Structures and Low Temperature Magnetic Anomalies of High Pressure RE_2CuO_4

A series of oxygen-doped RE_2CuO_4 (RE=Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm) was synthesized using high-pressure/oxygen-doped technique. The structures and low temperature magnetic properties were investigated. The XRD patterns indicate that the structures of high oxygen pressure RE_2CuO_4 (only for RE=Sm, Eu) samples are pure T′ phase, but when RE= Gd, Tb, Dy, Ho, Er, Tm, the structures turn to disorder. The magnetic anomalies that occurred at T^30 K are observed in high oxygen pressure RE_2CuO_4. It is found that the transition temperatures of weak ferromagnetic anomalies are nearly independent of the rare-earth components. Thus, the O-doping plays an important role in anomalous magnetic properties of RE_2CuO_(4+δ). The magnetic anomalies in RE_2CuO_4 are considered to be due to ferromagnetic clusters formed in the Cu-O plane after the oxygen doping.

Advanced high-pressure transport measurement system integrated with low temperature and magnetic field

We briefly introduce a new high-pressure transport measurement system integrated with low temperature and magnetic field that is being established as one of the user experimental stations of the Synergetic Extreme Condition User Facilities in the Huairou District of Beijing, China. To demonstrate the capabilities of the system for condensed matter research, the emergence of some pressure-induced phenomena and physics related to superconductivity found previously is also introduced, and then a perspective for such an advanced high-pressure system is presented.

Pressure-Induced Metallization and Electrical Phase Diagram for Polycrystalline CaB_6 under High Pressure and Low Temperature

The electrical properties of polycrystaltine CaB6 are revealed by in-situ resistance measurements under high pressure and low temperature. Due to the existence of grain boundaries, polycrystalline CaB6 behaves with semiconducting transport properties, which is different from the semimetallic CaB6 single crystals. The temperaturedependent resistance measurement results show that before the structural phase transition at 12.3 GPa the high pressure first induces the metallization at 6.5 GPa for CAB6. Moreover, the phase diagram for CaB6 is drawn based on the investigated electric conducting properties and at least three different conducting phases are found even at moderate high pressure and low temperature, indicating that the electric nature of CaB6 is very sensitive to the environment.

Polycrystalline cubic boron nitride prepared with cubic-hexagonal boron nitride under high pressure and high temperature

Polycrystalline cubic boron nitride(Pc BN)compacts,using the mixture of submicron cubic boron nitride(c BN)powder and hexagonal BN(h BN)powder as starting materials,were sintered at pressures of 6.5–10.0 GPa and temperature of1750℃without additives.In this paper,the sintering behavior and mechanical properties of samples were investigated.The XRD patterns of samples reveal that single cubic phase was observed when the sintering pressure exceeded 7.5 GPa and h BN contents ranged from 20 vol.%to 24 vol.%,which is ascribed to like-internal pressure generated at grain-to-grain contact under high pressure.Transmission electron microscopy(TEM)analysis shows that after high pressure and high temperature(HPHT)treatments,the submicron c BN grains abounded with high-density nanotwins and stacking faults,and this contributed to the outstanding mechanical properties of Pc BN.The pure bulk Pc BN that was obtained at 7.7 GPa/1750℃possessed the outstanding properties,including a high Vickers hardness(~61.5 GPa),thermal stability(~1290℃in air),and high density(~3.46 g/cm^(3)).

Characterization of diamond MWCNTs composite fiber synthesized under high pressure and high temperature

A regrown composite fiber was synthesized during the sintering of diamond under high pressure 5.8 GPa and high temperature 1500℃for 1 min,using 3wt%MWCNTs as additive.SEM observation of the fiber after alkali and acid treatment revealed that the outer layer of the fiber is composed of nano-polycrystalline diamond.EDS,XPS,XRD and Raman spectrum analysis further identified that the fiber is composed of MWCNTs in the inner part and nano-polycrystalline diamond in the out layer.It is proposed that the untransformed MWCNTs may act as a template for the regrown outer layer of nano diamond fiber under high pressure and high temperature.

