During air injection into an oil reservoir,an oxidation reaction generates some heat to raise the reservoir temperature.When the reservoir temperature reaches an ignition temperature,spontaneous ignition occurs.There ...During air injection into an oil reservoir,an oxidation reaction generates some heat to raise the reservoir temperature.When the reservoir temperature reaches an ignition temperature,spontaneous ignition occurs.There is a time delay from the injection to ignition.There are mixed results regarding the feasibility of spontaneous ignition in real-field projects and in laboratory experiments.No analytical model is available in the literature to estimate the oxidation time required to reach spontaneous ignition with heat loss.This paper discusses the feasibility of spontaneous ignition from theoretical points and experimental and field project observations.An analytical model considering heat loss is proposed.Analytical models with and without heat loss investigate the factors that affect spontaneous ignition.Based on the discussion and investigations,we find that it is more difficult for spontaneous ignition to occur in laboratory experiments than in oil reservoirs;spontaneous ignition is strongly affected by the initial reservoir temperature,oil activity,and heat loss;spontaneous ignition is only possible when the initial reservoir temperature is high,the oil oxidation rate is high,and the heat loss is low.展开更多
In the present study, the kinetics of thermal decomposition of hydrated minerals associated in natural hematite iron ores has been investigated in a fixed bed system using isothermal methods of kinetic analysis. Hydra...In the present study, the kinetics of thermal decomposition of hydrated minerals associated in natural hematite iron ores has been investigated in a fixed bed system using isothermal methods of kinetic analysis. Hydrated minerals in these hematite iron ores are kaolinite, gibbsite and goethite, which contribute to the loss on ignition(LOI) during thermal decomposition. Experiments in fixed bed have been carried out at variable bed depth(16, 32, 48 and 64 mm),temperature(400-1200 ℃) and residence time(30,45, 60 and 75 min) for iron ore samples. It is observed that beyond a certain critical bed depth(16 mm), 100% removal of LOI is not found possible even at higher temperature and higher residence time. Most of the solid-state reactions of isothermal kinetic analysis have been used to analyze the reaction mechanism. The raw data are modified to yield fraction reacted "α" versus time and used for developing various forms of "α" functions.f(α) is the inverse of first derivative of g(α) with respect to α. The study demonstrates that decomposition of hydrated mineral in hematite follows the chemical kinetics.The estimated activation energy values in all the experimental situations are found to high, of the order of 60 kJ/mol, reinstating that the reactions are indeed controlled by moving phase boundary and random nucleation.展开更多
Understanding organic matter characteristics （e.g., amount and state） of sediments is necessary for evaluating both the sediment and water environments; however, methods that have been proposed to investigate these ...Understanding organic matter characteristics （e.g., amount and state） of sediments is necessary for evaluating both the sediment and water environments; however, methods that have been proposed to investigate these characteristics are relatively expensive. This study attempted to evaluate the organic matter characteristics of littoral sediments by employing solely the loss on ignition （LOI） method, which is the most economical and accessible method in developing countries. Different types of sediments were first oven dried at 100 ~C and then continuously burned at 200, 300, 400, 500, and 600 ~C for 4 h at each temperature. The mass LOI at each temperature was calculated and compared with the 100 ℃oven-dried weight. Our results suggested that the mass LOI across the temperature range of 200-300 ℃（LOI200-300）：mass LOI at 600 ℃ （LOI600） ratio （LOI200-300/LOI600） could represent different types of sediments as well as the organic matter：organic C ratio. Compared with the sediments unaffected by wastewater, the sediments that were more influenced by the inflow of domestic wastewater had a higher LOI200-300/LOI600. Interestingly, LOI200-300/LOI600 could also represent changes in the organic matter characteristics as a function of organic matter decomposition in sediments. In conclusion, the organic matter characteristics of littoral sediments could be evaluated using solely the LOI method, particularly with LOI200 - 300/LOI600.展开更多
