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The Creative Design Research of Product Appearance Based on Human-machine Interaction and Interface 被引量:1
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作者 WANG Zheng, HE Wei-ping, ZHANG Ding-hua, YU Sui-huai, CAI Hong-ming (Contemporary Design and Integrated Manufacturing Technology Laboratory , Northwestern Polytechnical University, Xi’an 710072, China) 《厦门大学学报(自然科学版)》 CAS CSCD 北大核心 2002年第S1期152-153,共2页
Today’s product creative design has rendered many fe atures and has brought a great change in our everyday life, there are many new c hallenges in its traditional theory and principle. According to the traditional de... Today’s product creative design has rendered many fe atures and has brought a great change in our everyday life, there are many new c hallenges in its traditional theory and principle. According to the traditional design theory, the FBS design model pays more attention to the function and stru cture of the product. But this model still couldn’t strengthen the relation bet ween product appearance design and human-machine design effectively. This paper adopt converse design thinking and presents an improved design thinking methodo logy based on C: FBS for product appearance design and give a general summarizat ion for the features, methods and technology based on human-machine interaction and interface. Meanwhile it also combines with the behavior design of product r elated IT fields and constructs a new outline to improve the design of product a ppearance supported by the technology of computer aided design. So the new metho d about design thinking for computer aided design, the new abstract product design model and the key problem of design thinking based on human-machine inte raction and interface are addressed in this paper. This kind of creative design theory that is driven by human-machine interaction and interface will help the development of CAD software system and the research of product design and manufa cture. Additionally, this paper gives some beneficial characters to address the theory based on human-machine interaction and interface. Meanwhile, combining with the developing of computer technology, the trends of design thinking based on t he technology of human-machine interaction and interface are also analyzed and discussed at the end of this paper. 展开更多
关键词 C:FBS model product appearance design human-ma chine interaction and interface(HMI&I) computer aided design(CAD)
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Web GIS Human-Machine Interactive Interface Design with VISI
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作者 XIONG Lan HU Hongliang +2 位作者 DU Qingyun HUANG Maojun WANG Mingjun 《Geo-Spatial Information Science》 2008年第1期66-70,共5页
The fusion of VlSI (visual identity system Internet), digital maps and Web GIS is presented. Web GIS interface interactive design with VISI needs to consider more new factors. VISI can provide the design principle, ... The fusion of VlSI (visual identity system Internet), digital maps and Web GIS is presented. Web GIS interface interactive design with VISI needs to consider more new factors. VISI can provide the design principle, elements and contents for the Web GIS. The design of the Wuhan Bus Search System is fulfilled to confirm the validity and practicability of the fusion. 展开更多
关键词 Web GIS human-machine interactive interface design VISI
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Designing interactive glazing through an engineering psychology approach:Six augmented reality scenarios that envision future car human-machine interface
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作者 Wei LIU Yancong ZHU +5 位作者 Ruonan HUANG Takumi OHASHI Jan AUERNHAMMER Xiaonan ZHANG Ce SHI Lu WANG 《Virtual Reality & Intelligent Hardware》 2023年第2期157-170,共14页
Background With an increasing number of vehicles becoming autonomous,intelligent,and connected,paying attention to the future usage of car human-machine interface with these vehicles should become more relevant.Severa... Background With an increasing number of vehicles becoming autonomous,intelligent,and connected,paying attention to the future usage of car human-machine interface with these vehicles should become more relevant.Several studies have addressed car HMI but were less attentive to designing and implementing interactive glazing for every day(autonomous)driving contexts.Methods Reflecting on the literature,we describe an engineering psychology practice and the design of six novel future user scenarios,which envision the application of a specific set of augmented reality(AR)support user interactions.Additionally,we conduct evaluations on specific scenarios and experiential prototypes,which reveal that these AR scenarios aid the target user groups in experiencing a new type of interaction.The overall evaluation is positive with valuable assessment results and suggestions.Conclusions This study can interest applied psychology educators who aspire to teach how AR can be operationalized in a human-centered design process to students with minimal pre-existing expertise or minimal scientific knowledge in engineering psychology. 展开更多
