A novel flower-like hydrated magnesium carbonate hydroxide, Mg5 （CO3 ）4 （OH）2·4H2O, with micro-structure composed of individual thin nano-sheets was synthesized using a facile solution route without the use o...A novel flower-like hydrated magnesium carbonate hydroxide, Mg5 （CO3 ）4 （OH）2·4H2O, with micro-structure composed of individual thin nano-sheets was synthesized using a facile solution route without the use of template or organic surfactant. Reaction time has an important effect on the final morphology of the product. The micro-structure and morphology of Mg5 （CO3）4 （OH）2·4H2O were characterized by means of X-ray diffractometry （XRD）, fieldemission scanning electron microscopy（FE-SEM）. Brunauer-Emmett-Teller（BET） surface areas of the samples were also measured. The probable formation mechanism of flower-like micro-structure was discussed. It was found that Mg5 （CO3）4（ OH）2·4H2O with flower-like micro-structure was a novel and efficient catalyst for the synthesis of diphenyl carbonate （DPC） by transesterification of dimethyl carbonate （DMC） with phenol.展开更多
In this paper, a two dimensional Voronoi cell element, formulated with creep, thermal and plastic strain, is applied for the numerical simulation of thermo-mechanical fatigue behavior for particulate reinforced compos...In this paper, a two dimensional Voronoi cell element, formulated with creep, thermal and plastic strain, is applied for the numerical simulation of thermo-mechanical fatigue behavior for particulate reinforced composites. The relation between mechanical fatigue phases and thermal fatigue phases influences the thermo-mechanical fatigue behavior and cyclic creep damage. The topological features of micro-structure in particulate reinforced composites, such as the orientation, depth-width ratio, distribution and volume fraction of inclusions, have a great influence on thermo-mechanical behavior. Some related conclusions are obtained by examples of numerical simulation.展开更多
Electrical property of a micro-plasma spray system with different working-gas feed- ing schemes was tested to optimize the plasma spray process. The arc voltage with an integrated gas injection mode is higher than tha...Electrical property of a micro-plasma spray system with different working-gas feed- ing schemes was tested to optimize the plasma spray process. The arc voltage with an integrated gas injection mode is higher than that with radial injection or axial injection modes. Thus, an integrated gas injection mode with an excellent electrical characteristic was adopted to deposit alumina-titania coating. The microstructure, bonding strength and hardness of the plasma sprayed alumina-titania coating, as a function of the spraying parameters, e.g., plasma current, gas flow rate and gas pressure, were studied. It was shown that the spraying parameters affected remarkably on the microstructure of the coating. Different tendencies in bonding strength and hardness were also shown for different spraying parameters. At an arc current of 250 A, a gas flow rate of 20 L/min and a gas pressure of 0.5 MPa, the bonding strength and micro-hardness of the coatings reach 40.6 MPa and HV1406.1, respectively.展开更多
In this study,we develop and empirically test a valuation model for a commonly encountered option in office leases:a tenant’s option to renew at future market rent(a fair market value)with lease termination as the ma...In this study,we develop and empirically test a valuation model for a commonly encountered option in office leases:a tenant’s option to renew at future market rent(a fair market value)with lease termination as the maturity date.The model integrates decision analysis with real options analysis and market risk with private risks.“Option value”is defined as the private value of the option to either party pre-contract,while“option price”assumes a fair agreement between transacting parties and can be positive(rental premium paid)or negative(rental discount offered).Without manifest expectations,an analysis of a sample of office leases supports the model’s logic with price estimates in a practical range.The tenants’option price/value is shown to have a negative relationship with the original/renewal lease term;conversely,the landlords’option value is positively related to the original/renewal term.Comparative analyses show that transaction costs have a positive effect on tenants’option value and on prices,while vacancy costs and the vacancy period are both positively related to the landlords’option value and negatively related to price.Market rent is found to have a negative relationship with option price.Overall,this study provides a theoretical analysis and empirical tests of the value of a real option that allows option holders to renew/extend their contracts at a fair market value.展开更多
基金Supported by the National Natural Science Foundation of China(Nos.20671011,20331010,90406002and90406024)the 111 Project(No.B07012)the Key Laboratory of Structural Chemistry Foundation(No.060017).
