Quantum computing is a field with increasing relevance as quantum hardware improves and more applications of quantum computing are discovered. In this paper, we demonstrate the feasibility of modeling Ising Model Hami...Quantum computing is a field with increasing relevance as quantum hardware improves and more applications of quantum computing are discovered. In this paper, we demonstrate the feasibility of modeling Ising Model Hamiltonians on the IBM quantum computer. We developed quantum circuits to simulate these systems more efficiently for both closed and open boundary Ising models, with and without perturbations. We tested these various geometries of systems in both 1-D and 2-D space to mimic two real systems: magnetic materials and biological neural networks (BNNs). Our quantum model is more efficient than classical computers, which can struggle to simulate large, complex systems of particles.展开更多
Permanent magnetic materials capable of operating at high temperature up to 500℃ have wide potential applications in fields such as aeronautics, space, and electronic cars. SmCo alloys are candidates for high tempera...Permanent magnetic materials capable of operating at high temperature up to 500℃ have wide potential applications in fields such as aeronautics, space, and electronic cars. SmCo alloys are candidates for high temperature applications, since they have large magnetocrystalline anisotropy field (6-30 T), high Curie temperature (720-920℃), and large energy product (〉200 kJ.m-3) at room temperature. However, the highest service temperature of commercial 2:17 type SmCo magnets is only 300℃, and many efforts have been devoted to develop novel high temperature permanent magnets. This review focuses on the development of three kinds of SmCo based magnets: 2:17 type SmCo magnets, nanocrystalline SmCo magnets, and nanocomposite SmCo magnets. The oxidation protection, including alloying and surface modification, of high temperature permanent magnets is discussed as well.展开更多
This paper presents a method to study the vector magnetic properties of magnetic materials under alternating and rotational magnetic field using 2-D vector hybrid hysteresis model.Combining Preisach model and Stoner-W...This paper presents a method to study the vector magnetic properties of magnetic materials under alternating and rotational magnetic field using 2-D vector hybrid hysteresis model.Combining Preisach model and Stoner-Wohlfarth(S-W)model,the vector hybrid hysteresis model is established for magnetic materials.The alternating and rotational hysteresis properties are calculated under different excitation frequency,respectively.And the computed results are compared with the experimental measurement ones.It is shown that the vector model can simulate the alternating and rotational magnetic properties effectively under low magnetization fields and low excitation frequency.展开更多
The μi-T curves of the alloy Fe73.5Cu1 Nb3Si13.5B9 in the amorphous state and in the nanocrys-talline state have been investigated. For comparison, μi-T curves of the other two kinds of typical soft magnetic alloys ...The μi-T curves of the alloy Fe73.5Cu1 Nb3Si13.5B9 in the amorphous state and in the nanocrys-talline state have been investigated. For comparison, μi-T curves of the other two kinds of typical soft magnetic alloys also have been measured. It was found that a sharp Hopkinson peak appeared at the Curie point for each amorphous and crystalline alloy but there was no Hopkinson peak for the nanocrystalline alloy at the Curie point of the residual amorphous phase. This phenomenon has been explained in terms of the characteristic temperature dependence of the effective magnetic anisotropy.展开更多
The discovery of the first Fe-based ferromagnetic amorphous alloy in 1966 had made an impact on conventional magnetic materials because of its unique properties. Since then, a number of amorphous magnetic materials ha...The discovery of the first Fe-based ferromagnetic amorphous alloy in 1966 had made an impact on conventional magnetic materials because of its unique properties. Since then, a number of amorphous magnetic materials have been successfully developed and used in a wide variety of applications. A brief review of R & D activities on amorphous soft magnetic materials in China is given from the beginning to the present in a somewhat chronological order, followed by a brief introduction to their applications on electric and electronic industries. An analysis and a prospect of Chinese market of such amorphous materials are also presented.展开更多
