Fine grains migration is a primary cause of landslides and debris flows.This study investigates the effect of fine-grain migration on slope failure through flume experiments,focusing on the spatiotemporal characterist...Fine grains migration is a primary cause of landslides and debris flows.This study investigates the effect of fine-grain migration on slope failure through flume experiments,focusing on the spatiotemporal characteristics and mechanisms of slope stability.A series of artificial rainfall flume experiments with varying rainfall intensities and slopes were conducted using soil samples collected from Wei Jia Gully.The experiments monitored pore-water pressure,grain migration,and failure sequences.Grain-size distribution parameters(μand Dc)were analyzed to understand the migration path and accumulation of fine grains.The experiments reveal that fine-grain migration significantly alters soil structure,leading to random blockage and interconnection of internal pore channels.These changes result in fluctuating pore-water pressure distributions and uneven fine-grain accumulation,critical factors in slope stability.Slope failures occur randomly and intermittently,influenced by fine-grain content in runoff and resulting pore-water pressure variations.This study highlights that fine-grain migration plays a vital role in slope stability,with significant implications for predicting and mitigating slope failures.The stochastic nature of fine-grain migration and its impact on soil properties should be incorporated into predictive models to enhance their accuracy and reliability.展开更多
To provide a scientific basis for sustainable land management, a 20-year fertility experiment was conducted in Changwu County, Shaanxi Province, China to investigate the effects of long-term application of chemical fe...To provide a scientific basis for sustainable land management, a 20-year fertility experiment was conducted in Changwu County, Shaanxi Province, China to investigate the effects of long-term application of chemical fertilizers on wheat grain yield and yield stability on the Loess Plateau using regression and stability analysis. The experiment consisted of 17 fertilizer treatments, containing the combinations of different N and P levels, with three replications arranged in a randomized complete block design. Nitrogen fertilizer was applied as urea, and P was applied as calcium superphosphate. Fertilizer rates had a large effect on the response of wheat yield to fertilization. Phosphorus, combined with N, increased yield significantly (P 〈 0.01). In the unfertilized control and the N or P sole application treatments, wheat yield had a declining trend although it was not statistically significant. Stability analysis combined with the trend analysis indicated that integrated use of fertilizer N and P was better than their sole application in increasing and sustaining the productivity of rainfed winter wheat.展开更多
In this paper, the coupled thermo-mechanical (TM) processes in the AEspoe Pillar Stability Experiment (APSE) carried out by the Swedish Nuclear Fuel and Waste Management Company (SKB) were simulated using both c...In this paper, the coupled thermo-mechanical (TM) processes in the AEspoe Pillar Stability Experiment (APSE) carried out by the Swedish Nuclear Fuel and Waste Management Company (SKB) were simulated using both continuum and discontinuum based numerical methods. Two-dimensional (2D) and three- dimensional (3D) finite element method (FEM) and 2D distinct element method (DEM) with particles were used. The main objective for the large scale in situ experiment is to investigate the yielding strength of crystalline rock and the formation of the excavation disturbed/damaged zone (EDZ) during excavation of two boreholes, pressurizing of one of the boreholes and heating. For the DEM simulations, the heat flow algorithm was newly introduced into the original code. The calculated stress, displacement and temperature distributions were compared with the ones obtained from in situ measurements and FEM simulations. A parametric study for initial microcracks was also performed to reproduce the spalling phenomena observed in the APSE.展开更多
The paper describes an analysis of thermo-mechanical (TM) processes appearing during the Aspo Pillar Stability Experiment (APSE). This analysis is based on finite elements with elasticity, plasticity and dam- age ...The paper describes an analysis of thermo-mechanical (TM) processes appearing during the Aspo Pillar Stability Experiment (APSE). This analysis is based on finite elements with elasticity, plasticity and dam- age mechanics models of rock behaviour and some least squares calibration techniques. The main aim is to examine the capability of continuous mechanics models to predict brittle damage behaviour of gran- ite rocks. The performed simulations use an in-house finite element software GEM and self-developed experimental continuum damage MATLAB code. The main contributions are twofold. First, it is an inverse analysis, which is used for (1) verification of an initial stress measurement by back analysis of conver- gence measurement during construction of the access tunnel and (2) identification of heat transfer rock mass properties by an inverse method based on the known heat sources and temperature measurements. Second, three different hierarchically built models are used to estimate the pillar damage zones, i.e. elas- tic model with Drucker-Prager strength criterion, elasto-plastic model with the same yield limit and a combination of elasto-plasticity with continuum damage mechanics. The damage mechanics model is also used to simulate uniaxial and triaxial compressive strength tests on the ,Aspo granite.展开更多
This paper presents a study of the full three-dimensional thermo-mechanical (TM) behavior of rock pillar in,Aspo Pillar Stability Experiment (APSE) using a self-developed numerical code TM-EPCA3D. The transient th...This paper presents a study of the full three-dimensional thermo-mechanical (TM) behavior of rock pillar in,Aspo Pillar Stability Experiment (APSE) using a self-developed numerical code TM-EPCA3D. The transient thermal conduction function was descritized on space and time scales, and was solved by using cellular automaton (CA) method on space scale and finite difference method on time scale, respectively. The advantage of this approach is that no global, but local matrix is used so that it avoids the need to develop and solve large-scale linear equations and the complexity therein. A thermal conductivity versus stress function was proposed to reflect the effect of stress on thermal field. The temperature evolution and induced thermal stress in the pillar part during the heating and cooling processes were well simulated by the developed code. The factors that affect the modeling results were discussed. It is concluded that, the complex TM behavior of Aspo rock pillar is significantly influenced by the complex boundary and initial conditions.展开更多
The inclining experiment is the only regulatory tool to assess ship stability. This experiment is a time consuming process for both real-life tests and ship model experiments. The difficulty is mainly due to a bias in...The inclining experiment is the only regulatory tool to assess ship stability. This experiment is a time consuming process for both real-life tests and ship model experiments. The difficulty is mainly due to a bias in the measurement of heel angle. Nowadays, digital inclinometers are available, but they are expensive. In this study, the use of a smartphone application is presented for ship inclination and rolling-period tests. The idea consists of using accelerometer and gyroscope sensors built into the current smartphones for the measurements. Therefore, some experiments are carried out on an example trawler model to exhibit the uses and advantages of this method. The obtained results are in good agreement with those provided from the pendulum method and natural roll-period test. This application is new, easy, and more accurately assesses metacentric height during the inclining and rolling-period tests.展开更多
