Cosmogenic Ne isotopes are stable and are routinely used for constraining the timing of events and the rate of surface change beyond the limit that can be studied with radionuclides ^10Be, ^26Al, and ^36Cl. Cosmogenic...Cosmogenic Ne isotopes are stable and are routinely used for constraining the timing of events and the rate of surface change beyond the limit that can be studied with radionuclides ^10Be, ^26Al, and ^36Cl. Cosmogenic Ne analysis can be used in quartz and in a range of other minerals. Analysis typically requires significantly less material than do cosmogenic ^10Be and ^26Al, opening up the technique for small samples--individual pebbles in fiver sediments, for example. Analysis is easier and faster than for radionuclides, not least because Ne measurements do not require significant chemical procedures. However, the presence of other sources of Ne in minerals tends to restrict the use of cosmogenic ^21Ne to old landscapes and long exposure durations. In this review we briefly outline the background of cosmogenic Ne production in rocks and minerals at the Earth＇s surface, then document the key uses of the technique by highlighting some earlier studies, and finish with a short perspective on the future of the technique.展开更多
由于电离层电子密度随时间变化,且空间分布不均匀,对不同频段的无线电波产生延缓和折射,因此电离层电子密度变化是影响短波通信、卫星通信、全球导航卫星系统和其他空间通信质量的一个主要因素,本文对全球电离层电子密度(Number of elec...由于电离层电子密度随时间变化,且空间分布不均匀,对不同频段的无线电波产生延缓和折射,因此电离层电子密度变化是影响短波通信、卫星通信、全球导航卫星系统和其他空间通信质量的一个主要因素,本文对全球电离层电子密度(Number of electron,Ne)的预测工作对短波通信设备三维射线实时追踪定位提供必要条件。本文采用国际电离层参考模型提供的2016年电离层Ne数据,根据数据的三维空间时间序列特征,搭建了自编码器和卷积长短期记忆(Convolutional Long Short-Term Memory Network,Conv LSTM)网络组成的网络结构,在不引入地球自转周期之外任何先验知识的条件下,对Ne数据进行深度学习并实现预测,首先通过实验对比了SGD、Adagrad、Adadelta、Adam、Adamax和Nadam六种优化算法的性能,又对比了三种预测策略的均方根误差(Root Mean Square Error, RMSE),1h-to-1h预测策略的全球平均RMSE为1.0 NEU(最大值的0.4%),1h-to-24h和24h-to-24h预测策略的全球平均RMSE为6.3 NEU(2.6%)。由实验结果得出以下结论,一是Nadam优化算法更适合电离层Ne的深度学习,二是1h预测策略的性能与之前类似的电离层TEC预测工作(RMSE高于1.5 TECU,最大值的1%)相比有竞争力,但预测时间太短且对数据的实时性要求较高,三是两种24h预测策略虽能实现长期预测但性能不理想,要实现三维空间时间序列的长期高精度预测需要进一步改善神经网络、模型结构和预测策略。展开更多
The assignment of the rovibrational spectra of molecule-Ne complexes is always a challenge to study van der Waals systems, since they usually exhibit behavior intermediate between free rotor and rigid rotor. In this p...The assignment of the rovibrational spectra of molecule-Ne complexes is always a challenge to study van der Waals systems, since they usually exhibit behavior intermediate between free rotor and rigid rotor. In this paper, the microwave and infrared spectra of CH3F-Ne, a model system for symmetric-top-atom dimer, were firstly pre- dicted and analyzed based on the four-dimensional ab initio intermolecular potential energy surfaces（PESs）, which explicitly incorporate the v3（C--F） stretch normal model coordinate of the CH3F monomer. Analytic three-dimensional PESs were obtained by least-squares fitting vibrationally averaged interaction energies for v3（CH3F）=0 and 1 to the Morse/long-range（MLR） potential function for symmetry top impurity with atom model. These PESs fitting to 2340 points have root-mean-square（RMS） deviations of 0.07 cm1, and require only 167 parameters. Based on the analytical vibrationally averaged PESs, the rovibrational energy levels were calculated by employing Lanczos algorithm, with combined radial discrete variable representation and parity-adapted angular finite basis representation. Based on the wavefunction analysis and comparison of CH3F-Ne with CH3F-He and CH3F-Ar complexes, the bound states were assigned. Spectral parameters for CH3F-Rg（Rg： rare gas, Rg=He, Ne, Ar） complexes were fitted and discussed. Temperature dependent transition intensities for CH3F-Ne were also reported and analyzed. The complete microwave and infrared spectra information for CH3F-Ne made it possible to provide important guidance for future experimental spectroscopic assignments.展开更多
基金supported by the basic scientific research fund, Institute of Geology, China Earthquake Administration (Grant Nos. IGCEA1504 and IGCEA1417)
文摘Cosmogenic Ne isotopes are stable and are routinely used for constraining the timing of events and the rate of surface change beyond the limit that can be studied with radionuclides ^10Be, ^26Al, and ^36Cl. Cosmogenic Ne analysis can be used in quartz and in a range of other minerals. Analysis typically requires significantly less material than do cosmogenic ^10Be and ^26Al, opening up the technique for small samples--individual pebbles in fiver sediments, for example. Analysis is easier and faster than for radionuclides, not least because Ne measurements do not require significant chemical procedures. However, the presence of other sources of Ne in minerals tends to restrict the use of cosmogenic ^21Ne to old landscapes and long exposure durations. In this review we briefly outline the background of cosmogenic Ne production in rocks and minerals at the Earth＇s surface, then document the key uses of the technique by highlighting some earlier studies, and finish with a short perspective on the future of the technique.