关键词 Augmented reality interactive glazing Engineering psychology Car human-machine interface Human-computer interaction Human-centered design User experience Generation Z
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Transport diffuse interface model for simulation of solid-fluid interaction 被引量:1
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作者 Li LI Qian CHEN Baolin TIAN 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2019年第3期321-330,共10页
For solid-fluid interaction, one of the phase-density equations in diffuse interface models is degenerated to a "0 = 0" equation when the volume fraction of a certain phase takes the value of zero or unity. ... For solid-fluid interaction, one of the phase-density equations in diffuse interface models is degenerated to a "0 = 0" equation when the volume fraction of a certain phase takes the value of zero or unity. This is because the conservative variables in phasedensity equations include volume fractions. The degeneracy can be avoided by adding an artificial quantity of another material into the pure phase. However, nonphysical waves,such as shear waves in fluids, are introduced by the artificial treatment. In this paper,a transport diffuse interface model, which is able to treat zero/unity volume fractions, is presented for solid-fluid interaction. In the proposed model, a new formulation for phase densities is derived, which is unrelated to volume fractions. Consequently, the new model is able to handle zero/unity volume fractions, and nonphysical waves caused by artificial volume fractions are prevented. One-dimensional and two-dimensional numerical tests demonstrate that more accurate results can be obtained by the proposed model. 展开更多
关键词 solid-fluid interaction DIFFUSE interface model phase-density EQUATION Mie-Gruneisen EQUATION of state(EOS) EULERIAN method
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Parameter selection of pocket extraction algorithm using interaction interface 被引量:1
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作者 KIM Chong-Min WON Chung-In +3 位作者 RYU Joonghyun CHO Cheol-Hyung BHAK Jonghwa KIM Deok-Soo 《Journal of Zhejiang University-Science A(Applied Physics & Engineering)》 SCIE EI CAS CSCD 2006年第9期1492-1499,共8页
Pockets in proteins have been known to be very important for the life process. There have been several studies in the past to automatically extract the pockets from the structure information of known proteins. However... Pockets in proteins have been known to be very important for the life process. There have been several studies in the past to automatically extract the pockets from the structure information of known proteins. However, it is difficult to find a study comparing the precision of the extracted pockets from known pockets on the protein. In this paper, we propose an algorithm for extracting pockets from structure data of proteins and analyze the quality of the algorithm by comparing the extracted pockets with some known pockets. These results in this paper can be used to set the parameter values of the pocket extraction algorithm for getting better results. 展开更多
关键词 POCKET PROTEIN interaction interface Protein interaction Voronoi diagram
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INTERACTION OF PARTICLES WITH A SOLIDIFIED INTERFACE DURING SOLIDIFICATION OF METAL MATRIX COMPOSITE REINFORCED WITH PARTICLES
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作者 CHU Shuangjie WANG Haowei +1 位作者 WU Renjie LIN Xiaotang(Institute of Composite Materials,Shanghai Jiaotong University,Shanghai 200030,China 《Acta Metallurgica Sinica(English Letters)》 SCIE EI CAS CSCD 1996年第1期71-78,共8页
