Simulation of anchor chain based on lumped mass method

In order to develop a anchoring operation simulation system and improve safety during anchoring operations,a relatively accurate mathematical model of anchoring operations needs to be established.In this paper,the stress condition of anchor chain under environmental and subsea geological conditions is further studied and the stress condition of anchor chain is analyzed based on the previous research.In this paper,a quasi-static model based on catenary method is used as the basis of dynamic analysis,and the dynamic model of anchor chain is established based on the concentrated mass method,which fully considers the influence of anchor chain weight,hydrodynamic force,ocean current and interaction with the seabed.The fourth-order Runge Kutta method was used to solve the model numerically,and a calculation procedure was developed.The accuracy of the model was verified by comparing the calculated results with the experimental results,indicating that the constructed anchor chain dynamics model has a high accuracy.

Urinary Creatinine-Skeletal Muscle Mass Method:A Prediction Equation Based on Computerized Axial Tomography

A classic body composition method is estimation of total body skeletal muscle mass (SM, kg) from 24 h urinary creatinine excretion (Cr, g). Two types of prediction equations were suggested: one assumes a constant SM/Cr ratio; and the other assumes a highly variable SM/Cr ratio. We explored these two extreme possibilities by measuring SM with whole-body computerized axial tomography and collecting Cr during meat-free dietary conditions in 12 healthy young men. Prediction equations were developed in the men that fit these two equation types, SM = 21.8×Cr (SD and CV of SM/Cr ratio, 1.3 kg and 6.0%,respectively) and SM = 18.9 × Cr + 4.1 (r = 0.92, p = 2.55 × 10-5, and SEE = 1.9 kg). The validity of each model is reviewed. This is the first investigation of Cr-SM method using modern techniques for quantifying total body SM mass

Mass scale screening of common arboviral infections by an affordable,cost effective RT-PCR method

Objective:To develop a rapid,cost effective RT-PCR method for the mass scale diagnosis of such diseases at the vireraia stage to find out the actual disease burden in that area.Methods:For this purpose,cases with the history of only short febrile illness were considered.Thus 157 samples with the history of dengue/chikungunya like illness and only 58 samples with a history of acute encephalitis syndrome(AES)were selected.Results:Out of 157 samples,42 and 74 were detected as dengue and chikungunya,respectively and out of 58 AES cases only 23 could be detected as Japanese encephalitis by this RT-PCR method.Conclusions:This cost effective RT-PCR method can detect the total positive cases that remain undetected by EL1SA method.Moreover,this method is capable to detect the viral RNA from patients'sera even after the appearance of IgM antibody at one fifth costs as compared with the other commercially available kits.

Distinct element modelling of fracture plan control in continuum and jointed rock mass in presplitting method of surface mining

Controlled blasting techniques are used to control overbreak and to aid in the stability of the remaining rock formation. Presplitting is one of the most common methods which is used in many open pit mining and surface blast design. The purpose of presplitting is to form a fracture plane across which the radial cracks from the production blast cannot travel. The purpose of this study is to investigate of effect of presplitting on the generation of a smooth wall in continuum and jointed rock mass. The 2D distinct element code was used to simulate the presplitting in a rock slope. The blast load history as a function of time was applied to the inner wall of each blasthole. Important parameters that were considered in the analysis were stress tensor and fracturing pattern. The blast loading magnitude and blasthole spacing and jointing pattern were found to be very significant in the final results.

An Explanation on the Electron Ionization Mass Spectra of Crown Ethers by MNDO Computational Method

he bond lengths and bond orders of four kinds of chemical bonds in crownethers(15) were calculated based on the model molecules using MNDO method.With the calculation results, some predictions to the EI mass spectral fragmenta-tion behaviour of crown ethers are suggested. The EI mass spectra of studied crownethers are in satisfactory agreenient with the predictions.

Source Apportionment of Ambient PM_(10) in the Urban Area of Longyan City,China:a Comparative Study Based on Chemical Mass Balance Model and Factor Analysis Method

In order to identify the day and night pollution sources of PM10 in ambient air in Longyan City,the authors analyzed the elemental composition of respirable particulate matters in the day and night ambient air samples and various pollution sources which were collected in January 2010 in Longyan with inductivity coupled plasma-mass spectrometry（ICP-MS）.Then chemical mass balance（CMB） model and factor analysis（FA） method were applied to comparatively study the inorganic components in the sources and receptor samples.The results of factor analysis show that the major sources were road dust,waste incineration and mixed sources which contained automobile exhaust,soil dust/secondary dust and coal dust during the daytime in Longyan City,China.There are two major sources of pollution which are soil dust and mixture sources of automobile exhaust and secondary dust during the night in Longyan.The results of CMB show that the major sources are secondary dust,automobile exhaust and road dust during the daytime in Longyan.The major sources are secondary dust,soil dust and automobile exhaust during the night in Longyan.The results of the two methods are similar to each other and the results will guide us to plan to control the PM10 pollution sources in Longyan.

