging Infectious Diseases’ (grant no. ANR-10-LABX62-IBEID.)+1 种基金the Fondation pour la Recherche Médicale (grant no. DEQ. 20140329508)the Center for Translational Science of the Institut Pasteur (S-PI15007-02A)
文摘A lock solution composed of gentamicin sulfate(5 mg/mL) and ethylenediaminetetraacetic acid disodium salt(EDTA-Na2, 30 mg/mL) could fully eradicate in vivo bacterial biofilms in totally implantable venous access ports(TIVAP). In this study, fabrication, conditioning and sterilization processes of antimicrobial lock solution(ALS) were detailed and completed by a stability study. Stability of ALS was conducted for12 months in vial(25 °C 7 2 °C, 60% 7 5% relative humidity(RH), and at 40 °C 7 2 °C, RH 75% 7 5%)and for 24 h and 72 h in TIVAP(40 °C 7 2 °C, RH 75% 7 5%). A stability indicating HPLC assay with UV detection for simultaneous quantification of gentamicin sulfate and EDTA-Na2 was developed. ALS was assayed by ion-pairing high performance liquid chromatography(HPLC) needing gentamicin derivatization, EDTA-Na2 metallocomplexation of samples and gradient mobile phase. HPLC methods to separate four gentamicin components and EDTA-Na2 were validated. Efficiency of sterility procedure and conditioning of ALS was confirmed by bacterial endotoxins and sterility tests. Physicochemical stability of ALS was determined by visual inspection, osmolality, pH, and sub-visible particle counting. Results confirmed that the stability of ALS in vials was maintained for 12 months and 24 h and 72 h in TIVAP.
文摘This paper introduces a multi-granularity locking model (MGL) for concurrency control in object-oriented database system briefiy, and presents a MGL model formally. Four lockingscheduling algorithms for MGL are proposed in the paper. The ideas of single queue scheduling(SQS) and dual queue scheduling (DQS) are proposed and the algorithm and the performance evaluation for these two scheduling are presented in some paper. This paper describes a new idea of thescheduling for MGL, compatible requests first (CRF). Combining the new idea with SQS and DQS,we propose two new scheduling algorithms called CRFS and CRFD. After describing the simulationmodel, this paper illustrates the comparisons of the performance among these four algorithms. Asshown in the experiments, DQS has better performance than SQS, CRFD is better than DQS, CRFSperforms better than SQS, and CRFS is the best one of these four scheduling algorithms.
基金the financial support fromtheNSFC(21975055,U2001222,52103352,52120105006,and 51925306)National Key R&D Program of China(2018FYA 0305800)+2 种基金Key Research Program of Chinese Academy of Sciences(XDPB08-2)the Youth Innovation Promotion Association of Chinese Academy of Sciences(2022165)the Fundamental Research Funds for the Central Universities.DFT results described in this article were obtained from the National Supercomputing Centre in Shenzhen(Shenzhen Cloud Computing Centre).
文摘By employing the asymmetric end-group engineering,an asymmetric nonfused-ring electron acceptor(NFREA)was designed and synthesized.Compared with the symmetric analogs(NoCA-17 and NoCA-18),NoCA-19 possesses broader light absorption range,more coplanarπ-conjugated backbone,and appropriate crystallinity according to the experimental and theoretical results.The organic solar cells based on J52:NoCA-19 exhibited a power conversion efficiency as high as 12.26%,which is much higher than those of J52:NoCA-17(9.50%)and J52:NoCA-18(11.77%),mainly due to more efficient exciton dissociation,better and balanced charge mobility,suppressed recombination loss,shorter charge extraction time,longer charge carrier lifetimes,and more favorable blend film morphology.These findings demonstrate the great potential of asymmetric end-group engineering in exploring low-cost and high-performance NFREAs.
基金the National Natural Science Foundation of China(Nos.52103352,51925306 and 52120105006)National Key R&D Program of China(No.2018FYA 0305800)+3 种基金Key Research Program of Chinese Academy of Sciences(No.XDPB08-2)the Strategic Priority Research Program of Chinese Academy of Sciences(No.XDB28000000)the Youth Innovation Promotion Association of Chinese Academy of Sciences(No.2022165)the Fundamental Research Funds for the Central Universities.