The interaction of particles with a solid-liquid interface during solidification of metal matrix composites has been investigated theoretically in this paper.Owing to the presence of particles in the melt,the shape of... The interaction of particles with a solid-liquid interface during solidification of metal matrix composites has been investigated theoretically in this paper.Owing to the presence of particles in the melt,the shape of the solidification front and solute concentration field in front of solidification interface have been disturbed The thermodynamic method was employed,and a mathematical expression of the shape of the solidification interface and solute concentration field were deduced.Meanwhile,a theory is developed for evaluation of critical velocities of particles pushed by the solidification interface.A numerical simulation is done in which the critical velocity is evaluated as a function of particle size,thermal conductivity,diffusion coefficient,temperature gradient at the solidification front,the solid-liquid interfacial energy and the melt viscosity.The critical velocity is shown to be closely linked to the shape of the solidification interface and solute concentration field, and hence all the parameters also affect the shape of the solidification interface and solute concentration field of the front. 展开更多
关键词 metal matrix composite solid-liquid interface interaction SOLIDIFICATION
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Monolithic approach to thermal fluid-structure interaction withnonconforming interfaces
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作者 殷亮 蒋军成 张立翔 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 2012年第2期211-222,共12页
This paper presents a monolithic approach to the thermal fluidstructure interaction (FSI) with nonconforming interfaces. The thermal viscous flow is governed by the Boussinesq approximation and the incompressible Na... This paper presents a monolithic approach to the thermal fluidstructure interaction (FSI) with nonconforming interfaces. The thermal viscous flow is governed by the Boussinesq approximation and the incompressible NavierStokes equations. The motion of the fluid domain is accounted for by an arbitrary LagrangianEulerian (ALE) strategy. A pseudosolid formulation is used to manage the deformation of the fluid do main. The structure is described by the geometrically nonlinear thermoelastic dynamics. An efficient data transfer strategy based on the Gauss points is proposed to guarantee the equilibrium of the stresses and heat along the interface. The resulting strongly coupled set of nonlinear equations for the fluid, solution procedure. A numerical example efficiency of the methodology. structure, and heat is solved by a monolithic is presented to demonstrate the robustness and 展开更多
关键词 thermal fluid-structure interaction (FSI) nonconforming interface mono-lithic solution
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Research on menu-typed man-machine interaction system of digital TIG welding machine
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作者 何建萍 张春波 +2 位作者 孙广 吴毅雄 焦馥杰 《China Welding》 EI CAS 2004年第2期128-131,共4页
A digital man-machine interaction system controlled by communications between two processors of TMS320F240 and AT98C2051 was researched in the paper. The system is easy to set and modify welding process parameters by ... A digital man-machine interaction system controlled by communications between two processors of TMS320F240 and AT98C2051 was researched in the paper. The system is easy to set and modify welding process parameters by keyboards, and display information of welding site by LCD (Liquid Crystal Display). As one part of multi-task system about TIG welding machine, the coordination of man-machine interaction system with other tasks is the main point to the stability and reliability of its operation. Experiments result indicates that the system is stable, operation-flexible, high precision, and anti-interfering. 展开更多
关键词 man-machine interaction system DIGITALIZATION two-processor MENU
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Interaction energy of interface dislocation loops in piezoelectric bi-crystals
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作者 Jianghong Yuan Yin Huang +1 位作者 Weiqiu Chen Ernian Pan 《Theoretical & Applied Mechanics Letters》 CAS CSCD 2017年第2期76-80,共5页
Interface dislocations may dramatically change the electric properties, such as polarization, of the piezoelectric crystals. In this paper, we study the linear interactions of two interface dislocation loops with arbi... Interface dislocations may dramatically change the electric properties, such as polarization, of the piezoelectric crystals. In this paper, we study the linear interactions of two interface dislocation loops with arbitrary shape in generally anisotropic piezoelectric bi-crystals. A simple formula for calculating the interaction energy of the interface dislocation loops is derived and given by a double line integral along two closed dislocation curves. Particularly, interactions between two straight segments of the interface dislocations are solved analytically, which can be applied to approximate any curved loop so that an analytical solution can be also achieved. Numerical results show the influence of the bi-crystal interface as well as the material orientation on the interaction of interface dislocation loops. 展开更多
