A novel magnetic field sensing system based on the fiber loop ring-down technique is proposed in this paper. In the fiber loop, a U-bent single-mode-fiber structure coated with magnetic fluid(MF) serves as the sensing...A novel magnetic field sensing system based on the fiber loop ring-down technique is proposed in this paper. In the fiber loop, a U-bent single-mode-fiber structure coated with magnetic fluid(MF) serves as the sensing head, and an erbium-doped fiber amplifier(EDFA) is introduced to compensate for the intrinsic loss of the cavity. The ring-down time of the system varies with the change of applied magnetic field due to the tunable absorption coefficient and refractive index of the MF. Therefore, measurement of the magnetic field can be realized by monitoring the ringdown time. The experimental results show that the performance of the system is extremely dependent on the interrogation wavelength, because both the gain of the EDFA and the loss of the sensing head are wavelength dependent.We found that at the optimal wavelength, the ratio of the gain to loss attained its maximum. The sensing system was experimentally demonstrated and a sensitivity of-0.5951 μs∕Oe was achieved.展开更多
Finesse is a critical parameter for describing the characteristics of an optical enhancement cavity(OEC). This paper first presents a review of finesse measurement techniques, including a comparative analysis of the a...Finesse is a critical parameter for describing the characteristics of an optical enhancement cavity(OEC). This paper first presents a review of finesse measurement techniques, including a comparative analysis of the advantages, disadvantages, and potential limitations of several main methods from both theoretical and practical perspectives. A variant of the existing method called the free spectral range(FSR) modulation method is proposed and compared with three other finesse measurement methods, i.e., the fast-switching cavity ring-down(CRD) method, the rapidly swept-frequency(SF) CRD method, and the ringing effect method. A high-power OEC platform with a high finesse of approximately 16000 is built and measured with the four methods. The performance of these methods is compared, and the results show that the FSR modulation method and the fast-switching CRD method are more suitable and accurate than the other two methods for high-finesse OEC measurements. The CRD method and the ringing effect method can be implemented in open loop using simple equipment and are easy to perform. Additionally, recommendations for selecting finesse measurement methods under different conditions are proposed, which benefit the development of OEC and its applications.展开更多
Continuous-wave cavity ring-down spectroscopy(CW-CRDS)is an important technical means to monitor greenhouse gases in atmospheric environment.In this paper,a CW-CRDS system is built to meet the needs of atmospheric met...Continuous-wave cavity ring-down spectroscopy(CW-CRDS)is an important technical means to monitor greenhouse gases in atmospheric environment.In this paper,a CW-CRDS system is built to meet the needs of atmospheric methane monitoring.The problem of mode matching is explained from the perspective of transverse mode and longitudinal mode,and the influence of laser injection efficiency on measurement precision is further analyzed.The results of cavity ring-down time measurement show that the measurement precision is higher when the laser is coupled with the fundamental mode.In the experiment,DFB laser is used to calibrate the system with standard methane concentration,and the measurement residual is less than±4×10^(-4)μs^(-1).The methane concentration in the air is monitored in real time for two days.The results show the consistency of the concentration changes over the two days,which further demonstrates the reliability of the system for the measurement of trace methane.By analyzing the influence of mode matching,it not only assists the adjustment of the optical path,but also further improves the sensitivity of the system measurement.展开更多
Near-infrared continuous wave cavity ring-down spectroscopy was applied to mea- sure the OH radicals in dielectric barrier discharge plasmas, which play an important role in combustion systems, atmospheric chemistry a...Near-infrared continuous wave cavity ring-down spectroscopy was applied to mea- sure the OH radicals in dielectric barrier discharge plasmas, which play an important role in combustion systems, atmospheric chemistry and the removal of air pollutants by non-thermal plasmas. The P-branches of OH X2YIi (vI : 2 +-- it 0) bands were used for number density measurements. The OH number density and plasma temperature were determined for different applied voltages, gas pressures and concentrations of both oxygen and water. The temporal evolu- tion of the OH number density was obtained by using the "time window" method, which was used to extract individual ring-down times at different times in a half period of the sine wave applied voltage in dielectric barrier discharge plasmas.展开更多
