Potential of Magmatic Ni-Cu Deposits of the Hualong Block,Qilian Mountains

The Jinchuan magmatic Ni-Cu deposit,located in the Longshou Mountain region,is the largest producer of Ni and Cu in China,with mineralization being related to mafic and ultramafic magmatism.Previous studies have shown that the Longshou Mountain was combined with the Qilian Mountains before Neoproterozoic,and was separated from each other due to the opening of late Qilian oceanic basin in the Paleozoic.The relict Precambrian microcontinents of the Longshou Mountain and Qilian Mountain

Geology and mineralization of the Hongqiling large magmatic nickel-copper-cobalt deposit(22×10^(4)t)in Jilin Province,China:A review

The Hongqiling large nickel-copper-cobalt deposit(hereafter referred to as the Hongqiling deposit),a typical mafic-ultramafic copper-nickel deposit in China,boasts proven Ni(Ni)resources of approximately 22×10^(4)t,associated copper resources of 2×10^(4)t,and associated cobalt(Co)resources of 0.5×10^(4)t,with Ni reserves ranking 10th among China's magmatic nickel deposits.Geotectonically,the Hongqiling deposit is situated in the superimposed zone between the Xing'an-Mongolian orogenic belt and the circum-Western Pacific's active continental margin belt.Its ore-bearing plutons occur within the metamorphic rocks of the Ordovician Hulan Group,with the emplacement of plutons and the locations of orebodies governed by the deep-seated Huifahe fault and its secondary NW-trending Fujia-Hejiagou-Beixinglong-Changsheng fault zone.In the deposit,the rock assemblages of ore-bearing plutons predominantly encompass gabbro-pyroxenite-olivine pyroxenite-pyroxene peridotite(pluton No.1)and norite-orthopyroxenite-harzburgite(pluton No.7),with ore-bearing lithofacies consisting primarily of olivine pyroxenite and pyroxenite facies.The Hongqiling deposit hosts stratoid,overhanging lentoid,veined,and pure-sulfide veined orebodies.Its ores principally contain metallic minerals including pyrrhotite,pentlandite,chalcopyrite,violarite,and pyrite.Despite unidentified magma sources of ore-bearing mafic-ultramafic rocks,it is roughly accepted that the magmatic evolution in the Hongqiling deposit primarily involved fractional crystallization and crustal contamination.The ore-forming materials were primarily derived from the upper mantle,mixed with minor crustal materials.The ore-bearing mafic-ultramafic rocks in the deposit,primarily emplaced during the Indosinian(208-239 Ma),were formed in an intense extension setting followed by the collisional orogeny between the North China Plate and the Songnen-Zhangguangcai Range Block during the Middle-Late Triassic.From the perspective of the metallogenic geological setting,surrounding rocks,ore-controlling structures,and rock assemblages,this study identified one favorable condition and seven significant indicators for prospecting for Hongqiling-type nickel deposits and developed a prospecting model of the Hongqiling deposit.These serve as valuable references for exploring similar nickel deposits in the region,as well as the deep parts and margins of the Hongqiling deposit.

Time scales and length scales in magma ?ow pathways and the origin ofmagmatic Ni-Cu-PGE ore deposits

Ore forming processes involve the redistribution of heat, mass and momentum by a wide range of processes operating at different time and length scales. The fastest process at any given length scale tends to be the dominant control. Applying this principle to the array of physical processes that operate within magma flow pathways leads to some key insights into the origins of magmatic Ni-Cu-PGE sulfide ore deposits. A high proportion of mineralised systems, including those in the super-giant Noril'sk-Talnakh camp, are formed in small conduit intrusions where assimilation of country rock has played a major role. Evidence of this process is reflected in the common association of sulfides with varitextured contaminated host rocks containing xenoliths in varying stages of assimilation. Direct incorporation of S-bearing country rock xenoliths is likely to be the dominant mechanism for generating sulfide liquids in this setting. However, the processes of melting or dissolving these xenoliths is relatively slow compared with magma flow rates and, depending on xenolith lithology and the composition of the carrier magma, slow compared with settling and accumulation rates. Chemical equilibration between sulfide droplets and silicate magma is slower still, as is the process of dissolving sulfide liquid into initially undersaturated silicate magmas. Much of the transport and deposition of sulfide in the carrier magmas may occur while sulfide is still incorporated in the xenoliths, accounting for the common association of magmatic sulfide-matrix ore breccias and contaminated "taxitic" host rocks. Effective upgrading of so-formed sulfide liquids would require repetitive recycling by processes such as reentrainment, back flow or gravity flow operating over the lifetime of the magma transport system as a whole. In contrast to mafic-hosted systems, komatiite-hosted ores only rarely show an association with externally-derived xenoliths, an observation which is partially due to the predominant formation of ores in lava flows rather than deep-seated intrusions, but also to the much shorter timescales of key component systems in hotter, less viscous magmas. Nonetheless, multiple cycles of deposition and entrainment are necessary to account for the metal contents of komatiite-hosted sulfides. More generally, the time and length scale approach introduced here may be of value in understanding other igneous processes as well as non-magmatic mineral systems.

