Coking and decoking chemistry for resource utilization of polycyclic aromatic hydrocarbons(PAHs)and low-carbon process

Low-carbon process for resource utilization of polycyclic aromatic hydrocarbons(PAHs)in zeolitecatalyzed processes,geared to carbon neutrality-a prominent trend throughout human activities,has been bottlenecked by the lack of a complete mechanistic understanding of coking and decoking chemistry,involving the speciation and molecular evolution of PAHs,the plethora of which causes catalyst deactivation and forces regeneration,rendering significant CO_(2) emission.Herein,by exploiting the high-resolution matrix-assisted laser desorption/ionization Fourier-transform ion cyclotron resonance mass spectrometry(MALDI FT-ICR MS),we unveil the missing fingerprints of the mechanistic pathways for both formation and decomposition of cross-linked cage-passing PAHs for SAPO-34-catalyzed,industrially relevant methanol-to-olefins(MTO)as a model reaction.Notable is the molecule-resolved symmetrical signature:their speciation originates exclusively from the direct coupling of in-cage hydrocarbon pool(HCP)species,whereas water-promoted decomposition of cage-passing PAHs initiates with selective cracking of inter-cage local structures at 8-rings followed by deep aromatic steam reforming.Molecular deciphering the reversibly dynamic evolution trajectory(fate)of full-spectrum aromatic hydrocarbons and fulfilling the real-time quantitative carbon resource footprints advance the fundamental knowledge of deactivation and regeneration phenomena(decay and recovery motifs of autocatalysis)and disclose the underlying mechanisms of especially the chemistry of coking and decoking in zeolite catalysis.The positive yet divergent roles of water in these two processes are disentangled.These unprecedented insights ultimately lead us to a steam regeneration strategy with valuable CO and H_(2) as main products,negligible CO_(2) emission in steam reforming and full catalyst activity recovery,which further proves feasible in other important chemical processes,promising to be a sustainable and potent approach that contributes to carbon-neutral chemical industry.

Lightweight Dual‑Functional Segregated Nanocomposite Foams for Integrated Infrared Stealth and Absorption‑Dominant Electromagnetic Interference Shielding

Lightweight infrared stealth and absorption-dominant electromagnetic interference(EMI)shielding materials are highly desirable in areas of aerospace,weapons,military and wearable electronics.Herein,lightweight and high-efficiency dual-functional segregated nanocomposite foams with microcellular structures are developed for integrated infrared stealth and absorption-dominant EMI shielding via the efficient and scalable supercritical CO_(2)(SC-CO_(2))foaming combined with hydrogen bonding assembly and compression molding strategy.The obtained lightweight segregated nanocomposite foams exhibit superior infrared stealth performances benefitting from the synergistic effect of highly effective thermal insulation and low infrared emissivity,and outstanding absorption-dominant EMI shielding performances attributed to the synchronous construction of microcellular structures and segregated structures.Particularly,the segregated nanocomposite foams present a large radiation temperature reduction of 70.2℃ at the object temperature of 100℃,and a significantly improved EM wave absorptivity/reflectivity(A/R)ratio of 2.15 at an ultralow Ti_(3)C_(2)T_(x) content of 1.7 vol%.Moreover,the segregated nanocomposite foams exhibit outstanding working reliability and stability upon dynamic compression cycles.The results demonstrate that the lightweight and high-efficiency dual-functional segregated nanocomposite foams have excellent potentials for infrared stealth and absorption-dominant EMI shielding applications in aerospace,weapons,military and wearable electronics.

Numerical Study of Air Nozzles on Mild Combustion for Application to Forward Flow Furnace

An attempt was made to extend mild combustion to forward flow furnace, such as the refinery and petrochemical tube furnace. Three dimensional numerical simulation was carried out to study the performance of this furnace. The Eddy Dissipation Concept(EDC) model coupled with the reaction mechanism DRM-19 was used. The prediction showed a good agreement with the measurement. The effect of air nozzle circle(D), air nozzle diameter(d), air nozzle number(N), and air preheating temperature(Tair) on the flow, temperature and species fields, and the CO and NO emissions was investigated. The results indicate that there are four zones in the furnace, viz.: a central jet zone, an ignition zone, a combustion reaction zone, and a flue gas zone, according to the distribution profiles of H_2 CO and OH. The central jet entrains more flue gas in the furnace upstream with an increasing D while the effect of D is negligible in the downstream. The air jet momentum increases with a decreasing d or an increasing Tair, and entrains more flue gas. The effect of N is mainly identified near the burner exit. More heat is absorbed in the radiant section and less heat is discharged to the atmosphere with a decreasing d and an increasing N as evidenced by the flue gas temperature. The CO and NO emissions are less than 50 μL/L and 10 μL/L, respectively, in most of conditions.