文摘A novel flower-like hydrated magnesium carbonate hydroxide, Mg5 （CO3 ）4 （OH）2·4H2O, with micro-structure composed of individual thin nano-sheets was synthesized using a facile solution route without the use of template or organic surfactant. Reaction time has an important effect on the final morphology of the product. The micro-structure and morphology of Mg5 （CO3）4 （OH）2·4H2O were characterized by means of X-ray diffractometry （XRD）, fieldemission scanning electron microscopy（FE-SEM）. Brunauer-Emmett-Teller（BET） surface areas of the samples were also measured. The probable formation mechanism of flower-like micro-structure was discussed. It was found that Mg5 （CO3）4（ OH）2·4H2O with flower-like micro-structure was a novel and efficient catalyst for the synthesis of diphenyl carbonate （DPC） by transesterification of dimethyl carbonate （DMC） with phenol.
基金The project supported by the Special Funds for the National Major Fundamental Research Projects(2004CB619304)the National Natural Science Foundation of China(10276020 and 50371042)the Key Grant Project of Chinese Ministry of Education(0306)
文摘In this paper, a two dimensional Voronoi cell element, formulated with creep, thermal and plastic strain, is applied for the numerical simulation of thermo-mechanical fatigue behavior for particulate reinforced composites. The relation between mechanical fatigue phases and thermal fatigue phases influences the thermo-mechanical fatigue behavior and cyclic creep damage. The topological features of micro-structure in particulate reinforced composites, such as the orientation, depth-width ratio, distribution and volume fraction of inclusions, have a great influence on thermo-mechanical behavior. Some related conclusions are obtained by examples of numerical simulation.
文摘Electrical property of a micro-plasma spray system with different working-gas feed- ing schemes was tested to optimize the plasma spray process. The arc voltage with an integrated gas injection mode is higher than that with radial injection or axial injection modes. Thus, an integrated gas injection mode with an excellent electrical characteristic was adopted to deposit alumina-titania coating. The microstructure, bonding strength and hardness of the plasma sprayed alumina-titania coating, as a function of the spraying parameters, e.g., plasma current, gas flow rate and gas pressure, were studied. It was shown that the spraying parameters affected remarkably on the microstructure of the coating. Different tendencies in bonding strength and hardness were also shown for different spraying parameters. At an arc current of 250 A, a gas flow rate of 20 L/min and a gas pressure of 0.5 MPa, the bonding strength and micro-hardness of the coatings reach 40.6 MPa and HV1406.1, respectively.
基金research grants(P0030199 and P0038209)from the Hong Kong Polytechnic University。
文摘In this study,we develop and empirically test a valuation model for a commonly encountered option in office leases:a tenant’s option to renew at future market rent(a fair market value)with lease termination as the maturity date.The model integrates decision analysis with real options analysis and market risk with private risks.“Option value”is defined as the private value of the option to either party pre-contract,while“option price”assumes a fair agreement between transacting parties and can be positive(rental premium paid)or negative(rental discount offered).Without manifest expectations,an analysis of a sample of office leases supports the model’s logic with price estimates in a practical range.The tenants’option price/value is shown to have a negative relationship with the original/renewal lease term;conversely,the landlords’option value is positively related to the original/renewal term.Comparative analyses show that transaction costs have a positive effect on tenants’option value and on prices,while vacancy costs and the vacancy period are both positively related to the landlords’option value and negatively related to price.Market rent is found to have a negative relationship with option price.Overall,this study provides a theoretical analysis and empirical tests of the value of a real option that allows option holders to renew/extend their contracts at a fair market value.
