Two silicon resins with excellent thermal stability,JH1123 and JH7102,are used as the insulated agents and binders for the gas-atomized FeSiAl powder,and corresponding magnetic powder cores(MPCs)are fabricated.The ins...Two silicon resins with excellent thermal stability,JH1123 and JH7102,are used as the insulated agents and binders for the gas-atomized FeSiAl powder,and corresponding magnetic powder cores(MPCs)are fabricated.The insulation capability and application prospects of the two silicon resins are evaluated by comparing the magnetic properties of the coated powder and MPCs.The scanning electron microscopy,energy dispersive X-ray spectroscopy and Fourier transform infrared spectroscopy results show that uniform insulation layers are both formed on the powder surfaces.JH1123 has stronger binding ability,and the JH1123-coated powder exhibits severe agglomeration,with d50(average particle size)approximately twice that of the JH7102-coated powder.Both as-prepared MPCs exhibit outstanding soft magnetic properties.Wherein,the permeability of FeSiAl@JH1123 is up to 74.0,which is 35.5%higher than that of FeSiAl@JH7102 because JH1123 can further improve the density of the MPCs.As for FeSiAl@JH7102,it has better direct current bias and lower core loss of 716.9 mW cm^(−3) at 20 mT and 1000 kHz due to its lower coercivity and greater anti-magnetic saturation ability.A comprehensive comparison shows that FeSiAl@JH1123 is suitable for medium and high frequency applications,while FeSiAl@JH7102 is more suitable for high frequency applications.This indicates that the use of JH1123 and JH7102 silicon resins for binding and insulated coating not only simplifies the preparation process of MPCs,but also enables the controlled production of MPCs for different applications.展开更多
High-entropy alloys(HEAs),which are composed of 3d transition metals such as Fe,Co,and Ni,exhibit an exceptional combination of magnetic and other properties;however,the addition of non-ferromagnetic elements always n...High-entropy alloys(HEAs),which are composed of 3d transition metals such as Fe,Co,and Ni,exhibit an exceptional combination of magnetic and other properties;however,the addition of non-ferromagnetic elements always negatively affects the saturation magnetization strength(M s).Co_(4)Fe_(2)Al_(x)Mn_(y) alloys were designed and investigated in this study to develop a novel HEA with excellent soft magnetic properties.The Co_(4)Fe_(2)Al_(1.5)Mn_(1.5) HEA possesses the highest M s of 161.3 emu g^(-1) thus far reported for magnetic HEAs,a low coercivity of 1.9 Oe,a high electrical resistivity of 173μΩ cm,a superior thermal stability up to 600℃,which originates from the novel microstructure of B2 nanoparticles distributed in a DO_(3) matrix phase,and the crucial transition of Mn from antiferromagnetism to ferromagnetism with the assistance of Al.The Co_(4)Fe_(2_)Al_(1.5)Mn_(1.5) HEA was selected to produce micron-sized powder and soft magnetic powder cores(SMPCs)for application in the exploration field.The SMPCs exhibit a high stable effective perme-ability of 35.9 up to 1 MHz,low core loss of 38.1 mW cm^(-3)(@100 kHz,20 mT),and an excellent direct current(DC)bias performance of 87.7%at 100 Oe.This study paves the way for the development of soft magnetic HEAs with promising applications as magnetic functional materials.展开更多
基金supported by the Key R&D Program of Shandong Province,China(Grant No.2022CXGC020308).
文摘Two silicon resins with excellent thermal stability,JH1123 and JH7102,are used as the insulated agents and binders for the gas-atomized FeSiAl powder,and corresponding magnetic powder cores(MPCs)are fabricated.The insulation capability and application prospects of the two silicon resins are evaluated by comparing the magnetic properties of the coated powder and MPCs.The scanning electron microscopy,energy dispersive X-ray spectroscopy and Fourier transform infrared spectroscopy results show that uniform insulation layers are both formed on the powder surfaces.JH1123 has stronger binding ability,and the JH1123-coated powder exhibits severe agglomeration,with d50(average particle size)approximately twice that of the JH7102-coated powder.Both as-prepared MPCs exhibit outstanding soft magnetic properties.Wherein,the permeability of FeSiAl@JH1123 is up to 74.0,which is 35.5%higher than that of FeSiAl@JH7102 because JH1123 can further improve the density of the MPCs.As for FeSiAl@JH7102,it has better direct current bias and lower core loss of 716.9 mW cm^(−3) at 20 mT and 1000 kHz due to its lower coercivity and greater anti-magnetic saturation ability.A comprehensive comparison shows that FeSiAl@JH1123 is suitable for medium and high frequency applications,while FeSiAl@JH7102 is more suitable for high frequency applications.This indicates that the use of JH1123 and JH7102 silicon resins for binding and insulated coating not only simplifies the preparation process of MPCs,but also enables the controlled production of MPCs for different applications.
基金supported by Youth Innovation Promotion Association CAS (Grant No.2021294)the S&T Innovation 2025 Major Special Program (Grant No.2021Z038)+1 种基金the 2022 Xinjiang Uygur Autonomous Region Postgraduate Innovation Research Program (Grand No.XJ2022G070)the Tianshan Innovation Team Program of Xinjiang Uygur Autonomous Region (Grand No.2020D14038).
文摘High-entropy alloys(HEAs),which are composed of 3d transition metals such as Fe,Co,and Ni,exhibit an exceptional combination of magnetic and other properties;however,the addition of non-ferromagnetic elements always negatively affects the saturation magnetization strength(M s).Co_(4)Fe_(2)Al_(x)Mn_(y) alloys were designed and investigated in this study to develop a novel HEA with excellent soft magnetic properties.The Co_(4)Fe_(2)Al_(1.5)Mn_(1.5) HEA possesses the highest M s of 161.3 emu g^(-1) thus far reported for magnetic HEAs,a low coercivity of 1.9 Oe,a high electrical resistivity of 173μΩ cm,a superior thermal stability up to 600℃,which originates from the novel microstructure of B2 nanoparticles distributed in a DO_(3) matrix phase,and the crucial transition of Mn from antiferromagnetism to ferromagnetism with the assistance of Al.The Co_(4)Fe_(2_)Al_(1.5)Mn_(1.5) HEA was selected to produce micron-sized powder and soft magnetic powder cores(SMPCs)for application in the exploration field.The SMPCs exhibit a high stable effective perme-ability of 35.9 up to 1 MHz,low core loss of 38.1 mW cm^(-3)(@100 kHz,20 mT),and an excellent direct current(DC)bias performance of 87.7%at 100 Oe.This study paves the way for the development of soft magnetic HEAs with promising applications as magnetic functional materials.
基金financially supported by Guangdong Major Project of Basic and Applied Basic Research,China (Grant No.2019B030302010)the National Natural Science Foundation of China (No.52301212,52071157,52071222)+1 种基金the National Key Research and Development Program of China (Grant No.2021YFA0716302)the open research fund of Songshan Lake Materials Laboratory (No.2022SLABFN11)。