Research of Environment-friendly Low Emissivity Glass

The environment-friendly glasses which integrate function and structure were introduced, among these glasses can save energy very efficiently due to its low infrared emissivity. The fundamental principle of the low emissivity glass and the research progress of this kind glass were analyzed. Meanwhile, high performance and low applied development trend of emissivity glass were reviewed.

Fundamental investigations for lowering emissions and improving operability

This paper first highlights recent developments in lean direct injection(LDI)combustion technology.In view of the needs and opportunities to lower emissions and expand the operability range of LDI,fundamental research has been undertaken to elucidate the effects of air swirler vane angle,air swirler rotation direction,and overall equivalence ratio on the LDI flow field and flame structure/response.Moreover,additional investigation has been conducted to understand the fundamental differences between representative LDI and airblast injectors in order to highlight the importance of the flare feature to LDI venturi geometry.The results of these fundamental studies are discussed to help identify possible areas for optimization to generic LDI designs that may improve individual swirler performance.

Effects of Doubled_CO_2 Concentration on Ultrastructure, Supramolecular Architecture and Spectral Characteristics of Chloroplasts from Wheat

Wheat ( Triticum aestivum L.) plants were grown under ambient and doubled_CO 2(plus 350 μL/L) concentration in cylindrical open_top chamber to examine their effects on the ultrastructure, supramolecular architecture, absorption spectrum and low temperature (77 K) fluorescence emission spectrum of the chloroplasts from wheat leaves. The results were briefly summarized as follows: (1) The wheat leaves possessed normally developed chloroplasts with intact grana and stroma thylakoid membranes; The grana intertwined with stroma thylakoid membranes and increased slightly in stacking degree and the width of granum, in spite of more accumulated starch grains within the chloroplasts than those in control; (2) The particle density in the stacked region of the endoplasmic fracture face (EFs) and protoplasmic fracture face (PFs) and in the unstacked region the endoplasmic fracture face (EFu) and the protoplasmic fracture face (PFu) was significantly higher than that of control. Furthermore, in some cases many more particles on EFs faces of thylakoid membranes appeared as a paracrystalline particle array; (3) The variations in the structure of chloroplasts were consistent with the absorption spectra and the low temperature (77 K) fluorescence emission spectra of the chloroplasts developed under the doubled_CO 2 concentration. Results indicate that the capability of light energy absorption of chloroplasts and regulative capability of excitation energy distribution between PSⅡ and PSⅠ were raised by doubled_CO 2 concentration. This is very favorable for final productivity of wheat.

Design and Development of High Efficiency 150 kW Very Compact PLA Core Electromagnetic Coupler for Highly Resonant Power Transfer Technology

Highly Resonant Power Transfer (HRPT) technology is currently receiving very significant attention from the industry and the smart power grid distribution community in particular. This technology ensures electrical power transmission between two points while controlling the level of transmitted power and ensures the immediate shutdown of the transmitted power in the event of a problem. This paper reviews the inductive power transfer method and describes the design of an ultra-compact PLA core electromagnetic coupler. The proposed architecture confines the magnetic field in a toroidal PLA core transformer, and by avoiding the use of heavy and bulky shielding plates, reduces magnetic losses and avoids the Curie point. As a result, the overall unit has a weight of 5 kg and a volume of only 0.013 m3. The electromagnetic coupler is capable of transferring a peak power of 150 kW with an operating frequency of 193 kHz, giving a satisfactory efficiency of 95%. The proposed novel system was first investigated through CST 3D numerical modelling to determine the electrical parameters of the coupler’s equivalent circuit and its efficiency, to verify its compatibility with the ICNIRP 2010 standard and to evaluate its temperature rise with an air-cooling system. Afterwards, the designed coupler was built with a 3D printing device and finally tested experimentally. Simulation and experimental results are compared and show a good agreement.

COMPOSITIVE EMISSION CONTROL SYSTEM OF GASOLINE VEHICLE

The working principle of a kind of compositive emission control system is inquired into, which includes exhaust heater, secondary air supplement, exhaust gas recirculation （EGR）, thermal reactor and catalytic converter, etc. The purification effect of CO, HC and NOx emission of the gasoline spark ignite （S.I.） engine is studied. The entire vehicle driving cycle tests based on the national emission standard and a series of the gasoline engine-testing bench tests including full load characteristic experiment, load characteristic experiment and idle speed experiment are done. The results show that the system has a very good emission control effect to CO, HC and NOx of gasoline engine. The construction of the system is very simple and can be mounted on the exhaust pipe conveniently without any alteration of the vehicle-use gasoline engine.

