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Compact magneto-optical traps using planar optics
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作者 Zhi Tan Bo Lu +1 位作者 Chengyin Han Chaohong Lee 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第9期93-108,共16页
Magneto-optical traps (MOTs) composed of magnetic fields and light fields have been widely utilized to cool andconfine microscopic particles. Practical technology applications require miniaturized MOTs. The advancemen... Magneto-optical traps (MOTs) composed of magnetic fields and light fields have been widely utilized to cool andconfine microscopic particles. Practical technology applications require miniaturized MOTs. The advancement of planaroptics has promoted the development of compact MOTs. In this article, we review the development of compact MOTs basedon planar optics. First, we introduce the standardMOTs. We then introduce the gratingMOTs with micron structures, whichhave been used to build cold atomic clocks, cold atomic interferometers, and ultra-cold sources. Further, we introducethe integrated MOTs based on nano-scale metasurfaces. These new compact MOTs greatly reduce volume and powerconsumption, and provide new opportunities for fundamental research and practical applications. 展开更多
关键词 magneto-optical trap (MOT) planar optics grating MOT metasurface MOT
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Magneto-optical Kerr Effect of Mono-layer NiX_(2)(X=Cl,Br,I):A Density Functional Theory Study
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作者 FAN Qingqian DU Chaochao 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第5期1121-1128,共8页
The full-potential linearized augmented plane wave plus local orbital method is utilized for exploring the electronic,magnetic,and magneto-optical properties of the NiX_(2)(X=Cl,Br,and I)single layer.The first-princip... The full-potential linearized augmented plane wave plus local orbital method is utilized for exploring the electronic,magnetic,and magneto-optical properties of the NiX_(2)(X=Cl,Br,and I)single layer.The first-principles calculation demonstrates that these compounds are ferromagnetic indirect semiconductors,and the energy band gaps of NiX_(2)for X=Cl,Br,and I are 3.888,3.134,and 2.157 eV,respectively.The magnetic moments of Ni atoms in NiX_(2)monolayer are 1.656,1.588,1.449μB,and their magneto-crystalline anisotropy energies are 0.167,0.029,0.090 meV,respectively.Based on the macro-linear response theory,we systematically studied the influences of the external magnetic field and out-of-plane strain on the magneto-optical Kerr effect(MOKE)spectrum of the NiX_(2)single layer.It is found that,when the external magnetic field is perpendicular to the sample plane,the value of the Kerr rotation angle reaches the maximum,and the single-layer NiI_(2)material has a Kerr rotation angle of 1.89°at the photon energy of 1.986 eV.Besides,the Kerr rotation spectrum of NiCl_(2)and NiBr_(2)monolayers redshift as the out-of-plane strain increases,while NiI_(2)monolayer blueshifts.Accurate computation of the MOKE spectrum of NiX_(2)materials provides an opportunity for applications of 2D magnetic material ranging from sensing to data storing. 展开更多
关键词 magneto-optical Kerr effect(MOKE) first-principles calculations external magnetic field out-of-plane strain
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Glass-forming Ability and Chemical Stability of Magneto-optical Glass Heavily Doped with Rare Earth Oxide 被引量:1
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作者 殷海荣 章春香 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2009年第4期640-643,共4页
The glass-forming region of B2O3-Al2O3-SiO2 (BAS) glass heavily doped with rare earth oxides was investigated by an effective method, and the chemical stability was investigated by powder method. Influences of rare ... The glass-forming region of B2O3-Al2O3-SiO2 (BAS) glass heavily doped with rare earth oxides was investigated by an effective method, and the chemical stability was investigated by powder method. Influences of rare earth oxides on the glass-forming ability and the chemical stability of the BAS glass were also discussed. The experimental results show that the BAS glass-forming region expands firstly with the increase of the Tb2O3 content up to 30mol% and then shrinks. The acid-resistant capacity of the BAS glass doped with rare earth oxides is the lowest, the water-resistant capacity is secondary, and the alkali-resistant capacity is the best. Besides, the glass chemical stability can be improved by doping appropriate amount of rare earth oxides. Moreover, the stronger the ionic polarization ability of the rare earth ions is, the better the chemical stability of the BAS glass will be. 展开更多