文摘Nonfused ring electron acceptors(NFREAs)have attracted much attention due to their concise synthetic routes and low cost.However,developing high-performance NFREAs with simple structure remains a great challenge.In this work,a simple building block(POBT)with noncovalently conformational locks(No CLs)was designed and synthesized.Single-crystal X-ray study indicated the presence of S…O NOCLs in POBT,thus enabling it to possess a coplanar conformation comparable to that of fused-ring CPT.Two novel NFREAs based on CPT and POBT were developed,namely TT-CPT and TT-POBT,respectively.Besides,TT-POBT possessed a smaller Stokes shift and a reduced reorganization energy compared with TT-CPT,indicating the introduction of S…O No CLs can enhance the molecular rigidity even if simplifying the molecular structure.As a result,the TT-POBT-based PSC device afforded an impressive power conversion efficiency of 11.15%,much higher than that of TT-CPT counterpart(7.03%),mainly resulting from the tighterπ-πstacking,improved and balanced charge transport,and more favorable film morphology.This work demonstrates the potential of the simple building block POBT with No CLs towards constructing low-cost and highperformance NFREAs.
基金the National Natural Science Foundation of China((52120105006,52103352,and 51925306)National Key R&D Program of China(2018FYA 0305800)+3 种基金Key Research Program of Chinese Academy of Sciences(XDPB08-2)the Strategic Priority Research Program of Chinese Academy of Sciences(XDB28000000)the Youth Innovation Promotion Association of Chinese Academy of Sciences(2022165)the Fundamental Research Funds for the Central Universities.DFT results described in this report were obtained from the National Supercomputing Center in Shenzhen(Shenzhen CloudComputing Center).
文摘Comprehensive Summary By employing thiazole and 4-chlorothiazole as the A′units,two A-D-A′-D-A type nonfused-ring electron acceptors(NFREAs)Tz-H and Tz-Cl were designed and synthesized.Replacing thiazole in Tz-H with 4-chlorothiazole can not only remarkably shorten the synthetic route through C—H direct arylation but also enhance molecular planarity with the simultaneous incorporation of S…N and S…Cl noncovalently conformational locks(NoCLs).The photovoltaic devices based on PM6:Tz-Cl exhibited a power conversion efficiency as high as 11.10%,much higher than that of PM6:Tz-H(6.41%),mainly due to more efficient exciton dissociation,better and more balanced carrier mobility,less charge recombination,and more favorable morphology.These findings demonstrate the great potential of NoCLs in achieving low-cost and high-performance NFREAs.
基金supported by the National Natural Science Foundation of China (21774130, 21574135)Beijing Municipal Natural Science Foundation (2162043)+2 种基金the Key Research Program of Frontier Science, Chinese Academy of Sciences (QYZDB-SSW-JSC046)Key Research Program of the Chinese Academy of Sciences (XDPB08-2)One Hundred Talents Program of Chinese Academy of Sciences, and University of Chinese Academy of Sciences
文摘Highly planar conformation is considered to be one of the most important properties for high performance organic semiconductors. Among all kinds strategies for designing highly performing materials, noncovalent conformational locks (NCLs) have been widely used to increase the planarity and rigidity for x-conjugated systems. This review summarizes π-conjugated small molecules and polymers by employing various NCLs for controlling molecular conformation in the past two years. The optoelectronic properties of the conjugated materials, together with their applications on organic field-effect transistors (OFETs) and organic photovoltaics (OPVs) are discussed. Besides, the outlook and challenges in this field are also presented. It is obvious that NCLs play an important role in the design and synthesis of high-performance organic semiconductors.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11621404,11561121003,11727812,61775059,12074122,62022033,and 11704123)Shanghai Rising-Star Program,the Sustainedly Supported Foundation by the National Key Laboratory of Science and Technology on Space Microwave(Grant No.HTKT2022KL504008)+1 种基金Shanghai Natural Science Foundation(Grant No.23ZR1419000)the National Key Laboratory Foundation of China(Grant No.6142411196307).
文摘Nyquist pulses have wide applications in many areas,from electronics to optics.Mode-locked lasers are ideal platforms to generate such pulses.However,how to generate high-quality Nyquist pulses in mode-locked lasers remains elusive.We address this problem by managing different physical effects in mode-locked fiber lasers through extensive numerical simulations.We find that net dispersion,linear loss,gain and filter shaping can affect the quality of Nyquist pulses significantly.We also demonstrate that Nyquist pulses experience similariton shaping due to the nonlinear attractor effect in the gain medium.Our work may contribute to the design of Nyquist pulse sources and enrich the understanding of pulse shaping dynamics in mode-locked lasers.
