Porous rock chemical grouting simulation test was conducted using established large scale physical model.Chemical grout diffusing rule in porous media with different permeability was studied by monitoring the spontane...Porous rock chemical grouting simulation test was conducted using established large scale physical model.Chemical grout diffusing rule in porous media with different permeability was studied by monitoring the spontaneous potential and exciting current response during grouting.The results show that chemical grout spread evenly in all directions and diffusion areas are approximately concentric circles in the cross section of homogeneous transverse isotropic pore medium,the grout spread flling range can be quantitatively decrypted by the diffusion radius.The average diffusion speed and radius increase approximately as the square root with the permeability coeffcient in different permeability media under the same conditions.Calculation results using Maag cylindrical diffusion equation show that the calculated value of diffusion radius is in good agreement with the test value under different grouting pressures and permeability conditions.展开更多
Low-lying prairie wetland, which has characteristics of both grassland and wetland, has irreplaceable ecological functions in inland river basins of Northwest China. Owing to its small-scale distribution, so far, the ...Low-lying prairie wetland, which has characteristics of both grassland and wetland, has irreplaceable ecological functions in inland river basins of Northwest China. Owing to its small-scale distribution, so far, the observation and research on it are rare. The estimation of evapotranspiration is significant to ecological and environmental construction, scientific management of pasture and protection of wetland. For studying the evapotranspiration （ET） of low-lying prairie wetland in the middle reaches of the Heihe River, an inland river, in Northwest China, the automatic weather station in Linze Ecological Experimental Station of Lanzhou University （39°15′ 3″N, 100°03′ 52″ E）, Linze, Gansu Province, was selected as a case study. Based on meteorological data collected, Bowen-Ratio Energy Balance （BREB） method was used to calculate the evapotranspiration （ET） of low-lying prairie wetland. The analysis results showed that in a whole year （September 2003 -August 2004）, the total ET was 611.5mm and mean daily 1.67mm/d. The ET varied with different growing stages. In non-growing stage （NGS）, initial growing stage （IGS）, middle growing stage （MGS） and end growing stage （EGS）, the ET was 0.57, 2.01, 3.82 and 1.49mrrdd, with a percentage of total ET of 18.26%, 9.20%, 61.83% and 10.71% respectively. In March, ET began to increase. But in April, the ET increased most. After that, it increased gradually and got the maximal value in July. From then on, the ET decreased gradually. In September, the ET decreased rapidly. With the ending of growing and the freezing of soil, the ET stopped from the middle of November to February in next year. Hourly ET analysis showed that at 8：00 a.m. （during MGS at 7：00 a.m.）, the evapotranspiration began, at 13：00 p.m. got its maximal value and at 19：00 p.m. （during MGS at 20：00 p.m.）, the evapotranspiration stopped. The intensity of ET in sunny day was much larger than that in cloudy day in the same growing stage.展开更多
The completely unexplored LaP molecule is investigated by ab initio methods. Potential energy curves for the lowlying states of LaP are constructed by means of the diffusion Monte Carlo method combined with three diff...The completely unexplored LaP molecule is investigated by ab initio methods. Potential energy curves for the lowlying states of LaP are constructed by means of the diffusion Monte Carlo method combined with three different trial functions. Spectroscopic constants are also numerically derived and the ground state is assigned, looking forward to experimental comparisons. Moreover, variations of the permanent dipole moments as a function of the internuclear separation for the two lowest states of the diatomic LaP are studied and analyzed.展开更多