An integrated production planning and control model based on MRPⅡand JIT is put forward through analyzing the characteristics of magnetic materials manufacturing companies. Master Production Schedule with limited cap...An integrated production planning and control model based on MRPⅡand JIT is put forward through analyzing the characteristics of magnetic materials manufacturing companies. Master Production Schedule with limited capacity and operational plan in workshop level based on the basic data of flow chart are formulated by this model which applied JIT idea and based on customer order demand. Push production is adapted during execution phase combined with process flow cards. The model is helpful to reduce inventory,keep certain flexbility of production and improve continuity and equilibrium of manufacturing process.展开更多
This paper presents theoretical computations of magnetic force bearings made of new type hard magnetic materials neodymium iron boron. A set of devices capable of simultaneously measuring magnetic eccentricity, ...This paper presents theoretical computations of magnetic force bearings made of new type hard magnetic materials neodymium iron boron. A set of devices capable of simultaneously measuring magnetic eccentricity, crosswise stiffness and magnetic pulling force is designed.展开更多
In many situations such as the cores of a rotating electrical machine and the T joints of a multiphase transformer, the local flux density varies with time in terms of both magnitude and direction, i.e. the flux densi...In many situations such as the cores of a rotating electrical machine and the T joints of a multiphase transformer, the local flux density varies with time in terms of both magnitude and direction, i.e. the flux density vector is rotating. Therefore, the magnetic properties of the core materials under the rotating flux density vector excitation should be properly measured, modeled and applied in the design and analysis of these electromagnetic devices. This paper presents an extensive review on the development of techniques and apparatus for measuring the rotational core losses of soft magnetic materials based on the experiences of various researchers in the last hundred years.展开更多
Based on the force-heat equivalence energy density principle,a theoretical model for magnetic metallic materials is developed,which characterizes the temperature-dependent magnetic anisotropy energy by considering the...Based on the force-heat equivalence energy density principle,a theoretical model for magnetic metallic materials is developed,which characterizes the temperature-dependent magnetic anisotropy energy by considering the equivalent relationship between magnetic anisotropy energy and heat energy;then the relationship between the magnetic anisotropy constant and saturation magnetization is considered.Finally,we formulate a temperature-dependent model for saturation magnetization,revealing the inherent relationship between temperature and saturation magnetization.Our model predicts the saturation magnetization for nine different magnetic metallic materials at different temperatures,exhibiting satisfactory agreement with experimental data.Additionally,the experimental data used as reference points are at or near room temperature.Compared to other phenomenological theoretical models,this model is considerably more accessible than the data required at 0 K.The index included in our model is set to a constant value,which is equal to 10/3 for materials other than Fe,Co,and Ni.For transition metals(Fe,Co,and Ni in this paper),the index is 6 in the range of 0 K to 0.65T_(cr)(T_(cr) is the critical temperature),and 3 in the range of 0.65T_(cr) to T_(cr),unlike other models where the adjustable parameters vary according to each material.In addition,our model provides a new way to design and evaluate magnetic metallic materials with superior magnetic properties over a wide range of temperatures.展开更多
Er_(20)Ho_(20)Dy_(20)Cu_(20)Ni_(20)high-entropy metallic glass exhibited excellent magnetic refrigeration material with a wide temperature range and high refrigeration capacity(RC)was reported.Er_(20)Ho_(20)Dy_(20)Cu_...Er_(20)Ho_(20)Dy_(20)Cu_(20)Ni_(20)high-entropy metallic glass exhibited excellent magnetic refrigeration material with a wide temperature range and high refrigeration capacity(RC)was reported.Er_(20)Ho_(20)Dy_(20)Cu_(20)Ni_(20)high-entropy metallic glass was observed with typical spin glass behavior around 15.5 K.In addition,we find that the magnetic entropy change(-△S_(M))originates from the sample undergoing a ferromagnetic(FM)to paramagnetic(PM)transition around 20 K.Under a field change from 0 T to 7 T,the value of maximum magnetic entropy change(-△S_(M)^(max))reaches 12.5 J/kg·K,and the corresponding value of RC reaches 487.7 J/kg in the temperature range from 6 K to 60 K.The large RC and wide temperature range make the Er_(20)Ho_(20)Dy_(20)Cu_(20)Ni_(20)high-entropy metallic glass be a promising material for application in magnetic refrigerators.展开更多
