Research on shell-side heat and mass transfer with multi-component in LNG spiral-wound heat exchanger under sloshing conditions

The spiral-wound heat exchanger(SWHE) is the primary low-temperature heat exchanger for large-scale LNG plants due to its high-pressure resistance, compact structure, and high heat exchange efficiency. This paper studied the shell-side heat and mass transfer characteristics of vapor-liquid two-phase mixed refrigerants in an SWHE by combining a multi-component model in FLUENT software with a customized multicomponent mass transfer model. Besides, the mathematical model under the sloshing condition was obtained through mathematical derivation, and the corresponding UDF code was loaded into FLUENT as the momentum source term. The results under the sloshing conditions were compared with the relevant parameters under the steady-state condition. The shell-side heat and mass transfer characteristics of the SWHE were investigated by adjusting the component ratio and other working conditions. It was found that the sloshing conditions enhance the heat transfer performance and sometimes have insignificant effects. The sloshing condition is beneficial to reduce the flow resistance. The comprehensive performance of multi-component refrigerants has been improved and the improvement is more significant under sloshing conditions, considering both the heat transfer and pressure drop.These results will provide theoretical support for the research and design of multi-component heat and mass transfer enhancement of LNG SWHE under ocean sloshing conditions.

Effect of bipolar-plates design on corrosion,mass and heat transfer in proton-exchange membrane fuel cells and water electrolyzers:A review

Attaining a decarbonized and sustainable energy system,which is the core solution to global energy issues,is accessible through the development of hydrogen energy.Proton-exchange membrane water electrolyzers(PEMWEs)are promising devices for hydrogen production,given their high efficiency,rapid responsiveness,and compactness.Bipolar plates account for a relatively high percentage of the total cost and weight compared with other components of PEMWEs.Thus,optimization of their design may accelerate the promotion of PEMWEs.This paper reviews the advances in materials and flow-field design for bipolar plates.First,the working conditions of proton-exchange membrane fuel cells(PEMFCs)and PEMWEs are compared,including reaction direction,operating temperature,pressure,input/output,and potential.Then,the current research status of bipolar-plate substrates and surface coatings is summarized,and some typical channel-rib flow fields and porous flow fields are presented.Furthermore,the effects of materials on mass and heat transfer and the possibility of reducing corrosion by improving the flow field structure are explored.Finally,this review discusses the potential directions of the development of bipolar-plate design,including material fabrication,flow-field geometry optimization using threedimensional printing,and surface-coating composition optimization based on computational materials science.

Calculation of Mass Concrete Temperature and Creep Stress under the Influence of Local Air Heat Transfer

Temperature-induced cracking during the construction of mass concrete is a significant concern.Numerical simulations of concrete temperature have primarily assumed that the concrete is placed in an open environment.The problem of heat transfer between the air and concrete has been simplified to the concrete’s heat dissipation boundary.However,in the case of tubular concrete structures,where air inlet and outlet are relatively limited,the internal air temperature does not dissipate promptly to the external environment as it rises.To accurately simulate the temperature and creep stress in tubular concrete structures with enclosed air spaces during construction,we establish an air–concrete coupled heat transfer model according to the principles of conjugate heat transfer,and the accuracy of the model is verified through experiments.Furthermore,we conduct a case study to analyze the impact of airflow within the ship lock corridor on concrete temperature and creep stress.The results demonstrate that enhancing airflow within the corridor can significantly reduce the maximum concrete temperature.Compared with cases in which airflow within the corridor is neglected,the maximum concrete temperature and maximum tensile stress can be reduced by 12.5℃ and 0.7 MPa,respectively,under a wind speed of 4 m/s.The results of the traditional calculation method are relatively close to those obtained at a wind speed of 1 m/s.However,the temperature reduction process in the traditional method is faster,and the method yields greater tensile stress values for the corridor location.