关键词 interface dislocation Piezoelectric bi-crystals Anisotropic elasticity interaction energy
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Microstructure of interaction interface between Al-Si,Zn-Al alloys and Al_2O_(3p)/6061Al composite
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作者 许志武 闫久春 +1 位作者 吕世雄 杨士勤 《中国有色金属学会会刊:英文版》 CSCD 2004年第2期351-355,共5页
Interaction behaviors between Al-Si, Zn-Al alloys and Al2O)3p)/6061Al composite at different heating temperatures were investigated. It is found that Al2O)3p)/6061Al composite can be wetted well by AlSi-1, AlSi-4 and ... Interaction behaviors between Al-Si, Zn-Al alloys and Al2O)3p)/6061Al composite at different heating temperatures were investigated. It is found that Al2O)3p)/6061Al composite can be wetted well by AlSi-1, AlSi-4 and Zn-Al alloys and an interaction layer forms between the alloy and composite during interaction. Little Al-Si alloys remain on the surface when they fully wet the composite and Si element in Al-Si alloy diffuses into composite entirely and assembles in the composite near the interface of Al-Si alloy/composite to form a Si-rich zone. The microstructure in interaction layer with Si penetration is still dense. Much more residual Zn-Al alloy exists on the surface of composite when it wets the composite, and porosities appear at the interface of Zn-Al alloy/composite. The penetration of elements Zn, Cu of Zn-Al alloy into composite leads to the generation of shrinkage cavities in the interaction layer and makes the microstructure of Al2O)3p)/6061Al composite loose. 展开更多
关键词 AL-SI合金 ZN-AL合金 Al2O3p/6061Al复合材料 显微结构 湿润性 TLP 压力焊接
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Molecular dynamics simulations on the interactions between nucleic acids and a phospholipid bilayer
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作者 徐耀 黄舒伟 +1 位作者 丁泓铭 马余强 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第2期512-521,共10页
Recently,lipid nanoparticles(LNPs)have been extensively investigated as non-viral carriers of nucleic acid vaccines due to their high transport efficiency,safety,and straightforward production and scalability.However,... Recently,lipid nanoparticles(LNPs)have been extensively investigated as non-viral carriers of nucleic acid vaccines due to their high transport efficiency,safety,and straightforward production and scalability.However,the molecular mechanism underlying the interactions between nucleic acids and phospholipid bilayers within LNPs remains elusive.In this study,we employed the all-atom molecular dynamics simulation to investigate the interactions between single-stranded nucleic acids and a phospholipid bilayer.Our findings revealed that hydrophilic bases,specifically G in single-stranded RNA(ssRNA)and single-stranded DNA(ssDNA),displayed a higher propensity to form hydrogen bonds with phospholipid head groups.Notably,ssRNA exhibited stronger binding energy than ssDNA.Furthermore,divalent ions,particularly Ca2+,facilitated the binding of ssRNA to phospholipids due to their higher binding energy and lower dissociation rate from phospholipids.Overall,our study provides valuable insights into the molecular mechanisms underlying nucleic acidphospholipid interactions,with potential implications for the nucleic acids in biotherapies,particularly in the context of lipid carriers. 展开更多
关键词 RNA DNA lipid bilayer molecular dynamics interface interaction divalent cation
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Sulfur vacancies and heterogeneous interfaces promote high performance sodium storage of bimetallic chalcogenide hollow nanospheres
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作者 Shiyue Cao Xiaoting Xu +2 位作者 Qiming Liu Huijuan Zhu Ting Hu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第8期596-610,I0013,共16页
Transition metal sulfides have high theoretical capacities and are considered as potential anode materials for sodium-ion batteries.However,due to low inherent conductivity and significant volume expansion,the electro... Transition metal sulfides have high theoretical capacities and are considered as potential anode materials for sodium-ion batteries.However,due to low inherent conductivity and significant volume expansion,the electrochemical performance is greatly limited.In this study,a nickel/manganese sulfide material(Ni_(0.96)S_(x)/MnS_(y)-NC)with adjustable sulfur vacancies and heterogeneous hollow spheres was prepared using a simple method.The introduction of a concentration-adjustable sulfur vacancy enables the generation of a