关键词 magneto-optical glass glass-forming ability chemical stability rare earth oxide
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Classic analogue of Autler–Townes-splitting transparency using a single magneto-optical ring resonator
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作者 吴利婷 曹文康 蒋昊林 《Chinese Physics B》 SCIE EI CAS CSCD 2023年第10期420-427,共8页
We show that an optical transparency can be obtained by using only one single magneto-optical ring resonator. This effect is based on the splitting of counterclockwise and clockwise modes in the ring resonator. Within... We show that an optical transparency can be obtained by using only one single magneto-optical ring resonator. This effect is based on the splitting of counterclockwise and clockwise modes in the ring resonator. Within a proposed resonator-waveguide configuration the superposition between the two degeneracy broken modes produces a transparency window,which can be closed, open, and modified by tuning the applied magnetic field. This phenomenon is an analogue of Autler–Townes splitting, and the magnetic field is equivalent to the strong external pump field. We provide a theoretic analysis on the induced transparency, and numerically demonstrate the effect using full-wave simulation. Feasible implication of this effect and its potential applications are also discussed. 展开更多
关键词 magneto-optic effect dynamic tunable single optical ring resonator
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Corrosion and in vitro cytocompatibility investigation on the designed Mg-Zn-Ag metallic glasses for biomedical application 被引量:1
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作者 Jian Wang Lingzhong Meng +6 位作者 Weixin Xie Chen Ji Ronghua Wang Pinghu Zhang Liling Jin Liyuan Sheng Yufeng Zheng 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2024年第4期1566-1580,共15页
In the present work,seven Mg-Zn-Ag alloys with the nominal composition of Mg_(96-x)Zn_(x)Ag_(4)(x=17,20,23,26,29,32,35 in at.%)were prepared by induction melting and single-roller melt-spinning.The X-ray diffraction(X... In the present work,seven Mg-Zn-Ag alloys with the nominal composition of Mg_(96-x)Zn_(x)Ag_(4)(x=17,20,23,26,29,32,35 in at.%)were prepared by induction melting and single-roller melt-spinning.The X-ray diffraction(XRD)analyses indicate the metallic glasses with three composition of Mg_(73)Zn_(23)Ag_(4),Mg_(70)Zn_(26)Ag_(4),and Mg_(67)Zn_(29)Ag_(4)were obtained successfully.The differential scanning calorimetry(DSC)measurement was used to obtain the characteristic temperature of Mg-Zn-Ag metallic glasses for the glass-forming ability analysis.The maximum glass transition temperature(Trg)was found to be 0.525 with a composition close to Mg_(67)Zn_(29)Ag_(4),which results in the best glass-forming ability.Moreover,the immersion test in simulated body fluid(SBF)demonstrate the relative homogeneous corrosion behavior of the Mg-Zn-Ag metallic glasses.The corrosion rate of Mg-Zn-Ag metallic glasses in SBF solution decreases with the increase of Zn content.The sample Mg_(67)Zn_(29)Ag_(4)has the lowest corrosion rate of 0.19mm/yr,which could meet the clinical application requirement well.The in vitro cell experiments show that the Madin-Darby canine kidney(MDCK)cells cultured in sample Mg_(67)Zn_(29)Ag_(4)and its extraction medium have higher activity.However,the Mg-Zn-Ag metallic glasses exhibit obvious inhibitory effect on human rhabdomyosarcoma(RD)tumor cells.The present investigations on the glass-forming ability,corrosion behavior,cytocompatibility and tumor inhibition function of the Mg-Zn-Ag based metallic glass could reveal their biomedical application possibility. 展开更多
关键词 Metallic glasses Mg-Zn-Ag Corrosion behavior In vitro cytocompatibility
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Magneto-optical Kerr and Faraday effects in bilayer antiferromagnetic insulators
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作者 朱婉情 单文语 《Chinese Physics B》 SCIE EI CAS CSCD 2023年第8期472-478,共7页
