Corrosion behavior of 2A97 Al-Cu-Li alloys in different thermomechanical conditions by quasi-in-situ analysis

As a promising material in the aircraft industry,2A97 Al-Cu-Li alloy exhibits high corrosion susceptibility that may limit its application.In the present work,to illustrate the influences of precipitate and grain-stored energy on localized corrosion evolution in 2A97 Al-Cu-Li alloy,cold working and artificial aging were carried out to produce 2A97 Al-Cu-Li alloys under different thermomechanical conditions.Quasi-in-situ analysis,traditional immersion test and electrochemical measurement were then conducted to examine the corrosion behavior of 2A97 alloys.It is revealed that precipitate significantly affects Cu enrichment at corrosion fronts,which determines corrosion susceptibility of alloys,whereas grain-stored energy distribution is closely associated with localized corrosion propagation.It is also indicated that quasi-in-situ analysis exhibits a consistent corrosion evolution with traditional immersion tests,which is regarded as a proper method to explore localized corrosion mechanisms by providing local microstructural information with enhanced time and spatial resolutions.

Finite element analysis of temperature and stress fields during selective laser melting process of Al−Mg−Sc−Zr alloy

A 3D finite element model was established to investigate the temperature and stress fields during the selective laser melting process of Al−Mg−Sc−Zr alloy.By considering the powder−solid transformation,temperaturedependent thermal properties,latent heat of phase transformations and molten pool convection,the effects of laser power,point distance and hatch spacing on the temperature distribution,molten pool dimensions and residual stress distribution were investigated.Then,the effects of laser power,point distance and hatch spacing on the microstructure,density and hardness of the alloy were studied by the experimental method.The results show that the molten pool size gradually increases as the laser power increases and the point distance and hatch spacing decrease.The residual stress mainly concentrates in the middle of the first scanning track and the beginning and end of each scanning track.Experimental results demonstrate the accuracy of the model.The density of the samples tends to increase and then decrease with increasing laser power and decreasing point distance and hatch spacing.The optimum process parameters are laser power of 325−375 W,point distance of 80−100μm and hatch spacing of 80μm.

Weibull analysis of effect of T6 heat treatment on fracture strength of AM60B magnesium alloy

The effect of T6heat treatment on the fracture strength and reliability of AM60B alloy was studied.The tensile specimens were poured at three different temperatures of670,685and700?C for different holding times of5,10and15min.The fluidity test was also conducted to determine the fluidity length under different pouring temperatures and holding times.According to the results,the optimum pouring temperature and holding time were determined as685?C and10min,respectively.SEM fractography of the tensile specimens reveals that the entrained oxides and oxide-related porosities are the main factors responsible for the reduction of fracture strength under the non-optimal casting conditions.The Weibull statistical approach was used to quantify the scatter of fracture strength in as-cast and heat-treated conditions.For this purpose,T6schedule was applied to the specimens prepared under the optimal casting condition.It is found that,despite minor effect on the average fracture strength,T6heat treatment improves the reliability of castings,where the Weibull modulus is increased by75%.According to the microstructural and fractography observations,this improvement is related to the evolution of more uniform microstructure and the elimination of coarse brittleβ-particles in heat-treated samples.

Impact analysis of casting parts considering shrinkage cavity defect

Shrinkage cavity may be detrimental to mechanical performances of casting parts.As a consequence,design engineers often use overly large safety factors in many designs due to insufficient understanding of quantitative effects of shrinkage cavity defects.In this paper,process of Al alloy wheel impact test was computationally analyzed for both the wheel models with and without shrinkage cavity defects.Based on shrinkage cavity data obtained from industrial CT (Computerized Tomography),the shrinkage cavity defects were modeled with SSM (Shape Simplification Method),which reconstructs shrinkage cavity defects to hollow spheroid primitives.After the impact simulation was conducted,the results show that under impact test condition,the wheel considering shrinkage cavity defects may fracture while the sound-assumed wheel may not.

Finite element analysis of stress-strain localization and distribution in Al-4.5Cu-2Mg alloy

Finite element analysis has been carried out to understand the effect of various processing routes and condition on the microscale deformation behavior of Al–4.5 Cu–2 Mg alloy. The alloy has been developed through four different routes and condition, i.e. conventional gravity casting with and without refiner, rheocasting and SIMA process. The optical microstructures of the alloy have been used to develop representative volume elements（RVEs）. Two different boundary conditions have been employed to simulate the deformation behavior of the alloy under uniaxial loading. Finally, the simulated stress-strain behavior of the alloy is compared with the experimental result. It is found that the microstructural morphology has a significant impact on stress and strain distribution and load carrying capacity. The eutectic phase always carries a higher load than the α（Al） phase. The globular α（Al） grains with thinner and uniformly distributed eutectic network provide a better stress and strain distribution. Owing to this, SIMA processed alloy has better stress and strain distribution than other processes. Finally, the simulated yield strength of the alloy is verified by experiment and they have great agreement.