Permanent ferrite magnet materials are extensively employed due to their exceptional magnetic properties and cost-effectiveness.The fast development in electromobile and household appliance industries contributes to a...Permanent ferrite magnet materials are extensively employed due to their exceptional magnetic properties and cost-effectiveness.The fast development in electromobile and household appliance industries contributes to a new progress in permanent ferrite materials.This paper reviews the deveolpement and progress of permanent ferrite magnet industry in recent years.The emergence of new raw material,the advancement of perparation methods and manufacturing techniques,and the potential applications of permanent ferrite materials are introduced and discussed.Specifically,nanocrystallization plays a crucial role in achieving high performance at a low cost and reducing reliance on rare earth resources,and therefore it could be a promising development trendency.展开更多
Anisotropic Pr-Fe-B films with soft-magnetic layer (Fe) and/or antiferromagnetic layer (Mn, FeMn or MnO) were prepared by direct-current (DC) magnetron sputtering on Si (100) substrates heated at 650℃. The in...Anisotropic Pr-Fe-B films with soft-magnetic layer (Fe) and/or antiferromagnetic layer (Mn, FeMn or MnO) were prepared by direct-current (DC) magnetron sputtering on Si (100) substrates heated at 650℃. The influence of four types' different structures on the magnetic properties of Pr-Fe-B films was investigated. The phase and magnetic properties were characterized by means of X-ray diffraction (XRD) and superconducting quantum interference device (SQUID). Addition of anti-ferromagnetic layer enhances both the coercivity and the remanence ratios of Pr-Fe-B films with suitable structures. The interface number increases and the antiferromagnetic-ferromagnetic exchange interaction is likely to become stronger, which affect the improvement of magnetic properties. To further understand the influence of structures with soft-magnetic Fe layer and/or antifer- romagnetic FeMn layer on the magnetic properties of Pr-Fe-B hard-magnetic films, the thickness of Pr-Fe-B layer was designed to decrease from 600 to 50 nm. The improvement of magnetic properties becomes obvious in Mo(50 nm)/Pr-Fe-B(25 nm)Mo(2 nm)FeMn(20 nm)Mo (2 nm)Pr-Fe-B(25 nm)/Mo(50 rim) film.展开更多
Abstract:Material properties play an important role in the performance of electromagnetic mechanism. For an aeronautic Hermetically-Sealed Electromagnetic Relay(HSER), more than 50%parts are made of soft magnetic mate...Abstract:Material properties play an important role in the performance of electromagnetic mechanism. For an aeronautic Hermetically-Sealed Electromagnetic Relay(HSER), more than 50%parts are made of soft magnetic materials. Therefore, the performance of soft magnetic materials directly determines the static and dynamic characteristics of the HSER. Based on the theory of crystal recrystallization, this paper analyzes cold extrusion and heat treatment in the processing of soft magnetic materials, simulates the grain change process of an armature at different heat treatment temperatures, establishes a correlation model of temperature, grain size, and magnetic energy,and verifies results by scanning electron microscopy. Results of heat treatment temperatures from 800 ℃to 920 ℃are obtained and compared. A sample soft magnetic material after heat treatment at different temperatures has the largest difference in the initial magnetization range, up to 22%. In order to verify the fluctuation of the overall output characteristics of an HSER caused by the difference between soft magnetic materials, a static and dynamic analysis model of a typical HSER is established, and the accuracy of the model is verified by a set of actual test system. The difference of dynamic characteristics under different heat treatment temperatures is nearly 3%.展开更多
As the family of magnetic materials is rapidly growing,two-dimensional(2D)van der Waals(vdW)magnets have attracted increasing attention as a platform to explore fundamental physical problems of magnetism and their pot...As the family of magnetic materials is rapidly growing,two-dimensional(2D)van der Waals(vdW)magnets have attracted increasing attention as a platform to explore fundamental physical problems of magnetism and their potential applications.This paper reviews the recent progress on emergent vd W magnetic compounds and their potential applications in devices.First,we summarize the current vd W magnetic materials and their synthetic methods.Then,we focus on their structure and the modulation of magnetic properties by analyzing the representative vd W magnetic materials with different magnetic structures.In addition,we pay attention to the heterostructures of vd W magnetic materials,which are expected to produce revolutionary applications of magnetism-related devices.To motivate the researchers in this area,we finally provide the challenges and outlook on 2D vd W magnetism.展开更多
