Effect of the graphitic degree of carbon supports on the catalytic performance of ammonia synthesis over Ba-Ru-K/HSGC catalyst

A series of high surface area graphitic carbon materials （HSGCs） were prepared by ball-milling method. Effect of the graphitic degree of HSGCs on the catalytic performance of Ba-Ru-K/HSGC-x （x is the ball-milling time in hour） catalysts was studied using ammonia synthesis as a probe reaction. The graphitic degree and pore structure of HSGC-x supports could be successfully tuned via the variation of ball-milling time. Ru nanoparticles of different Ba-Ru-K/HSGC-x catalysts are homogeneously distributed on the supports with the particle sizes ranging from 1.6 to 2.0 nm. The graphitic degree of the support is closely related to its facile electron transfer capability and so plays an important role in improving the intrinsic catalytic performance of Ba-Ru-K/HSGC-x catalyst.

Temporal variation of gravity field prior to the Ludian Ms6.5 and Kangding Ms6.3 earthquakes

Using mobile gravity data from the central area of Sichuan and Yunnan Provinces, the relationship between gravity variation and earthquakes was studied based on the Ludian Ms6.5 earthquake that occurred on August 3rd, 2014, and the Kangding Ms6.3 earthquake that occurred on November 22 nd, 2014; the mechanism of gravity variation was also explored. The results are as follows：（1） Prior to both earthquakes, gravity variation exhibited similar characteristics as those observed before both the Tangshan and Wenchuan earthquakes, in which typical precursor anomalies were positive gravity variation near the epicenter and the occurrence of a high-gravity-gradient zone across the epicenter prior to the earthquake.（2） A relatively accurate prediction of the occurrence locations of the two earthquakes was made by the Gravity Network Center of China（GNCC） based on these precursor anomalies. In the gravity study report on the 2014 earthquake trends submitted at the end of 2013, the Daofu-Shimian section at the junction of the Xianshuihe and Longmenshan fault zones was noted as an earthquake-risk region with a predicted magnitude of 6.5, which covered the epicenter of the Kangding Ms6.3 earthquake. In another report on earthquake trends in southwestern China submitted in mid-2014, the Lianfeng, Zhaotong fault zone was also classified as an earthquake-risk region with a magnitude of 6.0, and the central area of this region basically overlapped with the epicenter of the Ludian Ms6.5 earthquake.（3） The gravity variation characteristics are reasonably consistent with crustal movements, and deep material migration is likely the primary cause of gravity variation.