[Objectives]To investigate the stability of Shuji tablets.[Methods]Accelerated test and long-term test were used to investigate the changes of tablet properties,weight difference,alcohol-soluble extract,disintegration...[Objectives]To investigate the stability of Shuji tablets.[Methods]Accelerated test and long-term test were used to investigate the changes of tablet properties,weight difference,alcohol-soluble extract,disintegration time and microbial limit.[Results]All the indicators of the three batches of samples(after 6 months of accelerated test and 18 months of long-term test)basically remained unchanged and all met the standards of the quality standard.[Conclusions]The preparation is stable and reliable,and the stability test provides a reliable basis for its validity.展开更多
The content of organic matter (OM), nitrogen (N), phosphorus (P), and potassium (K) in the three selected soils, including Calcaric Purpli-Orthic Primosols (purple sand-shale parent material), Dystric Turbi-...The content of organic matter (OM), nitrogen (N), phosphorus (P), and potassium (K) in the three selected soils, including Calcaric Purpli-Orthic Primosols (purple sand-shale parent material), Dystric Turbi-Anthric Primosols (quaternary red clay parent material) and Typic Udi-Sandic Primosols (granite parent material) were studied under a long-term experiment by using crop straw and inorganic fertilizers at the Hunan Red Soil Experiment Station of Chinese Academy of Agricultural Sciences. The results showed that the contents of OM, N, P and K in the three selected soils increased after 23 years application of crop straw and inorganic fertilizers, but the contents increased much less when crop straw or inorganic fertilizers was applied alone. The nutrient contents in the three soils developed from granite changed more remarkably than those in the soil derived from quaternary red clay and purple sand-shale. It was also found that the contents of OM, N, and P increased slightly in the treatments without applying fertilizers or returning the crop straw to the root bed. Combined application of inorganic fertilizers and crop straw could remarkably increase the contents of OM, alkalihydrolyzable N and available K, the positive correlation between application of organic fertilizers and increase of OM in soil did not always happened, it provided evidence for the relation between appropriate C/N ratio and accumulation of OM in soil. The increase of nutrient content was influenced by the soil properties. By comparing the contents of nutrient in 0-20 cm depth in the three different soils, it was concluded that the most increases of OM, alkali-hydrolyzable N, and available P were observed in Typic Udi-Sandic Primosols with the average increase by 3.03, 27.38, and 21.73 mg kg^-1, respectively. The available K increased in Dystric Turbi-Anthric Primosols with the average increase by 25.82 mg kg^-1, while it decreased in Calcaric Purpli-Orthic Primosols and Typic Udi-Sandic Primosols. It was concluded that the application of inorganic fertilizer and crop straw was important to improve the soil fertility for all of three selected soils. The straw return to the field had played a significant role for enhancement of the soil quality in the study areas. The application of inorganic fertilizer combined with the straw return to the fields could remarkably improve the soil fertility.展开更多
An understanding of wheat yield and yield stability response to fertilization is important for sustainable wheat production. A 36-year long-term fertilization experiment was employed to evaluate the yield and yield st...An understanding of wheat yield and yield stability response to fertilization is important for sustainable wheat production. A 36-year long-term fertilization experiment was employed to evaluate the yield and yield stability of winter wheat. Five fertilization regimes were compared,including(1) CK, no fertilizer;(2) NPK, inorganic fertilizer only;(3) O, organic fertilizer only;(4)NPKO, 50% of NPK plus 50% of O, and(5) HNPKO, 80% of NPK plus 80% of O. The greatest yield increase was recorded in HNPKO, followed by NPKO, with O producing the lowest mean yield increase. Over the 36 years, the rate of wheat yield increase in fertilized plots ranged from95.31 kg ha-1 year-1 in the HNPKO to 138.65 kg ha-1 year-1 in the O. Yield stability analysis using the additive main effects and multiplicative interactions(AMMI) method assigned 62.3%, 26.3%,and 11.4% of sums of squares to fertilization effect, environmental effect, and fertilization ×environment interaction effect, respectively. The combination of inorganic and organic fertilization(NPKO and HNPKO) appeared to produce more stable yields than O or NPK, with lower coefficients of variation and AMMI stability value. However, wheat grown with O seemed to be the most susceptible to climate change and the least productive among the fertilized plots.Significant correlations of grain yield with soil properties and with mean air temperature were observed. These findings suggest that inorganic + organic fertilizer can increase wheat yield and its stability by improvement in soil fertility and reduction in variability to climate change.展开更多
Straw incorporation is a global common practice to improve soil fertility and rice yield.However,the effect of straw incorporation on rice yield stability is still unknown,especially under high fertilization level con...Straw incorporation is a global common practice to improve soil fertility and rice yield.However,the effect of straw incorporation on rice yield stability is still unknown,especially under high fertilization level conditions.Here,we reported the effect of straw returning on rice yield and yield stability under high fertilization levels in the rice–wheat system over nine years.The results showed that straw incorporation did not significantly affect the average rice yield of nine years.Straw incorporation reduced the coefficient of variation of rice yield by 25.8%and increased the sustainable yield index by 8.2%.The rice yield positively correlated with mean photosynthetically active radiation (PAR) of rice growth season and the effects of straw incorporation on rice yield depended on the PAR.Straw incorporation increased the rice yield by 5.4%in the low PAR years,whereas it did not affect the rice yield in the high PAR years.Long-term straw incorporation lowered soil bulk density but improved the soil organic matter,total N,available N,available P,and available K more strongly than straw removal.Our findings suggest that straw incorporation can increase rice yield stability through improving the resistance of rice plant growth to low PAR.展开更多
Perovskite solar cells(PSCs)have made great advances in terms of power conversion efficiency(PCE),yet their subpar stability continues to hinder their commercialization.The interface between the perovskite layer and t...Perovskite solar cells(PSCs)have made great advances in terms of power conversion efficiency(PCE),yet their subpar stability continues to hinder their commercialization.The interface between the perovskite layer and the charge-carrier transporting layers plays a crucial role in undermining the stability of PSCs.In this work,we propose a strategy to stabilize high-performance PSCs with PCE over 23%by introducing a cesium-doped graphene oxide(GO-Cs)as an interlayer between the perovskite and hole-transporting material.The GO-Cs treated PSCs exhibit excellent operational stability with a projected T80(the time where the device PCE reduces to 80%of its initial value)of 2143 h of operation at the maximum powering point under one sun illumination.展开更多