Precipitated phases and thermodynamic analysis during solidification of Al-Fe-X system at slow cooling rate

The solidification curves of Al 8.5Fe, Al 8.5Fe 1.7Fe, Al 8.5Fe 1.7Si 1.3V alloys were examined by DTA under the condition of slow cooling rate, the phase constitutes were examined by OM and XRD. The results show that, under slow cooling rate, the phases in Al 8.5Fe alloy are mainly α (Al) and Al 13 Fe 4, the phases in Al 8.5Fe 1.7Si alloy are mostly α (Al), Al 13 Fe 4, α AlFeSi, β AlFeSi, and comparing to Al 8.5Fe 1.7Si alloy, no other phases form in the Al 8.5Fe 1.3V 1.7Si alloy, but the chemical compositions of the phases are changed and the thermal stability of α AlFeSi phase and β AlFeSi phase is improved, due to the partial substitution of V for Fe atoms. The phase formation was calculated by Thermo calc software at equilibrium condition, the calculated results were agreement with the experimental results.

Species distribution of polymeric aluminium ferrum——timed complexation colorimetric analysis method of Al-Fe-Ferron

The effects of the calorimetric buffer solutions were investigated while the two colorimetric reactions of AI-ferron complex and Fe-ferron complex occurred individually, and the effects of the testing wavelength and the pH of the solutions were also investigated. A timed complexatian colorimetric analysis method of Al-Fe-ferron in view of the total concentration of {AI + Fe} was then established to determine the species distribution of polymeric Al-Fe. The testing wavelength was recommended at 362 net and the testing pH value was 5. With a comparison of the ratios of n(Al)/n(Fe), the standard adsorption curves of the polymeric Al-Fe solutions were derived from the experimental results. Furthermore, the solutions' composition were carious in both the molar n(Al)/n(Fe) ratios, i.e. 0/0, 5/5, 9/1 and 0/10, and the concentrations associated with the total ( Al + Fe which ranged from 10(-5) to 10(-4) mol/L..

Parametric analysis of warm forming of aluminum blanks with FEA and DOE

The effect of temperature distribution on warm forming performance was investigated for 5083-O (Al-Mg) sheet metal blanks. Combined isothermal/non-isothermal FEA with design of experiments tools were used to predict appropriate warm forming temperature conditions for deep drawing and two-dimensional stamping cases. In the investigated temperature range of 25?250 ℃, the formability of Al-5083 alloy is found to be greatly dependent on the temperature distribution of the die and punch. To achieve increased degrees of forming, different temperature levels should be assigned to the corner and body of the die and punch. And the optimal temperature distributions for warm deep drawing and warm two-dimensional stamping are not identical.

Experimental and Thermodynamic Analysis on Phase Equilibria of Ni-rich Region in Ni-Al-Ti System

Phase equilibria including γ,γ′,η,β and H in Ni Al Ti system were investigated by diffusion couple method and calculated with thermodynamic model.The experimental phase equilibria generally agree with ones reported till now.Regular solution and sublattice models were used in order to calculate these phase equilibria.The calculated results show agreement with experimental data.

Phase analysis of Al metal in complex deoxidizer

Complex deoxidizer is an important supplementary material for steelmaking,which can not only absorb liquid steel inclusions and improve the quality of molten steel,but also enhance deoxidation,desulfurization, dephosphorization,to prevent the molten steel suction and reduce the molten steel temperature loss.Currently,the complex deoxidizer all contain a certain amount of metal aluminium.The metal aluminium can not be determined for the steel.The entire aluminium contents were regarded as the content of approximate metal aluminium,that often bring great economic losses.Because A1,0,price is cheaper than metal aluminite powder,suppliers added a certain amount of Al_2O_3 in complex deoxidizer,pretend to be the metal aluminium to reap huge profits.This paper put forward a kind of method for determining aluminum,which would reduce loss of the enterprise.Research and put forward an iron triehloride,which extracted from Al metal from complex deoxidizer.Meantime,using orthogonal design of the experiment has been optimized for working conditions.The RSD of the samples are I. 07%-1.94%,the recoveries of the experiment results are 97.0%-110.0%,which expressed the precision and accuracy of the experiment are good.The establishment of the iron triehloride as a extractor,which is rapid and accurate for determination of Al metal in complex deoxidizer.