Magmatic Ni-Cu-(PGE) deposits in magma plumbing systems:Features,formation and exploration

The three most crucial factors for the formation of large and super-large magmatic sulfide deposits are： （1） a large volume of mantle-derived mafic-ultramafic magmas that participated in the formation of the deposits; （2） fractional crystallization and crustal contamination, particularly the input of sulfur from crustal rocks, resulting in sulfide immiscibility and segregation; and （3） the timing of sulfide concentration in the intrusion. The super-large magmatic Ni-Cu sulfide deposits around the world have been found in small mafic-ultramafic intrusions, except for the Sudbury deposit. Studies in the past decade indicated that the intrusions hosting large and super-large magmatic sulfide deposits occur in magma conduits, such as those in China, including Jinchuan （Gansu）, Yangliuping （Sichuan）, Kalatongke （Xinjiang）, and Hongqiling （Jilin）. Magma conduits as open magma systems provide a perfect environment for extensive concentration of immiscible sulfide melts, which have been found to occur along deep regional faults. The origin of many mantle-derived magmas is closely associated with mantle plumes, intracontinental rifts, or post-collisional extension. Although it has been confirmed that sulfide immiscibility results from crustal contamination, grades of sulfide ores are also related to the nature of the parental magmas, the ratio between silicate magma and immiscible sulfide melt, the reaction between the sulfide melts and newly injected silicate magmas, and fractionation of the sulfide melt. The field relationships of the ore-bearing intrusion and the sulfide ore body are controlled by the geological features of the wall rocks. In this paper, we attempt to demonstrate the general characteristics, formation mechanism,tectonic settings, and indicators of magmatic sulfide deposits occurring in magmatic conduits which would provide guidelines for further exploration.

Platinum-group Elements Geochemistry of the Yangliuping Magmatic Ni-Cu-PGE Sulfide Deposit:Implications of Its Genetic Link with the Extrusive Basalts

Primitive mantle normalized Platinum group elements (PGE) concentration patterns for the Zhengziyanwo intrusion and Dashibao Formation basalts are of positive slope, similar to most of the world class magmatic Ni Cu PGE sulfide deposits. Characters of this intrusion and its related ores and Dashibao Formation basalts are their negative Pt anomaly and high concentration of Rh relative to Pt and Pd, facts being interpreted to be the results of crystallization and fractionation of Pt alloys and spinel phase free crystallization history for the magma, respectively. PGE parameters of the Dashibao Formation basalts are consistent with the general trend of those found for the Zhengziyanwo intrusion, and this might infer a genetic link between them.

Magmatic Sulfide Ni-Cu Deposits in China

Deep seated magmatic liquation injection deposits form a major type of magmatic sulfide deposit in China. The reserves of nickel and copper in this type of deposit may attain several hundred thousand tons (e.g.Hongqi 7 and Karatunggu) to nearly ten million tons (e.g.Jinchuan). Those deposits can be classified as large or superlarge deposits. The ore grade is relatively high, commonly with w (Ni)>1 %. The mineralized intrusions are small in size, generally only 0.0 n km 2 to 0. n km 2, with the largest one not exceeding a few km 2. Before intruding, the primary magmas have undergone liquation and partial crystallization at depth; as a result, the magmas have partitioned into barren magma, ore bearing magma, ore rich magma and ore magma, which then ascended and injected into the present locations once or multiple times, to form ore deposits. The above mentioned mineralizing process is known as deep seated magmatic liquation injection mineralization. The volume of the barren magma is generally much larger than those of the ore bearing magma, ore rich magma and ore magma. In the ascending process, most of the barren magma intruded into different locations or outpoured onto the ground surface, forming intrusions or lava flows. The rest barren magma, ore bearing magma, ore rich magma and ore magma may either multiple times inject into the same place in which rocks and ores are formed or separately inject into different spaces to form rocks and ores. Such deep seated magmatic liquation injection deposits have a much smaller volume, greater ore potential and higher ore grade than those of in situ magmatic liquation deposits. Consequently, this mineralizing process leads to the formation of large deposits in small intrusions.