The long-term dynamic evolution and underlying mechanisms of coastal landscape pattern stability,driven by strong anthropogenic interference and consequently climate change,are topics of major interest in national and...The long-term dynamic evolution and underlying mechanisms of coastal landscape pattern stability,driven by strong anthropogenic interference and consequently climate change,are topics of major interest in national and international scientific research.Guangdong Province,located in southeastern China,has been undergoing rapid urbanization over several decades.In this study,we quantitatively determined the scale threshold characteristics of coastal landscape pattern stability in Guangdong Province,from the dual perspective of spatial heterogeneity and spatial autocorrelation.An analysis of the spatiotemporal evolution of the coastal landscape was conducted after the optical scale was determined.Then,we applied the geodetector statistical method to quantitatively explore the mechanisms underlying coastal landscape pattern stability.Based on the inflection point of landscape metrics and the maximum value of the MoranⅠindex,the optimal scale for analyzing coastal landscape pattern stability in Guangdong Province was 240 m×240 m.Within the past several decades,coastal landscape pattern stability increased slightly and then decreased,with a turning point around 2005.The most significant variations in coastal landscape pattern stability were observed in the transition zone of rural-urban expansion.A q-statistics analysis showed that the explanatory power of paired factors was greater than that of a single driving factor;the paired factors with the greatest impact on coastal landscape pattern stability in Guangdong Province were the change in gross industrial output and change in average annual precipitation from 2010 to 2015,based on a q value of 0.604.These results will contribute to future efforts to achieve sustainable coastal development and provide a scientific basis and technical support for the rational planning and utilization of resources in large estuarine areas,including marine disaster prevention and seawall ecological restoration.展开更多
A long-term fertilization experiment was set up in northern Xinjiang, China to evaluate the dynamics of crop production and soil organic carbon (SOC) from 1990 to 2012 with seven fertilization treatments. The seven ...A long-term fertilization experiment was set up in northern Xinjiang, China to evaluate the dynamics of crop production and soil organic carbon (SOC) from 1990 to 2012 with seven fertilization treatments. The seven treatments included an unfertilized control (CK) and six different combinations of phosphorus (P), potassium (K), nitrogen (N), straw (S) and animal manure (M). The balanced fertilization treatments had significantly (P〈0.05) higher average yields than the unbalanced ones. The treatment with 2/3 N from potassium sulfate (NPK) and 1/3 N from farmyard manure (NPKM) had a higher average yield than the other treatments. The average yields (over the 23 years) in the treatments of NPK, and urea, calcium superphosphate (NP) did not differ significantly (P〉0.05) but were higher than that in the treatment with urea and potassium sulfate (NK; P〈0.05). The results also show that the highest increases in SOC (P〈0.05) occurred in NPKM with a potential increase of 1.2 t C/(hm2.a). The increase in SOC was only 0.31, 0.30 and 0.12 t C/(hm2.a) for NPKS (9/10 N from NPK and 1/10 N from straw), NPK and NP, respectively; and the SOC in the NP, NK and CK treatments were approaching equilibrium and so did not rise or fall significantly over the 23-year experiment. A complete NPK plus manure fertilization program is recommended for this extremely arid region to maximize both yields and carbon sequestration.展开更多
Callovo-Oxfordian(COx)claystone has been considered as a potential host rock for geological radioactive waste disposal in France(Cigéo project).During the exploitation phase(100 years),the stability of drifts(e.g...Callovo-Oxfordian(COx)claystone has been considered as a potential host rock for geological radioactive waste disposal in France(Cigéo project).During the exploitation phase(100 years),the stability of drifts(e.g.galleries/alveoli)within the disposal is assured by the liner,which includes two layers:concrete arch segment and compressible material.The latter exhibits a significant deformation capacity(about 50%)under low stress(<3 MPa).Although the response of these underground structures can be governed by complex thermo-hydro-mechanical coupling,the creep behavior of COx claystone has been considered as the main factor controlling the increase of stress state in the concrete liner and hence the long-term stability of drifts.Therefore,by focusing only on the purely mechanical behavior,this study aims at investigating the uncertainty effect of the COx claystone time-dependent properties on the stability of an alveolus of Cigéo during the exploitation period.To describe the creep behavior of COx claystone,we use Lemaitre’s viscoplastic model with three parameters whose uncertainties are identified from laboratory creep tests.For the reliability analysis,an extension of a well-known Kriging metamodeling technique is proposed to assess the exceedance probability of acceptable stress in the concrete liner of the alveolus.The open-source code Code_Aster is chosen for the direct numerical evaluations of the performance function.The Kriging-based reliability analysis elucidates the effect of the uncertainty of COx claystone on the long-term stability of the concrete liner.Moreover,the role of the compressible material layer between the concrete liner and the host rock is also highlighted.展开更多
All-inorganic CsPbI_(2)Br perovskite solar cells(PSCs)have received extensive research interests recently.Nevertheless,their low efficiency and poor long-term stability are still obstacles for further commercial appli...All-inorganic CsPbI_(2)Br perovskite solar cells(PSCs)have received extensive research interests recently.Nevertheless,their low efficiency and poor long-term stability are still obstacles for further commercial application.Herein,we demonstrate that high efficiency and exceptional long-term stability are realized by incorporating gadolinium(III)chloride(GdCl_(3))into the CsPbI_(2)Br perovskite film.The incorporation of GdCl_(3) enhances the Goldschmidt tolerance factor of CsPbI_(2)Br perovskite,yielding a dense perovskite film with small grains,thus the a-phase CsPbI_(2)Br is remarkably stabilized.Additionally,it is found that the GdCl_(3)-incorporated perovskite film achieves suppressed charge recombination and appropriate energy level alignment compared with the pristine CsPbI_(2)Br film.The noticeable increment in efficiency from14.01%(control PSC)to 16.24%is achieved for GdCl_(3)-incorporated PSC.Moreover,the nonencapsulated GdCl_(3)-incorporated PSC exhibits excellent environmental and thermal stability,remaining over 91%or90%of the original efficiency after 1200 h aging at 40%relative humidity or 480 h heating at 85℃ in nitrogen glove box respectively.The encapsulated GdCl_(3)-incorporated PSC presents an improved operational stability with over 88%of initial efficiency under maximum power point(MPP)tracking at 45℃ for1000 h.This work presents an effective ion-incorporation approach for boosting efficiency and long-term stability of all-inorganic PSCs.展开更多