An extended displacement discontinuity method for analysis of stress wave propagation in viscoelastic rock mass

An extended displacement discontinuity method (EDDM) is proposed to analyze the stress wave propagation in jointed viscoelastic rock mass (VRM).The discontinuities in a rock mass are divided into two groups.The primary group with an average geometrical size larger than or in the same order of magnitude of wavelength of a concerned stress wave is defined as 'macro-joints',while the secondary group with a high density and relatively small geometrical size compared to the wavelength is known as 'micro-defects'.The rock mass with micro-defects is modeled as an equivalent viscoelastic medium while the macro-joints in the rock mass are modeled explicitly as physical discontinuities.Viscoelastic properties of a micro-defected sedimentary rock are obtained by longitudinally impacting a cored long sedimentary rod with a pendulum.Wave propagation coefficient and dynamic viscoelastic modulus are measured.The EDDM is then successfully employed to analyze the wave propagation across macro-joint in VRM.The effect of the rock viscosity on the stress wave propagation is evaluated by comparing the results of VRM from the presented EDDM with those of an elastic rock mass (ERM) from the conventional displacement discontinuity method (CDDM).The CDDM is a special case of the EDDM under the condition that the rock viscosity is ignored.Comparison of the reflected and transmitted waves shows that the essential rock viscosity has a significant effect on stress wave attenuation.When a short propagation distance of a stress wave is considered,the results obtained from the CDDM approximate to the EDDM solutions,however,when the propagation distance is sufficiently long relative to the wavelength,the effect of rock viscosity on the stress wave propagation cannot be ignored.

Reinforcing a Dangerous Rock Mass Using the Flexible Network Method

Because the main failure type of a dangerous rock mass is collapse, the treatment of such a mass should focus on controlling collapse failure. When treating dangerous rock masses, disturbing the mass （e. g. by blasting） needs to be avoided, as this new damage could cause collapse. So the self-bearing capacity of the mountain mass must be used to treat the dangerous rock mass. This article is based on a practical example of the control of a dangerous rock mass at Banyan Mountain, Huangshi, Hubei Province. On the basis of an analysis of damage mechanism and the stability of the dangerous rock mass, a flexible network reinforcement method was designed to prevent the collapse of the rock mass. The deformations of section Ⅱ w of the dangerous rock mass before and after the flexible network reinforcement were calculated using the two-dimensional finite element method. The results show that the maximum deformation reduced by 55 % after the application of the flexible network reinforcement, from 45.99 to 20.75 ram, which demonstrates that the flexible network method is effective, and can provide some scientific basis for the treatment of dangerous rock masses.

A Study on Propagation Mechanism of Fracture Systems in Rock Masses by Discontinuity Displacement Method

The main task of fracture mechanics of rock masses is the study on the propagating mechanism of fractures in rock masses , which can be efficiently conducted by discontinuty displacement (DD) numerical evaluation . Firstly ,the element stress and displacement are analysed and the principle and steps of the numerical calculation of stress intensity factor and fracture extension force are introduced .The numerical results of parallel and echelon fracture systems ,which are compared with real field fractures .are presented. Finally . a simple engineering application example is presented .

A novel sample preparation method of matrix-assisted laser desorption/ionization time of flight mass spectrometry for polystyrene

A novel sample preparation method of matrix-assisted laser desorption/ionization mass spectrometry for polystyrene was reported. Compared to the conventional dried-droplet method, the efficiency of ionization and signal intensity of mass spectra were improved. The mechanism was also analyzed.

A mass-conserved multiphase lattice Boltzmann method based on high-order difference

The Z–S–C multiphase lattice Boltzmann model [Zheng, Shu, and Chew(ZSC), J. Comput. Phys. 218, 353(2006)]is favored due to its good stability, high efficiency, and large density ratio. However, in terms of mass conservation, this model is not satisfactory during the simulation computations. In this paper, a mass correction is introduced into the ZSC model to make up the mass leakage, while a high-order difference is used to calculate the gradient of the order parameter to improve the accuracy. To verify the improved model, several three-dimensional multiphase flow simulations are carried out,including a bubble in a stationary flow, the merging of two bubbles, and the bubble rising under buoyancy. The numerical simulations show that the results from the present model are in good agreement with those from previous experiments and simulations. The present model not only retains the good properties of the original ZSC model, but also achieves the mass conservation and higher accuracy.