Practice and Cognition of Midway VSP in High Temperature and High Pressure Field of South China Sea

Ying-Qiong Basin is a typical high-temperature and overpressure basin, which is the main battlefield of oil and gas exploration in South China Sea and has made great breakthroughs in recent years. During drilling process in high pressure, the relationship between the deep and the pressure is directly related to the drilling safety and costs. In order to improve prediction accuracy, the VSP operation is carried out through the midway, and three points have been obtained: 1) The VSP has a higher accuracy of the interface depth in certain depth range of the drill bit. 2) When the low-frequency trend prediction is accurate before the drill bit, interval velocity of the VSP inversion is consistent with the formation velocity. 3) The VSP pressure forecast is based on the inversion layer velocity and under-compaction pressure. If the velocity prediction is not accurate, the pressure forecast must be erroneous. If the pressure has other sources, the formation pressure is not accurate even if the inversion velocity is accurate. The application scope and exploration effect of midway VSP operation are summarized and applied to Ledong 10-1 block in Yinggehai basin, which realize the breakthrough in the field of high temperature overpressure and provide the basis for other similar exploration areas to do VSP operation.

Study of high pressure sintering behavior of CBN composites starting with CBN-Al mixtures

Cubic boron nitride(CBN) composites starting with CBN-Al mixtures were sintered on WC-16 wt%Co substrate under static high pressure of 5.0 GPa at temperatures of 800 to 1 400℃for 30 min.Vickers hardness of the sintered samples increased with increasing CBN content and the highest hardness of 32.7 GPa was achieved for the CBN-5 wt%Al specimens sintered at 1 400℃.The reactions between CBN and Al started to occur at about 900℃and the reaction products strongly depended on the Al content,sintering temperature and Co diffused from the substrates according to the x-ray diffraction(XRD) observations.The CBN composite sintered at 1 200℃from a CBN-15 wt%Al mixture showed the best cutting performance.

Interannual and Interdecadal Variability of East Asian Acas and Their Impact on Temperature of China in Winter Season for the Last Century

The interannual and interdecadal varinbility of the Siberian High (SH) and the Aleutian Low (AL) from aspects of strength and location for the past one hundred years as well as their possible relations with temperature changes over China's Mainland are investigated. The data sets used are the historical sea level pressure for 1871-1995 and surface air temperature (SAT) over China in the last 100 years. The results show that the SAT in different regions over China, central strength of the SH and the AL, the south-reaching latitude of the 1030 hPa contour of the SH and the pressure gradient between the SH and the AL experienced two obvious changes during this period. One occurred in the 1920s, with a more prominent one in the 1980s. These variations are closely linked with the change of winter temperature over China in the interdecadal timescale. In the last 50 years, there is a remarkable interannual correlation between the strength of Active Centers of Atmosphere (Acas) and the winter temperature of northern and eastern regions in China. The abrupt change of Acas in the 1980s is consistent with the rising of the SAT in China. Since the late 1980s, the atmospheric circulation is experiencing a remarkable modulation, which may cause the interdecadal transition of warming trend.

Microstructure and Electrical Properties of Er_2O_3-Doped ZnO-Based Varistor Ceramics Prepared by High-Energy Ball Milling

The microstructure, electrical properties and density of ZnO-based varistor ceramics with different Er2O3 content prepared by high-energy ball milling （HEBM） and sintered at 800℃ were investigated. With increasing Er2O3 content, the ZnO grain size decreases due to the Er-rich phases inhibiting grain growth ; and nonlinear coefficient （ α ） decreases because of the decrease of barrier height （φB） The breakdown voltage （Eb） and density increase, whereas leakage current （IL） decreases with increasing Er2O3 content. The barrier height （φB）, donor concentration （Nd）, density of interface states （Ns） decrease and barrier width （ω） increases with increasing Er2O3 content due to acceptor effect of Er2O3 in varistor ceramics.