Sustainable acquisition of bioactive compounds from biomass-based platform molecules is a green alternative for existing CO_(2)-emitting fossil-fuel technologies.Herein,a core–shell magnetic biocarbon catalyst functi...Sustainable acquisition of bioactive compounds from biomass-based platform molecules is a green alternative for existing CO_(2)-emitting fossil-fuel technologies.Herein,a core–shell magnetic biocarbon catalyst functionalized with sulfonic acid(Fe3O4@SiO_(2)@chitosan-SO_(3)H,MBC-SO_(3)H)was prepared to be efficient for the synthesis of various N-substituted pyrroles(up to 99% yield)from bio-based hexanedione and amines under mild conditions.The abundance of Bronsted acid sites in the MBC-SO_(3)H ensured smooth condensation of 2,5-hexanedione with a variety of amines to produce N-substituted pyrroles.The reaction was illustrated to follow the conventional Pall-Knorr coupling pathway,which includes three cascade reaction steps:amination,loop closure and dehydration.The prepared MBC-SO_(3)H catalyst could effectively activate 2,5-hexanedione,thus weakening the dependence of the overall conversion process on the amine nucleophilicity.The influence of different factors(e.g.,reaction temperature,time,amount of catalyst,molar ratio of substrates,and solvent type)on the reaction activity and selectivity were investigated comprehensively.Moreover,the MBC-SO_(3)H possessed excellent thermochemical stability,reusability,and easy separation due to the presence of magnetic core-shell structures.Notably,there was no activity attenuation after 5 consecutive catalytic experiments.This work demonstrates a wide range of potential applications of developing functionalized core-shell magnetic materials to construct bioactive backbones from biomass-based platform molecules.展开更多
Some magnetocaloric materials were used successfully in magnetic refrigeration application and became one of the critical parts of magnetic refrigeration technology whose delightful progresses were made worldwide in t...Some magnetocaloric materials were used successfully in magnetic refrigeration application and became one of the critical parts of magnetic refrigeration technology whose delightful progresses were made worldwide in the past 30 years. At the same time, the research on giant magnetocaloric materials will accelerate the development of room temperature magnetic refrigeration. In this paper, the new theoretical and experimental investigations on magnetic materials in room temperature application were described, including Gd and its binary and ternary intermetallic compounds, Mn-based compounds, La(Fe13-xMx)-based compounds and manganites. Based on the analysis of hysteresis, corrosion, cost and heat process, the comparison between different families of magnetic materials was discussed. Further research of room temperature magnetic refrigerant was suggested.展开更多
文摘Quantum computing is a field with increasing relevance as quantum hardware improves and more applications of quantum computing are discovered. In this paper, we demonstrate the feasibility of modeling Ising Model Hamiltonians on the IBM quantum computer. We developed quantum circuits to simulate these systems more efficiently for both closed and open boundary Ising models, with and without perturbations. We tested these various geometries of systems in both 1-D and 2-D space to mimic two real systems: magnetic materials and biological neural networks (BNNs). Our quantum model is more efficient than classical computers, which can struggle to simulate large, complex systems of particles.
基金supported by the National Natural Science Foundation of China (Nos. 51071010 and 50925101)the Innovation Foundation of Beihang University for Ph.D. Graduates
文摘Permanent magnetic materials capable of operating at high temperature up to 500℃ have wide potential applications in fields such as aeronautics, space, and electronic cars. SmCo alloys are candidates for high temperature applications, since they have large magnetocrystalline anisotropy field (6-30 T), high Curie temperature (720-920℃), and large energy product (〉200 kJ.m-3) at room temperature. However, the highest service temperature of commercial 2:17 type SmCo magnets is only 300℃, and many efforts have been devoted to develop novel high temperature permanent magnets. This review focuses on the development of three kinds of SmCo based magnets: 2:17 type SmCo magnets, nanocrystalline SmCo magnets, and nanocomposite SmCo magnets. The oxidation protection, including alloying and surface modification, of high temperature permanent magnets is discussed as well.
