An online method using continuous flow isotope ratio mass spectrometry （CF-IRMS） interfaced with a Gasbench Ⅱ was presented to determine chlorine stable isotope composition. Silver chloride （AgCl） was quantitativ...An online method using continuous flow isotope ratio mass spectrometry （CF-IRMS） interfaced with a Gasbench Ⅱ was presented to determine chlorine stable isotope composition. Silver chloride （AgCl） was quantitatively derived from chloride by using silver nitrate （AgNO3）, and then was reacted with iodomethane （CH3Ⅰ） to produce methyl chloride （CH3Cl）. A GasBench Ⅱ equipped with a PoraPlot Q column was used to separate CH3Cl from any other gas species. Finally, chlorine stable isotope analysis was carried out on CH3Cl introduced to the IRMS in a helium stream via an active open split. The minimum amount of Cl used in this method is of the order of 1.4 μmol. Inter-laboratory and inter-technique comparisons show that the total uncertainty incorporating both the precision and accuracy of this method is better than 0.007%. Furthermore, ten seawaters sampled from different locations have a narrow δ37Cl value range from -0.008% to 0.010%, with a mean value of （0.000±0.006）%. This supports the assumption that any seawater can be representative of standard mean ocean chloride （SMOC） and used as an international reference material.展开更多
The Euler-Euler numerical method was used to investigate the effects of contraction ratio on twophase flow mixing with mass transfer in the flow injection nozzle. The geometric shape of the nozzle was modified to impr...The Euler-Euler numerical method was used to investigate the effects of contraction ratio on twophase flow mixing with mass transfer in the flow injection nozzle. The geometric shape of the nozzle was modified to improve carbonation efficiency. A gas inlet hole was created to increase the flow mixing of CO2 with water. A nozzle throat was also introduced to increase the gas dissolution by increasing flow rates. Various contraction ratios of nozzle throat, inlet gas and liquid velocities, and gas bubble sizes were employed to determine their effects on gas hold-up, gas concentration, and mass transfer coefficient. Results revealed that the flow injection nozzle with high contraction ratios improved carbonation because of high gas hold-up. Gas concentration was directly related to contraction ratio and gas flow velocities. Carbonation reduced when high liquid velocities and large gas bubbles were employed because of inefficient flow mixing. This study indicated that flow injection nozzle with large contraction ratios were suitable for carbonation because of their ability to increase gas hold-up, gas concentration, and mass transfer coefficient.展开更多
以海洋温差能发电(Ocean Thermal Energy Conversion,OTEC)平台的冷水管为研究对象,根据结构方程和尾流振子方程建立冷水管流固耦合模型,采用有限元方法和Newmark-β法对冷水管涡激振动(Vortex-Induced Vibration,VIV)进行时域分析,并在...以海洋温差能发电(Ocean Thermal Energy Conversion,OTEC)平台的冷水管为研究对象,根据结构方程和尾流振子方程建立冷水管流固耦合模型,采用有限元方法和Newmark-β法对冷水管涡激振动(Vortex-Induced Vibration,VIV)进行时域分析,并在MATLAB软件中开发相应的求解程序。针对冷水管所面临的复杂工况,分别研究外部流场、内部流场、长径比和压载质量等因素对VIV产生的影响。结果表明:随着外流流速和长径比的增大,冷水管横流向VIV模态和振动幅值也发生相应改变,振动强度呈现波动上升;在不发生动态失稳的情况下,内流流速的增加可有效减小冷水管横流向振动幅值,压载质量可大幅减小冷水管自由端的振动位移。展开更多
基金Projects(40772156, 41072179) supported by the National Natural Science Foundation of China
文摘An online method using continuous flow isotope ratio mass spectrometry （CF-IRMS） interfaced with a Gasbench Ⅱ was presented to determine chlorine stable isotope composition. Silver chloride （AgCl） was quantitatively derived from chloride by using silver nitrate （AgNO3）, and then was reacted with iodomethane （CH3Ⅰ） to produce methyl chloride （CH3Cl）. A GasBench Ⅱ equipped with a PoraPlot Q column was used to separate CH3Cl from any other gas species. Finally, chlorine stable isotope analysis was carried out on CH3Cl introduced to the IRMS in a helium stream via an active open split. The minimum amount of Cl used in this method is of the order of 1.4 μmol. Inter-laboratory and inter-technique comparisons show that the total uncertainty incorporating both the precision and accuracy of this method is better than 0.007%. Furthermore, ten seawaters sampled from different locations have a narrow δ37Cl value range from -0.008% to 0.010%, with a mean value of （0.000±0.006）%. This supports the assumption that any seawater can be representative of standard mean ocean chloride （SMOC） and used as an international reference material.
文摘The Euler-Euler numerical method was used to investigate the effects of contraction ratio on twophase flow mixing with mass transfer in the flow injection nozzle. The geometric shape of the nozzle was modified to improve carbonation efficiency. A gas inlet hole was created to increase the flow mixing of CO2 with water. A nozzle throat was also introduced to increase the gas dissolution by increasing flow rates. Various contraction ratios of nozzle throat, inlet gas and liquid velocities, and gas bubble sizes were employed to determine their effects on gas hold-up, gas concentration, and mass transfer coefficient. Results revealed that the flow injection nozzle with high contraction ratios improved carbonation because of high gas hold-up. Gas concentration was directly related to contraction ratio and gas flow velocities. Carbonation reduced when high liquid velocities and large gas bubbles were employed because of inefficient flow mixing. This study indicated that flow injection nozzle with large contraction ratios were suitable for carbonation because of their ability to increase gas hold-up, gas concentration, and mass transfer coefficient.
文摘以海洋温差能发电(Ocean Thermal Energy Conversion,OTEC)平台的冷水管为研究对象,根据结构方程和尾流振子方程建立冷水管流固耦合模型,采用有限元方法和Newmark-β法对冷水管涡激振动(Vortex-Induced Vibration,VIV)进行时域分析,并在MATLAB软件中开发相应的求解程序。针对冷水管所面临的复杂工况,分别研究外部流场、内部流场、长径比和压载质量等因素对VIV产生的影响。结果表明:随着外流流速和长径比的增大,冷水管横流向VIV模态和振动幅值也发生相应改变,振动强度呈现波动上升;在不发生动态失稳的情况下,内流流速的增加可有效减小冷水管横流向振动幅值,压载质量可大幅减小冷水管自由端的振动位移。