Overhanging rock slope by design:An integrated approach using rock mass strength characterisation,large-scale numerical modelling and limit equilibrium methods

Overhanging rock slopes(steeper than 90°) are typically avoided in rock engineering design, particularly where the scale of the slope exceeds the scale of fracturing present in the rock mass. This paper highlights an integrated approach of designing overhanging rock slopes where the relative dimensions of the slope exceed the scale of fracturing and the rock mass failure needs to be considered rather than kinematic release of individual blocks. The key to the method is a simplified limit equilibrium(LE) tool that was used for the support design and analysis of a multi-faceted overhanging rock slope. The overhanging slopes required complex geometries with constantly changing orientations. The overhanging rock varied in height from 30 m to 66 m. Geomechanical modelling combined with discrete fracture network(DFN)representation of the rock mass was used to validate the rock mass strength assumptions and the failure mechanism assumed in the LE model. The advantage of the simplified LE method is that buttress and support design iterations(along with sensitivity analysis of design parameters) can be completed for various cross-sections along the proposed overhanging rock sections in an efficient manner, compared to the more time-intensive, sophisticated methods that were used for the initial validation. The method described presents the development of this design tool and assumptions made for a specific overhanging rock slope design. Other locations will have different geological conditions that can control the potential behaviour of rock slopes, however, the approach presented can be applied as a general guiding design principle for overhanging rock cut slope.

首批异替勃龙国家对照品的标定研究

目的制备并标定首批异替勃龙国家对照品,以有效控制替勃龙及其制剂产品质量。方法应用红外光谱、质谱、核磁共振谱对异替勃龙进行结构确证,采用反相高效液相色谱(HPLC)法测定待标品纯度,采用质量平衡法对待标品进行赋值,并对待标品的均一性和稳定性进行考察。结果异替勃龙待标品经标定,以C_(21)H_(28)O_(2)计,含量为99.6%;均一性考察符合要求,25℃±2℃、RH 75%±5%条件,40℃±2℃、RH 75%±5%条件,光照4500 lx±500 lx条件下放置10 d,纯度略有下降。结论本批待标品确认为异替勃龙,可作为第一批异替勃龙国家对照品,以供异替勃龙HPLC法鉴别和含量测定用,以C_(21)H_(28)O_(2)计,本批待标品含量为99.6%。

Calculation of Neutron-Proton Mass Difference by the Monte Carlo Method

Calculation results of the Monte Carlo method of the average energy of the electrostatic interaction between the quarks are presented to the neutron and proton. The proposed model of the distribution of quarks in protons and neutrons is possible to assess the area which included a strong (gluon) interaction. Given the fact that the probability of finding a quark in the field with strong interaction is less than one, there is a good agreement between the experimental and calculated values of the mass difference between the neutron and the proton.

高效液相色谱-串联四极杆质谱法测定人参组培不定根中11种皂苷成分

建立高效液相色谱-串联四极杆质谱(HPLC-MS/MS)法定量分析人参组培不定根中11种皂苷成分。样品经粉碎研磨,以70%甲醇水溶液为溶剂进行超声提取,离心过滤后测定。采用C_(18)色谱柱(100 mm×2.1 mm,1.8μm),用水和乙腈进行梯度洗脱,流量为0.3 mL/min,柱温为35℃。质谱采用电喷雾电离源,负离子扫描,多反应监测模式进行检测。11种皂苷的质量浓度在0.1~10μg/mL(Rb1为0.2~10μg/mL)范围内和响应强度线性相关,相关系数均大于0.995,各皂苷的定量限为0.001~0.010 g/kg,加标回收率为90.43%~97.82%,相对标准偏差为1.93%~6.33%(n=6)。该方法操作简单,分析时间短,灵敏度高,准确可靠,适用于人参组培不定根中多种皂苷类成分的同时测定。

高效液相色谱-串联质谱法检测牛组织和奶中咪多卡残留的研究

建立了一种检测牛组织和牛奶中咪多卡残留检测的高效液相色谱-串联质谱法。牛组织(肌肉、肝脏、肾脏、脂肪)和奶在NaAc缓冲体系中酶解,经HCl溶液提取,WCX固相萃取柱净化,以0.3%甲酸水溶液(含20 mM甲酸铵)和0.3%甲酸乙腈为流动相进行梯度洗脱,在HILIC色谱柱上分离,在电喷雾正离子(ESI^(+))模式下,用多反应监测(MRM)模式检测,同位素内标法定量。结果表明:咪多卡在2.5~1000 ng/mL的浓度范围内呈现良好线性关系,相关系数(R^(2))大于0.99;咪多卡在牛组织和奶中的检测限均为10μg/kg,定量限均为20μg/kg;咪多卡在牛组织和奶中20~4000μg/kg添加浓度水平上的回收率在70.9%~109%范围内;批内RSD在0.55%~9.59%之间,批间RSD在2.21%~12.1%之间。该方法具有灵敏度高、定量准确,重复性好等特点,可以满足牛组织和奶中咪多卡残留检测的要求。