基金Project supported by the Innovation Program for Quantum Science and Technology(Grant No.2023ZD0301000)the National Natural Science Foundation of China(Grant Nos.11621404,11561121003,11727812,61775059,12074122,62022033,and 11704123)+2 种基金Sustainedly supported by the National Key Laboratory of Science and Technology on Space Microwave(Grant No.HTKT2022KL504008)the Shanghai Natural Science Foundation(Grant No.23ZR1419000)the National Key Laboratory Foundation of China(Grant No.6142411196307)。
文摘Dissipative soliton resonance(DSR) was previously studied in separated mode-locked fiber lasers within different dispersion regimes including anomalous, near-zero and normal dispersion. Here we propose a method to study DSR in a single mode-locked laser in these different dispersion regimes. This is achieved by virtue of a waveshaper which can control the laser dispersion readily using software, avoiding the usual tedious cutback method. We find that dispersion has a negligible effect on DSR since the pulse duration keeps constant while dispersion is varied. Moreover, we examine the dynamics of DSR on the parameters of the SA including modulation depth and saturation power, and find that the pulse duration can be changed in a large range when the saturation power is decreased. Our numerical simulations could be important to guide relative experimental studies.
基金support from the National Natural Science Foundation of China(Nos.62374179,62104251,and 62174178.)the Key Research Program of Frontier Sciences,CAS(ZDBS-LY-JSCo31)+3 种基金the Youth Innovation Promotion Association CAS(2022115),the Beijing Nova Program(2022032)the National Key Basic Research Program(2022YFB2803000),the Shanghai Sailing Program(23YF1429500)the Science and Technology Commission of Shanghai Municipality(Grant No.21DZ1100500)the Shanghai Municipal Science and Technology Major Project,and the Shanghai Frontiers Science Center Program(2021-2025 No.20).
文摘Vertical cavity surface emitting lasers(VCSELs)have emerged as a versatile and promising platform for developing advanced integrated photonic devices and systems due to their low power consumption,high modulation bandwidth,small footprint,excellent scalability,and compatibility with monolithic integration.By combining these unique capabilities of VCSELs with the functionalities offered by micro/nano optical structures(e.g.metasurfaces),it enables various versatile energy-efficient integrated photonic devices and systems with compact size,enhanced performance,and improved reliability and functionality.This review provides a comprehensive overview of the stateof-the-art versatile integrated photonic devices/systems based on VCSELs,including photonic neural networks,vortex beam emitters,holographic devices,beam deflectors,atomic sensors,and biosensors.By leveraging the capabilities of VCSELs,these integrated photonic devices/systems open up new opportunities in various fields,including artificial intelligence,large-capacity optical communication,imaging,biosensing,and so on.Through this comprehensive review,we aim to provide a detailed understanding of the pivotal role played by VCSELs in integrated photonics and highlight their significance in advancing the feld towards effcient,compact,and versatile photonic solutions.
基金funded by National Natural Science Foundation of China, grant numbers 62335006, 62274014, 62235016, 61734006, 61835011, 61991430funded by Key Program of the Chinese Academy of Sciences, grant numbers XDB43000000, QYZDJSSW-JSC027Beijing Municipal Science & Technology Commission, grant number Z221100002722018
文摘We demonstrated a scheme of phase-locked terahertz quantum cascade lasers(THz QCLs)array,with a single-mode pulse power of 108 mW at 13 K.The device utilizes a Talbot cavity to achieve phase locking among five ridge lasers with first-order buried distributed feedback(DFB)grating,resulting in nearly five times amplification of the single-mode power.Due to the optimum length of Talbot cavity depends on wavelength,the combination of Talbot cavity with the DFB grating leads to better power amplification than the combination with multimode Fabry-Perot(F-P)cavities.The Talbot cavity facet reflects light back to the ridge array direction and achieves self-imaging in the array,enabling phase-locked operation of ridges.We set the spacing between adjacent elements to be 220μm,much larger than the free-space wavelength,ensuring the operation of the fundamental supermode throughout the laser's dynamic range and obtaining a high-brightness far-field distribution.This scheme provides a new approach for enhancing the single-mode power of THz QCLs.
