This study presents a solvent-free,facile synthesis of a bio-based green antibacterial agent and aromatic monomer methacrylated vanillin(MV)using vanillin.The resulting MV not only imparted antibacterial properties to...This study presents a solvent-free,facile synthesis of a bio-based green antibacterial agent and aromatic monomer methacrylated vanillin(MV)using vanillin.The resulting MV not only imparted antibacterial properties to coatings layered on leather,but could also be employed as a green alternative to petroleum-based carcinogen styrene(St).Herein,MV was copolymerized with butyl acrylate(BA)to obtain waterborne bio-based P(MV-BA)miniemulsion via miniemulsion polymerization.Subsequently,MXene nanosheets with excellent photothermal conversion performance and antibacterial properties,were introduced into the P(MV-BA)miniemulsion by ultrasonic dispersion.During the gradual solidification of P(MV-BA)/MXene nanocomposite miniemulsion on the leather surface,MXene gradually migrated to the surface of leather coatings due to the cavitation effect of ultrasonication and amphiphilicity of MXene,which prompted its full exposure to light and bacteria,exerting the maximum photothermal conversion efficiency and significant antibacterial efficacy.In particular,when the dosage of MXene nanosheets was 1.4 wt%,the surface temperature of P(MV-BA)/MXene nanocomposite miniemulsioncoated leather(PML)increased by about 15℃ in an outdoor environment during winter,and the antibacterial rate against Escherichia coli and Staphylococcus aureus was nearly 100%under the simulated sunlight treatment for 30 min.Moreover,the introduction of MXene nanosheets increased the air permeability,water vapor permeability,and thermal stability of these coatings.This study provides a new insight into the preparation of novel,green,and waterborne bio-based nanocomposite coatings for leather,with desired warmth retention and antibacterial properties.It can not only realize zerocarbon heating based on sunlight in winter,reducing the use of fossil fuels and greenhouse gas emissions,but also improve ability to fight off invasion by harmful bacteria,viruses,and other microorganisms.展开更多
In recent years,water evaporation-induced electricity has attracted a great deal of attention as an emerging green and renewable energy harvesting technology.Although abundant materials have been developed to fabricat...In recent years,water evaporation-induced electricity has attracted a great deal of attention as an emerging green and renewable energy harvesting technology.Although abundant materials have been developed to fabricate hydrovoltaic devices,the limitations of high costs,inconvenient storage and transport,low environmental benefits,and unadaptable shape have restricted their wide applications.Here,an electricity generator driven by water evaporation has been engineered based on natural biomass leather with inherent properties of good moisture permeability,excellent wettability,physicochemical stability,flexibility,and biocompatibility.Including numerous nano/microchannels together with rich oxygen-bearing functional groups,the natural leather-based water evaporator,Leather_(Emblic-NPs-SA/CB),could continuously produce electricity even staying outside,achieving a maximum output voltage of∼3 V with six-series connection.Furthermore,the leather-based water evaporator has enormous potential for use as a flexible self-powered electronic floor and seawater demineralizer due to its sensitive pressure sensing ability as well as its excellent photothermal conversion efficiency(96.3%)and thus fast water evaporation rate(2.65 kg m^(−2)h^(−1)).This work offers a new and functional material for the construction of hydrovoltaic devices to harvest the sustained green energy from water evaporation in arbitrary ambient environments,which shows great promise in their widespread applications.展开更多
This paper describes the interaction between deep-seated landslides and man-made structures such as dams, penstocks, viaducts, and tunnels. Selected case studies are reported first with the intent to gain insights int...This paper describes the interaction between deep-seated landslides and man-made structures such as dams, penstocks, viaducts, and tunnels. Selected case studies are reported first with the intent to gain insights into the complexities associated with the interaction of these structures with deep-seated landslides(generally referred to as deep-seated gravity slope deformations, DSGSDs). The main features, which characterize these landslides, are mentioned together with the interaction problems encountered in each case. Given the main objective of this paper, the numerical modeling methods adopted are outlined as means for increase in the understanding of the interaction problems being investigated. With the above in mind, the attention moves to an important and unique case history dealing with the interaction of a large-size twin-tunnel excavated with an earth pressure balance(EPB)tunnel boring machine(TBM) and a deep-seated landslide, which was reactivated due to the stress changes induced by tunnel excavation in landslide shear zone. The geological and geotechnical conditions are described together with the available monitoring data on the landslide movements, based on the advanced and conventional monitoring tools used. Numerical modeling is illustrated as an aid to back-analyze the monitored surface and subsurface deformations and to assist in finding the appropriate engineering solution for putting the tunnel into service and as a follow-up means for future understanding and control of the interaction problems. The simulation is based on a novel time-dependent model representing the landslide behavior.展开更多