风压平衡关系对高分辨率区域模式地面资料同化的影响分析

随着模式分辨率的提高,数值模式可分辨的短波信息增加,以地转平衡为基础的风压平衡约束关系不能完全满足低纬度地区及对流尺度高分辨率模式资料同化的需求。提出了基于多重网格方法构建1 km分辨率数值模式变分同化风压平衡约束关系的方案,基于CMA-MESO (China Meteorological Administration Mesoscale Model)三维变分(Three-Dimensional Variational Data Assimilation,简称3DVAR)和1 km分辨率中尺度区域模式开展了单点同化试验和典型个例分析。单点同化试验表明,气压和风的同化结果在没有平衡约束关系条件下比线性平衡约束下更接近观测。地面自动气象站观测资料同化试验表明新风压平衡约束关系将明显增加模式低层几十千米尺度的分析增量,其次是增加100—200 km尺度的分析增量。新风压平衡约束试验的同化分析增量相对于线性平衡约束的对照试验可以给出更多的增量中心位置,更好描述低层水汽辐合,对模式初始0—3 h降水、0—6 h地面10 m风和地面气压的模拟有改进。研究表明在大尺度风压平衡约束的基础上增加局地无风压平衡约束的订正,可以提高对流尺度天气系统地面短波信息的同化能力,改进高分辨率模式短时临近预报。

两地无花果微量元素及总放射性物质分析与质量评估

目的评估新疆阿图什与江苏南通两地无花果产品质量。方法运用电感耦合等离子体质谱仪和总放测量仪,分别对新疆阿图什和江苏南通两地无花果微量元素和总放射性物质进行分析检测。结果新疆阿图什无花果与江苏南通本地无花果微量元素相比,铝、钾、钙、钒、锰、钴、镍、铜、锌、硒、钡等11种微量元素含量明显较高,镁和钼元素略低,铬元素较低。两地无花果的总α放射性物质和总β放射性物质均合格。结论新疆阿图什无花果产品质量优于江苏南通本地的无花果,具有较高的产品开发价值。

建构共识:在精英结构分化的村庄落实“一肩挑”——基于“S村”的经验研究

村级组织负责人“一肩挑”制度对解决村庄“两委”矛盾,强化党组织在农村基层治理中的领导核心地位有重要意义。但是,在“两委”力量相互制衡、精英结构相对分化的村庄,“一肩挑”制度的推行并不顺利。2021年,A镇在所辖16个行政村推行“一肩挑”制度,其中15个村都顺利实现了村内组织“一肩挑”,唯独“S村”遭遇瓶颈。其主要原因是该村已形成比较稳定的村“两委”相互制衡的精英结构,仅靠村庄自治力量难以实现权力整合。在这种情况下,乡镇党委通过灵活运用党的工作方法分别在村庄精英内部以及村民内部建构共识,为强调权力整合的“一肩挑”制度创造条件。一方面,通过党内干部工作方法在原村干部内部打破隔阂,在村庄精英中凝聚候选人共识;另一方面,利用群众工作方法凝聚村庄民意,在村民中构建选举共识。在村庄自治力量存在分化的情况下,党的领导对整合村庄精英、建构村内共识起到了关键作用。

超高效液相色谱-串联质谱法同时测定当归9种真菌毒素

通过优化液相色谱条件和质谱条件等,建立超高效液相色谱-串联质谱法(UPLC-MS/MS)测定当归中药材中9种真菌毒素的检测方法。样品经70%甲醇溶液超声提取,经固相萃取柱净化;采用流动相A:2 mmol/L甲酸铵0.1%甲酸水溶液;流动相B:甲醇,经C18色谱柱分离后注入质谱仪,电喷雾电离源(ESI)和多反应监测模式(MRM)进行检测,基质外标法定量。经方法学验证,9种真菌毒素标准曲线线性关系良好(R^(2)>0.9950),方法的检出限0.04~1.43μg/kg,定量限0.12~4.75μg/kg,高、中、低3个浓度加标回收率为77.8%~113.6%,测定结果的相对标准偏差为0.2%~17.7%。该检测方法应用于72批当归样品9种真菌毒素同时检测,2批当归样品检出真菌毒素,检出率为2.8%,样品中主要的污染真菌毒素为黄曲霉毒素B_(1)(AFTB_(1))、黄曲霉毒素B2(AFTB_(2))、黄曲霉毒素G_(1)(AFTG_(1))。本研究建立的方法具有预处理简便、经济等优点,适用于当归样品9种真菌毒素的快速检测。