Estimating Evapotranspiration Using Chloride Mass Balance in a New Mexico Paired Basin Study 2009-2019

A paired basin study in the upper Santa Fe River watershed following forest thinning and prescribed burns successfully measured water budget components in a treated and an untreated (control) basin. The paired basin study was established to investigate questions that have arisen regarding changes in water yield from forest treatments. Precipitation, stream flow, soil moisture, and chloride concentrations in precipitation and stream flow were measured to quantify the water budget components. The results from eleven years of data collection and analysis have a high degree of confidence with respect to measuring the water budget components based on the mass balance of water and chloride. The differences in the geologic structure and topography between the two paired basins appeared to impact the water budgets more than the forest treatments, except during periods when winter precipitation and snowmelt represented a significant component of inflow. Although this paired basin study was not able to portray a simple relationship between forest thinning and water yield, the chloride concentration methodology used to estimate evapotranspiration (ET) was successful. These detailed observations of chloride deposition and transport characteristics may be relevant for other researchers working in forested basins with substantial ET. ET rates were estimated by examining the cycle of chloride entering and exiting each basin over six integration periods. ET was estimated to be about 90% to 94% of precipitation in the treated basin and 77% to 86% in the control basin. The higher ET in the treated basin both before and after forest treatments may be due to the much greater area of west-facing hillslopes in the treated basin, which receive warm afternoon sun, and the greater area of rock cover in the control basin. Variation in the chloride concentration of collected precipitation samples from different sites indicates that horizontal precipitation of chloride in the tree canopy is an important consideration when using the chloride mass balance approach to calculate water budget components.

Analyzing geomorphological and topographical controls for the heterogeneous glacier mass balance in the Sikkim Himalayas

Glacier response patterns at the catchment scale are highly heterogeneous and defined by a complex interplay of various dynamics and surface factors.Previous studies have explained heterogeneous responses in qualitative ways but quantitative assessment is lacking yet where an intrazone homogeneous climate assumption can be valid.Hence,in the current study,the reason for heterogeneous mass balance has been explained in quantitative methods using a multiple linear regression model in the Sikkim Himalayan region.At first,the topographical parameters are selected from previously published studies,then the most significant topographical and geomorphological parameters are selected with backward stepwise subset selection methods.Finally,the contributions of selected parameters are calculated by least square methods.The results show that,the magnitude of mass balance lies between-0.003±0.24 to-1.029±0.24 m.w.e.a^(-1) between 2000 and 2020 in the Sikkim Himalaya region.Also,the study shows that,out of the terminus type of the glacier,glacier area,debris cover,ice-mixed debris,slope,aspect,mean elevation,and snout elevation of the glaciers,only the terminus type and mean elevation of the glacier are significantly altering the glacier mass balance in the Sikkim Himalayan region.Mathematically,the mass loss is approximately 0.40 m.w.e.a^(-1) higher in the lake-terminating glaciers compared to the land-terminating glaciers in the same elevation zone.On the other hand,a thousand meters mean elevation drop is associated with 0.179 m.w.e.a-1of mass loss despite the terminus type of the glaciers.In the current study,the model using the terminus type of the glaciers and the mean elevation of the glaciers explains 76% of fluctuation of mass balance in the Sikkim Himalayan region.

Coupled heat/mass-balance model for analyzing correlation between excess AlF_3 concentration and aluminum electrolyte temperature

The influence of aluminum electrolyte component on its temperature is an important issue within the field of aluminum reduction with pre-baked cells. The characteristic correlation between excess AlF3 concentration and aluminum electrolyte temperature was explored through the modeling of heat and mass transfer processes in industrial pre-baked aluminum reduction cells. A coupled heat/mass-balance model was derived theoretically from the mass and energy balance of an electrolysis cell, and then was simplified properly into a practical expression. The model demonstrates that if environmental temperature and Al2O3 concentration keep constant, the excess AlF3 concentration decreases with the aluminum electrolyte temperature linearly and its decrease rate is dependent on the heat transfer property of aluminum electrolyte, side wall and cell shell. Secondly, experiments were conducted on site with two industrial cells in an aluminum electrolysis plant. Excess AlF3 concentration and aluminum electrolyte temperature were obtained simultaneously together with other parameters such as Al2O3, CaF2, MgF2 and LiF concentrations. Results show that the maximum absolute error between the tested value and the calculated value of excess AlF3 concentration using the proposed model is less than 2%. This reveals that the coupled heat/mass-balance model can appropriately characterize the correlation between excess AlF3 concentration and aluminum electrolyte temperature with good accuracy and practicability.