文摘由于电离层电子密度随时间变化,且空间分布不均匀,对不同频段的无线电波产生延缓和折射,因此电离层电子密度变化是影响短波通信、卫星通信、全球导航卫星系统和其他空间通信质量的一个主要因素,本文对全球电离层电子密度(Number of electron,Ne)的预测工作对短波通信设备三维射线实时追踪定位提供必要条件。本文采用国际电离层参考模型提供的2016年电离层Ne数据,根据数据的三维空间时间序列特征,搭建了自编码器和卷积长短期记忆(Convolutional Long Short-Term Memory Network,Conv LSTM)网络组成的网络结构,在不引入地球自转周期之外任何先验知识的条件下,对Ne数据进行深度学习并实现预测,首先通过实验对比了SGD、Adagrad、Adadelta、Adam、Adamax和Nadam六种优化算法的性能,又对比了三种预测策略的均方根误差(Root Mean Square Error, RMSE),1h-to-1h预测策略的全球平均RMSE为1.0 NEU(最大值的0.4%),1h-to-24h和24h-to-24h预测策略的全球平均RMSE为6.3 NEU(2.6%)。由实验结果得出以下结论,一是Nadam优化算法更适合电离层Ne的深度学习,二是1h预测策略的性能与之前类似的电离层TEC预测工作(RMSE高于1.5 TECU,最大值的1%)相比有竞争力,但预测时间太短且对数据的实时性要求较高,三是两种24h预测策略虽能实现长期预测但性能不理想,要实现三维空间时间序列的长期高精度预测需要进一步改善神经网络、模型结构和预测策略。
基金Supported by the National Natural Science Foundation of China（Nos.21273094, 21533003, 91541124）, the Program for New Century Excellent Talents in University of China（No.NCET-12-0230） and the Project of the Beijing National Laboratory for Molecular Sciences, China（BNLMS）.
文摘The assignment of the rovibrational spectra of molecule-Ne complexes is always a challenge to study van der Waals systems, since they usually exhibit behavior intermediate between free rotor and rigid rotor. In this paper, the microwave and infrared spectra of CH3F-Ne, a model system for symmetric-top-atom dimer, were firstly pre- dicted and analyzed based on the four-dimensional ab initio intermolecular potential energy surfaces（PESs）, which explicitly incorporate the v3（C--F） stretch normal model coordinate of the CH3F monomer. Analytic three-dimensional PESs were obtained by least-squares fitting vibrationally averaged interaction energies for v3（CH3F）=0 and 1 to the Morse/long-range（MLR） potential function for symmetry top impurity with atom model. These PESs fitting to 2340 points have root-mean-square（RMS） deviations of 0.07 cm1, and require only 167 parameters. Based on the analytical vibrationally averaged PESs, the rovibrational energy levels were calculated by employing Lanczos algorithm, with combined radial discrete variable representation and parity-adapted angular finite basis representation. Based on the wavefunction analysis and comparison of CH3F-Ne with CH3F-He and CH3F-Ar complexes, the bound states were assigned. Spectral parameters for CH3F-Rg（Rg： rare gas, Rg=He, Ne, Ar） complexes were fitted and discussed. Temperature dependent transition intensities for CH3F-Ne were also reported and analyzed. The complete microwave and infrared spectra information for CH3F-Ne made it possible to provide important guidance for future experimental spectroscopic assignments.
