Effect of Magnetic Field on Synthesis of Nano-FeOOH by Low-Temperature Neutralization Method

Using XRD,TEM and VSM methods,the phase,morphology and magnetic property of iron hydroxide oxide(FeOOH) which has been prepared by low-temperature neutralization reaction under different magnetic fields were analyzed.It can be found that the magnetic field had a great influence on the product.Acicular goethite(α-FeOOH) was synthetized without magnetic field.When the magnetic flux density was increased to 0.1T,γ-FeOOH was obtained.If the magnetic field intensity was raised to 0.5T,the product was all composed of δ-FeOOH.Moreover,the crystallization of FeOOH was greatly influenced by magnetic field as well.Thermodynamic calculation results show that the magnetic free energy of chemical reaction reached to more than hundreds KJ/mol when the magnetic field is applied.It meaned that the application of magnetic field was conducived to producing the products with higher susceptibility.Even under the low magnetic field,due to the stability of the reaction products was broken by the magnetic field,the magnetic free energy was also effective.

ASYMPTOTICAL STABILITY OF NEUTRAL REACTION-DIFFUSION EQUATIONS WITH PCAS AND THEIR FINITE ELEMENT METHODS

This paper focuses on the analytical and numerical asymptotical stability of neutral reaction-diffusion equations with piecewise continuous arguments.First,for the analytical solutions of the equations,we derive their expressions and asymptotical stability criteria.Second,for the semi-discrete and one-parameter fully-discrete finite element methods solving the above equations,we work out the sufficient conditions for assuring that the finite element solutions are asymptotically stable.Finally,with a typical example with numerical experiments,we illustrate the applicability of the obtained theoretical results.

Mutual neutralization in low-energy collisions of Na^(+)+H^(-)ions

The low-energy mutual neutralization(MN)reactions Na^(+)+H^(-)→Na(nl)+H have been studied by employing the full quantum-mechanical molecular-orbital close-coupling(QMOCC)method over a wide energy range of 10^(-3)-10^(3) e V/u.Total and state-selective cross sections have been investigated and compared with the available theoretical and experimental data,and the state-selective rate coefficients for the temperature range of 100-10000 K have been obtained.In the present work,all the necessary highly excited states are included,and the influences of rotational couplings and 10 active electrons are considered.It is found that in the energy below 10 e V/u,the Na(4s)state is the most dominant exit state with a contribution of approximately 78%to the branch fraction,which is in best agreement with the experimental data.For energies above 10 e V/u,the MN total cross section is larger than those obtained in other theoretical calculations and shows a slow decreasing trend because the main exit states change,when the energy is above 100 e V/u,the dominant exit state becomes the Na(3p)state,while the Na(4s)state becomes the third most important exit state.The datasets presented in this paper,including the potential energy curve,the radial and rotational couplings,the total and state-selective cross sections,are openly available at https://doi.org/10.57760/sciencedb.j00113.00112.

Low-temperature Denitration Mechanism of NH_(3)-SCR over Fe/AC Catalyst

To study the modification mechanism of activated carbon(AC)by Fe and the low-temperature NH_(3)-selective catalytic reduction(SCR)denitration mechanism of Fe/AC catalysts,Fe/AC catalysts were prepared using coconut shell AC activated by nitric acid as the support and iron oxide as the active component.The crystal structure,surface morphology,pore structure,functional groups and valence states of the active components of Fe/AC catalysts were characterised by X-ray diffraction,scanning electron microscopy,nitrogen adsorption and desorption,Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy,respectively.The effect of Fe loading and calcination temperature on the low-temperature denitration of NH_(3)-SCR over Fe/AC catalysts was studied using NH_(3)as the reducing gas at low temperature(150℃).The results show that the iron oxide on the Fe/AC catalyst is spherical and uniformly dispersed on the surface of AC,thereby improving the crystallisation performance and increasing the number of active sites and specific surface area on AC in contact with the reaction gas.Hence,a rapid NH_(3)-SCR reaction was realised.When the roasting temperature remains constant,the iron oxide crystals formed by increasing the amount of loading can enter the AC pore structure and accumulate to form more micropores.When the roasting temperature is raised from 400 to 500℃,the iron oxide is mainly transformed fromα-Fe_(2)O_(3)toγ-Fe_(2)O_(3),which improves the iron oxide dispersion and increases its denitration active site,allowing gas adsorption.When the Fe loading amount is 10%,and the roasting temperature is 500℃,the NO removal rate of the Fe/AC catalyst can reach 95%.According to the study,the low-temperature NH_(3)-SCR mechanism of Fe/AC catalyst is proposed,in which the redox reaction between Fe~(2+)and Fe~(3+)will facilitate the formation of reactive oxygen vacancies,which increases the amount of oxygen adsorption on the surface,especially the increase in surface acid sites,and promotes and adsorbs more reaction gases(NH_(3),O_(2),NO).The transformation from the standard SCR reaction to the fast SCR reaction is accelerated.