heterogeneous interface between bimetallic sulfide and sulfur vacancies.This interface collectively creates an internal electric field,improving the mobility of electrons and ions,increasing the number of electrochemically active sites,and further optimizing the performance of Na~+storage.The direction of electron flow is confirmed by Density functional theory(DFT)calculations.The hollow nano-spherical material provides a buffer for expansion,facilitating rapid transfer kinetics.Our innovative discovery involves the interaction between the ether-based electrolyte and copper foil,leading to the formation of Cu_9S_5,which grafts the active material and copper current collector,reinforcing mechanical supporting.This results in a new heterostructure of Cu_9S_5 with Ni_(0.96)S_(x)/MnS_(y),contributing to the stabilization of structural integrity for long-cycle performance.Therefore,Ni_(0.96)S_(x)/MnS_(y)-NC exhibits excellent electrochemical properties following our modification route.Regarding stability performance,Ni0_(.96)S_(x)/MnS_(y)-NC demonstrates an average decay rate of 0.00944%after 10,000 cycles at an extremely high current density of 10000 mA g^(-1),A full cell with a high capacity of 304.2 mA h g^(-1)was also successfully assembled by using Na_(3)V_(2)(PO_(4))_(3)/C as the cathode.This study explores a novel strategy for interface/vacancy co-modification in the fabrication of high-performance sodium-ion batteries electrode. 展开更多
关键词 Sulfur vacancies Heterogeneous interface interactions Sodium ion batteries
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Spin wave resonance frequency in bilayer ferromagnetic films with the biquadratic exchange interaction
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作者 Xiaojie Zhang Yuting Wang +3 位作者 Yanqiu Chang Huan Wang Jianhong Rong Guohong Yun 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第9期607-613,共7页
The dependences of spin wave resonance(SWR)frequency on the surface anisotropy field,interface exchange coupling,symmetry,biquadratic exchange(BQE)interaction,film thickness,and the external magnetic field in bilayer ... The dependences of spin wave resonance(SWR)frequency on the surface anisotropy field,interface exchange coupling,symmetry,biquadratic exchange(BQE)interaction,film thickness,and the external magnetic field in bilayer ferromagnetic films are theoretically analyzed by employing the linear spin wave approximation and Green’s function method.A remarkable increase of SWR frequency,except for energetically lower two modes,can be obtained in our model that takes the BQE interaction into account.Again,the effect of the external magnetic field on SWR frequency can be increased by increasing the biquadratic to interlayer exchange ratio.It has been identified that the BQE interaction is of utmost importance in improving the SWR frequency of the bilayer ferromagnetic films.In addition,for bilayer ferromagnetic films,the frequency gap between the energetically highest mode and lowest mode is found to increase by increasing the biquadratic to interlayer exchange ratio and film thickness and destroying the symmetry of the system.These results can be used to improve the understanding of magnetic properties in bilayer ferromagnetic films and thus may have prominent implications for future magnetic devices. 展开更多
关键词 spin wave resonance frequency biquadratic exchange interaction interface exchange coupling surface anisotropy
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Research on the Man-machine Interactive Environment VR and the Applications on Vocational Education and Training under the Perspective of Interactivity
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作者 Xiaoyi Huo 《International Journal of Technology Management》 2016年第7期39-41,共3页
In this paper, we conduct research on the man-machine interactive environment VR and the applications on vocational educationand training under the perspective of interactivity. With the increase in the general standa... In this paper, we conduct research on the man-machine interactive environment VR and the applications on vocational educationand training under the perspective of interactivity. With the increase in the general standard of social knowledge level and competition intensifi es,more and more people have a goal to build a lifelong learning system, according to their own hobbies, work and the needs of the marketcompetition. Under this condition, the vocational education is becoming more and more essential. This paper integrates the VR and man-machineinteractive concept to propose the new education paradigm that is innovative. 展开更多
关键词 man-machine Environment VR Vocational Education Perspective of interactivity.
