Through exploring the effects of low pH on the composite system of desulfurization gypsum(DG)enhanced by melamine-formaldehyde resin(MF),it is found that the inducing of sulfate-ion,in contrast to chloride and oxalate...Through exploring the effects of low pH on the composite system of desulfurization gypsum(DG)enhanced by melamine-formaldehyde resin(MF),it is found that the inducing of sulfate-ion,in contrast to chloride and oxalate ions,favors the longitudinal growth of the crystalline form of the hydration product,which was relatively simple and had the highest length to width(L/D)ratio.At the same time,MF can also improve L/D ratio of gypsum hydration products,which favors the formation of hydrated whiskers.Finally,in a composite system composed of hemihydrate gypsum,MF,and glass fibers,when dilute sulfuric acid was used to regulate pH=3-4,the tight binding formed among the components of the composite system compared to pH=5-6.The hydration product of gypsum adheres tightly to glass fiber surface and produces a good cross-linking and binding effect with MF.The flexural strength,compressive strength,elastic modulus,and water absorption of the desulphurized gypsum composite board is 22.7 MPa,39.8 MPa,5608 MPa,and 1.8%,respectively.展开更多
TSV（through silicon via） is an emerging technology, which can realize micromation compared with the conventional packaging and extend Moore＇s law. Chemical mechanical polishing（CMP） is one of the most important s...TSV（through silicon via） is an emerging technology, which can realize micromation compared with the conventional packaging and extend Moore＇s law. Chemical mechanical polishing（CMP） is one of the most important steps in the process of TSV manufacture, and it is an enabling technology to extend Moore＇s law in the past two decades. Low pressure, low abrasive and low p H value are the main requirements for copper interconnection.In this paper, the effect of different kinds of TSV slurry with FA/OⅡ or FA/O IV type chelating agent on CMP are studied. All kinds of slurry used in this study are alkaline with no added inhibitors. From the experiment results, it can be seen that the copper removal rate and surface roughness achieved by using the FA/OⅣ type chelating agent with a low p H value is superior to using the FA/OⅡ type chelating agent.展开更多
文摘Through exploring the effects of low pH on the composite system of desulfurization gypsum(DG)enhanced by melamine-formaldehyde resin(MF),it is found that the inducing of sulfate-ion,in contrast to chloride and oxalate ions,favors the longitudinal growth of the crystalline form of the hydration product,which was relatively simple and had the highest length to width(L/D)ratio.At the same time,MF can also improve L/D ratio of gypsum hydration products,which favors the formation of hydrated whiskers.Finally,in a composite system composed of hemihydrate gypsum,MF,and glass fibers,when dilute sulfuric acid was used to regulate pH=3-4,the tight binding formed among the components of the composite system compared to pH=5-6.The hydration product of gypsum adheres tightly to glass fiber surface and produces a good cross-linking and binding effect with MF.The flexural strength,compressive strength,elastic modulus,and water absorption of the desulphurized gypsum composite board is 22.7 MPa,39.8 MPa,5608 MPa,and 1.8%,respectively.
基金supported by the Major National Science and Technology Special Projects(No.2009ZX02308)the Fund Project of Hebei Provincial Department of Education,China(No.QN2014208)+1 种基金the Natural Science Foundation of Hebei Province,China(No.E2013202247)the Colleges and Universities Scientific Research Project of Hebei Province,China(No.Z2014088)
文摘TSV（through silicon via） is an emerging technology, which can realize micromation compared with the conventional packaging and extend Moore＇s law. Chemical mechanical polishing（CMP） is one of the most important steps in the process of TSV manufacture, and it is an enabling technology to extend Moore＇s law in the past two decades. Low pressure, low abrasive and low p H value are the main requirements for copper interconnection.In this paper, the effect of different kinds of TSV slurry with FA/OⅡ or FA/O IV type chelating agent on CMP are studied. All kinds of slurry used in this study are alkaline with no added inhibitors. From the experiment results, it can be seen that the copper removal rate and surface roughness achieved by using the FA/OⅣ type chelating agent with a low p H value is superior to using the FA/OⅡ type chelating agent.