NO3 and N2O5 are important participants in nocturnal atmospheric chemical processes,and their concentrations are of great significance in the study of the mechanism of nocturnal atmospheric chemical reactions.A two-ch...NO3 and N2O5 are important participants in nocturnal atmospheric chemical processes,and their concentrations are of great significance in the study of the mechanism of nocturnal atmospheric chemical reactions.A two-channel diode laser based cavity ring-down spectroscopy(CRDS)instrument was developed to monitor the concentrations of NO3 and N2O5 in the atmosphere.The effective absorption length ratio and the total loss coefficient of the instrument were calibrated using laboratory standard samples.The effective absorption cross section of NO3 at 662 nm was derived.A detection sensitivity of 1.1 pptv NO3 in air was obtained at a time resolution of 1 s.N2O5 was converted to NO3 and detected online in the second CRDS channel.The instrument was used to monitor the concentrations of NO3 and N2O5 in the atmosphere of winter in Hefei in real time.By comparing the concentration changes of pollutants such as nitrogen oxides,ozone,PM2:5 in a rapid air cleaning process,the factors affecting the concentrations of NO3 and N2O5 in the atmosphere were discussed.展开更多
H_(2)S is one of the most important characteristic decomposition components of SF_(6)insulated gas,and the detection of trace H_(2)S is significant for early fault diagnosis of gas insulated electrical equipment.A 157...H_(2)S is one of the most important characteristic decomposition components of SF_(6)insulated gas,and the detection of trace H_(2)S is significant for early fault diagnosis of gas insulated electrical equipment.A 1578 nm wavelength distributed feedback diode laser(DFB-DL)based cavity ring-down spectroscopy(CRDS)experimental platform is developed to monitor the concentrations of H_(2)S in SF_(6)and SF_(6)/N_(2)mixture carrier gas.The detection sensitivity is higher than 1×10^(-6).The absorption cross section parameterσis vital for calculating the concentration.With repeated experiments using standard gas samples,parameterσof H_(2)S in pure SF_(6)and SF_(6)/N_(2)mixture carrier with different mixing ratios is calibrated.Compared with the simulatedσvalues,the influence of carrier gas on the broadening of spectral profile is discussed.The variation of absorption cross sectionσwith different carrier gas mixing ratios is studied as well,so that the calculation of the concentration in the carrier gas of any mixing ratio is possible.Thus,the application of CRDS in trace component detection of gas insulated electrical equipment is promising.展开更多
A cavity ring-down spectrometer (CRDS) is constructed with a single-mode continuous-wave Ti:Sapphire laser. It allows attaining a minimum detectable absorption of 1.8× 10^-10cm^-1. The spectrometer is applied ...A cavity ring-down spectrometer (CRDS) is constructed with a single-mode continuous-wave Ti:Sapphire laser. It allows attaining a minimum detectable absorption of 1.8× 10^-10cm^-1. The spectrometer is applied to record the overtone spectrum of ^12C2H2 in the 12240- 12350 cm-1. Compared with the previous CRDS and intra-cavity laser absorption spectroscopy studies in the same region, the present measurement achieved better sensitivity and better precision as well. As a result, the ro-vibrational parameters of the high overtone bands of acetylene at 12290.12, 12311.82, and 12350.61 cm^-1 have been refined. The advantages of the present CRD spectrometer is also demonstrated by the newly observed and well characterized perturbation on the f component of the very weak band near 12289 cm^-1. The quantitative measurement capability of the spectrometer is verified with the measurement of the water lines and employed to give the absolute band intensities of those three acetylene bands.展开更多
A two-channel thermal dissociation cavity ring down spectroscopy (CRDS) instrument has been built for in situ, real-time measurement of NO2 and total RNO2 (peroxy nitrates and alkyl nitrates) in ambient air, with ...A two-channel thermal dissociation cavity ring down spectroscopy (CRDS) instrument has been built for in situ, real-time measurement of NO2 and total RNO2 (peroxy nitrates and alkyl nitrates) in ambient air, with a NO2 detection limit of 0.10 ppbv at 1 s. A 6-day long measurement was conducted at urban site of Hefei by using the CRDS instrument with a time resolution of 3 s. A commercial molybdenum converted chemiluminescence (Mo-CL) instrument was also used for comparison. The average RNO2 concentration in the 6 days was measured to be 1.94 ppbv. The Mo-CL instrument overestimated the NO2 concentration by a bias of +1.69 ppbv in average, for the reason that it cannot distinguish RNO2 from NO2. The relative bias could be over 100% during the afternoon hours when NO2 was low but RNO2 was high.展开更多
