Ordered mesoporous materials for water pollution treatment:Adsorption and catalysis

To meet the growing emission of water contaminants,the development of new materials that enhance the efficiency of the water treatment system is urgent.Ordered mesoporous materials provide opportunities in environmental processing applications due to their exceptionally high surface areas,large pore sizes,and enough pore volumes.These properties might enhance the performance of materials concerning adsorption/catalysis capability,durability,and stability.In this review,we enumerate the ordered mesoporous materials as adsorbents/catalysts and their modifications in water pollution treatment from the past decade,including heavy metals(Hg^(2+),Pb^(2+),Cd^(2+),Cr^(6+),etc.),toxic anions(nitrate,phosphate,fluoride,etc.),and organic contaminants(organic dyes,antibiotics,etc.).These contributions demonstrate a deep understanding of the synergistic effect between the incorporated framework and homogeneous active centers.Besides,the challenges and perspectives of the future developments of ordered mesoporous materials in wastewater treatment are proposed.This work provides a theoretical basis and complete summary for the application of ordered mesoporous materials in the removal of contaminants from aqueous solutions.

Health risk assessment of heavy metal pollution in groundwater of a karst basin,SW China

To investigate the presence of metal elements and assess their health risk for the populace in the Nandong Underground River Basin(NURB),we conducted an analysis of eleven common heavy metals in the water body.A Health risk assessment(HRA)model was employed to analyze 84 water samples from the NURB.The detection results revealed the following order of heavy metals concentrations:Fe>Al>Mn>Zn>As>Cd>Pb>Cr>Ni>Cu>Hg.Correlation analysis indicated a certain similarity in material source and migration transformation among these eleven metal elements.Our study identified that the health risks for local residents exposed to metal elements in the water of NURB primarily stem from carcinogenic risk(10^(−6)–10^(−4)a^(−1))through the drinking water pathway.Moreover,the health risk of heavy metal exposure for children through drinking water was notably higher than for adults.The maximum health risks of Cr in both underground and surface water exceeded the recommendation standard(5.0×10^(−5)a^(−1))from ICRP,surpassing the values recommended by the Swedish Environmental Protection Agency,the Dutch Ministry of Construction and Environment and the British Royal Society(5.0×10^(−6)a^(−1)).The results of the health risk assessment indicate that Cr in the water of NURB is the primary source of carcinogenic risk for local residents,followed by Cd and As.Consequently,it is imperative to control these three carcinogenic metals when the water was used as drinking water resource.

Phytoremediation of heavy metal polluted soils and water:Progresses and perspectives

Environmental pollution affects the quality of pedosphere,hydrosphere,atmosphere,lithosphere and biosphere.Great efforts have been made in the last two decades to reduce pollution sources and remedy the polluted soil and water resources.Phytoremediation,being more cost-effective and fewer side effects than physical and chemical approaches,has gained increasing popularity in both academic and practical circles.More than 400 plant species have been identified to have potential for soil and water remediation.Among them,Thlaspi,Brassica,Sedum alfredii H.,and Arabidopsis species have been mostly studied.It is also expected that recent advances in biotechnology will play a promising role in the development of new hyperaccumulators by transferring metal hyperaccumulating genes from low biomass wild species to the higher biomass producing cultivated species in the times to come.This paper attempted to provide a brief review on recent progresses in research and practical applications of phytoremediation for soil and water resources.

Application of a Stereo Constructed Wetland Mode to the Treatment of Slightly Polluted Source Water

[Objective] The study aimed to discuss the application of a stereo constructed wetland to the treatment of slightly polluted source water. [Method] In this study, a new stereo constructed wetland mode was put forward, and a pilot project of water ecological purification in Xinsheng River, the diversion channel of Shijiuyang Waterwork in Jiaxing City, were analyzed. Afterwards, the impact factors of water purification by the technology were discussed from water quality and quantity, season and climate, species configuration, management and maintenance. [Result] Under three different hydraulic loading conditions, the pilot project effectively improved water SD and DO level, and reduced SS, CODCr, NH3-N, TN and TP significantly in summer and autumn, so that effluent water quality reached surface water standard at Grade III. [Conclusion] The stereo constructed wetland mode composed of constructed wetland and underwater forest used to treat slightly polluted source water is feasible and has a good promotion prospect.