Although there are diverse bond features of Ti and O atoms,so far only several isomers have been reported for each(TiO_(2))n cluster.Instead of the widely used global optimization,in this work,we search for the low-ly...Although there are diverse bond features of Ti and O atoms,so far only several isomers have been reported for each(TiO_(2))n cluster.Instead of the widely used global optimization,in this work,we search for the low-lying isomers of(TiO_(2))_(n)(n=2-8)clusters with up to 10000 random sampling initial structures.These structures were optimized by the PM6 method,followed by density functional theory calculations.With this strategy,we have located many more low-lying isomers than thosereported previously.The number of isomers increases dramatically with the size of the cluster,and about 50 isomers were found for(TiO_(2))_(7) and(TiO_(2))_(8) with the energy within 30 kcal/mol.Furthermore,new lowest isomers have been located for(TiO_(2))_(5) and(TiO_(2))_(8),and isomers with three terminal oxygen atoms,five coordinated oxygen atoms as well as six coordinated titanium atoms have been located.Our work highlights the diverse structural features and a large number of isomers of small TiO_(2) clusters.展开更多
Most of China's wetland areas are located in Sanjiang Plain (Three River Basin). It's area has 207×104 hm2 of wet and low-lying farmland, of which 59% is cropped. During 1970s and 1980s, the Chinese gover...Most of China's wetland areas are located in Sanjiang Plain (Three River Basin). It's area has 207×104 hm2 of wet and low-lying farmland, of which 59% is cropped. During 1970s and 1980s, the Chinese government organized intensive scientific research into potential changes to existing natural resources conditions for this farmland. The aim was to make the water resources regime beneficial to crop production. Arterial drainage, field drainage and appropriate sub-soil treatments were suggested. The Four Waters converting mechanism and the estimation of the Four Water converting amount in wet and low-lying farmland were discussed in the paper.展开更多
The equilibrium geometries,excitation energies,force constants and vibrational frequencies for the low-ly- ing electronic states X ~2B_1,~2A_1,~2B_2 and ~2A_2 of the AsH_2 radical have been calculated at the MRSDCI le...The equilibrium geometries,excitation energies,force constants and vibrational frequencies for the low-ly- ing electronic states X ~2B_1,~2A_1,~2B_2 and ~2A_2 of the AsH_2 radical have been calculated at the MRSDCI level with a 3-21G~* basis set.Our calculated geometries,excitation enegies and vibional frequencies for the X ~2B_1 and ~2A_1 states are in good agreement with available experimental data.The electronic transition dipole mo- ments,oscillator strengths for the ~2A_1→X ~2B_1 and ~2A_2→X ~2B_1 transitions,radiative lifetimes for the ~2A_1 and ~2A_2 states are calculated based on the MRSDC^1 wavefunctions,predicting results in reasonable agreement with available experiment.展开更多
Ab initio electronic structure calculations are reported for low-lying electronic states,X ~1Σ^+and A ~1Π of the N_2F^+ molecule.Geometric parameters for the ground state X ~1Σ^+ are predicted by means of mul- tire...Ab initio electronic structure calculations are reported for low-lying electronic states,X ~1Σ^+and A ~1Π of the N_2F^+ molecule.Geometric parameters for the ground state X ~1Σ^+ are predicted by means of mul- tireference single and double excitation configuration interaction(MRSDCI)calculations with a double zeta plus polarization(DZ+P)basis set.Vertical excitation energy for these two electronic states is determined using MRSDCI/DZ+P calculations at the ground state equilibrium geometry.The oscillator strength for the X^1Σ+→ A ~1Π transition and the radiative lifetime for the A^1Π state are calculated based on the MRSDCI wavefunc- tions.展开更多
The ground state and three low-lying states of the H_3^+ are determined by SOCI(Second Order Configuration Interaction) calculations. The results indicate that the ~3Σ_u^+ state of H_3^+ 3 is a bound state, but ~1A_1...The ground state and three low-lying states of the H_3^+ are determined by SOCI(Second Order Configuration Interaction) calculations. The results indicate that the ~3Σ_u^+ state of H_3^+ 3 is a bound state, but ~1A_1 and ~3A_1 states are not stable, each of them will dissociate into H_2^+ and H atom. The SOCI energy -1.1144065au at an equidistant nuclear separation of 1.296A is in good agreement with the lowest value reported so far.展开更多
Lifetime measurements of low-lying excited states in 87Zr and 87Nb have been performed via and coincidences. The 124 MeV 32S beam was delivered from the Sector-Focusing Cyclotron (SFC) of the Heavy Ion R-esearch Facil...Lifetime measurements of low-lying excited states in 87Zr and 87Nb have been performed via and coincidences. The 124 MeV 32S beam was delivered from the Sector-Focusing Cyclotron (SFC) of the Heavy Ion R-esearch Facility in Lanzhou (HIRFL). The parent nuclei 87Nb and 87Mo were produced by the respective reactions 58Ni (32S, 3p) and 58Ni (32S, 2p1n), at a beam energy 100 MeV through the 8 m Al degrader.展开更多