Control and detection of antiferromagnetic topological materials are challenging since the total magnetization vanishes.Here we investigate the magneto-optical Kerr and Faraday effects in bilayer antiferromagnetic ins... Control and detection of antiferromagnetic topological materials are challenging since the total magnetization vanishes.Here we investigate the magneto-optical Kerr and Faraday effects in bilayer antiferromagnetic insulator Mn Bi2Te4.We find that by breaking the combined mirror symmetries with either perpendicular electric field or external magnetic moment,Kerr and Faraday effects occur.Under perpendicular electric field,antiferromagnetic topological insulators(AFMTI)show sharp peaks at the interband transition threshold,whereas trivial insulators show small adjacent positive and negative peaks.Gate voltage and Fermi energy can be tuned to reveal the differences between AFMTI and trivial insulators.We find that AFMTI with large antiferromagnetic order can be proposed as a pure magneto-optical rotator due to sizable Kerr(Faraday)angles and vanishing ellipticity.Under external magnetic moment,AFMTI and trivial insulators are significantly different in the magnitude of Kerr and Faraday angles and ellipticity.For the qualitative behaviors,AFMTI shows distinct features of Kerr and Faraday angles when the spin configurations of the system change.These phenomena provide new possibilities to optically detect and manipulate the layered topological antiferromagnets. 展开更多
关键词 magneto-optical Kerr and Faraday effects antiferromagnetic topological insulators bilayer systems
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High-sensitivity phase imaging eddy current magneto-optical system for carbon fiber reinforced polymers detection
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作者 Jiang-Shan Ai Quan Zhou +5 位作者 Yi-Ping Liang Chun-Rui Feng Bing Long Li-Bing Bai Yong-Gang Wang Chao Ren 《Journal of Electronic Science and Technology》 EI CSCD 2023年第4期48-59,共12页
This paper proposed a high-sensitivity phase imaging eddy current magneto-optical (PI-ECMO) system for carbon fiber reinforced polymer (CFRP) defect detection. In contrast to other eddy current-based detection systems... This paper proposed a high-sensitivity phase imaging eddy current magneto-optical (PI-ECMO) system for carbon fiber reinforced polymer (CFRP) defect detection. In contrast to other eddy current-based detection systems, the proposed system employs a fixed position excitation coil while enabling the detection point to move within the detection region. This configuration effectively mitigates the interference caused by the lift-off effect, which is commonly observed in systems with moving excitation coils. Correspondingly, the relationship between the defect characteristics (orientation and position) and the surface vertical magnetic field distribution (amplitude and phase) is studied in detail by theoretical analysis and numerical simulations. Experiments conducted on woven CFRP plates demonstrate that the designed PI-ECMO system is capable of effectively detecting both surface and internal cracks, as well as impact defects. The excitation current is significantly reduced compared with traditional eddy current magneto-optical (ECMO) systems. 展开更多
关键词 Carbon fiber reinforced polymers Defect detection Eddy current magneto-optical Nondestructive testing Phase imaging
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Preparation and Performance of Magneto-optical Glasses Doped with Tb^(3+)/Dy^(3+)
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作者 殷海荣 ZHAO Gaoyang +2 位作者 LIU Pan WANG Shunni GUO Hongwei 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2014年第4期684-687,共4页
In order to increase the content of rare-earth oxides in magneto-optical glass and improve the Verdet constant, the rare-earth doped ternary Ga2O3-B2O3-SiO2(GBS) system magneto-optical glasses were prepared by the m... In order to increase the content of rare-earth oxides in magneto-optical glass and improve the Verdet constant, the rare-earth doped ternary Ga2O3-B2O3-SiO2(GBS) system magneto-optical glasses were prepared by the melt quenching technique. The infl uence of Tb3+ and Dy3+ ions on the structure of GBS glasses was investigated using FTIR, DSC and Faraday rotations. The experimental results showed that the content of rare-earth oxides in the glasses with the double incorporation of Tb2O3 and Dy2O3 was higher. The crystallization parameter β achieved the maximum 0.48 with Tb3+/Dy3+ content of 35mol%. Terbium oxide existed mainly in [TbO3] units in the glasses and [TbO4] units were converted into [TbO3] with increasing Tb2O3 content. As Ga3+ ion is larger than B3+ ion in radius, leading to an increasing of the glass network gap and improvement in the ability of accommodating rare earth ions, Verdet constant increased. 展开更多
关键词 magneto-optical glass faraday rotation rare earth oxide
