Ultrahigh strength and improved electrical conductivity in an aging strengthened copper alloy processed by combination of equal channel angular pressing and thermomechanical treatment

In this paper,equal channel angular pressing and thermomechanical treatment was employed to improve the strength and electrical conductivity of an aging strengthened Cu-Ti-Cr-Mg alloy,and the microstructure and properties of the alloy were investigated in detail.The results showed that the samples deformed by the combination of cryogenic equal channel angular pressing(ECAP)and rolling had good comprehensive properties after aging at 400℃.The tensile strength of the peak-aged and over-aged samples was 1120 MPa and 940 MPa,with their corresponding electrical conductivity of 14.7%IACS and 22.1%IACS,respectively.ECAP and cryogenic rolling introduced high density dislocations,leading to the inhibition of the softening effects and refinement of the grains.After a long time aging at 400℃,the alloy exhibited ultra-high strength with obvious increasing electrical conductivity.The high strength was attributed to the synergistic effect of work hardening,grain refinement strengthening and precipitation strengthening.The precipitation of a large amount of Ti atoms from the matrix led to the high electrical conductivity of the over-aged sample.

Development of a High Early Strength Non-fuorine and Non-alkaline Flash Setting Admixture and Flash Mechanism

To solve the problems of high rebound rate and strength reversion of shotcrete,a non-fluorine and non-alkaline liquid flash setting admixture(FSN)with low rebound and high early strength was synthesized under 60-65℃water bath environment through orthogonal test design and taking setting time and compressive strength as indicators.The experimental results show that the optimum mass ratio of FSN is aluminum sulfate:diethanolamine:triethanolamine:pseudo-boehmite:lithium carbonate:water=57%:8%:0.05%:2%:2%:31%.When FSN is added with 7%of the mass of portland cement,the cement paste can be initially set in 3 min and finally set in 5 min.The compressive strength of mortar is 1.2 MPa at 6 h,18.0 MPa at 1 d,and more than 100%at 28 days;The microscopic analysis shows that the rapid release of Li^(+),NH^(4+),and CO_(3)^(2-)ions by FSN in the paste solution effectively shortens the induction period of high C_(3)S content in Portland cement,directly forms early coagulation AFt crystals in FSN and CH dominated by Al_(2)(SO_(4))_(3),and forms a large number of C-S-H gels in the later stage,so that the cement can quickly coagulate and harden,and the strength in the later stage is not retracted.

Anisotropic strength,deformation and failure of gneiss granite under high stress and temperature coupled true triaxial compression

The anisotropic mechanical behavior of rocks under high-stress and high-temperature coupled conditions is crucial for analyzing the stability of surrounding rocks in deep underground engineering.This paper is devoted to studying the anisotropic strength,deformation and failure behavior of gneiss granite from the deep boreholes of a railway tunnel that suffers from high tectonic stress and ground temperature in the eastern tectonic knot in the Tibet Plateau.High-temperature true triaxial compression tests are performed on the samples using a self-developed testing device with five different loading directions and three temperature values that are representative of the geological conditions of the deep underground tunnels in the region.Effect of temperature and loading direction on the strength,elastic modulus,Poisson’s ratio,and failure mode are analyzed.The method for quantitative identification of anisotropic failure is also proposed.The anisotropic mechanical behaviors of the gneiss granite are very sensitive to the changes in loading direction and temperature under true triaxial compression,and the high temperature seems to weaken the inherent anisotropy and stress-induced deformation anisotropy.The strength and deformation show obvious thermal degradation at 200℃due to the weakening of friction between failure surfaces and the transition of the failure pattern in rock grains.In the range of 25℃ 200℃,the failure is mainly governed by the loading direction due to the inherent anisotropy.This study is helpful to the in-depth understanding of the thermal-mechanical behavior of anisotropic rocks in deep underground projects.