Study on Decision Method of Neutral Point Grounding Mode for Medium-Voltage Distribution Network

The neutral grounding mode of medium-voltage distribution network decides the reliability, overvoltage, relay protection and electrical safety. Therefore, a comprehensive consideration of the reliability, safety and economy is particularly important for the decision of neutral grounding mode. This paper proposes a new decision method of neutral point grounding mode for mediumvoltage distribution network. The objective function is constructed for the decision according the life cycle cost. The reliability of the neutral point grounding mode is taken into account through treating the outage cost as an operating cost. The safety condition of the neutral point grounding mode is preserved as the constraint condition of decision models, so the decision method can generate the most economical and reliable scheme of neutral point grounding mode within a safe limit. The example is used to verify the feasibility and effectiveness of the decision method.

Study of Mutual Improvement of Completed Weathered Phyllite and Red Clay Based on Neutralization Effects of Swelling and Shrinkage Deformation

Completely weathered phyllite(CWP)soil is a kind of special soil with high swell potential,while red clay is a special soil with high shrinkage.This means that these two kinds of special soils are usually not suitable for direct use as subgrade fill.To reduce the swell index of the CWP soil and the shrinkage of red clay at the same time,it was proposed to blend the CWP soil with red clay to improve their basic characteristics.A series of swell index tests and dry-wet cycle tests of the blended soils have been carried out at varying blending ratios,compaction coefficients and moisture contents.The test results show that the free swell index of the blended soil decreases with the increase of red clay,moisture content and compaction coefficient,respectively.The fissure density of the blended soil first decreases and then increases with the blending ratio,with the lowest being zero when the blending ratio is ranging from 20%to 40%.Through particle microscopic analysis and elemental composition analysis,it is found that the neutralization effect,the dilution effect of swell minerals,and the partition effect of coarse particles play an important role in restraining expansion and shrinkage deformation of the blended soil.Based on the liquid limit requirement of Chinese Railway Design Code(TB 10001-2016),the optimal blending ratio of red clay has been proposed to be 50%.Compared with the CWP soil,the free load swell index of the blended soil is reduced by 45.0%and the fissure density is reduced by 99.3%compared with that of red clay.Therefore,it is feasible to improve the CWP soil by blending it with red clay at an optimal ratio of 50%by using the neutralization effect of the expansion of CWP and shrinkage of red clay.

NGP_G-STABILITY OF LINEAR MULTISTEP METHODS FOR SYSTEMS OF GENERALIZED NEUTRAL DELAY DIFFERENTIAL EQUATIONS

The stability analysis of linear multistep methods for the numerical solutions of the systems of generalized neutral delay differential equations is discussed. The stability behaviour of linear multistep methods was analysed for the solution of the generalized system of linear neutral test equations, After the establishment of a sufficient condition for asymptotic stability of the solutions of the generalized system, it is shown that a linear multistep method is NGP(G)-stable if and only if it is A-stable.