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Conversational Documentarianism in Instagram: Multidimensional Interface and Interactivity
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作者 Jacob Banuelos 《Journalism and Mass Communication》 2015年第2期64-77,共14页
What are the articulative semiotic characteristics of the Instagram interface, and how do they contribute to the construction of documentary, conversational photographic discourses with social purposes? This is a sem... What are the articulative semiotic characteristics of the Instagram interface, and how do they contribute to the construction of documentary, conversational photographic discourses with social purposes? This is a semiotic analysis of the Instagram interface as an interactive and conversational platform in creating new photographic documentary strategies for social purposes, to which we have applied the model of textual conversation as outlined by Bettetini (1984) and the concept of multidimensional interactivity proposed by Sally McMillan (2006). We shall analyse the work of Pachi Tamer (@cachafaz) in Instagram,and in particular the "Jim-Oktoberfest" case, the One-Dollar-Dreams site and the same author's "Sebasti^in" case from a semiotic perspective. 展开更多
关键词 Instagram interface conversational textual interactivity photographic conversational documentarianism Pachi Tamer (@cachafaz)
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Functional-Material-Based Touch Interfaces for Multidimensional Sensing for Interactive Displays:A Review
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作者 Shuo Gao 《Semiconductor Science and Information Devices》 2019年第1期15-28,共14页
Multidimensional sensing is a highly desired attribute for allowing human-machine interfaces(HMIs)to perceive various types of information from both users and the environment,thus enabling the advancement of various s... Multidimensional sensing is a highly desired attribute for allowing human-machine interfaces(HMIs)to perceive various types of information from both users and the environment,thus enabling the advancement of various smart electronics/applications,e.g.,smartphones and smart cities.Conventional multidimensional sensing is achieved through the integration of multiple discrete sensors,which introduces issues such as high energy consumption and high circuit complexity.These disadvantages have motivated the widespread use of functional materials for detecting various stimuli at low cost with low power requirements.This work presents an overview of simply structured touch interfaces for multidimensional(x-y location,force and temperature)sensing enabled by piezoelectric,piezoresistive,triboelectric,pyroelectric and thermoelectric materials.For each technology,the mechanism of operation,state-of-the-art designs,merits,and drawbacks are investigated.At the end of the article,the author discusses the challenges limiting the successful applications of functional materials in commercial touch interfaces and corresponding development trends. 展开更多
关键词 TOUCH interfaceS FUNCTIONAL materials MULTIDIMENSIONAL sensing interactIVE DISPLAYS
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Numerical study on shock-accelerated heavy gas cylinderswith diffusive interfaces 被引量:4
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作者 Dongdong Li Ben Guan Ge Wang 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2019年第4期750-762,共13页
Interactions of shock wave and heavy gas cylinders with different diffusive interfaces are numerically investigated. Comparisons among these interfaces are made in terms of cylinder morphology, wave system evolution, ... Interactions of shock wave and heavy gas cylinders with different diffusive interfaces are numerically investigated. Comparisons among these interfaces are made in terms of cylinder morphology, wave system evolution, fluids mixing, and circulation generation. Navier-Stokes equations are solved in the present work to simulate the complex multi-fluid flow. The fifth-order weighted essentially non-oscillatory scheme is used to compute the numerical flux. The influence of interface diffusion is revealed by the numerical results. The cylinders with similar geometric scale but different diffusion interface have great similarities in the hydrodynamic characteristics, including the interface morphology, shock focusing and molecular mixing, as well as circulation deposition. For the cases with more serious interface diffusion, the cylinder develops into more regular vortex pairs. The diffusive interface greatly mitigates the strength of the reflected shock wave and weakens the shock focusing capability. Some interface structural features are also recorded and analyzed. The diffusive interface brings about slower molecular mixing and less circulation generation. The circulation deposition on different interfaces is quantitatively investigated and compared with the theoretical models. The theoretical models are found to be applicable to the scenarios of diffusive interfaces. 展开更多
关键词 Shock BUBBLE interaction interfacIAL INSTABILITY Diffusive interface CIRCULATION model
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Intermolecular and Surface Interactions in Engineering Processes 被引量:8
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作者 Jiawen Zhang Hongbo Zeng 《Engineering》 SCIE EI 2021年第1期63-83,共21页