Classification of Magmatic Sulphide Deposits in China and Mineralization of Small Intrusions

Many important metal resources, such as Ni （Cu, Co）, PGE, exist in magmatic sulfide deposits, are a hot spot in geological research. We divide the magmatic sulphide deposits in China into four types according to their tectonic setting, intruding mode, ore deposit mode, main metallogenic elements. The four types are as follows： （1） Small-intrusion deposits in paleo-continent; （2） Smallintrusion deposits in continental flood basalt; （3） Small-intrusion deposits in orogenic belt; and （4） The deposits associated with ophiolites. On the basis of the classification, we put forward that the main magmatic metallogenic type in China is small-intrusion metallogeny, and describe its characteristics from small intrusions related concept, three geologic settings, three volcanic-intrusive assemblages and metallogenic key factors. According to the experiences of prospecting at home and abroad, we point out that there is big potential in prospecting small-intrusion deposits, which need further study. At last, we indicate that small-intrusion metallogeny not only widely distributes in mafic-ultramafic intrusions, but also has an important economic value and scientific significance in intermediate-acid intrusions.

Rare Earth Element Geochemistry on Magmatic Rocks and Gold Deposits in Shizishan Ore-Field of Tongling, China

REE geochemical characteristics of the magmatic rocks and gold deposits in Shizishan ore-field of Tongling were studied. Three types of the magmatic rocks have almost the same chondrite-normalized REE patterns, Eu and Ce anomalous values, and ∑REE, ∑LREE/∑HREE regular changes, which indicates that their magmas come from the same source and their digenetic mechanism is fractional crystallization. In three gold deposits, the mineral ores and related altered rocks have similar chondrite-normalized REE patterns and sharp Eu positive anomalous values. The REE contents reduced from the magmatic rocks to skamization or alteration magmatic rocks, skam type ores, sulphide type ores, wall-rocks limestone or marble. The REE geochemical characteristics of the ores and related rocks show that primary fluids originated from magmatic differentiation in lower pressure of shallow crust, ore-forming hydrothermal solutions gained REE and mineralization elements further from leaching the magmatic rocks, then superimposed and reformed the limestones or marbles and deposited ore-forming material.

Geochronology, Geochemistry and Sr-Nd-Pb-Hf Isotopes of No. I Complex from the Shitoukengde Ni–Cu Sulfide Deposit in the Eastern Kunlun Orogen, Western China: Implications for the Magmatic Source, Geodynamic Setting and Genesis

The Shitoukengde Ni-Cu deposit, located in the Eastern Kunlun Orogen, comprises three mafic-ultramafic complexes, with the No. I complex hosting six Ni-Cu orebodies found recently. The deposit is hosted in the small ultramafic bodies intruding Proterozoic metamorphic rocks. Complexes at Shitoukengde contain all kinds of mafic-ultramafic rocks, and olivine websterite and pyroxene peridotite are the most important Ni-Cu-hosted rocks. Zircon U-Pb dating suggests that the Shitoukengde Ni-Cu deposit formed in late Silurian （426-422 Ma）, and their zircons have ~Hf（t） values of-9.4 to 5.9 with the older TDMm ages （0.80-1.42 Ga）. Mafic-ultramafic rocks from the No. I complex show the similar rare earth and trace element patterns, which are enriched in light rare earth elements and large ion iithophile elements （e.g., K, Rb, Th） and depleted in heavy rare earth elements and high field strength elements （e.g., Ta, Nb, Zr, Ti）. Sulfides from the deposit have the slightly higher ~34S values of 1.9-4.3%o than the mantle （0 ~ 2%o）. The major and trace element characteristics, and Sr-Nd-Pb and Hf, S isotopes indicate that their parental magmas originated from a metasomatised, asthenospheric mantle source which had previously been modified by subduction-related fluids, and experienced significant crustal contamination both in the magma chamber and during ascent triggering S oversaturation by addition of S and Si, that resulted in the deposition and enrichment of sulfides. Combined with the tectonic evolution, we suggest that the Shitoukengde Ni-Cu deposit formed in the post-collisional, extensional regime related to the subducted oceanic slab break-off after the Wanbaogou oceanic basalt plateau collaged northward to the Qaidam Block in late Silurian.