基金This work was supported in part by the National Natural Science Foundation of China(NO.51607157,51777055)the National Key R&D Program of China(NO.2017YFB0903904)+2 种基金the Key Scientific Research Project for Colleges and universities of Henan,China(NO.16A470017)the Hebei Province Science Foundation for Distinguished Young Scholars,Hebei,China(No.E2018202284)the Doctor Foundation of Zhengzhou University of Light Industry,Zhengzhou,Henan,China(NO.2015BSJJ012).
文摘This paper presents a method to study the vector magnetic properties of magnetic materials under alternating and rotational magnetic field using 2-D vector hybrid hysteresis model.Combining Preisach model and Stoner-Wohlfarth(S-W)model,the vector hybrid hysteresis model is established for magnetic materials.The alternating and rotational hysteresis properties are calculated under different excitation frequency,respectively.And the computed results are compared with the experimental measurement ones.It is shown that the vector model can simulate the alternating and rotational magnetic properties effectively under low magnetization fields and low excitation frequency.
基金National Natural Science Foundation of China! under grant No. 59871013.
文摘The μi-T curves of the alloy Fe73.5Cu1 Nb3Si13.5B9 in the amorphous state and in the nanocrys-talline state have been investigated. For comparison, μi-T curves of the other two kinds of typical soft magnetic alloys also have been measured. It was found that a sharp Hopkinson peak appeared at the Curie point for each amorphous and crystalline alloy but there was no Hopkinson peak for the nanocrystalline alloy at the Curie point of the residual amorphous phase. This phenomenon has been explained in terms of the characteristic temperature dependence of the effective magnetic anisotropy.
文摘The discovery of the first Fe-based ferromagnetic amorphous alloy in 1966 had made an impact on conventional magnetic materials because of its unique properties. Since then, a number of amorphous magnetic materials have been successfully developed and used in a wide variety of applications. A brief review of R & D activities on amorphous soft magnetic materials in China is given from the beginning to the present in a somewhat chronological order, followed by a brief introduction to their applications on electric and electronic industries. An analysis and a prospect of Chinese market of such amorphous materials are also presented.
基金supported by Ministry of Education Social Science and Humanities Fund(12YJA630187)SHANNXI Social Science Fund(10Q067)High Education Research Fund of Northwestern Polytechnical University(2014)
文摘An integrated production planning and control model based on MRPⅡand JIT is put forward through analyzing the characteristics of magnetic materials manufacturing companies. Master Production Schedule with limited capacity and operational plan in workshop level based on the basic data of flow chart are formulated by this model which applied JIT idea and based on customer order demand. Push production is adapted during execution phase combined with process flow cards. The model is helpful to reduce inventory,keep certain flexbility of production and improve continuity and equilibrium of manufacturing process.
文摘This paper presents theoretical computations of magnetic force bearings made of new type hard magnetic materials neodymium iron boron. A set of devices capable of simultaneously measuring magnetic eccentricity, crosswise stiffness and magnetic pulling force is designed.
文摘In many situations such as the cores of a rotating electrical machine and the T joints of a multiphase transformer, the local flux density varies with time in terms of both magnitude and direction, i.e. the flux density vector is rotating. Therefore, the magnetic properties of the core materials under the rotating flux density vector excitation should be properly measured, modeled and applied in the design and analysis of these electromagnetic devices. This paper presents an extensive review on the development of techniques and apparatus for measuring the rotational core losses of soft magnetic materials based on the experiences of various researchers in the last hundred years.
