The liquidliquid equilibrium data for two ternary systems, ethanolwaterKF and ethanol waterK2CO3, were determined at 25oC. Experiments show that by adding KF or K2CO3 into the ethanolwater system two phases are formed...The liquidliquid equilibrium data for two ternary systems, ethanolwaterKF and ethanol waterK2CO3, were determined at 25oC. Experiments show that by adding KF or K2CO3 into the ethanolwater system two phases are formed: an ethanol-rich phase with negligible salt and a water-rich phase with negligible ethanol, thus water can be separated out easily. A mathematical calculation of the liquidliquid equilibrium data was carried out with the Pitzer theory on water activity in the aqueous phase, and with the Wilson or NRTL or UNIQUAC equations for that in the ethanol phase, which is in good agreement with experimental data.展开更多
As a common precursor for supercritical CO_(2)(scCO_(2))deposition techniques,solubility data of organometallic complexes in scCO_(2)is crucial for the preparation of nanocomposites.Recently,metal acetylacetonates hav...As a common precursor for supercritical CO_(2)(scCO_(2))deposition techniques,solubility data of organometallic complexes in scCO_(2)is crucial for the preparation of nanocomposites.Recently,metal acetylacetonates have shown great potential for the preparation of single-atom catalytic materials.In this study,the solubilities of iron(Ⅲ)acetylacetonate(Fe(acac)3)and nickel(Ⅱ)acetylacetonate(Ni(acac)2)were measured at the temperature from 313.15 to 333.15 K and in the pressure range of 9.5–25.2 MPa to accumulate new solubility data.Solubility was measured using a static weight loss method.The semi-empirical models proposed by Chrastil and Sung et al.were used to correlate the solubility data of Fe(acac)3 and Ni(acac)2.The equations obtained can be used to predict the solubility of the same system in the experimental range.展开更多
In an equilibrium vessel,the solid-liquid equilibria(SLE) for three binary mixtures of phenyl salicylate with 1-butanol,2-butanol,and 2-methyl-1-propanol,respectively,have been measured from 283.15 K to the melting te...In an equilibrium vessel,the solid-liquid equilibria(SLE) for three binary mixtures of phenyl salicylate with 1-butanol,2-butanol,and 2-methyl-1-propanol,respectively,have been measured from 283.15 K to the melting temperature of the solute using a method in which an excess amount of solute was equilibrated with the alcohol solution.The liquid concentrations of the investigated phenyl salicylate in the saturated solution were analyzed by UV spectrometry.Activity coefficients for phenyl salicylate have been calculated by means of the Wilson,NRTL,and UNIQUAC equations and with them were correlated solubility data that were compared with the experimental ones.The best correlation of the solubility data has been obtained by the Wilson equation by which the average root-mean-square deviation of temperature for the three systems is 1.03 K.展开更多
The vapor-liquid equilibrium data of four binary systems (acetic acid +p-xylene, methyl acetate +n-propyl acetate, n-propyl acetate +p-xylene and methyl acetate +p-xylene) are measured at 101.33 kPa with Ellis equilib...The vapor-liquid equilibrium data of four binary systems (acetic acid +p-xylene, methyl acetate +n-propyl acetate, n-propyl acetate +p-xylene and methyl acetate +p-xylene) are measured at 101.33 kPa with Ellis equilibrium still, and then both the NRTL and UNIQUAC models are used in combination with the HOC model for correlating and estimating the vapor-liquid equilibrium of these four binary systems. The estimated binary VLE results using correlated parameters agree well with the measured data except the methyl acetate +p-xylene system which easily causes bumping and liquid rushing out of the sampling tap due to their dramatically different boiling points. The correlation results by NRTL and UNIQUAC models have little difference on the average absolute deviations of temperature and composition of vapor phase, and the results by NRTL model are slightly better than those by UNIQUAC model except for the methyl acetate +n-propyl acetate system, for which the latter gives more accurate correlations.展开更多
