Field-assisted electrocatalytic reactions are demonstrated to be sufficient strategies in enhancing the electrocatalyst activities for oxygen evolution reaction(OER).Here,we report the in-situ magnetic field enhanced ...Field-assisted electrocatalytic reactions are demonstrated to be sufficient strategies in enhancing the electrocatalyst activities for oxygen evolution reaction(OER).Here,we report the in-situ magnetic field enhanced electrocatalytic activity in ferromagnetic FeCo_(2)O_(4)nanofibers.Our results demonstrate that the overpotential of FeCo_(2)O_(4)nanofibers at 10 mA cm^(-2)shows a left-shift of 40 mV for the OER by applying an external magnetic field,and no obvious change has been observed in the non-ferromagnetic-order Co3O4nanofibers.Calculation results indicate that there are more overlaps between the density of states for Co3d and O 2p by applying an external magnetic field.Accordingly,the spin hybridization of 3d-2p and the kinetics of spin charge transfer are optimized in ferromagnetic FeCo_(2)O_(4),which can promote the adsorption of oxygen-intermediates and electron transfer,significantly improving its electrocatalytic efficiency.What’s more,the maximum power density of the FeCo_(2)O_(4)nanofibers based Zn-air battery(ZAB)increases from 97.3 mW cm^(-2)to 108.2 mW cm^(-2)by applying an external magnetic field,providing a new idea for the application of magnetic cathode electrocatalysts in ZABs.展开更多
Due to the growing interest in studying the compression and disruption of the plasma filament in magnetic fusion devices and Z-pinches, this work may be important for new developments in the field of controlled thermo...Due to the growing interest in studying the compression and disruption of the plasma filament in magnetic fusion devices and Z-pinches, this work may be important for new developments in the field of controlled thermonuclear fusion. Recently, on a coaxial plasma accelerator, we managed to obtain the relatively long-lived(~300 μs) plasma filaments with its self-magnetic field. This was achieved after modification of the experimental setup by using high-capacitive and lowinductive energy storage capacitor banks, as well as electrical cables with low reactive impedance. Furthermore, we were able to avoid the reverse reflection of the plasma flux from the end of the plasma accelerator by installing a special plasma-absorbing target. Thus, these constructive changes of the experimental setup allowed us to investigate the physical properties of the plasma filament by using the comprehensive diagnostics including Rogowski coil,magnetic probes, and Faraday cup. As a result, such important plasma parameters as density of ions and temperature of electrons in plasma flux, time dependent plasma filament’s azimuthal magnetic field were measured in discharge gap and at a distance of 23.5 cm from the tip of the cathode. In addition, the current oscillograms and Ⅰ–Ⅴ characteristics of the plasma accelerator were obtained. In the experiments, we also observed the charge separation during the acceleration of plasma flow via oscillograms of electron and ion beam currents.展开更多
In this study,an environmental simulation platform(ETS-02)was constructed for high-precision geodesic instruments(e.g.,absolute/relative gravimeters and inclinometers),to test the disturbances caused by environmental ...In this study,an environmental simulation platform(ETS-02)was constructed for high-precision geodesic instruments(e.g.,absolute/relative gravimeters and inclinometers),to test the disturbances caused by environmental fl uctuations.The outer layer of the platform was constructed with two sets of rectangular electromagnetic coils,which generated the required magnetic fi eld when current was applied.The inner layer was a closed cabin in which radiators were distributed such that the temperature of the experimental space inside the cabin could be controlled,by energy exchange between the radiators and a thermal controller through the fl owing liquid.A high-precision hexapod was used to simulate the tilt-related eff ect.The platform was capable of adjusting temperatures within a dynamic range of 0℃-70℃ at a resolution of 0.01℃.The noise of the power-spectrum density when the cabin was set to room temperature was measured as 0.03℃/Hz^(1/2) at 1 mHz.The magnetic field simulation had a dynamic range of±300μT and stability of 20 nT.The resolution of the ground-tilt simulation was 1 arc s.The inner space of the platform had a volume of approximately 5 m^(3),which is sufficient for most types of instruments to be tested for a general environmental coupling effect.To illustrate the application of the platform,a dual-axis inclinometer was built and tested carefully with the platform,and the accuracy of the calibration factors was found to be signifi cantly improved.展开更多
The main theme of the current article is to investigate the heat transfer in the pulsatile flow of an electrically conducting viscous fluid in a constricted channel under the effect of the magnetic field and thermal r...The main theme of the current article is to investigate the heat transfer in the pulsatile flow of an electrically conducting viscous fluid in a constricted channel under the effect of the magnetic field and thermal radiation.The unsteady governing equations simplified for low conducting fluids are solved numerically by finite difference method using stream-vorticity function formulation.The influence of the flow parameters such as the Hartmann number(magnetic parameter),Strouhal number(flow pulsation parameter),Prandtl number,and radiation parameter is studied on the relevant flow profiles.The influence of different emerging parameters on the skin friction coefficient and Nusselt number are examined,as well.In general,the profiles are observed to exhibit a relatively more regular pattern upstream of the construction than that downstream of the constriction.展开更多