Effect of casting process on the inner-wall band segregation of high-strength antisulfur pipes

Controlling inner-wall band segregation is one of the difficulties in the production of high-strength antisulfur pipes.Comparative tests were carried out on different casting processes(superheat,mold electromagnetic stirring,end electromagnetic stirring,casting speed and soft reduction)for the smelting of high-strength antisulfur pipes.The microstructures of continuous-casting billets and hot-rolled or tempered pipes were analyzed using a metallographic microscope and scanning electron microscope.The mechanism and evolution law regarding the inner-wall band segregation of high-strength antisulfur pipes were studied,and the influence of different casting processes was explored.

Effect of B_(2)O_(3) enrichment on microstructural inhomogeneity of high strength steel weldments

The present work attributes the role of boron on the high strength steel submerged arc weld using an undermatching filler wire.Mild steel filler wire was used for welding in constant machine parameters setting to evaluate the joint strength due to the enrichment of boron.To change the chemical composition of the weld metal,boron trioxide powder was blended with virgin flux in various proportions(2.5%−12.5%),which led to an increase in boron weight percentage in the range of 0−0.0065.The results show that weld metals(WM)optical micrographs depict the various types of ferrites,pearlites and secondary phases like martensite-austenite(M-A).Acicular ferrite content was influenced by the boron trioxide addition.Heat affected zone(HAZ)micrographs were not showing appreciable changes with oxide enrichment.Hardness and toughness of weld metals showed the mixed trend with B_(2)O_(3) enrichment whereas,small reduction in ultimate tensile strength(UTS)and yield strength(YS)was observed.

Product Development of High Strength and Toughness Spring Flat Steel

With the continuous development of mechanical industry,higher requirements are put forward for the comprehensive properties of spring steel.The chemical composition and production process of spring flat steel are designed to meet the requirements of high strength and high toughness of spring flat steel,through the test,the product surface quality and internal quality all meet the national standards,the performance indicators to meet user requirements.

Designing new low alloyed Mg-RE alloys with high strength and ductility via high-speed extrusion

Two new low-alloyed Mg-2RE-0.8Mn-0.6Ca-0.5Zn(wt%,RE=Sm or Y)alloys are developed,which can be produced on an in-dustrial scale via relatively high-speed extrusion.These two alloys are not only comparable to commercial AZ31 alloy in extrudability,but also have superior mechanical properties,especially in terms of yield strength(YS).The excellent extrudability is related to less coarse second-phase particles and high initial melting point of the two as-cast alloys.The high strength-ductility mainly comes from the formation of fine grains,nano-spaced submicron/nano precipitates,and weak texture.Moreover,it is worth noting that the YS of the two alloys can maintain above 160 MPa at elevated temperature of 250°C,significantly higher than that of AZ31 alloy(YS:45 MPa).The Zn/Ca solute segregation at grain boundaries,the improved heat resistance of matrix due to addition of RE,and the high melting points of strengthening particles(Mn,MgZn_(2),and Mg-Zn-RE/Mg-Zn-RE-Ca)are mainly responsible for the excellent high-temperature strength.

Various admixtures to mitigate the long-term strength retrogression of Portland cement cured under high pressure and high temperature conditions

In order to investigate the problem of long-term strength retrogression in oil well cement systems exposed to high pressure and high temperature(HPHT)curing conditions,various influencing factors,including cement sources,particle sizes of silica flour,and additions of silica fume,alumina,colloidal iron oxide and nano-graphene,were investigated.To simulate the environment of cementing geothermal wells and deep wells,cement slurries were directly cured at 50 MPa and 200?C.Mineral compositions(as determined by X-ray diffraction Rietveld refinement),water permeability,compressive strength and Young’s modulus were used to evaluate the qualities of the set cement.Short-term curing(2e30 d)test results indicated that the adoption of 6 m m ultrafine crystalline silica played the most important role in stabilizing the mechanical properties of oil well cement systems,while the addition of silica fume had a detrimental effect on strength stability.Long-term curing(2e180 d)test results indicated that nano-graphene could stabilize the Young’s modulus of oil well cement systems.However,none of the ad-mixtures studied here can completely prevent the strength retrogression phenomenon due to their inability to stop the conversion of amorphous to crystalline phases.