Objective:To analyze the enduring rotational steadiness of AcrySof IQ Toric intraocular lens(IOL)in cataract patients suffering from myopia in a long-term study.Methods:A retrospective study was conducted on a case se...Objective:To analyze the enduring rotational steadiness of AcrySof IQ Toric intraocular lens(IOL)in cataract patients suffering from myopia in a long-term study.Methods:A retrospective study was conducted on a case series involving 78 patients.A total of 120 eyes with an axial length(AL)ranging from 24-30 mm and corneal astigmatism≥1.50 D underwent implantation of AcrySof IQ Toric IOL guided by the version navigation system.The eyes were divided into two groups based on AL.Group A included 60 eyes with high myopia(AL≥26 mm),while Group B consisted of eyes with low to moderate myopia(24 mm≤AL<26 mm).Data on the preoperative AL were collected.Measurements were taken for residual astigmatism,the best corrected visual acuity(BCDVA),corneal astigmatism,and IOL rotation occurring between 24-and 48-months post-surgery.The percentage of eyes with an IOL rotation of under 5°and 10°was analyzed.Results:The mean length of follow-up times was recorded as 34.27±4.98,and the average rotation was 2.73±1.29°.Group A exhibited a slightly higher average rotation of 2.87±1.31°,compared to the rotation of 2.59±1.27°observed in Group B.At both the 24-36 month and 26-48 month post-operation marks,the degree of IOL rotation did not show a statistically significant difference between the two groups,with none of the patients experiencing a rotation exceeding 10°(P>0.05).The percentage of rotation degrees under 5°was recorded as 98.22%.After the procedure,the BCDVA was 0.1322±0.03 LogMAR.There was a substantial increase in theχvalue after the operation as compared to the pre-operativeχ^(2) value(χ^(2)=76.79).The standard deviation of preoperative corneal astigmatism was statistically significant(P<0.05)at 2.17±1.08 D.Following the surgical procedure,the remaining astigmatism was measured at 0.41±0.26 D.The data showed a notable gap in statistical significance(t=4.281,P<0.05).Conclusion:The AcrySof Toric IOL was a reliable solution for managing corneal astigmatism in cataract patients with myopia,demonstrating excellent long-term rotational stability.展开更多
Long-term stability of large-span caverns is a challenging issue for design and construction of underground rock engineering.The Heidong cavern group consisting of 21 caverns was constructed about 1400 years ago for q...Long-term stability of large-span caverns is a challenging issue for design and construction of underground rock engineering.The Heidong cavern group consisting of 21 caverns was constructed about 1400 years ago for quarrying in massive Cretaceous tuff.The cavern No.5 of the Heidong cavern group is characterized by an unsupported span up to 92 m,with the overburden thickness of only 3-25 m.To analyze its long-term stability,a detailed investigation was conducted to obtain its geometry and rock mass characteristics,and to monitor surrounding rock displacements.Based on field survey and laboratory tests,numerical simulations were performed using the finite difference code FLAC;.The analysis results revealed that for the long-term stability of the cavern No.5,some major factors should be carefully considered,such as cavern excavation method in hard massive rocks,site investigation using trial pits,tools like short iron chisel and hammer for manual excavation,geometric dome roof,and waste rocks within abutment or on the floor.The highlights of the technologies obtained from this large-scale ancient underground project can provide reference for other similar project excavations in practice.展开更多
The presence of defects and detrimental reactions at NiO_(x)/perovskite interface extremely limit the efficiency performance and long-term stability of the perovskite solar cells(PSCs) based on NiO_(x).Herein,an amphi...The presence of defects and detrimental reactions at NiO_(x)/perovskite interface extremely limit the efficiency performance and long-term stability of the perovskite solar cells(PSCs) based on NiO_(x).Herein,an amphipathic molecule Triton X100(Triton) is modified on the NiO_(x)surface.The hydrophilic chain of Triton as a Lewis base additive can coordinate with the Ni3+on the NiO_(x)surface which can passivate the interfacial defects and hinder the detrimental reactions at the NiO_(x)/perovskite interface.Additionally,the hydrophobic chain of Triton protrudes from the NiO_(x)surface to prevent moisture from penetrating into the NiO_(x)/perovskite interface.Consequently,the NiO_(x)/Triton-based devices(MAPbI3as absorbing layer) show superior moisture and thermal stability,retaining 88.4% and 64.3% of the initial power conversion efficiency after storage in air(40%-50% relative humidity(RH)) at 25 ℃ for 1070 h and in N2at 85℃ for 800 h,respectively.Moreover,the efficiency increases from 17.59% to 19.89% because of the passivation defect and enhanced hole-extraction capability.Besides,the NiO_(x)/Triton-based PSCs with Cs_(0.05)(MA_(0.15)FA_(0.85))_(0.95)Pb(I_(0.85)Br_(0.15))3perovskite as the light-absorbing layer also exhibits better moisture and thermal stability compared to the control devices,indicating the viability of our strategies.Of particular note,a champion PCE of 22.35% and 20.46% was achieved for small-area(0.1 cm^(2)) and large-area(1.2 cm^(2)) NiO_(x)/Triton-based devices,respectively.展开更多
In this work,we developed the PM6:Y6-based inverted structure organic photovoltaic(i-OPV)with improved power conversion efficiency(PCE)and long-term stability by resolving the origins of the performance deterioration....In this work,we developed the PM6:Y6-based inverted structure organic photovoltaic(i-OPV)with improved power conversion efficiency(PCE)and long-term stability by resolving the origins of the performance deterioration.The deep defects between the metal oxide-based electron transport layer and bulk-heterojunction photoactive layer interface were responsible for suboptimal PCE and facilitated degradation of devices.While the density of deep traps is increased during the storage of i-OPV,the penetrative oxygen-containing defects additionally generated shallow traps below the band-edge of Y6,causing an additional loss in the open-circuit voltage.The suppression of interfacial defects by chemical modification effectively improved the PCE and long-term stability of i-OPV.The modified i-OPV(mi-OPV)achieved a PCE of 17.42%,which is the highest value among the reported PM6:Y6-based i-OPV devices.Moreover,long-term stability was significantly improved:~90%and~80%retention of its initial PCE after 1200 h of air storage and illumination,respectively.展开更多
Many of the important questions facing farming systems in the world today require long-term studies to provide meaningful information and answers. A long-term agronomic experiment (LTAE) should (1) have long-term obje...Many of the important questions facing farming systems in the world today require long-term studies to provide meaningful information and answers. A long-term agronomic experiment (LTAE) should (1) have long-term objectives; (2) study important soil processes or ecological processes; and (3) be related to the productivity and sustainability of systems. A well established LTAE can provide both insights into how the system operates and foresight into where the system goes. The prerequisites for setting up a LTAE are the secured land, continuous funding and dedicated scientists. A number of principles must be considered carefully when establishing a LTAE, (1) the site must be representative of large areas; (2) the treatments should be simple, but focusing on the big questions; (3) the plots should be large enough to allow subsequent modification of the experiment if this becomes necessary; (4) crop rotations should minimise, wherever possible, the risk of build-up of pests and diseases, and rotational phase should be considered in a rotational experiment; (5) a clearly defined experimental protocol should be developed to ensure data collected is scientifically valid and statistically analysable, but with flexibility to allow essential changes; (6) soil samples, possibly plant samples, should be achieved to provide better answer to the original questions when new, perhaps more accurate analytical techniques are developed, or answer new research questions that were not considered in the original design. The MASTER experiment in Australia was used as a case study to demonstrate how these principles are implemented in practice.展开更多
基金supported by the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant No.XDA23090202)the Key Science and Technology Projects of Transportation Industry(Grant No.2021-MS4-104)the National Key Research and Development Program of China(Grant No.2019YFC1509900).