Industrial and Agricultural Effects on Water Environment and Its Optimization in Heavily Polluted Area in Taihu Lake Basin, China

The deteriorating water quality in the Taihu Lake Basin has attracted widespread attention for many years, and is correlated with a sharp increase in the quantity of pollutant discharge such as agricultural fertilizers and industrial wastewater. In this study, several factors were selected for evaluating and regionalizing the water environmental capacity by ArcG1S spatial analysis, including geomor- phologic characteristics, water quality goals, water body accessibility, water-dilution channels, and current water quality. Then, the spa- tial optimization of agriculture and industry was adjusted through overlay analysis, based on the balance between industrial space and water environmental capacity. The results show that the water environmental capacity gradually decreases from the west to the east, in contrast, the pollution caused by industrial and agricultural clustering is distributes along Taihu Lake, Gehu Lake and urban districts. The analysis of the agricultural space focuses on optimizing key protected areas of the Taihu Lake Basin, and the shores of Gehu Lake, optimally adjusting the second protected areas of the Taihu Lake Basin, and generally adjusting the urban areas of Changzhou and Wuxi cities. The analysis of industrial space focuses on optimizing the downtowns of Changzhou and Wuxi cities, optimally adjusting key protected areas and second protected areas of the Taihu Lake Basin, and generally adjusting the south and southwest of Gehu Lake. Lastly, some schemes of industrial and agricultural layouts and policies for the direction of industrial and agricultural development were proposed, reflecting a correlation between industry and agriculture and the water environment.

Review of Ecological Floating Bed Restoration in Polluted Water

Using Ecological Floating Bed (EFB) to purify polluted water is a process of ecological restoration at virgin position, as well as a complicated physical, chemical and biological process. Its core is utilizing aquatic plants and root’s microbes to absorb nitrogen and phosphorus elements, degrade organic matter and enrich heavy metal. EFB has been applied to some water pollution control projects at home and abroad, and has got several achievements. However, there are some factors influenced the removal rate of pollutants, including plants, temperature, seasons, processing time, coverage and initial concentration of pollutants. In the future, the development orientation has been prospected from plant and its combinations, the transformation of EFB structure and the utilization of aquatic resources, and probed the technology of EFB’s building and management, to implement the win-win of landscape benefit and ecological function.

Quantitative Evaluation of Heavy Metal Pollution and Its Influencing Factors in Water Bodies of Karst Areas

At present, there is relatively little research on the synergistic effects of heavy metals in soil, sediment, and bedrock on heavy metal pollution in water bodies. In this paper, heavy metals in soil, sediment, bedrock, and water of a typical karst watershed in southwest China were investigated. The results indicated that the average values of heavy metals in soil and sediment were relatively higher than those in bedrock except for Ni and As. During the research period, As and Cd were the main heavy metal elements polluting the soil and sediment in the study area, while water bodies were mainly polluted by Ni, As, and Cd. The pollution assessment indicated that there were instances of poor or very poor water quality in the study area during the study period;the soil as a whole was slightly polluted by Cd and As;sediment was subject to moderate Cd pollution and mild As pollution. Analysis of geochemical form for heavy metals showed that heavy metals in soil and sediment were mainly in residual form, and the proportions of exchangeable As and Cd were relatively high. Multiple statistical analysis showed that heavy metals in sediment, soil, and bedrock explained 23.8%, 16.8%, and 16.2% of the changes in heavy metals of water, respectively. The research results can provide scientific basis for the prevention and control of heavy metal pollution in water bodies.