基金Project supported by the National Key Research and Development Program of China(Grant No.2022YFB3203400)the National Natural Science Foundation of China(Grant Nos.U21A20141,62273314,and 51821003)+1 种基金the Fundamental Research Program of Shanxi Province(Grant No.202303021223001)Shanxi Province Key Laboratory of Quantum Sensing and Precision Measurement(Grant No.201905D121001)。
文摘Mode locking can be effectively achieved by using the thermo-optic effects in the whispering gallery mode(WGM)optical microcavity,without the help of external equipment.Therefore,it has the advantages of small size,low integration costs,and self-locking,which shows great potential for application.However,the conventional single-channel microcavity thermal-locking method that relies solely on internal thermal balance will inevitably be disturbed by the external environment.This limitation affects the locking time and stability.Therefore,in this paper,we propose a new method for closed-loop thermal locking of a dual-channel microcavity.The thermal locking of the signal laser and the thermal regulation of the control laser are carried out respectively by synchronously drawing a dual-path tapered fiber.The theoretical model of the thermal dynamics of the dual-channel microcavity system is established,and the influence of the control-laser power on the thermal locking of the signal laser is confirmed.The deviation between the locking voltage of the signal laser and the set point value is used as a closed-loop feedback parameter to achieve long-term and highly stable mode locking of the signal laser.The results show that in the 2.63 h thermal-locking test,the locking stability is an order of magnitude higher than that of the single tapered fiber.This solution addresses the issue of thermal locking being disrupted by the external environment,and offers new possibilities for important applications such as spectroscopy and micro-optical sensor devices.
基金Project supported by the National Key Research and Development Program of China (Grant Nos.2020YFA0309300 and 2022YFA1403700)the National Natural Science Foundation of China (Grant Nos.12004158,12074162,and 91964201)+2 种基金the Key-Area Research and Development Program of Guangdong Province (Grant No.2018B030327001)Guangdong Provincial Key Laboratory (Grant No.2019B121203002)Guangdong Basic and Applied Basic Research Foundation (Grant No.2022B1515130005)。
文摘Spin–momentum locking is a key feature of the topological surface state, which plays an important role in spintronics.The electrical detection of current-induced spin polarization protected by the spin–momentum locking in nonmagnetic systems provides a new platform for developing spintronics, while previous studies were mostly based on magnetic materials.In this study, the spin transport measurement of Dirac semimetal Cd_(3)As_(2) was studied by three-terminal geometry, and a hysteresis loop signal with high resistance and low resistance state was observed. The hysteresis was reversed by reversing the current direction, which illustrates the spin–momentum locking feature of Cd_(3)As_(2). Furthermore, we realized the on–off states of the spin signals through electric modulation of the Fermi arc via the three-terminal configuration, which enables the great potential of Cd_(3)As_(2) in spin field-effect transistors.
基金the National Natural Science Foundation of China(No.11572210).
文摘The finite element method (FEM) plays a valuable role in computer modeling and is beneficial to the mechanicaldesign of various structural parts. However, the elements produced by conventional FEM are easily inaccurate andunstable when applied. Therefore, developing new elements within the framework of the generalized variationalprinciple is of great significance. In this paper, an 8-node plane hybrid finite element with 15 parameters (PHQ8-15β) is developed for structural mechanics problems based on the Hellinger-Reissner variational principle.According to the design principle of Pian, 15 unknown parameters are adopted in the selection of stress modes toavoid the zero energy modes.Meanwhile, the stress functions within each element satisfy both the equilibrium andthe compatibility relations of plane stress problems. Subsequently, numerical examples are presented to illustrate theeffectiveness and robustness of the proposed finite element. Numerical results show that various common lockingbehaviors of plane elements can be overcome. The PH-Q8-15β element has excellent performance in all benchmarkproblems, especially for structures with varying cross sections. Furthermore, in bending problems, the reasonablemesh shape of the new element for curved edge structures is analyzed in detail, which can be a useful means toimprove numerical accuracy.
基金Supported by the Peak Discipline of Traditional Chinese Medicine(Orthopedics and Traumatology Integrated Traditional Chinese and Western Medicine),No.YC-2023-0601.
文摘BACKGROUND This article presents a rare case of a complex hip fracture involving the ipsilateral femoral neck,trochanter,and femoral head,that was accompanied by hip dislocation.Currently,there is no established standard treatment method for this specific type of fracture.Therefore,it is crucial to comprehensively consider factors such as patient age,fracture type,and degree of displacement to achieve a successful outcome.CASE SUMMARY A 38-year-old man sustained a comminuted fracture of his right hip as a result of a car accident.The injuries included a fracture of the femoral head,a fracture of the femoral neck,an intertrochanteric fracture of the femur,and a posterior dislocation of the hip on the same side.We opted for a treatment approach combining the use of a proximal femoral locking plate,cannulated screws,and Kirschner wires.Following the surgery,we developed an individualized rehabil-itation program to restore patient limb function.CONCLUSION For this complex fracture,we selected appropriate internal fixation and for-mulated individualized rehabilitation,which ultimately achieved good results.