Geological Characteristics and Metallogenic Setting of Representative Magmatic Cu-Ni Deposits in the Tianshan-Xingmeng Orogenic Belt, Central Asia

A great number of magmatic Cu-Ni deposits(including Kalatongke in Xinjiang and Hongqiling in Jilin) are distributed over a distance of almost 3000 km across the Tianshan-Xingmeng Orogenic Belt, from Tianshan Mountains in Xinjiang in the west, to Jilin in eastern China in the east. These deposits were formed during a range of magmatic episodes from the Devonian to the Triassic. Significant magmatic Cu-Ni-Co-PGE deposits were formed from the Devonian period in the Nalati arc(e.g. Jingbulake Cu-Ni in Xinjiang), Carboniferous period in the Puerjin-Ertai arc(e.g. Kalatongke Cu-Ni-Co-PGE in Xinjiang), Carboniferous period in the Dananhu-Touquan arc(e.g. Huangshandong, Xiangshan and Tulaergen in estern Tianshan, Xinjiang) to Triassic period in the Hulan arc(e.g. Hongqiling Cu-Ni in Jilin). In addition to the overall tectonic, geologic and distribution of magmatic Cu-Ni deposits in the Tianshan-Xingmeng Orogenic Belt, the metallogenic setting, deposit geology and mineralization characteristics of each deposit mentioned above are summarized in this paper. Geochronologic data of Cu-Ni deposits indicate that, from west to east, the metallogenic ages in the Tianshan-Xingmeng Orogenic Belt changed with time, namely, from the Late Caledonian(~440 Ma), through the Late Hercynian(300-265 Ma) to the Late Indosinian(225-200 Ma). Such variation could reflect a gradual scissor type closure of the paleo Asian ocean between the Siberia Craton and the North China Craton from west to east.

Dating Magmatic Hornblende and Biotite and Hydrothermal Sericite by Laser Probe Technique:Constraints on Genesis of Wangershan Gold Deposit,Eastern Shandong Province,China

The Wangershan gold deposit and spatially related Shangzhuang granite, eastern Shandong Province, have been precisely dated by 40 Ar/ 39 Ar laser incremental heating technique. Magmatic hornblende and biotite, collected from the Shangzhuang granites, yielded well-defined and reproducible plateau ages at 128.1-127.5 and 124.4-124.1 Ma (2 σ ), measuring the cooling ages of the intrusion at ca. 500 ℃ and 300-350 ℃, respectively. Hydrothermal sericite extracted from auriferous vein gave high-quality plateau ages between (120.6±0.3) Ma and (120.0±0.4) Ma (2 σ ). Given the similarity of the closure temperature for argon diffusion (300-350 ℃) in the sericite mineral to the homogenization temperature of primary fluid inclusions in the quartz from gold ores, and the intergrowth of sericite with native gold, present 40 Ar/ 39 Ar sericite ages can be reliably interpreted in terms of the mineralization age for the Wangershan deposit. 40 Ar/ 39 Ar hornblende and biotite ages permit an estimate for the cooling rate of the Shangzhuang granite at about 50 ℃/Ma. There are abundant intermediate-mafic dikes in most gold camps of eastern Shandong, whose ages of formation have been previously constrained mainly at 121-119 Ma. The temporal association between the Shangzhuang granite, the Wangershan gold deposit, and the widespread dikes confirms that intrusive activity, gold mineralization, and dike emplacement in this region were broadly coeval, reflecting significant continental lithosphere thinning and resulting crustal extension of Early Cretaceous in eastern China.

Magmatic Hydrothermal Origin of the Wenyu Copper Polymetallic Deposit, Southern Lancangjiang Zone, SW China

The Wenyu copper polymetallic deposit, with proven reserves of about 0.23 Mt Cu, 394 t Ag and 0.04 Mt Pb, is located in the central part of the Lancangjiang volcanic rock belt （Fig. l a）, which is one of the most potential copper polymetallic exploration areas in SW China.

Magmatic Evolution and Mineralization Process of the Super-Large Shihuiyao Rb–Nb–Ta Deposit,Southern Great Xing'an Range,China

Rare metal ore reserves are an important strategic resource, and their metallogenic mechanism and mineralization studies have also been received widespread international attention.