Resistivity response to the porosity and permeability of low rank coal

Laojunmiao coal samples from the eastern Junggar basin were studied to understand the relationship between coal resistivity and the physical parameters of coal reservoirs under high temperatures and pressures.Specifically,we analysed the relationship of coal resistivity to porosity and permeability via heating and pressurization experiments.The results indicated that coal resistivity decreases exponentially with increasing pressure.Increasing the temperature decreases the resistivity.The sensitivity of coal resistivity to the confining pressure is worse when the temperature is higher.The resistivity of dry coal samples was linearly related to φ~m.Increasing the temperature decreased the cementation exponent(m).Increasing the confining pressure exponentially decreases the porosity.Decreasing the pressure increases the resistivity and porosity for a constant temperature.Increasing the temperature yields a quadratic relationship between the resistivity and permeability for a constant confining pressure.Based on the Archie formula,we obtained the coupling relationship between coal resistivity and permeability for Laojunmiao coal samples at different temperatures and confining pressures.

Microstructure and electrical properties of Y_2O_3-doped ZnO-based varistor ceramics prepared by high-energy ball milling

Y2O3-doped ZnO-based varistor ceramics were prepared using high-energy ball milling （HEBM） and low-temperature sin- tering technique, with voltage-gradient of 1934-2197 V/mm, non-linear coefficients of 20.8-21.8, leakage currents of 0.59-1.04 μA, and densities of 5.46-5.57 g/cm3. With increasing Y2O3 content, the voltage-gradient increases because of the decrease of ZnO grain size; the non-linear coefficient and the leakage current improve but the density decreases because of more porosity; the donor con- centration and density of interface states decrease, whereas the barrier height and width increase because of the acceptor effect of Y2O3 in varistor ceramics.

Microstructure refinement and second phase particle regulation of Mo-Y_(2)O_(3) alloys by minor TiC additive

The oxide dispersion strengthened Mo alloys(ODS-Mo)prepared by traditional ball milling and subsequent sintering technique generally possess comparatively coarse Mo grains and large oxide particles at Mo grain boundaries(GBs),which obviously suppress the corresponding strengthening effect of oxide addition.In this work,the Y_(2)O_(3) and TiC particles were simultaneously doped into Mo alloys using ball-milling and subsequent low temperature sintering.Accompanied by TiC addition,the Mo-Y_(2)O_(3) grains are sharply refined from 3.12 to 1.36μm.In particular,Y_(2)O_(3) and TiC can form smaller Y-Ti-O-C quaternary phase particles(~230 nm)at Mo GBs compared to single Y_(2)O_(3) particles(~420 nm),so as to these new formed Y-Ti-O-C particles can more effectively pin and hinder GBs movement.In addition to Y-Ti-O-C particles at GBs,Y_(2)O_(3),TiOx,and TiCx nanoparticles(<100 nm)also exist within Mo grains,which is significantly different from traditional ODS-Mo.The appearance of TiOx phase indicates that some active Ti within TiC can adsorb oxygen impurities of Mo matrix to form a new strengthening phase,thus strengthening and purifying Mo matrix.Furthermore,the pure Mo,Mo-Y_(2)O_(3),and Mo-Y_(2)O_(3)-TiC alloys have similar relative densities(97.4%-98.0%).More importantly,the Mo-Y_(2)O_(3)-TiC alloys exhibit higher hardness(HV0.2(425±25))compared to Mo-Y_(2)O_(3) alloys(HV0.2(370±25)).This work could provide a relevant strategy for the preparation of ultrafine Mo alloys by facile ball-milling.

Partial Melting and Its Implications for Understanding the Seismic Velocity Structure within the Southern Tibetan Crust

In order to constrain the crustal wave velocity structure in the southernTibetan crust and provide insight into the contribution of crustal composition, geothermal gradientand partial melting to the velocity structure, which is characterized by low average crustalvelocities and widespread presence of low-velocity zone(s), the authors model the crustal velocityand density as functions of depth corresponding to various heat flow values in light of velocitymeasurements at high temperature and high pressure. The modeled velocity and density are regarded ascomparison standards. The comparison of the standards with seismic observations in southern Tibetimplies that the predominantly felsic composition at high heat flow cannot explain the observedvelocity structure there. Hence, the authors are in favor of attributing low average crustalvelocities and low-velocity zone(s) observed in southern Tibet mainly to partial melting. Modelingbased on the experimental results suggests that a melting percentage of 7-12 could account for thelow-velocity zone(s).