In this study the regeneration diversity of Syahkal forests afforestated and natural stands in north of Iran was studied and compared from the point of view of evenness and diversity index. In order to accomplish this...In this study the regeneration diversity of Syahkal forests afforestated and natural stands in north of Iran was studied and compared from the point of view of evenness and diversity index. In order to accomplish this study two natural and man-made stands that almost are located in the same height above the sea level were chosen. The area of each stand was 30 ha and the inventory was done by the random-systematic method with a 5R land measurement (500 m2) selected. Also, in order to study the regeneration in the center of each sample piece 125 square meters micro plots were formed. The results show that regeneration diversity index in natural stands is more than that in man-made stands which in this case Mc-Arthur index with 2.41 has the most amount while Simpson index with 0.543 has the least amount. But the evenness indexes in man-made stands are more than that in natural stand which the main reason is the purity of the man-made stand.展开更多
Man-made lakes are alternative and potential habitats for biodiversity conservation, fisheries and extensive aquaculture. We investigated the ecology and the fish community structure of two (2) sand-dragged man-made l...Man-made lakes are alternative and potential habitats for biodiversity conservation, fisheries and extensive aquaculture. We investigated the ecology and the fish community structure of two (2) sand-dragged man-made lakes, Lake Ahozon and Lake Bewacodji of Southern Benin, with implications for species conservation, fisheries management and aquaculture valorization. From August 2014 to July 2015, habitats conditions were evaluated and fishes were sampled monthly with seine, cast net, experimental gill net and hooks in the open water and aquatic vegetation habitats of both lakes. Overall, the water quality of Lake Ahozon was globally favorable for the growth and the survival of the fish resources whereas Lake Bewacodji exhibited a poor water quality indicated mainly by an acid pH (mean: 6.32 ± 0.58) and low dissolved oxygen concentrations (mean: 3.52 ± 1.25 mg/l) caused by dense floating plants, Nymphea sp mainly and huge daily dumping of domestic wastes. The study revealed low species richness, d = 5.89 and d = 3.87, and low species diversity, H’ = 0.76 and H’ = 0.48 for Lakes Ahozon and Bewacodji, respectively, with Lake Ahozon more diverse than Lake Bewacodji. The fish community of Lake Ahozon comprised six (6) species, 3 cichlids Sarotherodon galilaeus, Oreochromis niloticus and Tilapia guineensis, the silver catfish, Chrysichthys nigrodigitatus (Claroteidae), the African bonytongue, Heterotis niloticus (Osteoglossidae), and the African catfish, Clarias gariepinus (Clariidae). Numerically, S. galilaeus dominated Lake Ahozon and made 85.21% of the sample. In Lake Bewacodji, the fish composition comprised four (4) species, Sarotherodon galilaeus multifasciatus, the dominant species making numerically 91.58% of the total sample, T. guineensis, C. gariepinus and C. nigrodigitatus. With regard to trophic structure, the fish assemblages of both lakes were numerically dominated by planktinovores/ detritivores, mainly S. galilaeus, O. niloticus, T. guineensis and C. nigrodigitatus making together 99.46% of Lake Ahozon fish community, and S. galilaeus multifasciatus, T. guineensis and C. nigrodigitatus accounting together for about 98.59% of Lake Bewacodji. In Lake Ahozon, standard length (SL) frequencies histograms showed an unimodal size distribution for H. niloticus, the nile tilapia O. niloticus and C. gariepinus whereas the two cichlids, S. galilaeus and T. guineensis exhibited a bimodal size distribution. In Lake Bewacodji, S. galilaeus multifasciatus, C. nigrodigitatus and C. gariepinus exhibited an unimodal size distribution. A sustainable exploitation of both man-made lakes requires the implementation of an integrated management scheme which should include habitat restoration and protection plan, fisheries/aquacultural valorization, ecological sound agriculture/ecotourism and environmental monitoring. 展开更多