基金supported by the National Natural Science Foundation of China (No.51974334)Hainan Province Science and Technology Special Fund (ZDYF2022SHFZ107)local efficient reform and development funds for personnel training projects supported by the central government,Heilongjiang Postdoctoral Scientific Research Fund (LBH-Q21012)。
文摘During air injection into an oil reservoir,an oxidation reaction generates some heat to raise the reservoir temperature.When the reservoir temperature reaches an ignition temperature,spontaneous ignition occurs.There is a time delay from the injection to ignition.There are mixed results regarding the feasibility of spontaneous ignition in real-field projects and in laboratory experiments.No analytical model is available in the literature to estimate the oxidation time required to reach spontaneous ignition with heat loss.This paper discusses the feasibility of spontaneous ignition from theoretical points and experimental and field project observations.An analytical model considering heat loss is proposed.Analytical models with and without heat loss investigate the factors that affect spontaneous ignition.Based on the discussion and investigations,we find that it is more difficult for spontaneous ignition to occur in laboratory experiments than in oil reservoirs;spontaneous ignition is strongly affected by the initial reservoir temperature,oil activity,and heat loss;spontaneous ignition is only possible when the initial reservoir temperature is high,the oil oxidation rate is high,and the heat loss is low.
基金Ministry of Steel-India,New Delhi for sponsoring the program to carry out the research work
文摘In the present study, the kinetics of thermal decomposition of hydrated minerals associated in natural hematite iron ores has been investigated in a fixed bed system using isothermal methods of kinetic analysis. Hydrated minerals in these hematite iron ores are kaolinite, gibbsite and goethite, which contribute to the loss on ignition(LOI) during thermal decomposition. Experiments in fixed bed have been carried out at variable bed depth(16, 32, 48 and 64 mm),temperature(400-1200 ℃) and residence time(30,45, 60 and 75 min) for iron ore samples. It is observed that beyond a certain critical bed depth(16 mm), 100% removal of LOI is not found possible even at higher temperature and higher residence time. Most of the solid-state reactions of isothermal kinetic analysis have been used to analyze the reaction mechanism. The raw data are modified to yield fraction reacted "α" versus time and used for developing various forms of "α" functions.f(α) is the inverse of first derivative of g(α) with respect to α. The study demonstrates that decomposition of hydrated mineral in hematite follows the chemical kinetics.The estimated activation energy values in all the experimental situations are found to high, of the order of 60 kJ/mol, reinstating that the reactions are indeed controlled by moving phase boundary and random nucleation.
基金the Grantin-Aid for Science Research from the Japan Society for the Promotion of Science (Nos.26820204 and 26630229)
文摘Understanding organic matter characteristics （e.g., amount and state） of sediments is necessary for evaluating both the sediment and water environments; however, methods that have been proposed to investigate these characteristics are relatively expensive. This study attempted to evaluate the organic matter characteristics of littoral sediments by employing solely the loss on ignition （LOI） method, which is the most economical and accessible method in developing countries. Different types of sediments were first oven dried at 100 ~C and then continuously burned at 200, 300, 400, 500, and 600 ~C for 4 h at each temperature. The mass LOI at each temperature was calculated and compared with the 100 ℃oven-dried weight. Our results suggested that the mass LOI across the temperature range of 200-300 ℃（LOI200-300）：mass LOI at 600 ℃ （LOI600） ratio （LOI200-300/LOI600） could represent different types of sediments as well as the organic matter：organic C ratio. Compared with the sediments unaffected by wastewater, the sediments that were more influenced by the inflow of domestic wastewater had a higher LOI200-300/LOI600. Interestingly, LOI200-300/LOI600 could also represent changes in the organic matter characteristics as a function of organic matter decomposition in sediments. In conclusion, the organic matter characteristics of littoral sediments could be evaluated using solely the LOI method, particularly with LOI200 - 300/LOI600.