A model of continuous-time insider trading in which a risk-neutral in-sider possesses two imperfect correlated signals of a risky asset is studied.By conditional expectation theory and filtering theory,we first establ...A model of continuous-time insider trading in which a risk-neutral in-sider possesses two imperfect correlated signals of a risky asset is studied.By conditional expectation theory and filtering theory,we first establish three lemmas:normal corre-lation,equivalent pricing and equivalent profit,which can guarantee to turn our model into a model with insider knowing full information.Then we investigate the impact of the two correlated signals on the market equilibrium consisting of optimal insider trading strategy and semi-strong pricing rule.It shows that in the equilibrium,(1)the market depth is constant over time;(2)if the two noisy signals are not linerly correlated,then all private information of the insider is incorporated into prices in the end while the whole information on the asset value can not incorporated into prices in the end;(3)if the two noisy signals are linear correlated such that the insider can infer the whole information of the asset value,then our model turns into a model with insider knowing full information;(4)if the two noisy signals are the same then the total ex ant profit of the insider is increasing with the noise decreasing,while down to O as the noise going up to infinity;(5)if the two noisy signals are not linear correlated then with one noisy signal fixed,the total ex ante profit of the insider is single-peaked with a unique minimum with respect to the other noisy signal value,and furthermore as the noisy value going to O it gets its maximum,the profit in the case that the real value is observed.展开更多
Angular correlation of excitation functions in dissipative heavy ion collision 27Al+27Al has been measured. The incident beam energies ranged from 114MeV to 127MeV in steps of 200keV. The angular analysis region was c...Angular correlation of excitation functions in dissipative heavy ion collision 27Al+27Al has been measured. The incident beam energies ranged from 114MeV to 127MeV in steps of 200keV. The angular analysis region was continuous from 50°to 90°in the center of mass system. An angular coherent width, at least 4n° was obtained. This long-range angular correlation could not be interpreted in the framework of the standard statistical reaction theory with state of equilibrium or near equilibrium, maybe it reveals the formation of a new kind of dissipative structure in the reaction of 27Al+27AI with the state that is far from equilibrium.展开更多
A hierarchically correlated equilibrium Q-learning(HCEQ)algorithm for reactive power optimization that considers carbon emission on the grid-side as an optimization objective,is proposed here.Based on the multi-area d...A hierarchically correlated equilibrium Q-learning(HCEQ)algorithm for reactive power optimization that considers carbon emission on the grid-side as an optimization objective,is proposed here.Based on the multi-area decentralized collaborative framework,the controllable variables in each region are divided into several optimization layers,which is an effective method for solving the limitations posed by dimensionality.The HCEQ provides constant information on the interaction between the state-action value function matrices,as well as on the cooperative game equilibrium among agents in each region.After acquiring the optimal value function matrix in the pre-learning process,HCEQ is able to quickly achieve an optimal solution online.Simulation of the IEEE 57-bus system is performed,which demonstrates that the proposed algorithm can effectively solve multi-area decentralized collaborative reactive power optimization,with the desired global search capabilities and convergence speed.展开更多
文摘The liquidliquid equilibrium data for two ternary systems, ethanolwaterKF and ethanol waterK2CO3, were determined at 25oC. Experiments show that by adding KF or K2CO3 into the ethanolwater system two phases are formed: an ethanol-rich phase with negligible salt and a water-rich phase with negligible ethanol, thus water can be separated out easily. A mathematical calculation of the liquidliquid equilibrium data was carried out with the Pitzer theory on water activity in the aqueous phase, and with the Wilson or NRTL or UNIQUAC equations for that in the ethanol phase, which is in good agreement with experimental data.
基金financial support from the National Key Research and Development Program of China(2020YFA0710202)the National Natural Science Foundation of China(21978043,U1662130)+1 种基金Inner Mongolia University of Technology Scientific Research Initial Funding(DC2300001240)Talent Introduction Support Project of Inner Mongolia(DC2300001426).
文摘As a common precursor for supercritical CO_(2)(scCO_(2))deposition techniques,solubility data of organometallic complexes in scCO_(2)is crucial for the preparation of nanocomposites.Recently,metal acetylacetonates have shown great potential for the preparation of single-atom catalytic materials.In this study,the solubilities of iron(Ⅲ)acetylacetonate(Fe(acac)3)and nickel(Ⅱ)acetylacetonate(Ni(acac)2)were measured at the temperature from 313.15 to 333.15 K and in the pressure range of 9.5–25.2 MPa to accumulate new solubility data.Solubility was measured using a static weight loss method.The semi-empirical models proposed by Chrastil and Sung et al.were used to correlate the solubility data of Fe(acac)3 and Ni(acac)2.The equations obtained can be used to predict the solubility of the same system in the experimental range.