The transition energies, E1 transitional oscillator strengths of the spin-allowed as well as the spin-forbidden and the corresponding transition rates, and complete M1, E2, M2 forbidden transition rates for 1s^(2), 1s...The transition energies, E1 transitional oscillator strengths of the spin-allowed as well as the spin-forbidden and the corresponding transition rates, and complete M1, E2, M2 forbidden transition rates for 1s^(2), 1s2s, and 1s2p states of He I, are investigated using the multi-configuration Dirac–Hartree–Fock method. In the subsequent relativistic configuration interaction computations, the Breit interaction and the QED effect are considered as perturbation, separately. Our transition energies, oscillator strengths, and transition rates are in good agreement with the experimental and other theoretical results. As a result, the QED effect is not important for helium atoms, however, the effect of the Breit interaction plays a significant role in the transition energies, the oscillator strengths and transition rates.展开更多
基金Financial support for this workprovided by the National Natural Science Foundation of China(Nos.61102117 and 41102201)
文摘Porous rock chemical grouting simulation test was conducted using established large scale physical model.Chemical grout diffusing rule in porous media with different permeability was studied by monitoring the spontaneous potential and exciting current response during grouting.The results show that chemical grout spread evenly in all directions and diffusion areas are approximately concentric circles in the cross section of homogeneous transverse isotropic pore medium,the grout spread flling range can be quantitatively decrypted by the diffusion radius.The average diffusion speed and radius increase approximately as the square root with the permeability coeffcient in different permeability media under the same conditions.Calculation results using Maag cylindrical diffusion equation show that the calculated value of diffusion radius is in good agreement with the test value under different grouting pressures and permeability conditions.
基金Underthe auspicesofthe Sino-Japan Cooperation Projectand the SpecialFund ofC hina M etrologicalA dm inistration(N o.C CSF-2005-2-Q H 39)
文摘Low-lying prairie wetland, which has characteristics of both grassland and wetland, has irreplaceable ecological functions in inland river basins of Northwest China. Owing to its small-scale distribution, so far, the observation and research on it are rare. The estimation of evapotranspiration is significant to ecological and environmental construction, scientific management of pasture and protection of wetland. For studying the evapotranspiration （ET） of low-lying prairie wetland in the middle reaches of the Heihe River, an inland river, in Northwest China, the automatic weather station in Linze Ecological Experimental Station of Lanzhou University （39°15′ 3″N, 100°03′ 52″ E）, Linze, Gansu Province, was selected as a case study. Based on meteorological data collected, Bowen-Ratio Energy Balance （BREB） method was used to calculate the evapotranspiration （ET） of low-lying prairie wetland. The analysis results showed that in a whole year （September 2003 -August 2004）, the total ET was 611.5mm and mean daily 1.67mm/d. The ET varied with different growing stages. In non-growing stage （NGS）, initial growing stage （IGS）, middle growing stage （MGS） and end growing stage （EGS）, the ET was 0.57, 2.01, 3.82 and 1.49mrrdd, with a percentage of total ET of 18.26%, 9.20%, 61.83% and 10.71% respectively. In March, ET began to increase. But in April, the ET increased most. After that, it increased gradually and got the maximal value in July. From then on, the ET decreased gradually. In September, the ET decreased rapidly. With the ending of growing and the freezing of soil, the ET stopped from the middle of November to February in next year. Hourly ET analysis showed that at 8：00 a.m. （during MGS at 7：00 a.m.）, the evapotranspiration began, at 13：00 p.m. got its maximal value and at 19：00 p.m. （during MGS at 20：00 p.m.）, the evapotranspiration stopped. The intensity of ET in sunny day was much larger than that in cloudy day in the same growing stage.
文摘The completely unexplored LaP molecule is investigated by ab initio methods. Potential energy curves for the lowlying states of LaP are constructed by means of the diffusion Monte Carlo method combined with three different trial functions. Spectroscopic constants are also numerically derived and the ground state is assigned, looking forward to experimental comparisons. Moreover, variations of the permanent dipole moments as a function of the internuclear separation for the two lowest states of the diatomic LaP are studied and analyzed.