The mass-balance characteristics and sensitivities to climate variables of Laohugou Glacier No.12,western Qilian Mountains,China

Due to global warming, glaciers on the Tibetan Plateau(TP) are experiencing widespread shrinkage; however, the mechanisms controlling glacier variations across the TP are still rather unclear, especially on the northeastern TP. In this study, a physically based, distributed surface-energy and mass-balance model was used to simulate glacier mass balance forced by meteorological data. The model was applied to Laohugou No. 12 Glacier, western Qilian Mountains, China, during2010~2012. The simulated albedo and mass balance were validated and calibrated by in situ measurements. The simulated annual glacier-wide mass balances were-385 mm water equivalent(w.e.) in 2010/2011 and-232 mm w.e. in 2011/2012,respectively. The mean equilibrium-line altitude(ELA) was 5,015 m a.s.l., during 2010~2012, which ascended by 215 m compared to that in the 1970 s. The mean accumulation area ratio(AAR) was 39% during the two years. Climatic-sensitivity experiments indicated that the change of glacier mass balance resulting from a 1.5 °C increase in air temperature could be offset by a 30% increase in annual precipitation. The glacier mass balance varied linearly with precipitation, at a rate of130 mm w.e. per 10% change in total precipitation.

Heat flow balance and control strategies for a large GSHP

The possibility of underground imbalance between heat emission and absorption has a negative impact on the performance of ground-source heat pump systems （GSHPs）. Numerical and experimental researches were made in a residential building, which is supplied with a GSHP system and a ceiling radiation system combined with a replacement fresh air system. EnergyPlus simulations were used to estimate heating and cooling loads, and to assess the heat generated from the water pump, the fan and the heat pump unit. Then, Fluent simulations were used to compare three different control strategies of handling the underground heat exchange. These simulations were strongly based on an experimentally verified model. It is obtained that a ratio between cooling and heating loads is 5.08 ： 1 in a case study in Nanjing. Moreover, the control strategy based on the starting time is more efficient and reliable than the temperature and temperature difference strategies to control the underground heat exchange.

Mass Balance Modeling for Electric Arc Furnace and Ladle Furnace System in Steelmaking Facility in Turkey

In the electric arc furnace （EAF） steel production processes, scrap steel is principally used as a raw material instead of iron ore. In the steelmaking process with EAF, scrap is first melted in the furnace and then the desired chemical composition of the steel can be obtained in a special furnace such as ladle furnace （LF）. This kind of furnace process is used for the secondary refining of alloy steel. LF furnace offers strong heating fluxes and enables precise temperature control, thereby allowing for the addition of desired amounts of various alloying elements. It also provides outstanding desulfurization at high-temperature treatment by reducing molten steel fluxes and removing deoxidation products. Elemental analysis with mass balance modeling is important to know the precise amount of required alloys for the LF input with respect to scrap composition. In present study, chemical reactions with mass conservation law in EAF and LF were modeled altogether as a whole system and chemical compositions of the final steel alloy output can be obtained precisely according to different scrap compositions, alloying elements ratios, and other input amounts. Besides, it was found that the mass efficiency for iron element in the system is 95.93%. These efficiencies are calculated for all input elements as 8. 45% for C, 30.31% for Si, 46.36% for Mn, 30.64% for P, 41.96% for S, and 69.79% for Cr, etc. These efficiencies provide valuable ideas about the amount of the input materials that are vanished or combusted for 100 kg of each of the input materials in the EAF and LF system.

FREEZE PROFILE AND HEAT BALANCE CALCULATION OF THE 160kA DRAINED CELL

A 2D full cell thermo-electric model of 160kA drained cell was set up using finiteelement code to calculate its freeze profile, then the drained cell model was modifiedaccording to the freeze profile computed and its heat balance was calculated. Comparedwith that of a 160kA conventional Hall-Heroult cell (H-H cell), though the melts vol-ume of the drained cell reduced greatly, the whole heat loss from it didn't drop downapparently, and an analysis was presented in the paper. On the other hand, the anode-cathode distance (ACD) of a drained cell was much less than that of a H-H cell, sothe voltage drop on it and heat produced decreased too, steps should be taken to keepa workable heat balance on a drained cell.