Transitions of the 6υ3 overtone band of ^14N2 ^16O near 775 nm have been studied by continuous-wave cavity ring-down spectroscopy. Line positions and intensities were derived from a fit of the line shape using a hard...Transitions of the 6υ3 overtone band of ^14N2 ^16O near 775 nm have been studied by continuous-wave cavity ring-down spectroscopy. Line positions and intensities were derived from a fit of the line shape using a hard-collisional profile. The line positions determined with absolute accuracy of 5×10^-4 cm^-1 allowed us to reveal finer ro-vibrational couplings taking place after J〉14 except a strong anharmonic interaction identified by the effective Hamiltonian model. The absolute line intensities have also been retrieved with an estimated accuracy of 2% for a majority of the unblended lines. A new set of ro-vibrational and dipole moment parameters were derived from the experimental values. A comparison between the line positions and intensities of the 6υ3 band obtained in this work and those from previous studies is given.展开更多
For the accurate extraction of cavity decay time, a selection of data points is supplemented to the weighted least square method. We derive the expected precision, accuracy and computation cost of this improved method...For the accurate extraction of cavity decay time, a selection of data points is supplemented to the weighted least square method. We derive the expected precision, accuracy and computation cost of this improved method, and examine these performances by simulation. By comparing this method with the nonlinear least square fitting (NLSF) method and the linear regression of the sum (LRS) method in derivations and simulations, we find that this method can achieve the same or even better precision, comparable accuracy, and lower computation cost. We test this method by experimental decay signals. The results are in agreement with the ones obtained from the nonlinear least square fitting method.展开更多
基金National Key Scientific Instrument and Equipment Development Project of China(2013YQ03091502)National Natural Science Foundation of China(NSFC)(61378043,61107035)
文摘A novel magnetic field sensing system based on the fiber loop ring-down technique is proposed in this paper. In the fiber loop, a U-bent single-mode-fiber structure coated with magnetic fluid(MF) serves as the sensing head, and an erbium-doped fiber amplifier(EDFA) is introduced to compensate for the intrinsic loss of the cavity. The ring-down time of the system varies with the change of applied magnetic field due to the tunable absorption coefficient and refractive index of the MF. Therefore, measurement of the magnetic field can be realized by monitoring the ringdown time. The experimental results show that the performance of the system is extremely dependent on the interrogation wavelength, because both the gain of the EDFA and the loss of the sensing head are wavelength dependent.We found that at the optimal wavelength, the ratio of the gain to loss attained its maximum. The sensing system was experimentally demonstrated and a sensitivity of-0.5951 μs∕Oe was achieved.
基金Project supported by National Key Research and Development Program of China (Grant No.2022YFA1603403)。
文摘Finesse is a critical parameter for describing the characteristics of an optical enhancement cavity(OEC). This paper first presents a review of finesse measurement techniques, including a comparative analysis of the advantages, disadvantages, and potential limitations of several main methods from both theoretical and practical perspectives. A variant of the existing method called the free spectral range(FSR) modulation method is proposed and compared with three other finesse measurement methods, i.e., the fast-switching cavity ring-down(CRD) method, the rapidly swept-frequency(SF) CRD method, and the ringing effect method. A high-power OEC platform with a high finesse of approximately 16000 is built and measured with the four methods. The performance of these methods is compared, and the results show that the FSR modulation method and the fast-switching CRD method are more suitable and accurate than the other two methods for high-finesse OEC measurements. The CRD method and the ringing effect method can be implemented in open loop using simple equipment and are easy to perform. Additionally, recommendations for selecting finesse measurement methods under different conditions are proposed, which benefit the development of OEC and its applications.