Properties of Sustainable High Strength Concrete with Waste Copper Slag

The present work investigates copper slag as a substitute for river sand in high-strength concrete.The concrete mixtures were manufactured with 10%,30%,50%,70%,and 100%of copper slag to evaluate the mechanical and durability properties.The experimental results indicate that replacing copper slag above 50%affects the performance characteristics of the concrete due to its high angularity and lower water absorption characteristics.The strength of concrete with 50%copper slag is improved by 5.6%,whereas the strength of concrete with 100%copper slag is reduced by 2.75%at 28 days.However,increased curing to 90days improves the strength of the former by 7.16%and reduces the latter by only 0.23%.The water absorption,porosity,and rapid chloride penetration of the concrete mixtures with 100%copper slag are increased by 10.44%,13.20%,and 19.56%compared to control concrete.Micro-structural investigations through SEM infer higher replacement of copper results in higher void formation due to its reduced water absorption.

Fatigue Life Estimation of High Strength 2090-T83 Aluminum Alloy under Pure Torsion Loading Using Various Machine Learning Techniques

The ongoing effort to create methods for detecting and quantifying fatigue damage is motivated by the high levels of uncertainty in present fatigue-life prediction approaches and the frequently catastrophic nature of fatigue failure.The fatigue life of high strength aluminum alloy 2090-T83 is predicted in this study using a variety of artificial intelligence and machine learning techniques for constant amplitude and negative stress ratios(R?1).Artificial neural networks(ANN),adaptive neuro-fuzzy inference systems(ANFIS),support-vector machines(SVM),a random forest model(RF),and an extreme-gradient tree-boosting model(XGB)are trained using numerical and experimental input data obtained from fatigue tests based on a relatively low number of stress measurements.In particular,the coefficients of the traditional force law formula are found using relevant numerical methods.It is shown that,in comparison to traditional approaches,the neural network and neuro-fuzzy models produce better results,with the neural network models trained using the boosting iterations technique providing the best performances.Building strong models from weak models,XGB helps to predict fatigue life by reducing model partiality and variation in supervised learning.Fuzzy neural models can be used to predict the fatigue life of alloys more accurately than neural networks and traditional methods.

Residual Capacity of Friction⁃Type High⁃Strength Bolted T⁃stub Connection with Nut Corrosion Damage

Corrosion is a primary cause of the slippage of friction⁃type high⁃strength bolted(FHSB)T⁃stub connections.This paper attempts to quantify the residual capacity of FHSB T⁃stub connections with corroded nuts.Firstly,corrosion simulation tests were conducted on 48 manually cut nuts to find out the relationship between the damage degree of nut section and the residual clamping force(RCF)of bolt.Then,static load tests were carried out on 24 FHSB T⁃stub connections with nuts of different degrees of damage to obtain the failure modes.By finite⁃element(FE)models,a comparative analysis was performed on the initial friction load(IFL)and ultimate strength(US)of each connection with corroded nuts.Finally,the parameters of 96 FE models for FHSB T⁃stub connections were analyzed and used to derive the calculation formulas for the degree of damage for each nut and the IFL and US of each connection.The results show that the RCF decay of a bolt is a quadratic function of the equivalent radius loss ratio and the shear failure after nut corrosion;the IFL of each connection had a clear linear correlation with the RCF of the corresponding bolts,and the correlation depends on the applied load and static friction on connecting plate interface induced by the clamping force;the static friction had little impact on the US of the connection;the proposed IFL and US formulas can effectively derive the residual anti⁃slip capacity of FHSB T⁃stub connections from the degree of damage of the corroded nut section.The research results provide a scientific basis for the replacement and maintenance of corroded bolts of FHSB T⁃stub connections.