Effects of atmospheric circulation on summertime precipitation variability and glacier mass balance over the Tuyuksu Glacier in Tianshan Mountains, Kazakhstan

The amount and the form of precipitation have significant effects on glacier mass balances in high al- titude mountain areas by controlling the accumulation, the ablation and the energy balance of a glacier through impact on the surface albedo. The liquid precipitation has negative effects on glacier accumulation and may in- crease the ablation of surface ice through the heat input for melting. The timing and the forms of precipitation over glacierized regions depend on the weather processes both locally and regionally. Early studies showed that regional to large-scale atmospheric circulation processes play a key role in affecting the precipitation events over glaciers. This paper analyzed the relationship between the inter-annual variability of the summertime precipitation over the Tuyuksu Glacier and the atmospheric circulation types, which related to various atmospheric circulation types in the Northern Hemisphere. Results indicated that the decrease in the duration of zonal processes and the increase in the meridional northern processes were observed in the last decade. The total summer precipitation associated with these processes also increased along with an increase of summertime solid precipitation. Although the decadal fluctuation of glaciological parameters were found in dependent of the above large-scale atmospheric circulation processes, global warming was a dominant factor leading to the mass loss in the recent decades under the back- ground of the increase in precipitation over the Tuyuksu Glacier.

MASS BALANCE SENSITIVITY TO CLIMATE CHANGE: A CASE STUDY OF GLACIER NO. 1 AT URUMQI RIVERHEAD, TIANSHAN MOUNTAINS, CHINA

In this paper the degree day mass balance model is applied to the sensitivity test of mass balance/ELA(equilibrium line altitude) to climate change of Glacier No.1 at Urumqi Riverhead, the Tianshan Mountains, China. The results demonstrate that the mass balance of Glacier No.1, which is of continental type and accumulates in warm seasons, is less sensitive than that of a maritime glacier. On Glacier No.1, air temperature rise of 1℃ or precipitation increase by 20% can cause the ELA shift 81 m up or 31 m down respectively. Air temperature and precipitation play the different roles in the mass balance formation, in which the mass balance hypsometry follows the temperature variations by the means of rotation against the elevation axis and it shifts in parallel with precipitation change. Assuming a future temperature rise of 2 ℃ the mass losing trend on Glacier No.1 can not be radically alleviated even if there is a precipitation increase by 30%.

An investigation on changes in glacier mass balance and hypsometry for a small mountainous glacier in the northeastern Tibetan Plateau

Mass balance is a key indicator of the sensitivity of glaciers to climate change. Field measurement is one of the most important ways to study the mass balance of glaciers. Based on observations of mass balance in the ablation zone of Shuiguan Glacier No.4, Qilian Mountains, China, combined with the balance ratio between accumulation and ablation, we established a linear relation between mass balance and altitude. The results show that the mean annual mass balance of this glacier was ~510 mm w.e. from 2010 to 2013. The uncertainty in the balance ratio value does not lead to a significant difference in the mass balance. The equilibrium-line altitude rose by 180 m from 1972 to 2013, while the accumulation–area ratio decreased from 0.68 to 0.25. These variations may be caused by changes in air temperature. Meanwhile, the glacier is at present not in a steady state, and it may continue to shrink by a further ~900 m, even without further climate warming. In the western Lenglongling Mountains, assuming that the glaciers are in a steady state and the Equilibrium-line altitudes(ELAs)remain similar, there will be only 46 glaciers left, covering a total area of 19.2 km^2, in other words, only 22.3% of the glaciers area in 1972.

Numerical manifold method for thermo-mechanical coupling simulation of fractured rock mass

As a calculation method based on the Galerkin variation,the numerical manifold method(NMM)adopts a double covering system,which can easily deal with discontinuous deformation problems and has a high calculation accuracy.Aiming at the thermo-mechanical(TM)coupling problem of fractured rock masses,this study uses the NMM to simulate the processes of crack initiation and propagation in a rock mass under the influence of temperature field,deduces related system equations,and proposes a penalty function method to deal with boundary conditions.Numerical examples are employed to confirm the effectiveness and high accuracy of this method.By the thermal stress analysis of a thick-walled cylinder(TWC),the simulation of cracking in the TWC under heating and cooling conditions,and the simulation of thermal cracking of the SwedishÄspöPillar Stability Experiment(APSE)rock column,the thermal stress,and TM coupling are obtained.The numerical simulation results are in good agreement with the test data and other numerical results,thus verifying the effectiveness of the NMM in dealing with thermal stress and crack propagation problems of fractured rock masses.