Development of high intensity low emission combustor for achieving flameless combustion ofliquid fuels

This paper presents the experimental and numerical results for a two stagecombustor capable of achieving flameless combustion with liquid fuels for different thermalheat inputs of 20,30,40 and 60 kW and heat release density of 5-15 MW/m^(3).Combustioncharacteristics and pollutant emissions are studied for three different fuels,kerosene,diesel andgasoline.The influence of droplet diameter on pollutant emissions at all conditions is studied.The fuel and oxidizer are supplied at ambient conditions.The concept of high swirl flows hasbeen adopted to achieve high intemal recirculation rates,residence time and increased dilutionof the fresh reactants in the primary combustion zone,resulting in flameless combustion mode.Air is injected through four tangential injection ports located near the bottom of the combustorand liquid fuel is injected through a centrally mounted pressure swirl injector.Computationalanalysis of the flow features shows that decrease in the exit port diameter of the primarychamber increases the recirculation rate of combustion products and helps in achieving theflameless combustion mode.Based on preliminary computational studies,a 30 mm primarychamber exit pont diameter is chosen for experimental studies.Detailed experimentalinvestigations show that flameless combustion mode was achieved with evenly distributedcombustion reaction zone and unifom temperature distribution in the combustor.Pollutant emissions of CO, NO_(x),C_(x)H_(y) are measured and compared for all operating conditions ofdifferent fuels and different thermal inputs. The acoustic emission levels are reduced by6-8 dB as combustion mode shifts from conventional mode to flameless combustion mode.

Lubricating a bright future:Lubrication contribution to energy saving and low carbon emission

Both the academic society and the industry are hunting for new energy forms for the future.However,the world should not forget the conventional technologies that contribute to the sustainable society by technical innovations.Among them,lubrication plays a significant role in energy saving and in low CO2emission by increasing the fuel efficiency and by prolonging the service life of machines.With the advance of novel synthetic approaches,and nanoscience and technologies,novel lubrication oils and additives and their formulations are being developed to reduce friction and wear,and novel surface treatment routes and surface coatings are invented and provide more efficient lubrication.These technologies create tremendous chances for machines to work more efficiently with low energy consumption.Here we review the recent progresses and challenges associated with some novel lubrication techniques that include novel surface treatment(such as texturing,high-performance nanocomposite coatings,adapting coating),tribology design(solid and liquid lubrication),energy-conserving engine oil and novel lubricants and formula(such as ionic liquids,low S,P content additives)which are to be adopted to enhance the fuel efficiency to achieve energy saving and low carbon emission.There is increased demand to replace fossil lubricants by degradable green lubricants.Specially designed coatings can reduce drag significantly during navigation of both airplanes and ships.All these aspects will be also reviewed in the paper.

CFD Study of NO_x Emissions in a Model Commercial Aircraft Engine Combustor

Air worthiness requirements of the aircraft engine emission bring new challenges to the combustor research and design. With the motivation to design high performance and clean combustor, computational fluid dynamics （CFD） is utilized as the powerful design approach. In this paper, Reynolds averaged Navier-Stokes （RANS） equations of reactive two-phase flow in an experimental low emission combustor is performed. The numerical approach uses an implicit compressible gas solver together with a Lagrangian liquid-phase tracking method and the extended coherent flamelet model for turbulence-combustion interaction. The NOx formation is modeled by the concept of post-processing, which resolves the NOx transport equation with the assumption of frozen temperature distribution. Both turbulence-combustion interaction model and NOx formation model are firstly evaluated by the comparison of experimental data published in open literature of a lean direct injection （LDI） combustor. The test rig studied in this paper is called low emission stirred swirl （LESS） combustor, which is a two-stage model combustor, fueled with liquid kerosene （RP-3） and designed by Beihang University （BUAA）. The main stage of LESS combustor employs the principle of lean prevaporized and premixed （LPP） concept to reduce pollutant, and the pilot stage depends on a diffusion flame for flame stabili-zation. Detailed numerical results including species distribution, turbulence performance and burning performance are qualita-tively and quantitatively evaluated. Numerical prediction of NOx emission shows a good agreement with test data at both idle condition and full power condition of LESS combustor. Preliminary results of the flame structure are shown in this paper. The flame stabilization mechanism and NOx reduction effort are also discussed with in-depth analysis.