Thermodynamic Analysis of Thermal Decomposition of Al(OH)_3

Thermodynamic analysis of the main reactions in the process of thermal decomposition ofAl(OH)3 was made using Temkin-Schwarzman's method and by means of regression analysis.

Analysis of the Intrinsic Uncertainties in the Laser-Driven Iron Hugoniot Experiment Based on the Measurement of Velocities

One of the most challenging tasks in the laser-driven Hugoniot experiment is how to increase the reproducibility and precision of the experimental data to meet the stringent requirement in validating equation of state models. In such cases, the contribution of intrinsic uncertainty becomes important and cannot be ignored. A detailed analysis of the intrinsic uncertainty of the aluminum-iron impedance-match experiment based on the measurement of velocities is presented. The influence of mirror-reflection approximation on the shocked pressure of Fe and intrinsic uncertainties from the equation of state uncertainty of standard material are quantified, Furthermore, the comparison of intrinsic uncertainties of four different experimental approaches is presented. It is shown that, compared with other approaches including the most widely used approach which relies on the measurements of the shock velocities of AI and Fe, the approach which relies on the measurement of the particle velocity of Al and the shock velocity of Fe has the smallest intrinsic uncertainty, which would promote such work to significantly improve the diagnostics precision in such an approach.

A quasi-isentropic model of a cylinder driven by aluminized explosives based on characteristic line analysis

A quasi-isentropic study on the process of driving a cylinder with aluminized explosives was carried out to examine the influence of the aluminum(Al) reaction rate on cylinder expansion and the physical parameters of the detonation products. Based on the proposed quasi-isentropic hypothesis and relevant isentropic theories, the characteristic lines of aluminized explosives driving a cylinder were analyzed,and a quasi-isentropic model was established. This model includes the variation of the cylinder wall velocity and the physical parameters of the detonation products with the Al reaction degree. Using previously reported experimental results, the quasi-isentropic model was verified to be applicative and accurate. This model was used to calculate the physical parameters for cylinder experiments with aluminized cyclotrimethylenetrinitramine explosives with 15.0 % and 30.0 % Al content. The results show that this quasi-isentropic model can be used not only to calculate the cylinder expansion rule or Al reaction degree, but also to calculate the physical parameters of the detonation products in the process of cylinder expansion. For explosives with 15.0 % and 30.0 % Al, 24.3 % and 18.5 % of the Al was found to have reacted at 33.9 μs and 34.0 μs, respectively. The difference in Al content results in different reaction intensity, occurrence time, and duration of two forms of reaction(diffusion and kinetic) between the Al powder and the detonation products;the post-detonation burning reaction between the Al powder and the detonation products prolongs the positive pressure action time, resulting in a continuous rise in temperature after detonation.

A Seismic Facies Analysis to Determine the Relative Age and History of the Al Idrissi Mud Volcano from Offshore Larache Located in the NW Moroccan Atlantic Margin

Formed on top of the Gulf of Cadiz, the Al Idrissi mud volcano is the shallowest and largest mud volcano in the El Arraiche mud volcano field of the northwestern Moroccan margin. The development and morphology of mud volcanoes from the El Arraiche mud volcanoes group have been studied at a large scale. However, the time interval related to their formation period still needs to be better understood. In this regard, we interpreted and analyzed the seismic facies from the 2D reflection data of the GEOMARGEN-1 campaign, which took place in 2011. The aim was to identify the seismic sequences and draw the Al Idrissi mud volcano system to determine the formation period of the Al Idriss mud volcano. And as a result, the Al Idrissi mud volcano system is made of both buried and superficial bicone and was identified along with the Upper Tortonian to Messinian-Upper Pliocene facies. As the initial mud volcano extrusive edifice, the buried bicone was formed in the Late-Messinian to Early-Pliocene period. However, the superficial bicone, as the final extrusive edifice, was included in the Late Pliocene. In this case, the timing interval between the buried and superficial bicone is equivalent to the Late-Messinian to Upper-Pliocene period. Therefore, the latter corresponds to the Al Idrissi mud volcano formation period.