The processes and characteristics of mass balance on the Urumqi Glacier No. 1 during 1958-2009

As a solid reservoir, a glacier can regulate regional water resources. The annual net mass balance directly reflects the fluctuation of the glacier and climate variability. Based on 51 years of mass balance observation data, the mass balance of Tianshan Mountains Urumqi Glacier No. 1 experienced a nine times positive balance fluctuation and nine times negative balance fluctuation. There were 35 and 16 negative and positive balance years, respectively. From 1996/97 to 2008/09, 12 consecutive negative balance years were observed at Tianshan Mountains Urumqi Glacier No. 1. These results demon- strate that the Urumqi Glacier No. 1 is experiencing a strong negative balance, and the strongest negative balance, -931 mm w.e. （mm water equivalent）, during the observation period occurred in 2008. In addition, the cumulative mass balance reached 13,709 mm w.e. in 2008. However, in 2009, the mass balance was positive at 63 mm w.e. The equilibrium-line al- titude changes with the fluctuation in the mass balance, and the effective mass balance gradient is 7.4 mrn/m. In this paper, the headwaters of the Urumqi River were analyzed using meteorological data from 1958 to 2009, including the average seasonal temperature and precipitation. The results showed that the main factor associated with the mass balance variation of Glacier No. 1 is the fluctuation in the summer air temperature, followed by changes in the precipitation.

A Comprehensive Review of the Influence of Heat Exchange Tubes on Hydrodynamic,Heat,and Mass Transfer in Bubble and Slurry Bubble

Bubble and slurry bubble column reactors(BCRs/SBCRs)are used for various chemical,biochemical,and petro-chemical applications.They have several operational and maintenance advantages,including excellent heat and mass transfer rates,simplicity,and low operating and maintenance cost.Typically,a catalyst is present in addition to biochemical processes where microorganisms are used to produce industrially valuable bio-products.Since most applications involve complicated gas-liquid,gas-liquid-solid,and exothermic processes,the BCR/SBCR must be equipped with heat-exchanging tubes to dissipate heat and control the reactor’s overall performance.In this review,past and very recent experimental and numerical investigations on such systems are critically dis-cussed.Furthermore,gaps to befilled and critical aspects still requiring investigation are identified.

Glacier mass balance in High Mountain Asia inferred from a GRACE release-6 gravity solution for the period 2002–2016

We provide estimates of glacier mass changes in the High Mountain Asia (HMA) area from April2002 to August 2016 by employing a new version of gravity solutions of the Gravity Recovery and ClimateExperiment (GRACE) twin-satellite mission. We find a total mass loss trend of the HMA glaciers at a rateof –22.17 (±1.96) Gt/a. The largest mass loss rates of –7.02 (±0.94) and –6.73 (±0.78) Gt/a are found forthe glaciers in Nyainqentanglha Mountains and Eastern Himalayas, respectively. Although most glaciers inthe HMA area show a mass loss, we find a small glacier mass gain of 1.19 (±0.55) and 0.77 (±0.37) Gt/a inKarakoram Mountains and Western Kunlun Mountains, respectively. There is also a nearly zero massbalance in Pamirs. Our estimates of glacier mass change trends confirm previous results from the analysisof altimetry data of the ICESat (ICE, Cloud and Land Elevation Satellite) and ASTER (AdvancedSpaceborne Thermal Emission and Reflection Radiometer) DEM (Digital Elevation Model) satellites inmost of the selected glacier areas. However, they largely differ to previous GRACE-based studies which weattribute to our different post-processing techniques of the newer GRACE data. In addition, we explicitlyshow regional mass change features for both the interannual glacier mass changes and the 14-a averagedseasonal glacier mass changes. These changes can be explained in parts by total net precipitation (netsnowfall and net rainfall) and net snowfall, but mostly by total net radiation energy when compared to datafrom the ERA5-Land meteorological reanalysis. Moreover, nearly all the non-trend interannual masschanges and most seasonal mass changes can be explained by the total net radiation energy data. The massloss trends could be partly related to a heat effect due to increased net rainfall in Tianshan Mountains, QilianMountains, Nyainqentanglha Mountains and Eastern Himalayas. Our new results for the glacier mass changein this study could help improve the understanding of glacier variation in the HMA area and contribute tothe study of global change. They could also serve the utilization of water resources there and in neighboringareas.