基金financially supported by the Natural Science Foundation(NSF) of China(91963201 and 12174163)the Creation of Science and Technology of Northwest Normal University,China(NWNU-LKQN2020-22)。
文摘Field-assisted electrocatalytic reactions are demonstrated to be sufficient strategies in enhancing the electrocatalyst activities for oxygen evolution reaction(OER).Here,we report the in-situ magnetic field enhanced electrocatalytic activity in ferromagnetic FeCo_(2)O_(4)nanofibers.Our results demonstrate that the overpotential of FeCo_(2)O_(4)nanofibers at 10 mA cm^(-2)shows a left-shift of 40 mV for the OER by applying an external magnetic field,and no obvious change has been observed in the non-ferromagnetic-order Co3O4nanofibers.Calculation results indicate that there are more overlaps between the density of states for Co3d and O 2p by applying an external magnetic field.Accordingly,the spin hybridization of 3d-2p and the kinetics of spin charge transfer are optimized in ferromagnetic FeCo_(2)O_(4),which can promote the adsorption of oxygen-intermediates and electron transfer,significantly improving its electrocatalytic efficiency.What’s more,the maximum power density of the FeCo_(2)O_(4)nanofibers based Zn-air battery(ZAB)increases from 97.3 mW cm^(-2)to 108.2 mW cm^(-2)by applying an external magnetic field,providing a new idea for the application of magnetic cathode electrocatalysts in ZABs.
基金supported by the Ministry of Education and Science of the Republic of Kazakhstan(IRN AP08053373)。
文摘Due to the growing interest in studying the compression and disruption of the plasma filament in magnetic fusion devices and Z-pinches, this work may be important for new developments in the field of controlled thermonuclear fusion. Recently, on a coaxial plasma accelerator, we managed to obtain the relatively long-lived(~300 μs) plasma filaments with its self-magnetic field. This was achieved after modification of the experimental setup by using high-capacitive and lowinductive energy storage capacitor banks, as well as electrical cables with low reactive impedance. Furthermore, we were able to avoid the reverse reflection of the plasma flux from the end of the plasma accelerator by installing a special plasma-absorbing target. Thus, these constructive changes of the experimental setup allowed us to investigate the physical properties of the plasma filament by using the comprehensive diagnostics including Rogowski coil,magnetic probes, and Faraday cup. As a result, such important plasma parameters as density of ions and temperature of electrons in plasma flux, time dependent plasma filament’s azimuthal magnetic field were measured in discharge gap and at a distance of 23.5 cm from the tip of the cathode. In addition, the current oscillograms and Ⅰ–Ⅴ characteristics of the plasma accelerator were obtained. In the experiments, we also observed the charge separation during the acceleration of plasma flow via oscillograms of electron and ion beam currents.
基金This work was supported by National Scientifi c Instrument Development Fund(No.ZDYZ2012-1-04)State Natural Sciences Fund(No.11235004,91636112,41474163).
文摘In this study,an environmental simulation platform(ETS-02)was constructed for high-precision geodesic instruments(e.g.,absolute/relative gravimeters and inclinometers),to test the disturbances caused by environmental fl uctuations.The outer layer of the platform was constructed with two sets of rectangular electromagnetic coils,which generated the required magnetic fi eld when current was applied.The inner layer was a closed cabin in which radiators were distributed such that the temperature of the experimental space inside the cabin could be controlled,by energy exchange between the radiators and a thermal controller through the fl owing liquid.A high-precision hexapod was used to simulate the tilt-related eff ect.The platform was capable of adjusting temperatures within a dynamic range of 0℃-70℃ at a resolution of 0.01℃.The noise of the power-spectrum density when the cabin was set to room temperature was measured as 0.03℃/Hz^(1/2) at 1 mHz.The magnetic field simulation had a dynamic range of±300μT and stability of 20 nT.The resolution of the ground-tilt simulation was 1 arc s.The inner space of the platform had a volume of approximately 5 m^(3),which is sufficient for most types of instruments to be tested for a general environmental coupling effect.To illustrate the application of the platform,a dual-axis inclinometer was built and tested carefully with the platform,and the accuracy of the calibration factors was found to be signifi cantly improved.
文摘The main theme of the current article is to investigate the heat transfer in the pulsatile flow of an electrically conducting viscous fluid in a constricted channel under the effect of the magnetic field and thermal radiation.The unsteady governing equations simplified for low conducting fluids are solved numerically by finite difference method using stream-vorticity function formulation.The influence of the flow parameters such as the Hartmann number(magnetic parameter),Strouhal number(flow pulsation parameter),Prandtl number,and radiation parameter is studied on the relevant flow profiles.The influence of different emerging parameters on the skin friction coefficient and Nusselt number are examined,as well.In general,the profiles are observed to exhibit a relatively more regular pattern upstream of the construction than that downstream of the constriction.