文摘Fine grains migration is a primary cause of landslides and debris flows.This study investigates the effect of fine-grain migration on slope failure through flume experiments,focusing on the spatiotemporal characteristics and mechanisms of slope stability.A series of artificial rainfall flume experiments with varying rainfall intensities and slopes were conducted using soil samples collected from Wei Jia Gully.The experiments monitored pore-water pressure,grain migration,and failure sequences.Grain-size distribution parameters(μand Dc)were analyzed to understand the migration path and accumulation of fine grains.The experiments reveal that fine-grain migration significantly alters soil structure,leading to random blockage and interconnection of internal pore channels.These changes result in fluctuating pore-water pressure distributions and uneven fine-grain accumulation,critical factors in slope stability.Slope failures occur randomly and intermittently,influenced by fine-grain content in runoff and resulting pore-water pressure variations.This study highlights that fine-grain migration plays a vital role in slope stability,with significant implications for predicting and mitigating slope failures.The stochastic nature of fine-grain migration and its impact on soil properties should be incorporated into predictive models to enhance their accuracy and reliability.
基金Project supported by the Agricultural Development Program of the Chinese Academy of Sciences (No. KSCX1-YWN1504)the West Light Foundation of the Chinese Academy of Sciences (No. 2005404)the National Natural Science Foundation of China (Nos. 50479065 and 40601041).
文摘To provide a scientific basis for sustainable land management, a 20-year fertility experiment was conducted in Changwu County, Shaanxi Province, China to investigate the effects of long-term application of chemical fertilizers on wheat grain yield and yield stability on the Loess Plateau using regression and stability analysis. The experiment consisted of 17 fertilizer treatments, containing the combinations of different N and P levels, with three replications arranged in a randomized complete block design. Nitrogen fertilizer was applied as urea, and P was applied as calcium superphosphate. Fertilizer rates had a large effect on the response of wheat yield to fertilization. Phosphorus, combined with N, increased yield significantly (P 〈 0.01). In the unfertilized control and the N or P sole application treatments, wheat yield had a declining trend although it was not statistically significant. Stability analysis combined with the trend analysis indicated that integrated use of fertilizer N and P was better than their sole application in increasing and sustaining the productivity of rainfed winter wheat.
基金conducted within the context of the international DECOVALEX Project (DEvelopment of COupled models and their VALidation against EXperiments)financed by Japan Atomic Energy Agency (JAEA) who was also one of the Funding Organizations of the projectChrister Anders-son from Swedish Nuclear Fuel and Waste Management Co.(SKB),Sweden
文摘In this paper, the coupled thermo-mechanical (TM) processes in the AEspoe Pillar Stability Experiment (APSE) carried out by the Swedish Nuclear Fuel and Waste Management Company (SKB) were simulated using both continuum and discontinuum based numerical methods. Two-dimensional (2D) and three- dimensional (3D) finite element method (FEM) and 2D distinct element method (DEM) with particles were used. The main objective for the large scale in situ experiment is to investigate the yielding strength of crystalline rock and the formation of the excavation disturbed/damaged zone (EDZ) during excavation of two boreholes, pressurizing of one of the boreholes and heating. For the DEM simulations, the heat flow algorithm was newly introduced into the original code. The calculated stress, displacement and temperature distributions were compared with the ones obtained from in situ measurements and FEM simulations. A parametric study for initial microcracks was also performed to reproduce the spalling phenomena observed in the APSE.
基金the context of the international DECOVALEX Project (DEmonstration of COupled models and their VALidation against EXperiments)financed by Radioactive Waste Repository Authority (RAWRA),through Technical University of Liberec (TUL), Czech RepublicSKB through its sp Pillar Stability Experiment project
文摘The paper describes an analysis of thermo-mechanical (TM) processes appearing during the Aspo Pillar Stability Experiment (APSE). This analysis is based on finite elements with elasticity, plasticity and dam- age mechanics models of rock behaviour and some least squares calibration techniques. The main aim is to examine the capability of continuous mechanics models to predict brittle damage behaviour of gran- ite rocks. The performed simulations use an in-house finite element software GEM and self-developed experimental continuum damage MATLAB code. The main contributions are twofold. First, it is an inverse analysis, which is used for (1) verification of an initial stress measurement by back analysis of conver- gence measurement during construction of the access tunnel and (2) identification of heat transfer rock mass properties by an inverse method based on the known heat sources and temperature measurements. Second, three different hierarchically built models are used to estimate the pillar damage zones, i.e. elas- tic model with Drucker-Prager strength criterion, elasto-plastic model with the same yield limit and a combination of elasto-plasticity with continuum damage mechanics. The damage mechanics model is also used to simulate uniaxial and triaxial compressive strength tests on the ,Aspo granite.
基金the context of the international DECOVALEX Project (DEmonstration of COupled models and their VALidation against EXperiments)grateful to the Institute of Rock and Soil Mechanics, Chinese Academy of Sciences (CAS), China, as one of the Funding Organizations of the project+2 种基金supported by a grant from the National Basic Research Program of China (No. 2010CB732006)the National Natural Science Foundation of China (Nos. 10972231, 41272349)SKB through its sp Pillar Stability Experiment project
文摘This paper presents a study of the full three-dimensional thermo-mechanical (TM) behavior of rock pillar in,Aspo Pillar Stability Experiment (APSE) using a self-developed numerical code TM-EPCA3D. The transient thermal conduction function was descritized on space and time scales, and was solved by using cellular automaton (CA) method on space scale and finite difference method on time scale, respectively. The advantage of this approach is that no global, but local matrix is used so that it avoids the need to develop and solve large-scale linear equations and the complexity therein. A thermal conductivity versus stress function was proposed to reflect the effect of stress on thermal field. The temperature evolution and induced thermal stress in the pillar part during the heating and cooling processes were well simulated by the developed code. The factors that affect the modeling results were discussed. It is concluded that, the complex TM behavior of Aspo rock pillar is significantly influenced by the complex boundary and initial conditions.
文摘The inclining experiment is the only regulatory tool to assess ship stability. This experiment is a time consuming process for both real-life tests and ship model experiments. The difficulty is mainly due to a bias in the measurement of heel angle. Nowadays, digital inclinometers are available, but they are expensive. In this study, the use of a smartphone application is presented for ship inclination and rolling-period tests. The idea consists of using accelerometer and gyroscope sensors built into the current smartphones for the measurements. Therefore, some experiments are carried out on an example trawler model to exhibit the uses and advantages of this method. The obtained results are in good agreement with those provided from the pendulum method and natural roll-period test. This application is new, easy, and more accurately assesses metacentric height during the inclining and rolling-period tests.
基金Science and Technology Program of Zhongshan City,Guangdong Province(2014A1FC138)。
文摘[Objectives]To investigate the stability of Shuji tablets.[Methods]Accelerated test and long-term test were used to investigate the changes of tablet properties,weight difference,alcohol-soluble extract,disintegration time and microbial limit.[Results]All the indicators of the three batches of samples(after 6 months of accelerated test and 18 months of long-term test)basically remained unchanged and all met the standards of the quality standard.[Conclusions]The preparation is stable and reliable,and the stability test provides a reliable basis for its validity.