Delay-dependent stability analysis of Runge-Kutta methods for neutral delay differential equations

The aim of this paper is to study the asymptotic stability properties of Runge Kutta(R-K) methods for neutral differential equations(NDDEs) when they are applied to the linear test equation of the form: y′(t)=ay(t)+by(t-τ)+cy’(t-τ), t>0, y(t)=g(t), -τ≤t≤0, with a,b,c∈[FK(W+3mm\.3mm][TPP129A,+3mm?3mm,BP], τ>0 and g(t) is a continuous real value function. In this paper we are concerned with the dependence of stability region on a fixed but arbitrary delay τ. In fact, it is one of the N.Guglielmi open problems to investigate the delay dependent stability analysis for NDDEs. The results that the 2,3 stages non natural R-K methods are unstable as Radau IA and Lobatto IIIC are proved. And the s stages Radau IIA methods are unstable, however all Gauss methods are compatible.

A Semi-analytical Method for Vibrational and Buckling Analysis of Functionally Graded Nanobeams Considering the Physical Neutral Axis Position

In this paper,a semi-analytical method is presented for free vibration and buckling analysis of functionally graded(FG)size-dependent nanobeams based on the physical neutral axis position.It is the first time that a semi-analytical differential transform method(DTM)solution is developed for the FG nanobeams vibration and buckling analysis.Material properties of FG nanobeam are supposed to vary continuously along the thickness according to the power-law form.The physical neutral axis position for mentioned FG nanobeams is determined.The small scale effect is taken into consideration based on nonlocal elasticity theory of Eringen.The nonlocal equations of motion are derived through Hamilton’s principle and they are solved applying DTM.It is demonstrated that the DTM has high precision and computational efficiency in the vibration analysis of FG nanobeams.The good agreement between the results of this article and those available in literature validated the presented approach.The detailed mathematical derivations are presented and numerical investigations are performed while the emphasis is placed on investigating the effect of the several parameters such as neutral axis position,small scale effects,the material distribution profile,mode number,thickness ratio and boundary conditions on the normalized natural frequencies and dimensionless buckling load of the FG nanobeams in detail.It is explicitly shown that the vibration and buckling behaviour of a FG nanobeams is significantly influenced by these effects.

Remove of Phenolic Compounds in Water by Low-Temperature Plasma: A Review of Current Research

Phenolic compounds have very strong toxicity, so it has been paid sharply attention to find an effective way of controlling the wastewater containing phenolic compounds. The work on this subject done by domestic and overseas scholars is studied in this paper, and the progress of researches on low-temperature plasma treatment is summarized through the electrical discharge types, mechanism, kinetics of phenolic compounds decomposition and combination of several methods with low-temperature plasma treatment. In addition, the crucial problem and the developing tendency on low-temperature plasma treatment for phenol-bearing wastewater are briefly discussed.

Research progress and development direction of low-temperature drilling fluid for Antarctic region

By combing the characteristics of drilling in Antarctic region, performance requirements on drilling fluid for Antarctic low temperature conditions, and research progress of low temperature drilling fluid, current problems of the drilling fluid have been sorted out, and the development direction of the drilling fluid has been pointed out. Drilling in the Antarctic region mainly includes drilling in snow, ice and subglacial rock formations, and drilling in Antarctic low temperature conditions will face problems in four aspects:(1) low temperature and large temperature changes in the drilling area;(2) likely well leakage and drillstring-sticking in the snow layer, creep in the ice layer, ice chip gathering jamming in the warm ice layer, well wall collapse in the subglacial rock formations;(3) lack of infrastructure and difficulty in logistical support;(4) fragile environment and low carrying capacity. After years of development, progresses have been made on low-temperature drilling fluids for the Antarctic region. Low-temperature petroleum-based drilling fluid, ethanol/ethylene glycol-based drilling fluid, ester-based drilling fluid and silicone oil-based drilling fluid have been developed. However, these drilling fluids have problems such as insufficient low-temperature tolerance, low environmental performance and weak wellbore stability, etc. In order to meet the performance requirements of drilling fluid under low-temperature conditions in Antarctic region, the working mechanisms of low-temperature drilling fluid must be examined in depth;environment-friendly low-temperature base fluid of drilling fluid and related additives must be developed to prepare environmentally friendly low temperature drilling fluid systems;multi-functional integrated adjustment method for drilling fluid must be worked out to ensure well wall stability and improve cutting-carry capacity when drilling ice formations and ice-rock interlayers;and on-site support operation codes must be established to provide technical support for Antarctic drilling.