基金This research is financial supported by the Natural National Science Foundation of China(Grant Nos.11874364,41877311,and 42005107)the National Key Research and Development Program of China(Grant No.2017YFC0805004)the CAS&Bengbu Technology Transfer Project(Grant No.ZKBB202102).
文摘Continuous-wave cavity ring-down spectroscopy(CW-CRDS)is an important technical means to monitor greenhouse gases in atmospheric environment.In this paper,a CW-CRDS system is built to meet the needs of atmospheric methane monitoring.The problem of mode matching is explained from the perspective of transverse mode and longitudinal mode,and the influence of laser injection efficiency on measurement precision is further analyzed.The results of cavity ring-down time measurement show that the measurement precision is higher when the laser is coupled with the fundamental mode.In the experiment,DFB laser is used to calibrate the system with standard methane concentration,and the measurement residual is less than±4×10^(-4)μs^(-1).The methane concentration in the air is monitored in real time for two days.The results show the consistency of the concentration changes over the two days,which further demonstrates the reliability of the system for the measurement of trace methane.By analyzing the influence of mode matching,it not only assists the adjustment of the optical path,but also further improves the sensitivity of the system measurement.
基金supported by National Natural Science Foundation of China (Nos.10475015, 10975029)
文摘Near-infrared continuous wave cavity ring-down spectroscopy was applied to mea- sure the OH radicals in dielectric barrier discharge plasmas, which play an important role in combustion systems, atmospheric chemistry and the removal of air pollutants by non-thermal plasmas. The P-branches of OH X2YIi (vI : 2 +-- it 0) bands were used for number density measurements. The OH number density and plasma temperature were determined for different applied voltages, gas pressures and concentrations of both oxygen and water. The temporal evolu- tion of the OH number density was obtained by using the "time window" method, which was used to extract individual ring-down times at different times in a half period of the sine wave applied voltage in dielectric barrier discharge plasmas.
基金Hao Wu,Jian Chen,An-wen Liu,and Shui-ming Hu acknowledge the supports from the Ministry of Science and Technology of China(No.2013BAK12B00)the National Natural Science Foundation of China(No.21427804).
文摘NO3 and N2O5 are important participants in nocturnal atmospheric chemical processes,and their concentrations are of great significance in the study of the mechanism of nocturnal atmospheric chemical reactions.A two-channel diode laser based cavity ring-down spectroscopy(CRDS)instrument was developed to monitor the concentrations of NO3 and N2O5 in the atmosphere.The effective absorption length ratio and the total loss coefficient of the instrument were calibrated using laboratory standard samples.The effective absorption cross section of NO3 at 662 nm was derived.A detection sensitivity of 1.1 pptv NO3 in air was obtained at a time resolution of 1 s.N2O5 was converted to NO3 and detected online in the second CRDS channel.The instrument was used to monitor the concentrations of NO3 and N2O5 in the atmosphere of winter in Hefei in real time.By comparing the concentration changes of pollutants such as nitrogen oxides,ozone,PM2:5 in a rapid air cleaning process,the factors affecting the concentrations of NO3 and N2O5 in the atmosphere were discussed.
基金supported in part by the National Key R&D Program of China(No.2021YFF0603100)in part by the Leading Innovation and Entrepreneurship Team in Zhejiang Province(No.2019R01014)
文摘H_(2)S is one of the most important characteristic decomposition components of SF_(6)insulated gas,and the detection of trace H_(2)S is significant for early fault diagnosis of gas insulated electrical equipment.A 1578 nm wavelength distributed feedback diode laser(DFB-DL)based cavity ring-down spectroscopy(CRDS)experimental platform is developed to monitor the concentrations of H_(2)S in SF_(6)and SF_(6)/N_(2)mixture carrier gas.The detection sensitivity is higher than 1×10^(-6).The absorption cross section parameterσis vital for calculating the concentration.With repeated experiments using standard gas samples,parameterσof H_(2)S in pure SF_(6)and SF_(6)/N_(2)mixture carrier with different mixing ratios is calibrated.Compared with the simulatedσvalues,the influence of carrier gas on the broadening of spectral profile is discussed.The variation of absorption cross sectionσwith different carrier gas mixing ratios is studied as well,so that the calculation of the concentration in the carrier gas of any mixing ratio is possible.Thus,the application of CRDS in trace component detection of gas insulated electrical equipment is promising.