Heat balance of solar-soil source heat pump compound system

Based on the state-of-the-art studies of solar-soil source heat pump compound system, operation patterns of solar-soil compound system were analyzed, particularly the advantages of parallel operation pattern. It is found that parallel operation pattern is better for solar-soil compound system. Furthermore, the heat balance issue of solar-soil compound system was emphatically analyzed from four aspects, which were annual analysis of heating and cooling load, the heat exchange of ground heat exchanger, capacity determination of solar-assisted heat sottrce and heat balance calculation of solar-soil compound system. Moreover, annual rate of heat balance in a solar-soil source heat pump compound system was calculated with a case study. It is shown that the annual heat unbalance ratio is 19%, which is less than 20%. As a result, the practical solar-soil compound system can basically maintain the heat balance of soil.

Observation and modelling of snow and sea ice mass balance and its sensitivity to atmospheric forcing during spring and summer 2007 in the Central Arctic

Snow depth and sea ice thickness were observed applying an ice mass balance buoy(IMB)in the drifting ice station Tara during the International Polar Year in 2007.Detailed in situ observations on meteorological variables and surface fluxes were taken during May to August.For this study,the operational analyses and short-term forecasts from two numerical weather prediction(NWP)models(ECMWF and HIRLAM)were extracted for the Tara drift trajectory.We compared the IMB,meteorological and surface flux observations against the NWP products,also applying a one-dimensional thermodynamic sea ice model(HIGHTSI)to calculate the snow and ice mass balance and its sensitivity to atmospheric forcing.The modelled snow depth time series,controlled by NWP-based precipitation,was in line with the observed one.HIGHTSI reproduced well the snowmelt onset,the progress of the melt,and the first date of snow-free conditions.HIGHTSI performed well also in the late August freezing season.Challenges remain to model the“false bottom”observed during the melting season.The evolution of the vertical temperature profiles in snow and ice was better simulated when the model was forced by in situ observations instead of NWP results.During the melting period,the nonlinear ice temperature profile was successfully modelled with both forcing options.During spring and the melting season,total sea ice mass balance was most sensitive to uncertainties in NWP results for the downward longwave radiation,followed by the downward shortwave radiation,air temperature,and wind speed.

Rapid authentication of different herbal medicines by heating online extraction electrospray ionization mass spectrometry

The rapid and accurate authentication of traditional Chinese medicines(TCMs)has always been a key scientific and technical problem in the field of pharmaceutical analysis.Herein,a novel heating online extraction electrospray ionization mass spectrometry(H-oEESI-MS)was developed for the rapid and direct analysis of extremely complex substances without the requirement for any sample pretreatment or pre-separation steps.The overall molecular profile and fragment structure features of various herbal medicines could be completely captured within 10–15 s,with minimal sample(<0.5 mg)and solvent consumption(<20μL for one sample).Furthermore,a rapid differentiation and authentication strategy for TCMs based on H-oEESI-MS was proposed,including metabolic profile characterization,characteristic marker screening and identification,and multivariate statistical analysis model validation.In an analysis of 52 batches of seven types of Aconitum medicinal materials,20 and 21 key compounds were screened out as the characteristic markers of raw and processed Aconitum herbal medicines,respectively,and the possible structures of all the characteristic markers were comprehensively identified based on Compound Discoverer databases.Finally,multivariate statistical analysis showed that all the different types of herbal medicines were well differentiated and identified(R^(2)X>0.87,R^(2)Y>0.91,and Q^(2)>0.72),which further verified the feasibility and reliability of this comprehensive strategy for the rapid authentication of different TCMs based on H-oEESI-MS.In summary,this rapid authentication strategy realized the ultra-high-throughput,low-cost,and standardized detection of various complex TCMs for the first time,thereby demonstrating wide applicability and value for the development of quality standards for TCMs.