Sea-floor exhalative sedimentary and magmatic hydrothermal superimposition on the Bainiuchang polymetallic deposit in Yunnan Province: REE geochemical evidence

In order to study the characteristics of sea-floor exhalative sedimentary and magmatic hydrothermal superimposition on the Bainiuchang polymetallic deposit, the REE compositions of the granites, host-rocks and ores have been systematically analyzed by ICP-MS. As viewed from their REE compositions, the granites show obvious negative Eu anomalies and weak negative Ce anomalies. According to their REE characteristics, the host-rocks were derived partly from sea-floor exhalative sediments. In terms of their REE compositions, the ores can be divided into two groups: one group, of which the samples were collected from the Baiyang segment relatively far away from the Bozhushan granite batholith, possesses positive Eu anomalies or no Eu anomaly and negative Ce anomalies, indicating that ore-forming hydrothermal fluid was relatively reductive and its temperature was higher than 250 ℃. Furthermore, the coinstantaneous presence of positive Eu anomalies and negative Ce anomalies indicate that the convective mixing of a little amount of seawater with hydrothermal fluid had happened while ores were precipitated on ancient sea floor. The other group, of which the samples were mainly collected from the Chuanxindong and Duimenshan segments near the Bozhushan granite batholith, has similar chondrite-monalized REE distribution patterns to those of the magmatic rocks. But as a whole, the REE characteristics of both groups change gradually starting from the Bozhushan granite batholith. Based on the REE characteristics of the granites, host-rocks and ores, it is suggested that the ore-forming metals seem to have come from several different sources.

The Sachakou Deposit in West Kunlun of Xinjiang: A Pb-Zn Polymetallic Deposit Associated with Magmatic Metasomatism of Carbonate Rock

Objective The Sachakou Pb-Zn polymetallic deposit is located in Hetian County, Xinjiang （geographical coordinates of E78° 57＇ 54.30＂-78°59＇ 53.63＂, N34° 39＇ 27.50＂-34° 40＇ 57.21＂）. It belongs to the West Kunlun orogenic belt on the northwest edge of the Qinghai-Tibet Plateau and is connected to the Sanjiang orogenic belt to the south （Spurlin et al., 2005）. In recent years, a series of Pb-Zn mineralized spots and deposits have been discovered in this area one after another, which is called the Huoshaoyun ore concentration area. Among them, the Sachakou Pb-Zn deposit has reserves up to140 Mt, which has reached a large scale. However, the study on the genesis of deposits in this area has only just begun. This work studied the genesis ofthis Pb-Zn deposit in order to provide new ideas for the genesis of regional deposits and regional prospecting.

Magmatic Evolution and Mineralization of Porphyry Copper-Gold Deposits in the Duolong Ore Concentration Area, Tibet

The Bangong Lake-Nujiang River metallogenic belt is located between the Qiangtang Block and Lhasa Block, and the Duolong ore concentration area is located in the western section of the Bangong Lake-Nujiang River metallogenic belt. Till now, several large and super large copper-gold deposits, such as Duobuza, Bolong, Dibaonamugang, Naruo and Rongna deposits have been discovered in this area, mainly porphyry copper-gold ones.

Mineral Chemical Characteristics of Gabbro-diorite for Shulouqiu Uranium Deposit in Northern Guangdong, China: Constraint on the Magmatic Source

1 Introduction The uranium deposits related with Indosinian and Yanshanian granite have provided the abundant resource of uranium during the past several decades in China.The deposits are mainly distributing in the Guidong granite

Advances in Research of Mineral Chemistry of Magmatic and Hydrothermal Biotites

Biotite is an important hydrated ferromagnesian silicate mineral in igneous rocks and porphyry deposits.The determination of chemical compositions of biotite plays an important role in both igneous petrology and ore forming processes.This paper summarizes research results of magmatic and hydrothermal biotites exemplified by the Lakange porphyry Cu–Mo deposit and the Qulong porphyry Cu deposit in the Gangdese porphyry–skarn metallogenic belt,Tibet.Biotite mineral chemistry can provide critical insights into classification,geothermometer,geothermobarometry,oxygen fugacity,petrogenesis and tectonic setting,evaluating magmatic-hydrothermal process by halogen and halogen fugacity ratios,and distinguishing between barren and mineralized rocks.Biotite provides the latest mineralogical evidence on metallogenic prognosis and prospecting evaluation for porphyry Cu polymetallic deposits or magmatic hydrothermal deposits.