Towards designing high mechanical performance low-alloyed wrought magnesium alloys via grain boundary segregation strategy:A review

Low-alloyed magnesium(Mg)alloys have emerged as one of the most promising candidates for lightweight materials.However,their further application potential has been hampered by limitations such as low strength,poor plasticity at room temperature,and unsatisfactory formability.To address these challenges,grain refinement and grain structure control have been identified as crucial factors to achieving high performance in low-alloyed Mg alloys.An effective way for regulating grain structure is through grain boundary(GB)segregation.This review presents a comprehensive summary of the distribution criteria of segregated atoms and the effects of solute segregation on grain size and growth in Mg alloys.The analysis encompasses both single element segregation and multi-element co-segregation behavior,considering coherent interfaces and incoherent interfaces.Furthermore,we introduce the high mechanical performance low-alloyed wrought Mg alloys that utilize GB segregation and analyze the potential impact mechanisms through which GB segregation influences materials properties.Drawing upon these studies,we propose strategies for the design of high mechanical performance Mg alloys with desirable properties,including high strength,excellent ductility,and good formability,achieved through the implementation of GB segregation.The findings of this review contribute to advancing the understanding of grain boundary engineering in Mg alloys and provide valuable insights for future alloy design and optimization.

Combined use of fly ash and silica to prevent the long-term strength retrogression of oil well cement set and cured at HPHT conditions

The long-term strength retrogression of silica-enriched oil well cement poses a significant threat to wellbore integrity in deep and ultra-deep wells, which is a major obstacle for deep petroleum and geothermal energy development. Previous attempts to address this problem has been unsatisfactory because they can only reduce the strength decline rate. This study presents a new solution to this problem by incorporating fly ash to the traditional silica-cement systems. The influences of fly ash and silica on the strength retrogression behavior of oil well cement systems directly set and cured under the condition of 200°C and 50 MPa are investigated. Test results indicate that the slurries containing only silica or fly ash experience severe strength retrogression from 2 to 30 d curing, while the slurries containing both fly ash and silica experience strength enhancement from 2 to 90 d. The strength test results are corroborated by further evidences from permeability tests as well as microstructure analysis of set cement. Composition of set cement evaluated by quantitative X-ray diffraction analyses with partial or no known crystal structure(PONKCS) method and thermogravimetry analyses revealed that the conversion of amorphous C-(A)-S-H to crystalline phases is the primary cause of long-term strength retrogression.The addition of fly ash can reduce the initial amount of C-(A)-S-H in the set cement, and its combined use with silica can prevent the crystallization of C-(A)-S-H, which is believed to be the working mechanism of this new admixture in improving long-term strength stability of oil well cement systems.

Microstructure Distribution Characteristics of High-Strength Aluminum Alloy Thin-Walled Tubes during Multi-Passes Hot Power Backward Spinning Process

The microstructure of the thin-walled tubes with high-strength aluminum alloy determines their final forming quality and performance. This type of tube can be manufactured by multi-pass hot power backward spinning process as it can eliminate casting defects, refine microstructure and improve the plasticity of the tube. To analyze the microstructure distribution characteristics of the tube during the spinning process, a 3D coupled thermo-mechanical FE model coupled with the microstructure evolution model of the process was established under the ABAQUS environment. The microstructure evolution characteristics and laws of the tube for the whole spinning process were analyzed. The results show that the dynamic recrystallization is mainly produced in the spinning deformation zone and root area of the tube. In the first pass, the dynamic recrystallization phenomenon is not obvious in the tube. With the pass increasing, the trend of dynamic recrystallization volume percentage gradually increases and extends from the outer surface of the tube to the inner surface. The fine-grained area shows the states of concentration, dispersion, and re-concentration as the pass number increases. .

High strength magnesium alloy with α-Mg and W-phase processed by hot extrusion

Fine-grained Mg-6Zn-4Y alloy was prepared by an ingot metallurgy process with hot extrusion at 300 ℃.The microstructure was studied by XRD,OM,SEM and TEM,and the tensile properties were tested at room temperature.The results show that the alloy is composed of α-Mg and W-phase.The microstructure of the as-extruded alloy has a bimodal grain size distribution.The fine grains with the mean size of 1.2 μm are formed by dynamic recrystallization.The coarse grains（about 23% in area fraction） are unrecrystallized regions which are elongated along extrusion direction.The engineering stress—strain curve shows a pronounced yield point.The ultimate tensile strength,yield strength,and elongation are（371±10） MPa,（350±5） MPa and（7±2）%,respectively.The high strengths are attributed to the fine-grained matrix structure enhanced by W-phase particles,nano-scaled precipitates,and strong basal plane texture.