Coagulation of micro-polluted Pearl River water with IPF-PACls

Water samples collected from early March 2001 to the end of April 2002 at the branch of Pearl River around the Guangzhou City were analyzed for its micro-polluted characteristics. The coagulation behavior of polyaluminum chlorides(PACls) was then examined focusing on the effect of primary water quality and speciation distribution. The results showed that PACls exhibit better coagulation efficiency than alum in accordance with the different speciation. The turbidity removal property of PACls is evidently better than alum at low dosage. While in neutral zone(about 6.5—7.5), the turbidity removal of PACls decreases owing to the restabilization of particles at higher dosage. The organic matters in raw water exhibit marked influence on coagulation. In acidic zone, organic matters complex with polymer species and promote the formation of flocs. With an increase in pH, the complexation of organics with polymer species gradually decreases, and the removal of organics mainly depends on adsorption. The effect is evidently improved with the raise of B value.

Testing the Efficiency of Acacia Bark (Galool-Asal) as Disinfectant for Polluted Waters

Acacia bark efficiency for disinfecting polluted water for the purpose of using it for drinking purposes was tested. Five polluted water samples were collected from different locations in Jordan, namely, King Abdullah Canal, an Agricultural pond in the Jordan Valley, Yajouz wells, Hazeir spring, and Wadi-Seer spring. Different volumes of the water samples were treated with 10 g of the shredded acacia bark (obtained from Somalia) for different retention times. The volumes used were 1 L, 2.5 L, and 5 L and the detention times were 2, 4, and 24 hours. The samples were tested for total coliform, E. coli, electrical conductivity, pH, total dissolved solids, turbidity and color before and after treatment with the acacia bark. Results revealed that the optimum conditions for disinfection were: 1 L polluted water treated with 10 g acacia bark for 24 hours. Log removals of about 2.5 for E. coli were obtained under these conditions. Higher removals could be achieved by using larger amounts of the acacia bark, but the chemical water quality regarding turbidity and color will not be suitable for drinking purposes and levels of tannic acids present in the acacia bark might reach toxic levels. Toxic levels will not be reached if 1 glass of water/kg body weight every 4 - 5 hours daily is consumed.

Evaluation and Impact of a Polluted Stream on the Integrated Management of a Drinking Water Resource: A Case Study of the Middle Vaal River, South Africa

The Koekemoerspruit is a possible pollution source of the Middle Vaal River, an important drinking water source in South Africa. This case study aimed to establish the water quality of the Koekemoerspruit, to evaluate the impact of the Koekemoerspruit on the Vaal River, and to use this information to identify shortcomings in the monitoring program. Monthly and weekly samples from both the Vaal River and the Koekemoerspruit were analyzed at an accredited testing laboratory based on ISO 17025 for 20 chemical methods. A dataset from 2002 to 2015 was statistically analyzed by means of Statistica software, the Mann-Kendall test and the Sens’s slope to determine descriptive statistics and significant trends respectively. The sites’ water quality was evaluated by comparison with both national drinking water standards and environmental target water quality objectives. Results indicated that the target water quality objectives for orthophosphate, nitrate and nitrite, and ammonia concentrations were considerably exceeded in the Koekemoerspruit. The drinking water quality of the Koekemoerspruit and the Middle Vaal was noncompliant with South African standards. Color, electrical conductivity, turbidity, sulfate, recoverable cyanide and arsenic at one site posed aesthetic, operational, acute and chronic health risks. Color, mean ammonia and total chlorophyll concentrations displayed significant trends of increase over time and increased drastically after 2012 at the site where water enters the Middle Vaal River. However, the Koekemoerspruit did not seem to have a significant impact on the overall water quality of the Middle Vaal River, except for total chlorophyll concentrations. Moreover, the review and recommendations for optimizing the water quality monitoring program proved that original monitoring objectives have been achieved. The reviewed monitoring program has consequently been adopted in the water safety plan to address the shortcomings that were identified during this case study.