Electroless plating of copper layer on surfaces of urea-formaldehyde microcapsule particles containing paraffin for low infrared emissivity

A copper coating was deposited by electroless plating on the surfaces of urea-formaldehyde microcap- sules containing paraffin （UFP） particles. This composite microcapsule structure had low infrared OR） emissivity and maintained a constant temperature, and could be used in IR stealth applications. The eiectroless copper layer formation and its micro-appearance, and the effect of the copper layer on the IR emissivity and thermal properties of the composite microcapsules were investigated. The IR emissivity of the composite microcapsules at wavelengths of 1-14 μm gradually decreased with increasing copper mass on the surface. After formation of an integrated copper layer, the rate of IR emissivity decrease was lower. This is because the copper coating improves the surface conductivity of the UFP; a high conductivity results in high reflectivity, which leads to a decrease in IR emissivity. The lowest IR emissivity achieved was 0.68. The phase-change enthalpy of the composite microcapsules decreased with increasing amount of copper coated on the surface because of the high density of copper. When the mass increase of the UFP after electroless copper plating was about 300%, the composite microcapsules had low IR emissivity （about 0.8） and a high phase-change enthalpy （80J/g）.

Research on low emission MSW gasification and melting system

In order to eliminate secondary pollution caused by municipal solid waste(MSW)incineration,a MSW gasification and melting process is proposed.The process is expected to reduce the emission of pollutants,especially heavy-metals and dioxins.In this paper,the combustible components of MSW and simulated MSW were gasified in a lab-scale fluidized bed at 400°C-700°C when the excess air ratio(ER)was between 0.2 and 0.8.The experimental results indicated that the MSW could be gasified effectively in a fluidized bed at approximately 600°C-700°C when excess air ratio was 0.2-0.4.The melting characteristics of two typical fly ash samples from MSW incinerators were investigated.The results indicated that fly ash of pure MSW incineration could be melted at approximately 1,300°C and that of MSW and coal co-combustion could be melted at approximately 1,400°C.When temperature was over 1,100°C,more than 99.9%of the dioxins could be decomposed and most of the heavy-metals could be solidified in the slag.Based on the above experiments,two feasible MSW gasification and mel-ting processes were proposed for low calorific value MSW:(1)sieved MSW gasification and melting system,which was based on an idea of multi-recycle;(2)gasification and melting scheme of MSW adding coal as assistant fuel.

Preparation and Characterization of Sn-doped ZnO Particles with Low Infrared Emissivity

Sn-doped ZnO particles were successfully synthesized by chemical co-precipitation method.Their morphology,phase,microstructure and infrared emissivity were characterized.The results show that the Sn-doped ZnO particles are of ellipsoid shape,their crystalline structure changed with thermal process temperature,the optimal thermal process temperature and Sn-doped proportion are 1000℃ and 15%,respectively,the minimum emissivity values are 0.42,0.28,0.46 and 0.48 corresponding to the infrared wavelengths of 0~∞,3~5,8~14 and 14~20 μm,which indicates that the Sn-doped ZnO particles have the application potential as low infrared emissivity material.

Effects of diluted methanol and water as foaming agents on the performance of latex foamed warm asphalt mixtures

Latex as an asphalt modifier has gained popularity in the asphalt industry as it improves the durability of asphalt pavement.However,the elastomeric properties of latex stiffen the asphalt binders,resulting in additional energy consumption during the production of asphalt mixtures,which may cause a higher emission of greenhouse gases.This is undesirable for sustainable development and the environment.In this study,the applicability of diluted methanol and water was comparatively evaluated as foaming agents in the production of warm mix asphalt(WMA)mixtures incorporating latex.Diluted methanol was used because it has a lower boiling point and latent heat than water,allowing the asphalt mixture to be produced at a lower temperature and thus consuming less energy.The performance of the foamed asphalt mixture was investigated through service characteristics,mechanical performance,and moisture susceptibility of mixtures.The service characteristics,on the other hand,were measured in a laboratory while preparing and compacting the asphalt mixture,which refers to the amount of energy required during the production and construction stages in the asphalt plant and on the construction site,respectively.The degree of energy required was assessed based on the workability index,coatability index,and the compaction energy index.The mechanical performance of asphalt mixtures was characterized by indirect tensile strength,resilient modulus,and dynamic creep tests.The resistance to moisture damage was evaluated based on the common parameter,indirect tensile strength ratio.The findings revealed that the use of diluted methanol foaming agent helped improve the workability of latex modified asphalt mixtures.The foamed latex-modified WMA demonstrated better performance compared to asphalt mixtures prepared using water as the foaming agent.