Study on High Strength Concrete Confined by Continuous Carbon Fiber Sheet

Eight high strength concrete (HSC) prisms strengthened with continuous carbon fiber sheet(CFS)were tested.As a result of the confinement provided by CFS,the concrete would fail at a greater strain than the unconfined and then a significant increase in ductility can be achieved.The lateral pressure exerted by CFS would increase the compressive strength of the concrete,resulting in higher load bearing capacity.This paper proposes the stress strain curve of this kind of hybrid specimen,which agrees well with the test results.Based on the stress strain relationship and the assumptions proposed in this paper,a computer program was developed to analyze HSC columns,confined by CFS,which were subjected to axial compression and biaxial bending.The results shown in this paper indicate that the ductility of HSC column is significantly improved and the strength is also increased by some degree.

Research and Development of Cemented Carbide Multifacet Drill for Drilling High Strength Steel

Aim To research on a solid cemented carbide multi facet drill for drilling high strength steel. Methods Assimilating some features of multi facet drill edge structures, through systematic drilling experiments, a new type of solid cemented carbide drill was developed and the drill geometry was optimized. Results With the new type drill,the drilling force decreases by 10%-20%, the drilling productivity (drilled holes per hour) increases by 2-3 times, and the drilling precision and surface finish increase by one level. Conclusion The new type drill possesses excellent drilling performance.

RESEARCH ON T SHAPED HIGH STRENGTH CONCRETE MEMBERS SUBJECTED TO AXIAL COMPRESSION AND BIAXIAL BENDING

Based on experiments, a computer program is developed. The calculated results agree well with the experimental results. The flexural behavior of T shaped high strength concrete members subjected to axial compression and biaxial bending is studied. The main factors affecting the flexural behavior of T shaped high strength concrete members are loading angle, axial compression ratio and reinforcement ratio.

Strength regularity and failure criterion of plain HSHPC under biaxial compression after exposure to high temperatures

Biaxial compression tests are performed on 100 mm × 100 mm × 100 mm cubic specimens of plain high-strength highperformance concrete （HSHPC） at seven kinds of stress ratios, σ2：σ3 =0 ： - 1, -0.20 ： - 1, -0.30 ： - 1, -0.40 ： - 1, -0.50 ： -1, -0. 75 ： - 1, and - 1.00 ： - 1 after exposure to normal and high temperatures of 20, 200, 300, 400, 500 and 600 ℃, using a large static-dynamic true triaxial machine. Frictionreducing pads are three layers of plastic membranes with glycerine in-between for the compressive loading plane. Failure modes of the specimens are described. The two principally static compressive strengths are measured. The influences of the temperatures and stress ratios on the biaxial strengths of HSHPC after exposure to high temperatures are also analyzed. The experimental results show that the uniaxial compressive strength of plain HSHPC after exposure to high temperatures does not decrease completely with the increase in temperature; the ratios of the biaxial to its uniaxial compressive strengths depend on the stress ratios and brittleness-stiffness of HSHPC after exposure to different high temperatures. The formula of the Kupfer-Gerstle failure criterion modified with the temperature and stress ratio parameters for plain HSHPC is proposed.

Application of Lanthanum in High Strength and High Conductivity Copper Alloys

China is quite poor in argent resource. Roughly 80% of this industrial argent is imported every year. In order to improve the situation, we took advantage of rare earth (RE) mineral resource and successfully developed the non-argent Lanthanum-tellurium-copper alloy as a substitute for industry argent-copper. In our research, we were able to successfully apply rare earth lanthanum to copper alloy. The defects as porosity, inclusion, etc. originating from nonvacuum melting processing were controlled. Fine grain was obtained. Meanwhile, the comprehensive properties of the copper alloy, such as strength, conductivity and thermal conductivity were improved. The research results in increasing conductivity and thermal conductivity by 5% and 15%, respectively, while the tensile strength is increased by 6% higher than Ag-Cu alloy. The anti-electric corrosion property is good, and there is no argent-cadmium steam population originating from the electric arc effect. The addition of lanthanum further reduces the content of oxygen and hydrogen. The optimum quantity of the addition of RE lanthanum in the copper alloy is 0.010% - 0.020% .