基金Project supported by the Natural Science Foundation of Chongqing(Grant No.CSTB2022NSCQ-MSX0391)。
文摘Based on the force-heat equivalence energy density principle,a theoretical model for magnetic metallic materials is developed,which characterizes the temperature-dependent magnetic anisotropy energy by considering the equivalent relationship between magnetic anisotropy energy and heat energy;then the relationship between the magnetic anisotropy constant and saturation magnetization is considered.Finally,we formulate a temperature-dependent model for saturation magnetization,revealing the inherent relationship between temperature and saturation magnetization.Our model predicts the saturation magnetization for nine different magnetic metallic materials at different temperatures,exhibiting satisfactory agreement with experimental data.Additionally,the experimental data used as reference points are at or near room temperature.Compared to other phenomenological theoretical models,this model is considerably more accessible than the data required at 0 K.The index included in our model is set to a constant value,which is equal to 10/3 for materials other than Fe,Co,and Ni.For transition metals(Fe,Co,and Ni in this paper),the index is 6 in the range of 0 K to 0.65T_(cr)(T_(cr) is the critical temperature),and 3 in the range of 0.65T_(cr) to T_(cr),unlike other models where the adjustable parameters vary according to each material.In addition,our model provides a new way to design and evaluate magnetic metallic materials with superior magnetic properties over a wide range of temperatures.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.52371203 and 52271192)the Ministry of Science and Technology of China(Grant No.2021YFB3501201)。
文摘Er_(20)Ho_(20)Dy_(20)Cu_(20)Ni_(20)high-entropy metallic glass exhibited excellent magnetic refrigeration material with a wide temperature range and high refrigeration capacity(RC)was reported.Er_(20)Ho_(20)Dy_(20)Cu_(20)Ni_(20)high-entropy metallic glass was observed with typical spin glass behavior around 15.5 K.In addition,we find that the magnetic entropy change(-△S_(M))originates from the sample undergoing a ferromagnetic(FM)to paramagnetic(PM)transition around 20 K.Under a field change from 0 T to 7 T,the value of maximum magnetic entropy change(-△S_(M)^(max))reaches 12.5 J/kg·K,and the corresponding value of RC reaches 487.7 J/kg in the temperature range from 6 K to 60 K.The large RC and wide temperature range make the Er_(20)Ho_(20)Dy_(20)Cu_(20)Ni_(20)high-entropy metallic glass be a promising material for application in magnetic refrigerators.
基金Project(1053320222852)supported by the Graduate Student Innovation Program of Central South University,China。
文摘Permanent ferrite magnet materials are extensively employed due to their exceptional magnetic properties and cost-effectiveness.The fast development in electromobile and household appliance industries contributes to a new progress in permanent ferrite materials.This paper reviews the deveolpement and progress of permanent ferrite magnet industry in recent years.The emergence of new raw material,the advancement of perparation methods and manufacturing techniques,and the potential applications of permanent ferrite materials are introduced and discussed.Specifically,nanocrystallization plays a crucial role in achieving high performance at a low cost and reducing reliance on rare earth resources,and therefore it could be a promising development trendency.
基金financially supported by the National Key Basic Research Program of China (No. 2010CB934603)the National Nature Science Foundation of China (Nos. 50931006 and 50971123)
文摘Anisotropic Pr-Fe-B films with soft-magnetic layer (Fe) and/or antiferromagnetic layer (Mn, FeMn or MnO) were prepared by direct-current (DC) magnetron sputtering on Si (100) substrates heated at 650℃. The influence of four types' different structures on the magnetic properties of Pr-Fe-B films was investigated. The phase and magnetic properties were characterized by means of X-ray diffraction (XRD) and superconducting quantum interference device (SQUID). Addition of anti-ferromagnetic layer enhances both the coercivity and the remanence ratios of Pr-Fe-B films with suitable structures. The interface number increases and the antiferromagnetic-ferromagnetic exchange interaction is likely to become stronger, which affect the improvement of magnetic properties. To further understand the influence of structures with soft-magnetic Fe layer and/or antifer- romagnetic FeMn layer on the magnetic properties of Pr-Fe-B hard-magnetic films, the thickness of Pr-Fe-B layer was designed to decrease from 600 to 50 nm. The improvement of magnetic properties becomes obvious in Mo(50 nm)/Pr-Fe-B(25 nm)Mo(2 nm)FeMn(20 nm)Mo (2 nm)Pr-Fe-B(25 nm)/Mo(50 rim) film.