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Geochemistry of volcanic glass from Mahanadi offshore region,eastern continental margin of India:Constraints on the contribution of latest Toba super-eruption
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作者 Muralidhar Kocherla Durbar Ray +3 位作者 Manavalan Satyanarayanan Hilda Joao Virsen Gaikwad PB Ramamurty 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2024年第2期111-119,共9页
The tephra layers in multiple sediment cores from the offshore region of the Mahanadi basin in the northern Bay of Bengal were investigated for possible volcanic sources. The glass shards from those tephra layers were... The tephra layers in multiple sediment cores from the offshore region of the Mahanadi basin in the northern Bay of Bengal were investigated for possible volcanic sources. The glass shards from those tephra layers were studied for size distribution, texture, and elemental geochemistry to establish chronostratigraphic markers for regional and global Quaternary correlation. The textural features of fine-grained(silty) volcanic glasses suggest the distal source of these tephra deposits. Major element composition with elevated SiO_(2) contents ranging between75%–76% and dominance of K_(2)O(> 4.5%) over CaO(< 0.9%) suggest ashes have originated from siliceous rhyolitic melts, similar to the petrographic composition of tephra from the Toba volcano. The bulk trace element compositions of the same glass shards were comparable with those reported in the youngest Toba tephra reported elsewhere. Likewise, the LREE-dominated chondrite normalized REE profiles of tephra from the Mahanadi basin closely resemble the characteristic REE patterns in Toba ash from other parts of the Indian Ocean and thus confirmed the contribution of the youngest Toba super-eruption for this ash layers. 展开更多
关键词 Mahanadi basin Bay of Bengal volcanic glass glass morphology glass-chemistry
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Mixed Alkali-zinc Effects on Thermo-mechanical Properties in Borosilicate Glasses
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作者 XIAO Guanzhou TAO Yunhang +3 位作者 ZHOU Hemin ZHENG Qingshuang QIAO Ang TAO Haizheng 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第5期1093-1099,共7页
A series of mixed alkali-zinc borosilicate glasses with various r values(r=molar ratio of[ZnO]/([R^(2)O]+[ZnO]))from 0.00 to 1.00 were fabricated to probe the mixed alkali-zinc effects on thermo-mechanical properties.... A series of mixed alkali-zinc borosilicate glasses with various r values(r=molar ratio of[ZnO]/([R^(2)O]+[ZnO]))from 0.00 to 1.00 were fabricated to probe the mixed alkali-zinc effects on thermo-mechanical properties.The nonlinear evolution of glass transition temperature(T_(g))with the addition of ZnO is ascribed to the competition of two converse factors,i e,the T_(g)depression as one of the colligative properties for a solution,on the one hand,and the enhancement of T_(g)due to the higher field strength of zinc cations compared to that of alkali ions.However,the nonlinear evolution of elastic moduli and coefficients of thermal expansion with r is attributed to the variance of intermediate-range clusters,which is confirmed by infrared and Raman scattering spectra.These findings are very helpful in tailoring the performance of borosilicate glasses. 展开更多
关键词 glass transition temperature elastic moduli coefficient of thermal expansion borosilicate glass
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Effect of Ceramic Crucibles on Magneto-Optical PbO-Bi<sub>2</sub>O<sub>3</sub>-B<sub>2</sub>O<sub>3</sub>Glasses Properties
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作者 Qiuping Chen Qiuling Chen Monica Ferraris 《New Journal of Glass and Ceramics》 2012年第1期41-50,共10页
Heavy-metal-oxide (HMO) glasses attract much interest in many applications such as Faraday rotators, current sensors, etc., in the area of magneto-optic effects due to their unique magnetic-optical property, high refr... Heavy-metal-oxide (HMO) glasses attract much interest in many applications such as Faraday rotators, current sensors, etc., in the area of magneto-optic effects due to their unique magnetic-optical property, high refractive index and other interesting properties. However, during the melt-quenching process of these glasses, the high corrosive nature of the melt to the crucibles makes the fabrication of HMO glasses complicated and the properties of the obtained glasses show strong dependence on the crucible materials. Literatures reported that the gold and platinum crucibles are not suitable due to their contamination to