The 25th China International Man-made Fiber Conference (Bengbu 2019)(hereinafter referred to as CIMFC 2019), themed on “Opening and Integaration for Interactive Development — Coordinated Progress of Global Man-Made ...The 25th China International Man-made Fiber Conference (Bengbu 2019)(hereinafter referred to as CIMFC 2019), themed on “Opening and Integaration for Interactive Development — Coordinated Progress of Global Man-Made Fiber Industry”, was convened in Bengbu City, Anhui Province. CIMFC 2019 was sponcored by China National Textile and Apparel Council (CNTAC), organized by China Chemical Fibers Association, Chi-na Textile International Exchange Center, and China BBCA Group Corp., supported by Bengbu Municipal People’s Goverment, and co-organized by Bengbu Investment Promotion and Foreign cooperation Center, Bengbu Municipal Bureau of Commerce and Foreign Affairs, and Oerlikon Man-made Fiber.展开更多
As an important fundamental industry of the national economy,the man-made fiber industrial chain is integrated into the era development and it assumes the responsibility of advancing.Each link of the industrial chain ...As an important fundamental industry of the national economy,the man-made fiber industrial chain is integrated into the era development and it assumes the responsibility of advancing.Each link of the industrial chain is connected with each other.After the development and accumulation of several decades,the new produced polyester,PTA and other plants keep展开更多
In the festivedays whencelebrating the50th anniversa-ry of the found-ing of the Peo-ple’s Republic,and the 50th an-niversary of thefounding of theChinese Acad-emy of Scienc-es (CAS), it isnatural for thepeople to thi...In the festivedays whencelebrating the50th anniversa-ry of the found-ing of the Peo-ple’s Republic,and the 50th an-niversary of thefounding of theChinese Acad-emy of Scienc-es (CAS), it isnatural for thepeople to thinkwith pride ofChina’s展开更多
Studied by Mr. LIU Zhongzhu, ex Chairman of Fujian Academy of Agri Sciences, a combined technique of man—made biosphere in rice fields deserves notice. The research indicated that using man—made biosphere in rice fi...Studied by Mr. LIU Zhongzhu, ex Chairman of Fujian Academy of Agri Sciences, a combined technique of man—made biosphere in rice fields deserves notice. The research indicated that using man—made biosphere in rice fields can enrich soil, reduce the infects of diseases, insects and weeds, economize the use of pesticide and herbicide, decrease green house effect, and improve atmosphere. As tested, the yield for rice is usually 10500—12000 kg/ha, for fish is usually 2250—3250 kg/ha. Again, about 50%—60% fertilizer and 30%—50% pesticide can be saved. The net income increased $ 1,080—1,800 per ha.展开更多
Artificial leather and synthetic leather products have more than 60 years of development history,because the cost of artificial leather is lower than real leather,the manufacturing process is relatively simple,widely ...Artificial leather and synthetic leather products have more than 60 years of development history,because the cost of artificial leather is lower than real leather,the manufacturing process is relatively simple,widely used in textile,automotive and furniture decoration fields.展开更多
基金supported by the National Natural Science Foundation of China and(52073164 and 21838007).
文摘This study presents a solvent-free,facile synthesis of a bio-based green antibacterial agent and aromatic monomer methacrylated vanillin(MV)using vanillin.The resulting MV not only imparted antibacterial properties to coatings layered on leather,but could also be employed as a green alternative to petroleum-based carcinogen styrene(St).Herein,MV was copolymerized with butyl acrylate(BA)to obtain waterborne bio-based P(MV-BA)miniemulsion via miniemulsion polymerization.Subsequently,MXene nanosheets with excellent photothermal conversion performance and antibacterial properties,were introduced into the P(MV-BA)miniemulsion by ultrasonic dispersion.During the gradual solidification of P(MV-BA)/MXene nanocomposite miniemulsion on the leather surface,MXene gradually migrated to the surface of leather coatings due to the cavitation effect of ultrasonication and amphiphilicity of MXene,which prompted its full exposure to light and bacteria,exerting the maximum photothermal conversion efficiency and significant antibacterial efficacy.In particular,when the dosage of MXene nanosheets was 1.4 wt%,the surface temperature of P(MV-BA)/MXene nanocomposite miniemulsioncoated leather(PML)increased by about 15℃ in an outdoor environment during winter,and the antibacterial rate against Escherichia coli and Staphylococcus aureus was nearly 100%under the simulated sunlight treatment for 30 min.Moreover,the introduction of MXene nanosheets increased the air permeability,water vapor permeability,and thermal stability of these coatings.This study provides a new insight into the preparation of novel,green,and waterborne bio-based nanocomposite coatings for leather,with desired warmth retention and antibacterial properties.It can not only realize zerocarbon heating based on sunlight in winter,reducing the use of fossil fuels and greenhouse gas emissions,but also improve ability to fight off invasion by harmful bacteria,viruses,and other microorganisms.
