This research work developed a model for the MIP riser reactor using the data collected from an industrial MIP unit.Based on analysis of flow patterns in the reactor,three models were established and a comparison was ...This research work developed a model for the MIP riser reactor using the data collected from an industrial MIP unit.Based on analysis of flow patterns in the reactor,three models were established and a comparison was made on each other.The results indicated that Model Ⅲ,which was assumed a plug flow in the first reaction zone and a gas plug flow and a continuously stirred catalyst flow in the second reaction zone,was the best.The results of this research could offer an information and guidance for optimization and development of MIP unit.展开更多
In this article, a multiobjective optimization strategy for an industrial naphtha continuous catalytic reform-ing process that aims to obtain aromatic products is proposed. The process model is based on a 20-lumped ki...In this article, a multiobjective optimization strategy for an industrial naphtha continuous catalytic reform-ing process that aims to obtain aromatic products is proposed. The process model is based on a 20-lumped kinetics re-action network and has been proved to be quite effective in terms of industrial application. The primary objectives in-clude maximization of yield of the aromatics and minimization of the yield of heavy aromatics. Four reactor inlet tem-peratures, reaction pressure, and hydrogen-to-oil molar ratio are selected as the decision variables. A genetic algorithm, which is proposed by the authors and named as the neighborhood and archived genetic algorithm (NAGA), is applied to solve this multiobjective optimization problem. The relations between each decision variable and the two objectives are also proposed and used for choosing a suitable solution from the obtained Pareto set.展开更多
A mathematical model has been developed for the simulation of gas-particle flow and fluid catalytic cracking in downer reactors. The model takes into account both cracking reaction and flow behavior through a four-lum...A mathematical model has been developed for the simulation of gas-particle flow and fluid catalytic cracking in downer reactors. The model takes into account both cracking reaction and flow behavior through a four-lump reaction kinetics coupled with two-phase turbulent flow. The prediction results show that the relatively large change of gas velocity affects directly the axial distribution of solids velocity and void fraction, which significantly interact with the chemical reaction. Furthermore, model simulations are carried out to determine the effects of such parameters on product yields, as bed diameter, reaction temperature and the ratio of catalyst to oil, which are helpful for optimizing the yields of desired products. The model equations are coded and solved on CFX4.4.展开更多
文摘This research work developed a model for the MIP riser reactor using the data collected from an industrial MIP unit.Based on analysis of flow patterns in the reactor,three models were established and a comparison was made on each other.The results indicated that Model Ⅲ,which was assumed a plug flow in the first reaction zone and a gas plug flow and a continuously stirred catalyst flow in the second reaction zone,was the best.The results of this research could offer an information and guidance for optimization and development of MIP unit.
基金Supported by the National Natural Science Foundation of China (No.60421002).
文摘In this article, a multiobjective optimization strategy for an industrial naphtha continuous catalytic reform-ing process that aims to obtain aromatic products is proposed. The process model is based on a 20-lumped kinetics re-action network and has been proved to be quite effective in terms of industrial application. The primary objectives in-clude maximization of yield of the aromatics and minimization of the yield of heavy aromatics. Four reactor inlet tem-peratures, reaction pressure, and hydrogen-to-oil molar ratio are selected as the decision variables. A genetic algorithm, which is proposed by the authors and named as the neighborhood and archived genetic algorithm (NAGA), is applied to solve this multiobjective optimization problem. The relations between each decision variable and the two objectives are also proposed and used for choosing a suitable solution from the obtained Pareto set.
基金the Natura Science Foundation of China under contract number:20176024
文摘A mathematical model has been developed for the simulation of gas-particle flow and fluid catalytic cracking in downer reactors. The model takes into account both cracking reaction and flow behavior through a four-lump reaction kinetics coupled with two-phase turbulent flow. The prediction results show that the relatively large change of gas velocity affects directly the axial distribution of solids velocity and void fraction, which significantly interact with the chemical reaction. Furthermore, model simulations are carried out to determine the effects of such parameters on product yields, as bed diameter, reaction temperature and the ratio of catalyst to oil, which are helpful for optimizing the yields of desired products. The model equations are coded and solved on CFX4.4.