the melt glasses, ceramic crucible was considered suitable for the melting of HMO glasses. In this work, magnetic-optical glasses within the system of PbO-Bi2O3-B2O3 have been prepared using different kinds of ceramic crucibles for the aim of finding the most suitable crucible for melting HMO glasses. The glass properties in terms of Verdet constant, thermal stability and UV-Vis-IR transmittance in function of different crucibles were studied and reported. It was found that the same batch of glasses prepared under same conditions (melting temperature, melting time and annealing process), but in different ceramic crucibles (coded as C1, C2 and C3) showed significant difference in properties such as glass forming ability, thermal stability, optical absorption in UV-Vis-IR and Verdet constant (0.0812 - 0.1483 min/G.cm). The ceramic crucible made of 25%Al2O3 and 75%SiO2 (C2) was found to be the most suitable for PbO-Bi2O3-B2O3 glass preparation, compared with platinum, gold, C1 and C3. Glasses melted with C2 exhibit good performance in magneto and optical property, as well as good thermal stability. 展开更多
关键词 Magneto Optical glass CERAMIC Crucibles Verdet Constant
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Preparation and Characterization of ZnO-CuO-Bi_(2)O_(3)-B_(2)O_(3)-SiO_(2)System Low Melting Sealing Glasses
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作者 HE Yifeng LI Xiuying +5 位作者 LI Chaoyuan GUO Huiming XIAO Zhuohao ZHU Shengbin DONG Hongbo FU Zhen 《陶瓷学报》 CAS 北大核心 2024年第5期931-940,共10页
Lead-free low melting glasses,ZnO-CuO-Bi_(2)O_(3)-B_(2)O_(3)-SiO_(2)system,with fixed contents of 15 mol%CuO and 20 mol%Bi_(2)O_(3),were prepared by using melt cooling method.Structure and thermal properties of the gl... Lead-free low melting glasses,ZnO-CuO-Bi_(2)O_(3)-B_(2)O_(3)-SiO_(2)system,with fixed contents of 15 mol%CuO and 20 mol%Bi_(2)O_(3),were prepared by using melt cooling method.Structure and thermal properties of the glasses were studied by using X-ray diffractometer(XRD),infrared spectrometer(FIT-IR),thermal dilatometer and differential thermal analyzer(DTA).Chemical durability of the glasses was studied by using dissolution rate method.Wettability of glasses on substrate was tested by using button sintering experiment.It is found that alkaline resistance of the glass solders is lower than that of plate glass and the water resistance is comparable with that of plate glass.The sealing temperatures are Ts=445-490℃,while the average thermal expansion coefficient from room temperature to 300℃is in the range of(65-82)×10^(−7)℃^(−1).At sealing temperature,the glass solders have good wettability on plate glass or alumina substrate.They are not crystallized even sintered at the sealing temperature for 30 min.The solder glasses are suitable for sealing plate glass,alumina and other inorganic non-metallic materials. 展开更多
关键词 bismuth borate glass solder glasses WETTABILITY chemical durability thermal properties
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Solid-state NMR reveals that oxygen tri-clusters make glass highly crackresistant
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作者 Zhiwu Yu 《Magnetic Resonance Letters》 2024年第2期77-78,共2页
In a recent paper,advanced solid-state nuclear magnetic resonance(SSNMR)technology was employed to reveal the underlying mechanism contributing to the high hardness and exceptional resistance to fragmentation observed... In a recent paper,advanced solid-state nuclear magnetic resonance(SSNMR)technology was employed to reveal the underlying mechanism contributing to the high hardness and exceptional resistance to fragmentation observed in certain special glasses[1].This study utilized SSNMR to analyze the atomic-scale internal structure of glass,enabling the quantification of the fraction of three-coordinated oxygen([^((3))O]).The research findings demonstrate a quantitative relationship between[^((3))O]and the resistance of glass to crack initiation. 展开更多
关键词 CRACK resistance glass
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Design and characterization of biodegradable Mg-Zn-Ag metallic glasses
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作者 Jian WANG Chen WANG +1 位作者 Wei-feng RAO In-ho JUNG 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2024年第9期2814-2827,共14页