文摘The content of organic matter (OM), nitrogen (N), phosphorus (P), and potassium (K) in the three selected soils, including Calcaric Purpli-Orthic Primosols (purple sand-shale parent material), Dystric Turbi-Anthric Primosols (quaternary red clay parent material) and Typic Udi-Sandic Primosols (granite parent material) were studied under a long-term experiment by using crop straw and inorganic fertilizers at the Hunan Red Soil Experiment Station of Chinese Academy of Agricultural Sciences. The results showed that the contents of OM, N, P and K in the three selected soils increased after 23 years application of crop straw and inorganic fertilizers, but the contents increased much less when crop straw or inorganic fertilizers was applied alone. The nutrient contents in the three soils developed from granite changed more remarkably than those in the soil derived from quaternary red clay and purple sand-shale. It was also found that the contents of OM, N, and P increased slightly in the treatments without applying fertilizers or returning the crop straw to the root bed. Combined application of inorganic fertilizers and crop straw could remarkably increase the contents of OM, alkalihydrolyzable N and available K, the positive correlation between application of organic fertilizers and increase of OM in soil did not always happened, it provided evidence for the relation between appropriate C/N ratio and accumulation of OM in soil. The increase of nutrient content was influenced by the soil properties. By comparing the contents of nutrient in 0-20 cm depth in the three different soils, it was concluded that the most increases of OM, alkali-hydrolyzable N, and available P were observed in Typic Udi-Sandic Primosols with the average increase by 3.03, 27.38, and 21.73 mg kg^-1, respectively. The available K increased in Dystric Turbi-Anthric Primosols with the average increase by 25.82 mg kg^-1, while it decreased in Calcaric Purpli-Orthic Primosols and Typic Udi-Sandic Primosols. It was concluded that the application of inorganic fertilizer and crop straw was important to improve the soil fertility for all of three selected soils. The straw return to the field had played a significant role for enhancement of the soil quality in the study areas. The application of inorganic fertilizer combined with the straw return to the fields could remarkably improve the soil fertility.
基金supported by the National Key Research and Development Program of China(2016YFD0300803)the Special Fund for Agro-scientific Research in the Public Interest(201503116-10)+1 种基金the Agricultural Science and Technology Innovation Program(CAAS-XTCX2016019-03 and Y2016XT01-03)the Science and Technology Major Project of Anhui Province(16030701099)
文摘An understanding of wheat yield and yield stability response to fertilization is important for sustainable wheat production. A 36-year long-term fertilization experiment was employed to evaluate the yield and yield stability of winter wheat. Five fertilization regimes were compared,including(1) CK, no fertilizer;(2) NPK, inorganic fertilizer only;(3) O, organic fertilizer only;(4)NPKO, 50% of NPK plus 50% of O, and(5) HNPKO, 80% of NPK plus 80% of O. The greatest yield increase was recorded in HNPKO, followed by NPKO, with O producing the lowest mean yield increase. Over the 36 years, the rate of wheat yield increase in fertilized plots ranged from95.31 kg ha-1 year-1 in the HNPKO to 138.65 kg ha-1 year-1 in the O. Yield stability analysis using the additive main effects and multiplicative interactions(AMMI) method assigned 62.3%, 26.3%,and 11.4% of sums of squares to fertilization effect, environmental effect, and fertilization ×environment interaction effect, respectively. The combination of inorganic and organic fertilization(NPKO and HNPKO) appeared to produce more stable yields than O or NPK, with lower coefficients of variation and AMMI stability value. However, wheat grown with O seemed to be the most susceptible to climate change and the least productive among the fertilized plots.Significant correlations of grain yield with soil properties and with mean air temperature were observed. These findings suggest that inorganic + organic fertilizer can increase wheat yield and its stability by improvement in soil fertility and reduction in variability to climate change.
基金the National Key Research and Development Program of China (2017YFD0301203, 2017YFD0300100, and 2018YFD0300803)Jiangsu Agriculture Science and Technology Innovation Fund (CX(18)1002)。
文摘Straw incorporation is a global common practice to improve soil fertility and rice yield.However,the effect of straw incorporation on rice yield stability is still unknown,especially under high fertilization level conditions.Here,we reported the effect of straw returning on rice yield and yield stability under high fertilization levels in the rice–wheat system over nine years.The results showed that straw incorporation did not significantly affect the average rice yield of nine years.Straw incorporation reduced the coefficient of variation of rice yield by 25.8%and increased the sustainable yield index by 8.2%.The rice yield positively correlated with mean photosynthetically active radiation (PAR) of rice growth season and the effects of straw incorporation on rice yield depended on the PAR.Straw incorporation increased the rice yield by 5.4%in the low PAR years,whereas it did not affect the rice yield in the high PAR years.Long-term straw incorporation lowered soil bulk density but improved the soil organic matter,total N,available N,available P,and available K more strongly than straw removal.Our findings suggest that straw incorporation can increase rice yield stability through improving the resistance of rice plant growth to low PAR.
基金King Abdulaziz City for Science and Technology (KACST) for the fellowshipfunding from the European Union’s Horizon 2020 research and innovation program GRAPHENE Flagship Core 3 under agreement No.: 881603+2 种基金funding from the European Union’s Horizon 2020 research and innovation program under the Marie Sk?odowska-Curie grant agreement No. 945363funding from the Shanghai Pujiang Program (22PJ1401200)the National Natural Science Foundation of China (No. 52302229)
文摘Perovskite solar cells(PSCs)have made great advances in terms of power conversion efficiency(PCE),yet their subpar stability continues to hinder their commercialization.The interface between the perovskite layer and the charge-carrier transporting layers plays a crucial role in undermining the stability of PSCs.In this work,we propose a strategy to stabilize high-performance PSCs with PCE over 23%by introducing a cesium-doped graphene oxide(GO-Cs)as an interlayer between the perovskite and hole-transporting material.The GO-Cs treated PSCs exhibit excellent operational stability with a projected T80(the time where the device PCE reduces to 80%of its initial value)of 2143 h of operation at the maximum powering point under one sun illumination.
基金The National Natural Science Foundation of China under contract Nos 42201104 and 42071123the China Postdoctoral Research Foundation under contract No.2023M730758.