Low-temperature synthesis of ultrasmall spinel MnxCo3-xO4 nanoparticles for efficient oxygen reduction

Spinel-type manganese-cobalt oxides have been regarded as important class of electrocatalysts for oxygen reduction reaction(ORR).However,they are usually synthesized through oxidation-precipitation under aqueous ammonia and then crystallization at high temperature(150–180℃),which not only increases the energy consumption but also induces the growth of particles that is unfavorable for ORR.Herein,through a facile precipitation-dehydration method,ultrasmall spinel manganese-cobalt oxide nanoparticles(~5 nm)homogeneously dispersed on conductive carbon black(MnxCo3-xO4/C)were fabricated at low temperature(60℃).And the bimetallic composite oxide(Mn1.5Co1.5O4/C)with cubic spinel structure and high Mn content exhibits remarkable enhancement of ORR activity and stability compared with single metal oxide(both Mn3O4/C and Co3O4/C).The essential reason for the enhancement of activity can be attributed to the presence of the mixed Mn^3+ and Mn^4+ cations in Mn1.5Co1.5O4/C.Moreover,the ORR activity of Mn1.5Co1.5O4/C is comparable to that of commercial 20 wt% Pt/C,and the relative current density only decreases 1.4% after 12 h test,exceeding that of Pt/C and most reported manganese-cobalt oxide electrocatalysts.

Stability analysis of linear multistep methods for neutral delay differential equations

The stability analysis of linear multistep (LM) methods is carried out under Kreiss resolvent condition when they are applied to neutral delay differential equations of the form y′(t)=ay(t)+by(t-τ)+ cy′(t- τ) y(t)=g(t) -τ≤t≤0 with τ>0 and a, b and c∈, and it is proved that the ‖B n‖ is suitably bounded, where B is the companion matrix.

Determination of Chlorobenzene by Hydroxypropyl-β- Cyclodextrin Sensitized Fluorescence Quenching Method with Neutral Red as a Fluorescence Probe

The fluorescence quenching of inclusion complex of neutral red （NR） and hydroxypropyl-β-cyclodextrin （HP-β-CD） carried by chlorobenzene was investigated. The fluorescence intensity of NR increased due to the formed inclusion complex of HP-β-CD and NR. But the fluorescence intensity of NR-HP-β-CD diminished when chlorobenzene was added, and there was a linear relationship between the fluorescence quenching value of the system （△IF = IF, NR-HP-β-CD - IF, CB-NB-NR-HP-β-CD） and the concentration of chlorobenzene. Based on this, a novel fluorescence quenching method for the determination of chlorobenzene with NR as a fluorescence probe has been developed. Under the optimal conditions, the linear range of calibration curve for the determination of chlorobenzene was 5.0 × 10^-8 - 8.0 × 10^-6 mol/L and the detection limit was 1.0 × 10^-8 mol/L. It has been applied to determination ofchlorobenzene in synthetic waste water samples with satisfactory results.

Calculation of Neutral Particle Energy Spectra in Tokamak by Using the Monte Carlo Method

Neutral particle energy spectra in the HT-7 tokamak are calculated by using the Monte Carlo method. It can reproduce the spectra measured in experiment. Differences of neutral particle energy spectra in higher and lower electron density plasma are discussed. Results show that the ion temperature given by neutral particle energy spectra is lower than the real ion temperature, but the deviation is within 10% if the ion temperature is less than 800 eV and thecentral chord-averaged electron density does not exceed 3 ×1013 cm-3. But for ion temperature higher than 1000 eV at the central chord-averaged density limit up to 5 ×1013 cm-3, the neutral particle energy spectra can still give the ion temperature within 10% deviation.