In order to develop the Mg-Zn-Ag metallic glasses(MGs)for biodegradable implant applications,the glass formation ability(GFA)and biocompatibility of Mg-Zn-Ag alloys were investigated using a combination of the calcula... In order to develop the Mg-Zn-Ag metallic glasses(MGs)for biodegradable implant applications,the glass formation ability(GFA)and biocompatibility of Mg-Zn-Ag alloys were investigated using a combination of the calculation of phase diagrams(CALPHAD)and experimental measurements.High GFA potentiality of two alloy series,specifically Mg_(96-x)Zn_xAg_(4)and Mg_(94-x)Zn_xAg_6(x=17,20,23,26,29,32,35),was predicted theoretically and then substantiated through experimental testing.X-ray diffraction(XRD)and differential scanning calorimetry(DSC)techniques were used to evaluate the crystallinity,GFA,and crystallization characteristics of these alloys.The results showed that compositions between Mg_(73)Zn_(23)Ag_(4)and Mg_(64)Zn_(32)Ag_(4)for Mg_(96-x)Zn_xAg_4,Mg_(66)Zn_(28)Ag_(6)and Mg_(63)Zn_(31)Ag_(6for)Mg_(94-x)Zn_xAg_(6)displayed a superior GFA.Notably,the GFA of the Mg_(96-x)Zn_xAg_(4)series was better than that of the Mg_(94-x)Zn_xAg_(6)series.Furthermore,the Mg_(70)Zn_(26)Ag_4,Mg_(74)Zn_(20)Ag_6,and Mg_(71)Zn_(23)Ag_(6)alloys showed acceptable corrosion rates,good cytocompatibility,and positive effects on cell proliferation.These characteristics make them suitable for applications in medical settings,potentially materials as biodegradable implants. 展开更多
关键词 glass forming ability calculation phase diagram(CALPHAD) Mg−Zn−Ag metallic glasses CYTOCOMPATIBILITY
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Influence of Al_(2)O_(3)/SiO_(2) Ratio on the Structure and Properties of Na^(+)/K^(+)Ion Exchange Na_(2)O-MgO-Al_(2)O_(3)-SiO_(2) Glasses
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作者 吴建磊 CHEN Junzhu +4 位作者 TIAN Xiaokun LI Jiahao GAO Wenkai YUE Yunlong 康俊峰 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第3期606-612,共7页
In this work,the structure,viscosity and ion-exchange process of Na_(2)O-MgO-Al_(2)O_(3)-SiO_(2) glasses with different Al_(2)O_(3)/SiO_(2) molar ratios were investigated.The results showed that,with increasing Al_(2)... In this work,the structure,viscosity and ion-exchange process of Na_(2)O-MgO-Al_(2)O_(3)-SiO_(2) glasses with different Al_(2)O_(3)/SiO_(2) molar ratios were investigated.The results showed that,with increasing Al_(2)O_(3)/SiO_(2) ratio,the simple structural units Q_(1) and Q_(2) transformed into highly aggregated structural units Q_(3) and Q_(4),indicating the increase of polymerization degree of glass network.Meanwhile,the coefficient of thermal expansion decreased from 9.23×10^(-6)℃^(-1) to 8.88×10^(-6)℃^(-1).The characteristic temperatures such as melting,forming,softening and glass transition temperatures increased with the increase of Al_(2)O_(3)/SiO_(2) ratio,while the glasses working temperature range became narrow.The increasing Al_(2)O_(3)/SiO_(2) ratio and prolonging ion-exchange time enhanced the surface compressive stress(CS)and depth of stress layer(DOL).However,the increase of ion exchange temperature increased the DOL and decreased the CS affected by stress relaxation.There was a good linear relationship between stress relaxation and surface compressive stress.Chemical strengthening significantly improved the hardness of glasses,which reached the maximum value of(622.1±10)MPa for sample with Al_(2)O_(3)/SiO_(2) ratio of 0.27 after heat treated at 410℃for 2 h. 展开更多
关键词 network structure viscosity ion exchange aluminosilicate glass
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Structural color of metallic glass through picosecond laser
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作者 Yue’e Zhang Xing Tong +3 位作者 Yuqiang Yan Shuo Cao Hai-Bo Ke Wei-Hua Wang 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第10期120-128,共9页
The alteration in surface color of metallic glasses(MGs)holds great significance in the context of microstructuredesign and commercial utility.It is essential to accurately describe the structures that are formed duri... The alteration in surface color of metallic glasses(MGs)holds great significance in the context of microstructuredesign and commercial utility.It is essential to accurately describe the structures that are formed during the laser and colorseparation processes in order to develop practical laser coloring applications.Due to the high oxidation sensitivity of Labasedmetallic glass,it can broaden the color range but make it more complex.Structure coloring by laser processing on thesurface of La-based metallic glass can be conducted after thermoplastic forming.It is particularly important to clarify therole of structure and composition in the surface coloring process.The aim is to study the relationship between amorphoussurface structural color,surface geometry,and oxide formation by laser processing in metallic glasses.The findings revealedthat the periodic structure primarily determines the surface color at laser energy densities below 1.0 J/mm^(2).In contrast,thesurface color predominantly depends on the proportion of oxides that are formed when energy densities exceed 1.0 J/mm^(2).Consequently,this study provides a novel concept for the fundamental investigation of laser coloring and establishes a newavenue for practical application. 展开更多