基金supported by the National Natural Science Foundation of China(No.92061114 and No.21873096)the Chinese Academy of Sciences(XDB17010200)。
文摘Although there are diverse bond features of Ti and O atoms,so far only several isomers have been reported for each(TiO_(2))n cluster.Instead of the widely used global optimization,in this work,we search for the low-lying isomers of(TiO_(2))_(n)(n=2-8)clusters with up to 10000 random sampling initial structures.These structures were optimized by the PM6 method,followed by density functional theory calculations.With this strategy,we have located many more low-lying isomers than thosereported previously.The number of isomers increases dramatically with the size of the cluster,and about 50 isomers were found for(TiO_(2))_(7) and(TiO_(2))_(8) with the energy within 30 kcal/mol.Furthermore,new lowest isomers have been located for(TiO_(2))_(5) and(TiO_(2))_(8),and isomers with three terminal oxygen atoms,five coordinated oxygen atoms as well as six coordinated titanium atoms have been located.Our work highlights the diverse structural features and a large number of isomers of small TiO_(2) clusters.
文摘Most of China's wetland areas are located in Sanjiang Plain (Three River Basin). It's area has 207×104 hm2 of wet and low-lying farmland, of which 59% is cropped. During 1970s and 1980s, the Chinese government organized intensive scientific research into potential changes to existing natural resources conditions for this farmland. The aim was to make the water resources regime beneficial to crop production. Arterial drainage, field drainage and appropriate sub-soil treatments were suggested. The Four Waters converting mechanism and the estimation of the Four Water converting amount in wet and low-lying farmland were discussed in the paper.
文摘The equilibrium geometries,excitation energies,force constants and vibrational frequencies for the low-ly- ing electronic states X ~2B_1,~2A_1,~2B_2 and ~2A_2 of the AsH_2 radical have been calculated at the MRSDCI level with a 3-21G~* basis set.Our calculated geometries,excitation enegies and vibional frequencies for the X ~2B_1 and ~2A_1 states are in good agreement with available experimental data.The electronic transition dipole mo- ments,oscillator strengths for the ~2A_1→X ~2B_1 and ~2A_2→X ~2B_1 transitions,radiative lifetimes for the ~2A_1 and ~2A_2 states are calculated based on the MRSDC^1 wavefunctions,predicting results in reasonable agreement with available experiment.
文摘Ab initio electronic structure calculations are reported for low-lying electronic states,X ~1Σ^+and A ~1Π of the N_2F^+ molecule.Geometric parameters for the ground state X ~1Σ^+ are predicted by means of mul- tireference single and double excitation configuration interaction(MRSDCI)calculations with a double zeta plus polarization(DZ+P)basis set.Vertical excitation energy for these two electronic states is determined using MRSDCI/DZ+P calculations at the ground state equilibrium geometry.The oscillator strength for the X^1Σ+→ A ~1Π transition and the radiative lifetime for the A^1Π state are calculated based on the MRSDCI wavefunc- tions.
基金Project supported by the National Natural Science Foundation of China the Special Research Foundation of Doctoral Education of China
文摘The ground state and three low-lying states of the H_3^+ are determined by SOCI(Second Order Configuration Interaction) calculations. The results indicate that the ~3Σ_u^+ state of H_3^+ 3 is a bound state, but ~1A_1 and ~3A_1 states are not stable, each of them will dissociate into H_2^+ and H atom. The SOCI energy -1.1144065au at an equidistant nuclear separation of 1.296A is in good agreement with the lowest value reported so far.
文摘Lifetime measurements of low-lying excited states in 87Zr and 87Nb have been performed via and coincidences. The 124 MeV 32S beam was delivered from the Sector-Focusing Cyclotron (SFC) of the Heavy Ion R-esearch Facility in Lanzhou (HIRFL). The parent nuclei 87Nb and 87Mo were produced by the respective reactions 58Ni (32S, 3p) and 58Ni (32S, 2p1n), at a beam energy 100 MeV through the 8 m Al degrader.
基金Supported by the National Key Research and Development Program of China (Grant No. 2017YFA0402300)the National Natural Science Foundation of China (Grant Nos. 11774344 and 11474033)。
文摘The transition energies, E1 transitional oscillator strengths of the spin-allowed as well as the spin-forbidden and the corresponding transition rates, and complete M1, E2, M2 forbidden transition rates for 1s^(2), 1s2s, and 1s2p states of He I, are investigated using the multi-configuration Dirac–Hartree–Fock method. In the subsequent relativistic configuration interaction computations, the Breit interaction and the QED effect are considered as perturbation, separately. Our transition energies, oscillator strengths, and transition rates are in good agreement with the experimental and other theoretical results. As a result, the QED effect is not important for helium atoms, however, the effect of the Breit interaction plays a significant role in the transition energies, the oscillator strengths and transition rates.