文摘In an equilibrium vessel,the solid-liquid equilibria(SLE) for three binary mixtures of phenyl salicylate with 1-butanol,2-butanol,and 2-methyl-1-propanol,respectively,have been measured from 283.15 K to the melting temperature of the solute using a method in which an excess amount of solute was equilibrated with the alcohol solution.The liquid concentrations of the investigated phenyl salicylate in the saturated solution were analyzed by UV spectrometry.Activity coefficients for phenyl salicylate have been calculated by means of the Wilson,NRTL,and UNIQUAC equations and with them were correlated solubility data that were compared with the experimental ones.The best correlation of the solubility data has been obtained by the Wilson equation by which the average root-mean-square deviation of temperature for the three systems is 1.03 K.
基金Supported by the Major State Basic Research Development Program of China （2012CB720500）, the National Natural Science Foundation of China （U1162202, 61174118） and the Shanghai Leading Academic Discipline Project （B504）.
文摘The vapor-liquid equilibrium data of four binary systems (acetic acid +p-xylene, methyl acetate +n-propyl acetate, n-propyl acetate +p-xylene and methyl acetate +p-xylene) are measured at 101.33 kPa with Ellis equilibrium still, and then both the NRTL and UNIQUAC models are used in combination with the HOC model for correlating and estimating the vapor-liquid equilibrium of these four binary systems. The estimated binary VLE results using correlated parameters agree well with the measured data except the methyl acetate +p-xylene system which easily causes bumping and liquid rushing out of the sampling tap due to their dramatically different boiling points. The correlation results by NRTL and UNIQUAC models have little difference on the average absolute deviations of temperature and composition of vapor phase, and the results by NRTL model are slightly better than those by UNIQUAC model except for the methyl acetate +n-propyl acetate system, for which the latter gives more accurate correlations.
文摘A model of continuous-time insider trading in which a risk-neutral in-sider possesses two imperfect correlated signals of a risky asset is studied.By conditional expectation theory and filtering theory,we first establish three lemmas:normal corre-lation,equivalent pricing and equivalent profit,which can guarantee to turn our model into a model with insider knowing full information.Then we investigate the impact of the two correlated signals on the market equilibrium consisting of optimal insider trading strategy and semi-strong pricing rule.It shows that in the equilibrium,(1)the market depth is constant over time;(2)if the two noisy signals are not linerly correlated,then all private information of the insider is incorporated into prices in the end while the whole information on the asset value can not incorporated into prices in the end;(3)if the two noisy signals are linear correlated such that the insider can infer the whole information of the asset value,then our model turns into a model with insider knowing full information;(4)if the two noisy signals are the same then the total ex ant profit of the insider is increasing with the noise decreasing,while down to O as the noise going up to infinity;(5)if the two noisy signals are not linear correlated then with one noisy signal fixed,the total ex ante profit of the insider is single-peaked with a unique minimum with respect to the other noisy signal value,and furthermore as the noisy value going to O it gets its maximum,the profit in the case that the real value is observed.
基金the National Natural Science Foundation of China (No.19775057), the Chinese Academyof Sciences (KJ95T-03) and the Laboratoric
文摘Angular correlation of excitation functions in dissipative heavy ion collision 27Al+27Al has been measured. The incident beam energies ranged from 114MeV to 127MeV in steps of 200keV. The angular analysis region was continuous from 50°to 90°in the center of mass system. An angular coherent width, at least 4n° was obtained. This long-range angular correlation could not be interpreted in the framework of the standard statistical reaction theory with state of equilibrium or near equilibrium, maybe it reveals the formation of a new kind of dissipative structure in the reaction of 27Al+27AI with the state that is far from equilibrium.
基金supported in part by National Key Basic Research Program of China(973 Program:2013CB228205)National Natural Science Foundation of China(51177051,51477055).
文摘A hierarchically correlated equilibrium Q-learning(HCEQ)algorithm for reactive power optimization that considers carbon emission on the grid-side as an optimization objective,is proposed here.Based on the multi-area decentralized collaborative framework,the controllable variables in each region are divided into several optimization layers,which is an effective method for solving the limitations posed by dimensionality.The HCEQ provides constant information on the interaction between the state-action value function matrices,as well as on the cooperative game equilibrium among agents in each region.After acquiring the optimal value function matrix in the pre-learning process,HCEQ is able to quickly achieve an optimal solution online.Simulation of the IEEE 57-bus system is performed,which demonstrates that the proposed algorithm can effectively solve multi-area decentralized collaborative reactive power optimization,with the desired global search capabilities and convergence speed.