关键词 metallic glass picosecond laser periodic structure OXIDES
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Effect of Fe_(2)O_(3)on the Structure,Physical Properties and Crystallization of CaO-Al_(2)O_(3)-SiO_(2)Glass
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作者 张峰 XIONG Dehua +7 位作者 谢俊 张继红 HAN Jianjun CHEN Dequan WEN Zhongquan FAN Zhenhua CHEN Lina SUN Tengfei 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第4期954-961,共8页
The calcium aluminosilicate-based glasses(CaO-Al_(2)O_(3)-SiO_(2),CAS)with different Fe_(2)O_(3)content(0.10wt%,0.50wt%,0.90wt%,and 1.30wt%)were prepared by traditional melt-quenching method.The glass network structur... The calcium aluminosilicate-based glasses(CaO-Al_(2)O_(3)-SiO_(2),CAS)with different Fe_(2)O_(3)content(0.10wt%,0.50wt%,0.90wt%,and 1.30wt%)were prepared by traditional melt-quenching method.The glass network structure,thermal and mechanical properties,and crystallization behavior changes were investigated by nuclear magnetic resonance spectrometer,Fourier-transform infrared spectro-photometer,X-ray diffractometer,differential scanning calorimetry and field emission scanning electron microscope measurements.The change of Q^(n)in glass structures reveals the glass network connectivity decreases due to the increasing content of Fe_(2)O_(3)addition,resulting in the increasing of non-bridging number in glass structure.The glass densities slightly rise from 2.644 to 2.681 g/cm^(3),while Vickers’s hardness increases at first,from 6.469 to 6.901 GPa,then slightly drops to 6.745 GPa,with Fe_(2)O_(3)content increase.There is almost no thermal expansion coefficient change from different Fe_(2)O_(3)content.The glass transmittance in visible range gradually decreases with higher Fe_(2)O_(3)content,resulting from the strong absorption of Fe^(2+)and Fe^(3+)ions.The calculated activation energy from thermal analysis results first decreases from 282.70 to 231.18 kJ/mol,and then increases to 244.02 kJ/mol,with the Fe_(2)O_(3)content increasing from 0.10wt%to 1.30wt%.Meanwhile,the maximum Avrami constant of 2.33 means the CAS glasses exhibit two-dimensional crystallization.All of the CAS glass-ceramics samples contain main crystal phase of anorthite,the microstructure appears lamellar and columnar crystals. 展开更多
关键词 calcium aluminosilicate glass network structure physical properties CRYSTALLIZATION
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Provenance of colorless and brown volcanic glass in late Pleistocene tephra layers in the Western Philippine Sea
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作者 Fuqing JIANG Zhishun ZHANG +6 位作者 Zhaohui ZHANG Guoliang ZHANG Peng HUANG Xiaojing ZHOU Zhifang XIONG Congying LI Tiegang LI 《Journal of Oceanology and Limnology》 SCIE CAS CSCD 2024年第5期1438-1449,共12页
Tephra layers in the western Philippine Sea,characterized by abundant volcanic glass shards,may provide crucial evidence on the eruption history of volcanoes and tectonic evolution of the western Pacific.A 220-ka sedi... Tephra layers in the western Philippine Sea,characterized by abundant volcanic glass shards,may provide crucial evidence on the eruption history of volcanoes and tectonic evolution of the western Pacific.A 220-ka sediment core from the Benham Rise in the western Philippine Sea offers new insights into the provenance of four intercalated tephra layers(T1–T4,in chronological order)containing either colorless or brown glass shards.Relative to primitive mantle,all glass shards are enriched in large-ion lithophile elements,such as Rb,Cs,and Pb,and depleted in high field-strength elements,such as Th,Nb,and Ta,indicating a subduction-related origin.The colorless glass shards are characterized by high SiO_(2)(>78%)and light rare earth element(LREE)contents as well as high La/Sm ratios(>9),low FeO and MgO contents(<1%),low Sr/Y(<15)and high Ba/Th ratios(>100),pointing to a rhyolitic composition and a medium-K calc-alkaline serial affinity.In contrast,the brown glass shards are characterized by lower SiO_(2)(<63%)and LREE contents,higher FeO,MgO,and CaO contents,lower La/Sm(<6)and Ba/Th(<75),and similar Sr/Y ratios(<15),indicating derivation from medium to high-K calc-alkaline andesite magma.Brown glass shards from layers T3(152 ka)and T4(172 ka)were correlated with volcanic deposits from the Taal and Laguna Caldera in the Maccolod Corridor,respectively,while the colorless glass shards from layers T1(36.5 ka)and T2(61.2 ka)were likely sourced from the Irosin Caldera in the Bicol Arc.Establishing the provenance of late Pleistocene tephra layers in the western Philippine Sea is helpful to complement a Philippine volcanic history and establish a regional tephrochronostratigraphy. 展开更多