A new technology for harnessing the dye polluted water and dye collection in a chemical factory

A new technology for harnessing the dye polluted water and dye collection was developed. It is based on the enhanced evaporation by using solar, wind and air temperature energy and additional heat-electric energy. It consists of four parts: (1) evaporation carrier system (evaporation carrier and frame for evaporation carrier) for polluted water; (2)polluted water circulating system (pumping-spraying-collecting); (3)heating system; (4)workshop with polluted water reservoir-tanks and rainfall prevention roof. The polluted water was (heated in case necessary) sprayed to the evaporation carrier system and the water was evaporated when it moved in the space and downward along the carrier mainly by using natural (solar, wind and air temperature energy). In case, when there is no roof for the carrier system, the polluted water can be stored in the reservoirs (storage volume for about 20 days). The first 10-25 mm rainfall also need to be stored in the reservoirs to meet the state standard or discharging wastewater. The dye may be collected at the surface in the reservoir-tanks and the crystallized salt may be collected at the bottom plate. The black-color wastewater released by the factory is no more discharged to the surface water system of Taihu Lake Basin. About 2 kg dye and 200 kg industrial salt may be collected from each tone of the polluted water. The non-pollution production of dye may be realized by using this technology with environmental, economical and social benefits.

Influence on shallow ground water by heavy metal in polluted river

The main purpose of the research is to study the influence on shallow ground water by heavy metal in polluted river. In the lab-scale experiment polluted rivers were simulated by domestic sewage, and three kinds of natural sand were chosen as infiltration medium, it was found that Cr（Ⅵ）penetrated on the 13th day and then had a removal ratio of 77%-99% in coarse sand,over 91% and 96% in two kinds of medium sand. From beginning to end in column 2 and column 3 the removal ratio of lead were greater than 97%. It is difficult for Cr（Ⅵ） and lead to enter ground water. In on-site test it indicates that the concentration of Cr（Ⅵ） in No.1-3 and coal yard well along the bank of Liangshui River is not greater than background concentration in groundwater, so Cr （Ⅵ） in Liangshui River has a little influence on ground water. The mechanism of Cr（Ⅵ） removal is reducing action and sedimentation. The removal mechanism of lead primarily is chemical adsorption and generation deposit. Cr（Ⅵ） mainly is transformed to precipitation by reducing action because of abundant reduction agent in the infiltration media, so the tests indicat that polluted river is not the source of Cr （Ⅵ） pollution in ground water. Generally lead may polluted soil, but not groundwater.

Oil Pollutants Degradation of Nano-MgO in Micro-Polluted Water

The removal of oil pollutants from water and purifying process of oil-polluted water are studied through catalytic degradation method with nano-MgO. The results indicated that catalytic degradation effect of nano-MgO on the oil pollutants was associated with dosage of nano-MgO, pH and water temperature. When oil content was 1.8 mg/L, 0.17 g nano-MgO was used and the removal rate of oil was 93.92%. Furthermore, nano-Mgo was a non-photosensitive catalyst. GC/MS analysis showed that the amount of petroleum-based pollutants in water was reduced 73.77% from the previous 61 kinds to 16 kinds, and the total peak area was reduced 96.05% after catalytic degradation of nano-MgO. Therefore, nano-MgO has an excellent effect on the catalytic degradation of oil pollutants and can be applied in the treatment of oil wastewaters.

Influence on shallow ground water by nitrogen in polluted river

The main purpose of the research is to discuss the influence on ground water by NH4-N in polluted river and river bed.In the lab-scale experiment three kinds of natural sand were chosen as infiltration medium,and polluted rivers were simulated by domestic sewage,after 10-month sand column test it was found that NH_4-N came to adsorption sa- turation on the 17th day in coarse sand and on the 130～140th day in medium sand,then had a higher effluent concentration because of desorption.It is concluded that NH_4-N eas- ily moved to ground water.When the concentration of NH_4-N in Liangshui River were 46.86,26.95 mg/L,that in groundwater are less than 1.10 mg/L.It is found that Liangshui River have a little influence on groundwater because of bottom mud,thickness and char- acter of the infiltration medium under the river bed and seepage quantity of river water. Clean water leaching test states that after the silt is cleared away and clean water is poured,NH_4-N in the penetration media under the polluted river is obviously carried into ground water,and ground water is polluted secondly.