基金supported by the National Natural Science Foundation of China(22308210)the Scientific Research Program Funded by Shaanxi Provincial Education Department(23JK0350)+3 种基金the Open Foundation of Key Laboratory of Auxiliary Chemistry and Technology for Chemical Industry,Ministry of Education,and Shaanxi Collaborative Innovation Center of Industrial Auxiliary Chemistry and Technology,Shaanxi University of Science and Technology(KFKT2021-12)the Opening Project of Key Laboratory of Leather Chemistry and Engineering(Sichuan University),Ministry of Education(2022)the RIKEN-MOST Project between the Ministry of Science and Technology of the People's Republic of China(MOST)and RIKEN,the China Scholarship Council(202108610127)the Natural Science Foundation of Shaanxi University of Science&Technology(2019BT-44).
文摘In recent years,water evaporation-induced electricity has attracted a great deal of attention as an emerging green and renewable energy harvesting technology.Although abundant materials have been developed to fabricate hydrovoltaic devices,the limitations of high costs,inconvenient storage and transport,low environmental benefits,and unadaptable shape have restricted their wide applications.Here,an electricity generator driven by water evaporation has been engineered based on natural biomass leather with inherent properties of good moisture permeability,excellent wettability,physicochemical stability,flexibility,and biocompatibility.Including numerous nano/microchannels together with rich oxygen-bearing functional groups,the natural leather-based water evaporator,Leather_(Emblic-NPs-SA/CB),could continuously produce electricity even staying outside,achieving a maximum output voltage of∼3 V with six-series connection.Furthermore,the leather-based water evaporator has enormous potential for use as a flexible self-powered electronic floor and seawater demineralizer due to its sensitive pressure sensing ability as well as its excellent photothermal conversion efficiency(96.3%)and thus fast water evaporation rate(2.65 kg m^(−2)h^(−1)).This work offers a new and functional material for the construction of hydrovoltaic devices to harvest the sustained green energy from water evaporation in arbitrary ambient environments,which shows great promise in their widespread applications.
基金support of Spea Ingegneria Europea SpA and Società Autostrade per l’Italia SpA
文摘This paper describes the interaction between deep-seated landslides and man-made structures such as dams, penstocks, viaducts, and tunnels. Selected case studies are reported first with the intent to gain insights into the complexities associated with the interaction of these structures with deep-seated landslides(generally referred to as deep-seated gravity slope deformations, DSGSDs). The main features, which characterize these landslides, are mentioned together with the interaction problems encountered in each case. Given the main objective of this paper, the numerical modeling methods adopted are outlined as means for increase in the understanding of the interaction problems being investigated. With the above in mind, the attention moves to an important and unique case history dealing with the interaction of a large-size twin-tunnel excavated with an earth pressure balance(EPB)tunnel boring machine(TBM) and a deep-seated landslide, which was reactivated due to the stress changes induced by tunnel excavation in landslide shear zone. The geological and geotechnical conditions are described together with the available monitoring data on the landslide movements, based on the advanced and conventional monitoring tools used. Numerical modeling is illustrated as an aid to back-analyze the monitored surface and subsurface deformations and to assist in finding the appropriate engineering solution for putting the tunnel into service and as a follow-up means for future understanding and control of the interaction problems. The simulation is based on a novel time-dependent model representing the landslide behavior.
文摘In this study the regeneration diversity of Syahkal forests afforestated and natural stands in north of Iran was studied and compared from the point of view of evenness and diversity index. In order to accomplish this study two natural and man-made stands that almost are located in the same height above the sea level were chosen. The area of each stand was 30 ha and the inventory was done by the random-systematic method with a 5R land measurement (500 m2) selected. Also, in order to study the regeneration in the center of each sample piece 125 square meters micro plots were formed. The results show that regeneration diversity index in natural stands is more than that in man-made stands which in this case Mc-Arthur index with 2.41 has the most amount while Simpson index with 0.543 has the least amount. But the evenness indexes in man-made stands are more than that in natural stand which the main reason is the purity of the man-made stand.