关键词 volcanic glass PROVENANCE chemical composition Philippine Sea late Pleistocene
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Effect of overheating-induced minor addition on Zr-based metallic glasses
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作者 杨福 薄振兴 +7 位作者 黄瑶 王雨田 孙博阳 鲁振 孙保安 柳延辉 汪卫华 潘明祥 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第3期118-125,共8页
Melt treatment is well known to have an important influence on the properties of metallic glasses(MGs).However,for the MGs quenched from different melt temperatures with a quartz tube,the underlying physical origin re... Melt treatment is well known to have an important influence on the properties of metallic glasses(MGs).However,for the MGs quenched from different melt temperatures with a quartz tube,the underlying physical origin responsible for the variation of properties remains poorly understood.In the present work,we systematically studied the influence of melt treatment on the thermal properties of a Zr50Cu36Al14 glass-forming alloy and unveiled the microscopic origins.Specifically,we quenched the melt at different temperatures ranging from 1.1Tl to 1.5Tl(Tl is the liquidus temperature)to obtain melt-spun MG ribbons and investigated the variation of thermal properties of the MGs upon heating.We found that glass transition temperature,Tg,increases by as much as 36 K,and the supercooled liquid region disappears in the curve of differential scanning calorimetry when the melt is quenched at a high temperature up to 1.5Tl.The careful chemical analyses indicate that the change in glass transition behavior originates from the incorporation of oxygen and silicon in the molten alloys.The incorporated oxygen and silicon can both enhance the interactions between atoms,which renders the cooperative rearrangements of atoms difficult,and thus enhances the kinetic stability of the MGs. 展开更多
关键词 metallic glass thermal properties melt treatment OVERHEATING oxygen content
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The Effect of Na_(2)O/B_(2)O_(3)Composition Ratio on the Structure and Properties of Cu^(+)Doped Luminescent Glass
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作者 LI Bohan FENG Jinyang +3 位作者 FENG Xiaoping ZHAO Xiujian WU Donghua MA Xiao 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第6期1379-1390,共12页
Cu^(+)-doped alkali borosilicate glasses with different Na_(2)O contents were prepared by the melting method,and the effects of different R values(R=Na_(2)O/B_(2)O_(3))on the structure,ion presence state and luminesce... Cu^(+)-doped alkali borosilicate glasses with different Na_(2)O contents were prepared by the melting method,and the effects of different R values(R=Na_(2)O/B_(2)O_(3))on the structure,ion presence state and luminescence properties of Cu^(+)-doped alkali borosilicate glasses were investigated.The analysis by FT-IR and Raman spectroscopy shows that,with the increase of R value of the glass,the[BO_(3)]in the structure of Cu^(+)-doped alkali borosilicate glass transforms into[BO_(4)]and the number of non-bridging oxygen in the glass network appears to be slightly increased.The absorption spectra and EPR analysis reveal that the Cu^(+)content in the glass gradually decreases and the Cu^(2+)content gradually increases as the R value of the glass increases.XPS and PL tests further indicate that the transformation of the octahedral coordination structure of Cu^(+)to the octahedral coordination structure of Cu^(2+)and the cubic coordination structure of Cu^(+)occurs in the glass as the R value of the glass increases.This transformation can effectively reduce the concentration quenching phenomenon of Cu^(+)and improve the fluorescence luminescence intensity of the glass samples.Meanwhile,the samples were found to have luminescence tunability as well as good thermal stability. 展开更多
关键词 R value glass structure Cu ion valence LUMINESCENCE
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