The Occurrence and Prevention of Filamentous Algae in Ecological Purification System of Micro-polluted Water

[ Objective ] The aim was to study the influence of filamentous algae on the process of water ecological purification. [ Method ] The occurrence mechanism of filamentous algae and its ecological system were summarized and analyzed. Considering the ecological purification in north- ern Jiangsu, the occurrence and prevention of filamentous algae in water, the method to prevent filamentous algae in polluted water was discussed. [ Result] The results showed that by measures of improving planting density, regular harvesting, and water flow state control before the filamentous algae blooming period, together with improving local pH value, light interference and ecological control during the blooming period, can effectively control the filamentous algae blooming. [ Condusion] The study of the happening mechanism of filamentous algae provided theoretical references and the technical basis in the work of filamentous algae prevention and control.

Water Pollution Situation and Impacts in Rural China

With the development of national economics, water pollution is becoming a critical problem in rural China. This research presented a brief view of water pollution situation in rural areas of China in terms of water shortage, water-pollutant sources, eutrophication of water bodies and pollution development in temporal scale. Analysis was conducted on the negative effects of water pollution on human health, agricultural plantation and animal husbandry. Subsequently, some suggestions were proposed for wastewater treatment in rural areas.

Pollution of Environmental Endocrine Disrupting Chemicals(EDCs) in Water and Its Adverse Reproductive Effect on Fish

Environmental endocrine disrupting chemicals （EDCs）, commonly found in the environment, come from industry and agriculture, including pesticides, fungicides, insecticides, herbicides, and other chemicals. Nowadays, more and more EDCs were released into the environment. EDCs go into water body via atmosphere sedi-mentation, surface runoff, soil eluviation, etc., so water body becomes the main place for existing. In order to attract scientific and public attention worldwide and to prevent EDCs pol ution, in this study we reviewed the classification of EDCs and their concentrations in natural water bodies, drinking water sources and water plants, and the reproductive toxicity of EDCs to fish were reviewed. EDCs could disturb the endocrine system and make reproductive organs and reproduction abnor-mal, resulting in fertility descending, reproduction function damage, community quan-tity decrease and even species extinction. In addition, EDCs could disrupt the homeostasis maintained by hormones, which would result in defects of neural de-velopment and abnormalities of the endocrine and reproductive systems. The exact molecular mechanisms have not been completely reported, but researches have suggested that multiple mechanisms were involved in the action of EDCs. Although there have been researches on the biohazard of EDCs, there stil exist problems of weakness in fundamental researches, difficulties in recognizing and identifying EDCs and high cost, which restraint the knowledge on them.

Discussion on the Construction of Negotiation Mechanism of Cross-bounder Water Pollution Treatment in Changjiang River

In order to construct cooperation platform for the treatment of water pollution in Changjiang River,thoughts and revolution were performed from both central government and regional area two aspects.From the national level,Changjiang region water resources management cooperation counsel committee was constructed as the national cooperation platform;from the regional level,Changjiang region water resources management cooperation counsel committee was constructed as the platform of Changjiang cooperation platform.The two platforms built fine interaction mechanism to deal with the national water management and Changjiang regional water management.

Advances in Microbial Remediation on the Application of Heavy Metal Pollution in Agricultural Water Resources

Heavy metal pollution in agricultural water resources is very serious in re- cent years, resulting in large losses of the agricultural economy and endangering human life and health. Due to the advantages of low cost, high efficiency and less secondary pollution, microbial ramediation technology is widely used in the treatment of heavy metal pollution in agricultural water resources. At present, with the progress of modern biotechnology, microbial remediation of heavy metals in agricul- tural water resources has grown rapidly. The sources and status quo of heavy met- al pollution in agricultural water resources at home and aboard, and the principles of microbial remediation of heavy metals pollution in agricultural water resources were reviewed in this paper, as well as the several common microbial remediation technology of heavy metals in agricultural water resources. Additionally, the further research work of heavy metal contaminated agricultural water resources by microbial ramediation were prospected.

Research Progress of Analysis and Control Technologies against Urban Landscape Water Pollution

The root causes of urban landscape water pollution were analyzed in this study, the bio-ecological restoration technologies combing both exogenous and endogenous pollution control were put forward.