Effects of cooling rate on the microstructure and electrical properties of Dy_2O_3-doped ZnO-based varistor ceramics

The microstructure, electrical properties, and density of Dy2O3-doped ZnO-based varistor ceramics, prepared using high-energy ball milling （HEBM） and sintered at 800℃, were investigated by increasing the cooling rate in the order of H （slow cooling in furnace） → L （cooling in furnace） → K （cooling in air）. With the increase in cooling rate, the grain size and density decreased, the breakdown voltage （VImA/mm） increased, and the nonlinear coefficient （α） and leakage current （IL） exhibited extremum. The sample with the cooling type L showed the best properties with the breakdown voltage of 2650 V/ram, o：of 20.3, IL of 5.2 laA, and density of 5.42 g/cm^3. The barrier height （ФB）, donor concentration （Nd）, density of the interface states （Nd）, and barrier width （ω） all exhibited extremum during the alteration in cooling rate. The different relative amount of Bi-rich phase and its distribution as well as the characteristic parameters of grain boundary, resulting from the alteration of cooling rate, led to the changes in the properties of varistor ceramics.

基于压力衰减法的低渗透储层高温敏感性评价实验

低渗透油气藏在钻完井过程中易受到损害且难以解除,而利用传统的稳态驱替法评价低渗透储层损害存在适用性差及实验效率低等技术局限。为此,基于压力脉冲衰减法基本原理,分析了上游压力衰减规律及其与岩心渗透率的关系,以岩心损害前后压力脉冲衰减时间为评价指标,建立了适用于低渗透储层损害评价的实验设备与方法,并利用渤海湾盆地渤中凹陷深部低渗透砂岩岩心,开展了室温和150℃高温条件下的敏感性实验。研究结果表明:(1)当实验条件一定时,压力衰减时间仅与岩心的渗透率有关,压力脉冲衰减法可在无需计算渗透率的情况下对低渗透岩心的损害程度进行评价;(2)实验设备组成简单且操作便捷,避免了复杂的渗透率计算及其带来的误差,实验所需时间远低于常规的稳态法且可重复性良好,在低渗透气藏、特低渗透及超低渗透油藏具有很好的适用性;(3)高温环境明显加剧了储层的敏感性损害,深部高温储层损害特征及技术对策研究需要充分考虑高温的影响。结论认为,该认识解决了传统低渗透储层敏感性评价方法适用性差的难题,为高温低渗透储层保护技术对策研究提供了实验方法支撑和理论依据。

Mo_(2)C-TiN_(0.3)复合材料的高温高压制备及性能

将Mo_(2)C和TiN_(0.3)粉体采用机械合金化和高温高压烧结相结合的方法进行分层烧结,并制备30%Mo_(2)C-70%TiN_(0.3)的烧结体复合材料,分析Mo_(2)C-TiN_(0.3)烧结体的物相组成、微观组织结构及力学性能。结果表明:Mo_(2)C和TiN_(0.3)间存在明显的相互扩散,且形成了2层不同的扩散层;随着烧结温度不断升高,Mo_(2)C-TiN_(0.3)烧结体的晶粒尺寸逐渐变大,会导致烧结体的机械性能变差;在烧结过程中有高硬高脆的MoC生成,能够维持Mo_(2)C-TiN_(0.3)烧结体的硬度在19.0~20.0 GPa,但会降低其断裂韧性。