基金V. ACKNOWLEDGMENTS We are indebted to D. Romanini and S. Kassi for helpful discussion. This work was supported by the National Natural Science Foundation of China (No.20903085 and No.20533060), Chinese Ministry of Science and Technology (No.2006CB922001 and No.2007CB815203), and the Fok Ying Tong Education Foundation (No. 101013).
文摘A cavity ring-down spectrometer (CRDS) is constructed with a single-mode continuous-wave Ti:Sapphire laser. It allows attaining a minimum detectable absorption of 1.8× 10^-10cm^-1. The spectrometer is applied to record the overtone spectrum of ^12C2H2 in the 12240- 12350 cm-1. Compared with the previous CRDS and intra-cavity laser absorption spectroscopy studies in the same region, the present measurement achieved better sensitivity and better precision as well. As a result, the ro-vibrational parameters of the high overtone bands of acetylene at 12290.12, 12311.82, and 12350.61 cm^-1 have been refined. The advantages of the present CRD spectrometer is also demonstrated by the newly observed and well characterized perturbation on the f component of the very weak band near 12289 cm^-1. The quantitative measurement capability of the spectrometer is verified with the measurement of the water lines and employed to give the absolute band intensities of those three acetylene bands.
文摘A two-channel thermal dissociation cavity ring down spectroscopy (CRDS) instrument has been built for in situ, real-time measurement of NO2 and total RNO2 (peroxy nitrates and alkyl nitrates) in ambient air, with a NO2 detection limit of 0.10 ppbv at 1 s. A 6-day long measurement was conducted at urban site of Hefei by using the CRDS instrument with a time resolution of 3 s. A commercial molybdenum converted chemiluminescence (Mo-CL) instrument was also used for comparison. The average RNO2 concentration in the 6 days was measured to be 1.94 ppbv. The Mo-CL instrument overestimated the NO2 concentration by a bias of +1.69 ppbv in average, for the reason that it cannot distinguish RNO2 from NO2. The relative bias could be over 100% during the afternoon hours when NO2 was low but RNO2 was high.
基金This work was supported by the National Key Basic Research Program of China (2013CB834602 and 2013BAK12B02), and the National Natural Science Foundation of China (No.21473172, No.21411130183, No.21303176).
文摘Transitions of the 6υ3 overtone band of ^14N2 ^16O near 775 nm have been studied by continuous-wave cavity ring-down spectroscopy. Line positions and intensities were derived from a fit of the line shape using a hard-collisional profile. The line positions determined with absolute accuracy of 5×10^-4 cm^-1 allowed us to reveal finer ro-vibrational couplings taking place after J〉14 except a strong anharmonic interaction identified by the effective Hamiltonian model. The absolute line intensities have also been retrieved with an estimated accuracy of 2% for a majority of the unblended lines. A new set of ro-vibrational and dipole moment parameters were derived from the experimental values. A comparison between the line positions and intensities of the 6υ3 band obtained in this work and those from previous studies is given.
基金supported by the Preeminent Youth Fund of Sichuan Province,China(Grant No.2012JQ0012)the National Natural Science Foundation of China(Grant Nos.11173008,10974202,and 60978049)the National Key Scientific and Research Equipment Development Project of China(Grant No.ZDYZ2013-2)
文摘For the accurate extraction of cavity decay time, a selection of data points is supplemented to the weighted least square method. We derive the expected precision, accuracy and computation cost of this improved method, and examine these performances by simulation. By comparing this method with the nonlinear least square fitting (NLSF) method and the linear regression of the sum (LRS) method in derivations and simulations, we find that this method can achieve the same or even better precision, comparable accuracy, and lower computation cost. We test this method by experimental decay signals. The results are in agreement with the ones obtained from the nonlinear least square fitting method.