基于MCR-ALS-PLS对发酵液中葡萄糖的定量分析

葡萄糖浓度是生物发酵过程中的重要参数,精确控制葡萄糖浓度,可以优化发酵条件,提高生产效率和产品质量。然而大多数情况下,由于发酵液中物质复杂,导致葡萄糖的拉曼特征峰难以明确。针对这种情况下的葡萄糖定量分析,首先使用多元曲线分析-交替最小二乘(MCR-ALS)算法将葡萄糖拉曼光谱与发酵液基质光谱分离,然后采用竞争自适应重加权采样(CARS)算法进行降维和偏最小二乘2(PLS)算法进行浓度建模。结果表明使用这种方法建模的预测效果得到明显提高,测试集R由0.86026提升到了0.98031,均方根误差(RMSE)由0.00183降低到了0.00061。

ANALYSIS OF HOT IMPREGNATED Al-Si COATINGS

The microstructure and chemical composition of the hot impregnated Al-Si coating on 08Al steel sheet were analysed by SEM,EPMA and X-ray diffraction.The coating consists of three parts:the outer is an α-Al solid solution enriched Si and γ-(Fe,Al,Si)phases;the in- termediate FeAl_3 and Fe_2Al_5 phases mainly and the inner neighbouring the substrate mainly Fe_2Al_5 phase.

Thermodynamic analysis of the Ti-Al-N system

Motivated by the application of （Ti, Al）N alloy compound in the coating layer, the ternary phase diagram of Ti-Al-N was analyzed by the calculation of the phase diagram （CALPHAD） technique. The isothermal sections of the Ti-Al-N ternary system were constructed and compared with the literature experimental results. The thermodynamic parameters of the Ti-Al-N ternary system and the related Ti-N and Al-N binary systems were adopted from literatures, whereas, those of the Ti-Al binary from the literatures were adjusted according to both the ternary and the binary phase equilibria. The consistency between the calculated results and the experimental data shows that considering the ternary thermodynamic relationship, the adjustments to the thermodynamic parameters of the related binaries are necessary.

Modeling Landfill Suitability Based on GIS and Multicriteria Decision Analysis: Case Study in Al-Mahaweelqadaa

Waste management system is not regulated in Iraq. At present, there are various techniques used for solid waste management such as landfill, thermal treatment, biological treatment, recycling etc. Landfill is the most common mode for the disposal of solid waste. However, landfill site selection is a quite complex process and it depends on several criteria and regulations. In this study landfill site selection is performed for Al-Mahaweelqadaa using Multicriteria Decision Analysis (MCDA) and Geographic Information System (GIS). It should be mentioned however, that the existing landfill in this area, is temporary and does not fulfill the environmental conditions. To select suitable landfill site, several criteria were considered such as Urban centers, Land use, Airports, Pipes, Power lines, Railways, Roads, slope, streams, Surface water, Industrial areas, Oil pipes, Liquid gas pipes, Soil types which are prepared. (MCDA) was used to evaluate the relative importance of each criterion. Each map layers were formed with the aid of GIS and final suitability map was created by overlay analyses of each criterion map. According to obtained results, high and low suitable areas were determined in the study area. Field and office checks were performed out to determine the accuracy and suitability of the candidate sites.

New Trends in Corrosion Analysis of Al-Sn Alloy Duplex System

The corrosion characterization of binary Al – Sn alloy systems has been statistically analyzed in the light of developed model equations. It was observed that the modeled corrosion penetration rate values generated using the developed model equations are in tandem with the experimental values.

Thermodynamic analysis of Ti powder synthesized by SHS thermitreaction

According to the thermodynamics theories,the reactive Gibbs free energies,the reactive adiabatic temperature,the melting rate of Ti and the gasification mass of Mg in the Mg-TiO2 and Al-TiO2 systems were theoretically calculated and analyzed respectively. The results show that the reactions of Mg-TiO2 and Al-TiO2 are very easy to take place and the reaction of producing various suboxides of Ti may occur in Mg-TiO2 and Al-TiO2 reaction system;the adiabatic temperature of Mg-TiO2 becomes lower with increasing mass fraction of Mg. The adiabatic temperature is below 1 800 K when the mass fraction of excessive Mg exceeds 25%;The adiabatic temperature of Al-TiO2 also becomes lower with increasing mass fraction of Al,but it becomes higher with the preheat temperature increment. The adiabatic temperature plateau is the result of Ti melting endotherm;owing to the gasification of a great deal of Mg in Mg-TiO2 reaction process,Mg should be properly excessive in order to get Ti.