文摘The long-term dynamic evolution and underlying mechanisms of coastal landscape pattern stability,driven by strong anthropogenic interference and consequently climate change,are topics of major interest in national and international scientific research.Guangdong Province,located in southeastern China,has been undergoing rapid urbanization over several decades.In this study,we quantitatively determined the scale threshold characteristics of coastal landscape pattern stability in Guangdong Province,from the dual perspective of spatial heterogeneity and spatial autocorrelation.An analysis of the spatiotemporal evolution of the coastal landscape was conducted after the optical scale was determined.Then,we applied the geodetector statistical method to quantitatively explore the mechanisms underlying coastal landscape pattern stability.Based on the inflection point of landscape metrics and the maximum value of the MoranⅠindex,the optimal scale for analyzing coastal landscape pattern stability in Guangdong Province was 240 m×240 m.Within the past several decades,coastal landscape pattern stability increased slightly and then decreased,with a turning point around 2005.The most significant variations in coastal landscape pattern stability were observed in the transition zone of rural-urban expansion.A q-statistics analysis showed that the explanatory power of paired factors was greater than that of a single driving factor;the paired factors with the greatest impact on coastal landscape pattern stability in Guangdong Province were the change in gross industrial output and change in average annual precipitation from 2010 to 2015,based on a q value of 0.604.These results will contribute to future efforts to achieve sustainable coastal development and provide a scientific basis and technical support for the rational planning and utilization of resources in large estuarine areas,including marine disaster prevention and seawall ecological restoration.
基金funded by the National Basic Research Program of China(2014CB954200)the National Natural Science Foundation of China(41425007,41005001)the National Gray Desert Soil Fertility and Fertilizer Efficiency Monitoring Station of China
文摘A long-term fertilization experiment was set up in northern Xinjiang, China to evaluate the dynamics of crop production and soil organic carbon (SOC) from 1990 to 2012 with seven fertilization treatments. The seven treatments included an unfertilized control (CK) and six different combinations of phosphorus (P), potassium (K), nitrogen (N), straw (S) and animal manure (M). The balanced fertilization treatments had significantly (P〈0.05) higher average yields than the unbalanced ones. The treatment with 2/3 N from potassium sulfate (NPK) and 1/3 N from farmyard manure (NPKM) had a higher average yield than the other treatments. The average yields (over the 23 years) in the treatments of NPK, and urea, calcium superphosphate (NP) did not differ significantly (P〉0.05) but were higher than that in the treatment with urea and potassium sulfate (NK; P〈0.05). The results also show that the highest increases in SOC (P〈0.05) occurred in NPKM with a potential increase of 1.2 t C/(hm2.a). The increase in SOC was only 0.31, 0.30 and 0.12 t C/(hm2.a) for NPKS (9/10 N from NPK and 1/10 N from straw), NPK and NP, respectively; and the SOC in the NP, NK and CK treatments were approaching equilibrium and so did not rise or fall significantly over the 23-year experiment. A complete NPK plus manure fertilization program is recommended for this extremely arid region to maximize both yields and carbon sequestration.
文摘Callovo-Oxfordian(COx)claystone has been considered as a potential host rock for geological radioactive waste disposal in France(Cigéo project).During the exploitation phase(100 years),the stability of drifts(e.g.galleries/alveoli)within the disposal is assured by the liner,which includes two layers:concrete arch segment and compressible material.The latter exhibits a significant deformation capacity(about 50%)under low stress(<3 MPa).Although the response of these underground structures can be governed by complex thermo-hydro-mechanical coupling,the creep behavior of COx claystone has been considered as the main factor controlling the increase of stress state in the concrete liner and hence the long-term stability of drifts.Therefore,by focusing only on the purely mechanical behavior,this study aims at investigating the uncertainty effect of the COx claystone time-dependent properties on the stability of an alveolus of Cigéo during the exploitation period.To describe the creep behavior of COx claystone,we use Lemaitre’s viscoplastic model with three parameters whose uncertainties are identified from laboratory creep tests.For the reliability analysis,an extension of a well-known Kriging metamodeling technique is proposed to assess the exceedance probability of acceptable stress in the concrete liner of the alveolus.The open-source code Code_Aster is chosen for the direct numerical evaluations of the performance function.The Kriging-based reliability analysis elucidates the effect of the uncertainty of COx claystone on the long-term stability of the concrete liner.Moreover,the role of the compressible material layer between the concrete liner and the host rock is also highlighted.
基金supported by the National Natural Science Foundation of China(52172237,52072228)the Shaanxi International Cooperational Project(2020KWZ-018)+1 种基金the Research Fund of the State Key Laboratory of Solidification Processing(NPU),China(Grant No.2021-QZ-02)the Fundamental Research Funds for the Central Universities(3102019JC005)。
文摘All-inorganic CsPbI_(2)Br perovskite solar cells(PSCs)have received extensive research interests recently.Nevertheless,their low efficiency and poor long-term stability are still obstacles for further commercial application.Herein,we demonstrate that high efficiency and exceptional long-term stability are realized by incorporating gadolinium(III)chloride(GdCl_(3))into the CsPbI_(2)Br perovskite film.The incorporation of GdCl_(3) enhances the Goldschmidt tolerance factor of CsPbI_(2)Br perovskite,yielding a dense perovskite film with small grains,thus the a-phase CsPbI_(2)Br is remarkably stabilized.Additionally,it is found that the GdCl_(3)-incorporated perovskite film achieves suppressed charge recombination and appropriate energy level alignment compared with the pristine CsPbI_(2)Br film.The noticeable increment in efficiency from14.01%(control PSC)to 16.24%is achieved for GdCl_(3)-incorporated PSC.Moreover,the nonencapsulated GdCl_(3)-incorporated PSC exhibits excellent environmental and thermal stability,remaining over 91%or90%of the original efficiency after 1200 h aging at 40%relative humidity or 480 h heating at 85℃ in nitrogen glove box respectively.The encapsulated GdCl_(3)-incorporated PSC presents an improved operational stability with over 88%of initial efficiency under maximum power point(MPP)tracking at 45℃ for1000 h.This work presents an effective ion-incorporation approach for boosting efficiency and long-term stability of all-inorganic PSCs.
基金This study was funded by a research grant from Alcon(IIT#68022037)Subject of Medical and Health Research in Heilongjiang Province(20230707020332).
文摘Objective:To analyze the enduring rotational steadiness of AcrySof IQ Toric intraocular lens(IOL)in cataract patients suffering from myopia in a long-term study.Methods:A retrospective study was conducted on a case series involving 78 patients.A total of 120 eyes with an axial length(AL)ranging from 24-30 mm and corneal astigmatism≥1.50 D underwent implantation of AcrySof IQ Toric IOL guided by the version navigation system.The eyes were divided into two groups based on AL.Group A included 60 eyes with high myopia(AL≥26 mm),while Group B consisted of eyes with low to moderate myopia(24 mm≤AL<26 mm).Data on the preoperative AL were collected.Measurements were taken for residual astigmatism,the best corrected visual acuity(BCDVA),corneal astigmatism,and IOL rotation occurring between 24-and 48-months post-surgery.The percentage of eyes with an IOL rotation of under 5°and 10°was analyzed.Results:The mean length of follow-up times was recorded as 34.27±4.98,and the average rotation was 2.73±1.29°.Group A exhibited a slightly higher average rotation of 2.87±1.31°,compared to the rotation of 2.59±1.27°observed in Group B.At both the 24-36 month and 26-48 month post-operation marks,the degree of IOL rotation did not show a statistically significant difference between the two groups,with none of the patients experiencing a rotation exceeding 10°(P>0.05).The percentage of rotation degrees under 5°was recorded as 98.22%.After the procedure,the BCDVA was 0.1322±0.03 LogMAR.There was a substantial increase in theχvalue after the operation as compared to the pre-operativeχ^(2) value(χ^(2)=76.79).The standard deviation of preoperative corneal astigmatism was statistically significant(P<0.05)at 2.17±1.08 D.Following the surgical procedure,the remaining astigmatism was measured at 0.41±0.26 D.The data showed a notable gap in statistical significance(t=4.281,P<0.05).Conclusion:The AcrySof Toric IOL was a reliable solution for managing corneal astigmatism in cataract patients with myopia,demonstrating excellent long-term rotational stability.
