Time-stability of sintered Nd-Fe-B permanent magnet with lower oxygen content

Time-stability of sintered Nd-Fe-B magnet with lower content of oxygen at different temperatures and humidity conditions for 400 d was investigated.Results showed that the magnetic flux loss was-0.68% for the non-electroplating samples and-0.43% for the electroplating samples at room temperature and average humidity was 25% during 400 d,respectively.The magnetic flux loss of the plated samples was lower than non-plated samples under the conditions of room temperature and with the average humidity of 54%,but the magnetic flux loss of the plated samples was larger than that of the non-plated sample at 80 oC.The magnetic flux loss of electroplated and non-electroplated sintered Nd-Fe-B magnets was less than 1% for 400 d,which showed that the N40SH grade magnets have good time stability.

Effect of niobium substitution on microstructures and thermal stability of TbCu7-type Sm-Fe-N magnets

This paper reports crystal structures, magnetic properties and thermal stability of TbCu7-type Sm（8.5）Fe（（85.8-x）Co（4.5）Zr（1.2）Nbx（x = 0-1.8） melt-spun compounds and their nitrides, investigated by means of X-ray diffraction, vibrating sample magnetometer, flux meter and transmission electron microscope. It is found that the lattice parameter ratio c/a of TbCu7-type crystal structure increases with Nb substitution, which indicates that the Nb can increase the stability of the metastable phase in the Sm-Fe ribbons. Nb substitution impedes the formation of magnetic soft phase a-Fe in which reversed domains initially form during the magnetization reversal process. Meanwhile, Nb substitution refines grains and leads to homogeneous micro structure with augmented grain boundaries. Thus the exchange coupling pining field is enhanced and irreversible domain wall propagation gets suppressed. As a result, the magnetic properties are improved and the irreversible flux loss of magnets is notably decreased. A maximum value 771.7 kA/m of the intrinsic coercivity H（cj） is achieved in the 1.2 at% substituted samples.The irreversible flux loss for 2 h exposure at 120 ℃ declines from 8.26% for Nb-free magnets to 6.32% for magnets with 1.2 at% Nb substitution.