高低温对碳纤维/环氧树脂复合材料高压气瓶的性能影响

为了获得T1000碳纤维/环氧树脂复合材料高压气瓶环境适应能力,有效地掌握气瓶高低温适应性固有规律,以容积50 L、工作压力30 MPa的复合材料气瓶(钛为内衬、碳纤维/环氧树脂为复合层)为研究对象,首先介绍了高低温循环下带压气瓶(在-40~80℃范围内成功通过热真空、热循环验证,具备高压承载能力)的热真空、热循环试验数据,然后采用与气瓶相同复合材料的拉伸试样(缠绕角分别为0°和90°),通过高低温极限摸底试验获得了复合材料经历不同梯度高低温后的拉伸性能数据,通过数据比对分析获得了高低温影响拉伸强度衰减的规律。同时,提出了一种高低温极限摸底试验的可靠性评估方法。结果表明,在-50~100℃范围内,试样拉伸强度及断裂伸长率变化较小;当温度高于100℃时,纤维和树脂的性能发生衰减,导致拉伸强度明显降低;当温度低于-50℃时,树脂的性能发生衰减,纤维受到的影响较小。试样高低温极限摸底试验的可靠度大于0.999,表明采用拉伸试样高低温拉伸强度数据的替代方式具有较高的等效性。

煤的温压吸附试验方法与等温吸附试验方法比较研究

为了研究煤的温压吸附试验方法在煤层气吸附方面的可行性,本文对煤的温压吸附试验方法与煤的高压等温吸附试验方法进行了比较研究。分别取12个、10个、8个、和6个温压吸附试验点作为四组不同温度和相应不同压力作为温压吸附试验点,记为V_(实测)。使用温度-压力-吸附方程(Temperature-Pressure-AbsobingEquation(TPAE)),将方程转化为二元一次方程后进行线性回归计算其余三个参数,将所得的四个参数记为V_(计算)。通过计算_(实测)与V_(计算)之间的平均相对误差和标准偏差以衡量温压吸附试验方法的可行性。

无引线封装的SOI高温压力传感器设计

为解决高温环境下的压力监测问题,对无引线封装压力传感器进行了研究。首先,对高温压力敏感芯片进行设计,使用绝缘体上硅(SOI)材料提高了敏感芯片的高温稳定性;使用Ti⁃Pt⁃Au复合电极提高了金属电极与硅引线之间欧姆接触的可靠性。使用导电银浆实现敏感芯片电极和基座引脚的电连接,使用玻璃浆料实现芯片与基座的耐高温封装。利用同步热分析仪对导电银浆和玻璃浆料进行了DSC⁃TG同步分析,并借助扫描电镜对其微观形貌进行对比观察,确定其最佳烧结工艺曲线。对封装后的压力传感器进行测试,结果表明:传感器在25~300℃范围内具备优异的性能,综合精度可达0.25%FS。

低压静电场协同低温高湿解冻对牛肉嫩度和持水性的影响

为探究低压静电场协同低温高湿解冻对牛肉嫩度和持水性的影响,本研究以牛背最长肌为试验材料,分析了低压静电场解冻(电压2500 V,温度4℃,相对湿度50%)、低温高湿解冻(温度4℃,相对湿度98%)、低压静电场协同低温高湿解冻(电压2500 V,温度4℃,相对湿度98%)与低温解冻(温度4℃,相对湿度50%)四种解冻方式对冷冻牛肉剪切力、质构、水分分布、水分含量、持水性、感官评价的影响。结果表明:低压静电场协同低温高湿解冻的解冻时间最短(804 min),其中解冻损失(2.06%)、蒸煮损失(26.09%)与离心损失(15.00%)显著低于其余三种解冻方式(P<0.05),垂直肌纤维剪切力值(95.46 N)和平行肌纤维剪切力值(41.69 N)最低,自由水含量最低,水分迁移较少,水分含量(68.31%)最高,嫩度品质最优,该解冻方式样品的组织状态、气味、弹性及色泽均最优(总体可接受度最高);综上,低压静电场协同低温高湿解冻加快了牛肉解冻速率、减少了汁液流失,改善了牛肉持水性和嫩度,品质最佳。本研究结果将为低压静电场协同低温高湿解冻技术在冷冻牛肉解冻的产业应用提供理论依据。