Visible transparent,infrared stealthy polymeric films with nanocoating of ITO@MXene enable efficient passive radiative heating and solar/electric thermal conversion

Visible transparent yet low infrared-emissivity(ε)polymeric materials are highly anticipated in many applications,whereas the fabrication of which remains a formidable challenge.Herein,visible transparent,flexible,and low-εpolymeric films were fabricated by nanocoating decoration of indium tin oxide(ITO)and MXene on polyethylene terephthalate(PET)film surface through magnetron sputtering and spray coating,respectively.The obtained PET-ITO@MXene(PET-IM)film exhibits lowεof 24.7%and high visible transmittance exceeding 50%,endowing it with excellent visible transparent infrared stealthy by reducing human skin radiation temperature from 32 to 20.8°C,and remarkable zero-energy passive radiative heating capability(5.7°C).Meanwhile,the transparent low-εPET-IM film has high solar absorptivity and electrical conductivity,enabling superior solar/electric to thermal conversion performance.Notably,the three heating modes of passive radiative and active solar/electric can be integrated together to cope with complex heating scenarios.These visible transparent low-εpolymeric films are highly promising in infrared stealth,building daylighting and thermal management,and personal precision heating.

Optical transparent metamaterial structure for microwave-infrared-compatible camouflage based on indium tin oxide

A visible transparent metamaterial absorber was designed and fabricated with ultrabroadband microwave absorption and low infrared emissivity to meet the increasing demand for multispectral compatible camouflage. The absorber was fabricated with a low-infrared emissive layer at the top, a microwave-absorbing layer in the middle, and a reflective layer at the bottom, which were separated by polymethyl methacrylate plates. The absorber showed an average visible transmittance of 55%, infrared emissivity of ~0.37, and effective microwave absorption bandwidth of 32.1 GHz with a total thickness of 3.0 mm. Furthermore,microwave absorption exhibited wide-angle stability and polarization insensitivity characteristics. The mechanism of microwave attenuation was further explored through effective electromagnetic parameters as well as surface current, electric field, magnetic field, and energy loss density distributions. The experimental results were consistent with those of the simulations and calculations, indicating the potential of the designed metamaterial absorber for future applications in multispectral compatible camouflage.

Experimental and numerical studies of a lean-burn internally-staged combustor

A lean-burn internally-staged combustor for low emissions that can be used in civil avi-ation gas turbines is introduced in this paper. The main stage is designed and optimized in terms of fuel evaporation ratio, fuel/air pre-mixture uniformity, and particle residence time using commer-cial computational fluid dynamics （CFD） software. A single-module rectangular combustor is adopted in performance tests including lean ignition, lean blowout, combustion efficiency, emis-sions, and combustion oscillation using aviation kerosene. Furthermore, nitrogen oxides （NOx） emission is also predicted using CFD simulation to compare with test results. Under normal inlet temperature, this combustor can be ignited easily with normal and negative inlet pressures. The lean blowout fuel/air ratio （LBO FAR） at the idle condition is 0.0049. The fuel split proportions between the pilot and main stages are determined through balancing emissions, combustion efficiency, and combustion oscillation. Within the landing and take-off （LTO） cycle, this combustor enables 42%NOx reduction of the standard set by the 6th Committee on Aviation Environmental Protection （CAEP/6） with high combustion efficiency. The maximum board-band pressure oscillations of inlet air and fuel are below 1%of total pressure during steady-state operations at the LTO cycle specific conditions.

Experimental Investigation of Dynamic and Emission Characteristics of a DLE Gas Turbine Combustor

The DLE (dry low emission) technology has already been used on industrial gas turbine combustor and the NO X emission can be limited to 25 ppmv (@15% O 2 ), but one of the destructive effects is combustion instability. In this paper, the dynamic and emission characteristics of a DLE gas turbine combustor have been researched in the authors' laboratory, and the results show that the key source of combustion instability is the non-uniformity of fuel in the flame zone. Two main fuel supply methods have been used to form different fuel distribution types; it is shown that in the perfectly premixed case the emission level is low and combustion process is stable. The PPF also has an obvious effect on the combustor's emission and dynamic characteristics.

Atmospheric Test and Numerical Models Assessment of Annular Combustor on ZK2000 Gas Turbine

ZK2000 is a newly developed 2 MW all radial gas turbine with an annular combustor. In this paper, the authors present the atmospheric test results of the combustor on test rig. Evaluation of several RANS turbulence models and reaction models were used in order to determine which model was the most appropriate combination for comparison with the test results. FGM with SST were selected because of the better agreement with test results in terms of combustor temperature rise, primary zone temperature, liner metal temperature, and NO_x emission predictions.