Interactions involving chemical reagents,solid particles,gas bubbles,liquid droplets,and solid surfaces in complex fluids play a vital role in many engineering processes,such as froth flotation,emulsion and foam forma... Interactions involving chemical reagents,solid particles,gas bubbles,liquid droplets,and solid surfaces in complex fluids play a vital role in many engineering processes,such as froth flotation,emulsion and foam formation,adsorption,and fouling and anti-fouling phenomena.These interactions at the molecular,nano-,and micro scale significantly influence and determine the macroscopic performance and efficiency of related engineering processes.Understanding the intermolecular and surface interactions in engineering processes is of both fundamental and practical importance,which not only improves production technologies,but also provides valuable insights into the development of new materials.In this review,the typical intermolecular and surface interactions involved in various engineering processes,including Derjaguin–Landau–Verwey–Overbeek(DLVO)interactions(i.e.,van der Waals and electrical doublelayer interactions)and non-DLVO interactions,such as steric and hydrophobic interactions,are first introduced.Nanomechanical techniques such as atomic force microscopy and surface forces apparatus for quantifying the interaction forces of molecules and surfaces in complex fluids are briefly introduced.Our recent progress on characterizing the intermolecular and surface interactions in several engineering systems are reviewed,including mineral flotation,petroleum engineering,wastewater treatment,and energy storage materials.The correlation of these fundamental interaction mechanisms with practical applications in resolving engineering challenges and the perspectives of the research field have also been discussed. 展开更多
关键词 Intermolecular and surface interactions COLLOIDS Emulsions interface science Engineering processes Atomic force microscopy Surface forces apparatus
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Strong metal‐support interaction boosting the catalytic activity of Au/TiO_(2) in chemoselective hydrogenation 被引量:3
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作者 Feng Hong Shengyang Wang +4 位作者 Junying Zhang Junhong Fu Qike Jiang Keju Sun Jiahui Huang 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 2021年第9期1530-1537,共8页
Gold catalysts have been reported as highly effective catalysts in various oxidation reactions.However,for chemoselective hydrogenation reactions,gold‐based catalysts normally show much lowercatalytic activity than p... Gold catalysts have been reported as highly effective catalysts in various oxidation reactions.However,for chemoselective hydrogenation reactions,gold‐based catalysts normally show much lowercatalytic activity than platinum group metals,even though their selectivities are excellent.Here,wereport that the chemoselective hydrogenation activity of 3‐nitrostyrene to 3‐vinylaniline overAu/TiO_(2)can be enhanced up to 3.3 times through the hydrogen reduction strategy.It is revealedthat strong metal‐support interaction,between gold nanoparticles(NPs)and TiO_(2)support,is introducedthrough hydrogen reduction,resulting in partial dispersion of reduced TiOx on the Au surface.The partially covered Au not only increases the perimeter of the interface between the gold NPs andthe support,but also benefits H_(2)activation.Reaction kinetic analysis and H_(2)‐D2 exchange reactionshow that H_(2)activation is the critical step in the hydrogenation of 3‐nitrostyrene to 3‐vinylaniline.Density functional theory calculations verify that hydrogen dissociation and hydrogen transfer arefavored at the interface of gold NPs and TiO_(2)over the hydrogen‐reduced Au/TiO_(2).This study providesinsights for fabricating highly active gold‐based catalysts for chemoselective hydrogenationreactions. 展开更多
关键词 Gold catalysis Strong metal support interaction interface 3‐Nitrostyrene chemoselective hydrogenation Boosting activity
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Interaction behaviors between Zn-Al alloy and Al_2O_3p/6061Al composite with aid of ultrasonic vibration 被引量:1
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作者 许志武 闫久春 +1 位作者 孔祥利 杨士勤 《中国有色金属学会会刊:英文版》 CSCD 2005年第S2期60-65,共6页
Interactions between Zn-Al alloy and Al2O 3p/6061Al composite with the aid of ultrasonic vibration in air were investigated. For the composite without degassed treatment, the molten Zn-Al alloy cannot spread along the... Interactions between Zn-Al alloy and Al2O 3p/6061Al composite with the aid of ultrasonic vibration in air were investigated. For the composite without degassed treatment, the molten Zn-Al alloy cannot spread along the surface of the composite when the ultrasonic vibration amplitude is lower than 10μm. Instead, it undermines the substrate oxide layer and propagates along the substrate metal-substrate oxide interface, and penetrates into the composite at the same time. The penetration of the Zn-Al alloy into the composite makes the microstructure of the penetration zone unconsolidated. As the ultrasonic vibration amplitude increases, the spreading area of the molten Zn-Al alloy increases and the mass transfer at the interaction interface between the Zn-Al alloy and the composite intensifies. The porosity at the interaction interface results from the gas escaping from the base material by which the undermining phenomenon and the penetration of elements Zn, Cu into the composite is favoured. When the composite is degassed, the undermining zone and the penetration zone become significantly limited and the penetration zone remains consolidated. Only limited base metal melts during interaction, which is accompanied with fewer reinforcements and primary α-Al dendrites in the solidified Zn-Al alloy. 展开更多
关键词 particle-reinforced COMPOSITE interaction interface structure undermining PENETRATION layer ULTRASONIC vibration
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