文摘Man-made lakes are alternative and potential habitats for biodiversity conservation, fisheries and extensive aquaculture. We investigated the ecology and the fish community structure of two (2) sand-dragged man-made lakes, Lake Ahozon and Lake Bewacodji of Southern Benin, with implications for species conservation, fisheries management and aquaculture valorization. From August 2014 to July 2015, habitats conditions were evaluated and fishes were sampled monthly with seine, cast net, experimental gill net and hooks in the open water and aquatic vegetation habitats of both lakes. Overall, the water quality of Lake Ahozon was globally favorable for the growth and the survival of the fish resources whereas Lake Bewacodji exhibited a poor water quality indicated mainly by an acid pH (mean: 6.32 ± 0.58) and low dissolved oxygen concentrations (mean: 3.52 ± 1.25 mg/l) caused by dense floating plants, Nymphea sp mainly and huge daily dumping of domestic wastes. The study revealed low species richness, d = 5.89 and d = 3.87, and low species diversity, H’ = 0.76 and H’ = 0.48 for Lakes Ahozon and Bewacodji, respectively, with Lake Ahozon more diverse than Lake Bewacodji. The fish community of Lake Ahozon comprised six (6) species, 3 cichlids Sarotherodon galilaeus, Oreochromis niloticus and Tilapia guineensis, the silver catfish, Chrysichthys nigrodigitatus (Claroteidae), the African bonytongue, Heterotis niloticus (Osteoglossidae), and the African catfish, Clarias gariepinus (Clariidae). Numerically, S. galilaeus dominated Lake Ahozon and made 85.21% of the sample. In Lake Bewacodji, the fish composition comprised four (4) species, Sarotherodon galilaeus multifasciatus, the dominant species making numerically 91.58% of the total sample, T. guineensis, C. gariepinus and C. nigrodigitatus. With regard to trophic structure, the fish assemblages of both lakes were numerically dominated by planktinovores/ detritivores, mainly S. galilaeus, O. niloticus, T. guineensis and C. nigrodigitatus making together 99.46% of Lake Ahozon fish community, and S. galilaeus multifasciatus, T. guineensis and C. nigrodigitatus accounting together for about 98.59% of Lake Bewacodji. In Lake Ahozon, standard length (SL) frequencies histograms showed an unimodal size distribution for H. niloticus, the nile tilapia O. niloticus and C. gariepinus whereas the two cichlids, S. galilaeus and T. guineensis exhibited a bimodal size distribution. In Lake Bewacodji, S. galilaeus multifasciatus, C. nigrodigitatus and C. gariepinus exhibited an unimodal size distribution. A sustainable exploitation of both man-made lakes requires the implementation of an integrated management scheme which should include habitat restoration and protection plan, fisheries/aquacultural valorization, ecological sound agriculture/ecotourism and environmental monitoring.
文摘The 25th China International Man-made Fiber Conference (Bengbu 2019)(hereinafter referred to as CIMFC 2019), themed on “Opening and Integaration for Interactive Development — Coordinated Progress of Global Man-Made Fiber Industry”, was convened in Bengbu City, Anhui Province. CIMFC 2019 was sponcored by China National Textile and Apparel Council (CNTAC), organized by China Chemical Fibers Association, Chi-na Textile International Exchange Center, and China BBCA Group Corp., supported by Bengbu Municipal People’s Goverment, and co-organized by Bengbu Investment Promotion and Foreign cooperation Center, Bengbu Municipal Bureau of Commerce and Foreign Affairs, and Oerlikon Man-made Fiber.
文摘As an important fundamental industry of the national economy,the man-made fiber industrial chain is integrated into the era development and it assumes the responsibility of advancing.Each link of the industrial chain is connected with each other.After the development and accumulation of several decades,the new produced polyester,PTA and other plants keep
文摘In the festivedays whencelebrating the50th anniversa-ry of the found-ing of the Peo-ple’s Republic,and the 50th an-niversary of thefounding of theChinese Acad-emy of Scienc-es (CAS), it isnatural for thepeople to thinkwith pride ofChina’s
文摘Studied by Mr. LIU Zhongzhu, ex Chairman of Fujian Academy of Agri Sciences, a combined technique of man—made biosphere in rice fields deserves notice. The research indicated that using man—made biosphere in rice fields can enrich soil, reduce the infects of diseases, insects and weeds, economize the use of pesticide and herbicide, decrease green house effect, and improve atmosphere. As tested, the yield for rice is usually 10500—12000 kg/ha, for fish is usually 2250—3250 kg/ha. Again, about 50%—60% fertilizer and 30%—50% pesticide can be saved. The net income increased $ 1,080—1,800 per ha.
文摘Artificial leather and synthetic leather products have more than 60 years of development history,because the cost of artificial leather is lower than real leather,the manufacturing process is relatively simple,widely used in textile,automotive and furniture decoration fields.