基金supported by the National Natural Science Foundation of China(No.52177134)。
文摘Abstract:Material properties play an important role in the performance of electromagnetic mechanism. For an aeronautic Hermetically-Sealed Electromagnetic Relay(HSER), more than 50%parts are made of soft magnetic materials. Therefore, the performance of soft magnetic materials directly determines the static and dynamic characteristics of the HSER. Based on the theory of crystal recrystallization, this paper analyzes cold extrusion and heat treatment in the processing of soft magnetic materials, simulates the grain change process of an armature at different heat treatment temperatures, establishes a correlation model of temperature, grain size, and magnetic energy,and verifies results by scanning electron microscopy. Results of heat treatment temperatures from 800 ℃to 920 ℃are obtained and compared. A sample soft magnetic material after heat treatment at different temperatures has the largest difference in the initial magnetization range, up to 22%. In order to verify the fluctuation of the overall output characteristics of an HSER caused by the difference between soft magnetic materials, a static and dynamic analysis model of a typical HSER is established, and the accuracy of the model is verified by a set of actual test system. The difference of dynamic characteristics under different heat treatment temperatures is nearly 3%.
基金funding support of the National Natural Science Foundation of China(Grant Nos.11975035,51731001,11805006,and 11675006)the National Key Research and Development Program of China(Grant Nos.2017YFA0206303 and 2017YFA0403701)。
文摘As the family of magnetic materials is rapidly growing,two-dimensional(2D)van der Waals(vdW)magnets have attracted increasing attention as a platform to explore fundamental physical problems of magnetism and their potential applications.This paper reviews the recent progress on emergent vd W magnetic compounds and their potential applications in devices.First,we summarize the current vd W magnetic materials and their synthetic methods.Then,we focus on their structure and the modulation of magnetic properties by analyzing the representative vd W magnetic materials with different magnetic structures.In addition,we pay attention to the heterostructures of vd W magnetic materials,which are expected to produce revolutionary applications of magnetism-related devices.To motivate the researchers in this area,we finally provide the challenges and outlook on 2D vd W magnetism.
基金funded by the Guizhou Provincial S&T Project(ZK[2022]011)Guizhou Natural Science Foundation(20201Y182)College Students’Innovation and Entrepreneurship Training Program(S202110657036).
文摘Sustainable acquisition of bioactive compounds from biomass-based platform molecules is a green alternative for existing CO_(2)-emitting fossil-fuel technologies.Herein,a core–shell magnetic biocarbon catalyst functionalized with sulfonic acid(Fe3O4@SiO_(2)@chitosan-SO_(3)H,MBC-SO_(3)H)was prepared to be efficient for the synthesis of various N-substituted pyrroles(up to 99% yield)from bio-based hexanedione and amines under mild conditions.The abundance of Bronsted acid sites in the MBC-SO_(3)H ensured smooth condensation of 2,5-hexanedione with a variety of amines to produce N-substituted pyrroles.The reaction was illustrated to follow the conventional Pall-Knorr coupling pathway,which includes three cascade reaction steps:amination,loop closure and dehydration.The prepared MBC-SO_(3)H catalyst could effectively activate 2,5-hexanedione,thus weakening the dependence of the overall conversion process on the amine nucleophilicity.The influence of different factors(e.g.,reaction temperature,time,amount of catalyst,molar ratio of substrates,and solvent type)on the reaction activity and selectivity were investigated comprehensively.Moreover,the MBC-SO_(3)H possessed excellent thermochemical stability,reusability,and easy separation due to the presence of magnetic core-shell structures.Notably,there was no activity attenuation after 5 consecutive catalytic experiments.This work demonstrates a wide range of potential applications of developing functionalized core-shell magnetic materials to construct bioactive backbones from biomass-based platform molecules.
基金Project(50876082) supported by the National Natural Science Foundation of ChinaProject(IRT0746) supported by the Changjiang Scholars and Innovative Research Team in University
文摘Some magnetocaloric materials were used successfully in magnetic refrigeration application and became one of the critical parts of magnetic refrigeration technology whose delightful progresses were made worldwide in the past 30 years. At the same time, the research on giant magnetocaloric materials will accelerate the development of room temperature magnetic refrigeration. In this paper, the new theoretical and experimental investigations on magnetic materials in room temperature application were described, including Gd and its binary and ternary intermetallic compounds, Mn-based compounds, La(Fe13-xMx)-based compounds and manganites. Based on the analysis of hysteresis, corrosion, cost and heat process, the comparison between different families of magnetic materials was discussed. Further research of room temperature magnetic refrigerant was suggested.