基金financial support by the State Key Laboratory of Geohazard Prevention and Geoenvironment Protection,Chengdu University of Technology(Grant No.SKLGP2011K007)the Key Research Program of the Chinese Academy of Sciences(KZZD-EW05-02)the National Natural Science Foundation of China (Nos.41372324,40972198 and 41172269)
文摘Long-term stability of large-span caverns is a challenging issue for design and construction of underground rock engineering.The Heidong cavern group consisting of 21 caverns was constructed about 1400 years ago for quarrying in massive Cretaceous tuff.The cavern No.5 of the Heidong cavern group is characterized by an unsupported span up to 92 m,with the overburden thickness of only 3-25 m.To analyze its long-term stability,a detailed investigation was conducted to obtain its geometry and rock mass characteristics,and to monitor surrounding rock displacements.Based on field survey and laboratory tests,numerical simulations were performed using the finite difference code FLAC;.The analysis results revealed that for the long-term stability of the cavern No.5,some major factors should be carefully considered,such as cavern excavation method in hard massive rocks,site investigation using trial pits,tools like short iron chisel and hammer for manual excavation,geometric dome roof,and waste rocks within abutment or on the floor.The highlights of the technologies obtained from this large-scale ancient underground project can provide reference for other similar project excavations in practice.
基金supported by the National Key Research and Development Program of China(2018YFA0208701)the National Natural Science Foundation of China(21773308)+7 种基金the Research Funds of Renmin University of China(2017030013,201903020 and 20XNH059)the Fundamental Research Funds for Central Universities(China)supported by the Solar Energy Research Institute of Singapore(SERIS) at the National University of Singapore(NUS)supported by NUSthe National Research Foundation Singapore(NRF)the Energy Market Authority of Singapore(EMA)the Singapore Economic Development Board(EDB)the financial support from the China Scholarship Council(CSC) funding。
文摘The presence of defects and detrimental reactions at NiO_(x)/perovskite interface extremely limit the efficiency performance and long-term stability of the perovskite solar cells(PSCs) based on NiO_(x).Herein,an amphipathic molecule Triton X100(Triton) is modified on the NiO_(x)surface.The hydrophilic chain of Triton as a Lewis base additive can coordinate with the Ni3+on the NiO_(x)surface which can passivate the interfacial defects and hinder the detrimental reactions at the NiO_(x)/perovskite interface.Additionally,the hydrophobic chain of Triton protrudes from the NiO_(x)surface to prevent moisture from penetrating into the NiO_(x)/perovskite interface.Consequently,the NiO_(x)/Triton-based devices(MAPbI3as absorbing layer) show superior moisture and thermal stability,retaining 88.4% and 64.3% of the initial power conversion efficiency after storage in air(40%-50% relative humidity(RH)) at 25 ℃ for 1070 h and in N2at 85℃ for 800 h,respectively.Moreover,the efficiency increases from 17.59% to 19.89% because of the passivation defect and enhanced hole-extraction capability.Besides,the NiO_(x)/Triton-based PSCs with Cs_(0.05)(MA_(0.15)FA_(0.85))_(0.95)Pb(I_(0.85)Br_(0.15))3perovskite as the light-absorbing layer also exhibits better moisture and thermal stability compared to the control devices,indicating the viability of our strategies.Of particular note,a champion PCE of 22.35% and 20.46% was achieved for small-area(0.1 cm^(2)) and large-area(1.2 cm^(2)) NiO_(x)/Triton-based devices,respectively.
基金supported by a National Research Foundation of Korea(grant#:2020R1A2C1003929,2019R1A6A1A11053838,2020M1A2A2080746,2021M2E8A1044198,2016R1A5A1012966,2021M3H4A1A03051379).
文摘In this work,we developed the PM6:Y6-based inverted structure organic photovoltaic(i-OPV)with improved power conversion efficiency(PCE)and long-term stability by resolving the origins of the performance deterioration.The deep defects between the metal oxide-based electron transport layer and bulk-heterojunction photoactive layer interface were responsible for suboptimal PCE and facilitated degradation of devices.While the density of deep traps is increased during the storage of i-OPV,the penetrative oxygen-containing defects additionally generated shallow traps below the band-edge of Y6,causing an additional loss in the open-circuit voltage.The suppression of interfacial defects by chemical modification effectively improved the PCE and long-term stability of i-OPV.The modified i-OPV(mi-OPV)achieved a PCE of 17.42%,which is the highest value among the reported PM6:Y6-based i-OPV devices.Moreover,long-term stability was significantly improved:~90%and~80%retention of its initial PCE after 1200 h of air storage and illumination,respectively.
基金supported by the CAS/SAFEA International Partnership Program for Creative Research Teams (CXTD-Z2005-2-4)
文摘Many of the important questions facing farming systems in the world today require long-term studies to provide meaningful information and answers. A long-term agronomic experiment (LTAE) should (1) have long-term objectives; (2) study important soil processes or ecological processes; and (3) be related to the productivity and sustainability of systems. A well established LTAE can provide both insights into how the system operates and foresight into where the system goes. The prerequisites for setting up a LTAE are the secured land, continuous funding and dedicated scientists. A number of principles must be considered carefully when establishing a LTAE, (1) the site must be representative of large areas; (2) the treatments should be simple, but focusing on the big questions; (3) the plots should be large enough to allow subsequent modification of the experiment if this becomes necessary; (4) crop rotations should minimise, wherever possible, the risk of build-up of pests and diseases, and rotational phase should be considered in a rotational experiment; (5) a clearly defined experimental protocol should be developed to ensure data collected is scientifically valid and statistically analysable, but with flexibility to allow essential changes; (6) soil samples, possibly plant samples, should be achieved to provide better answer to the original questions when new, perhaps more accurate analytical techniques are developed, or answer new research questions that were not considered in the original design. The MASTER experiment in Australia was used as a case study to demonstrate how these principles are implemented in practice.