A Study on Neutral Point Earthed Method of Power System

This paper mainly is study on power system working state with neutral point different grounded methods, when the power system is normal working and the single-phase grounding. And further analysis of the different operating modes of voltage and current relationships, expounds the different operation occasions and characteristics.

Dissipativity of Multistep Runge-Kutta Methods for Nonlinear Neutral Delay-Integro-Differential Equations with Constrained Grid

This paper is concerned with the numerical dissipativity of multistep Runge-Kutta methods for nonlinear neutral delay-integro-differential equations.We investigate the dissipativity properties of-algebraically stable multistep Runge-Kutta methods with constrained grid.The finite-dimensional and infinite-dimensional dissipativity results of-algebraically stable multistep Runge-Kutta methods are obtained.

基于IO-SDA法的2020~2060年中国行业CO_(2)排放预测与分析

采用IO-SDA法测算2017~2020年CO_(2)排放,后结合国内权威预测报告,利用RAS法推导2025~2060年投入产出表和各行业能源消费数据,利用IO-SDA法定量评价各驱动因素在2020~2060年对CO_(2)排放总量和各行业CO_(2)排放量变化的贡献.结果表明:2020~2060年中国行业CO_(2)排放总量呈现先增后降的趋势,2030年左右达峰,后经历平台期,2035年开始快速减排,2050年后减排速度变慢;CO_(2)排放增长的驱动因素为最终需求规模,最主要的促降因素为碳排放强度;投入产出结构和最终需求结构只在个别时期促进CO_(2)排放增长,总体上对CO_(2)减排有积极作用,但作用有限,且伴随着经济结构趋于稳定,这两者的作用逐渐削弱;CO_(2)排放总量和4项因素的变化幅度在达峰平台期、快速减排期与全面中和期3个阶段由小变大再变小;从行业角度看,电力等公共品生产和供应业、金属产品制造业、交通运输仓储和邮政业、化学工业是CO_(2)减排的主要动力.为有效实现CO_(2)减排目标,政府实施CO_(2)减排政策的过程中,应在继续充分发挥碳排放强度积极效应的同时,更加注重释放重点行业技术创新、最终需求结构优化对CO_(2)减排的积极作用.

新能源材料与器件课程O2O智慧教学模式探索

新能源材料对“碳达峰、碳中和”国家战略目标的实现具有重要的支撑作用。新能源材料与器件课程是新能源材料研究与应用的基础,也是新能源人才培养过程中的主干课程,现有教学模式很难满足对高质量新能源人才的培养,因此该文提出将“智慧教学”理念及“O2O模式”应用到课程教学的各个环节。通过信息化技术搭建智慧教育平台,延伸教与学的边界,建构出一种虚实相生、情境结合、意象交融的教学空间;通过智能化的方式提高教学效率,增强教学互动,提升学生学习效率,加强信息反馈和教学管理。从而开发教师和学生的聪明才智和主观能动性,使投入得到最大化产出、获得最优学习效果,支撑我国新能源人才的培养。

IPDI改性水性醇酸乳液的制备及性能研究

水性醇酸涂料漆膜的硬度、光泽与耐水性较油性醇酸涂料差,改进这些性能对水性醇酸涂料的推广应用有重要意义。本研究以大豆油、季戊四醇及苯酐为原料,采用醇解法合成醇酸预聚体,并引入异佛尔酮二异氰酸酯(IPDI)改性,通过相反转法制成IPDI改性水性醇酸乳液。研究了IPDI用量、中和剂AMP-95用量、乳化工艺对水性醇酸乳液性能的影响。结果表明:当IPDI用量(以苯酐的质量计)为50%,AMP-95用量(以树脂的质量计)为0.6%,乳化剂用量(以树脂的质量计)为5%,搅拌速度为4000 r/min时,所制得的水性醇酸乳液漆膜硬度达2H,光泽为90.87,表干2 h,耐水性24 h无异常,漆膜综合性能表现良好。