ZrO2 nanopowders based stearic acid phase change materials （PCMS） were prepareo oy mgn-energy milling. The concept of heat capacity factor （HCF） was used to analyze the thermal properties of the materials. The hea...ZrO2 nanopowders based stearic acid phase change materials （PCMS） were prepareo oy mgn-energy milling. The concept of heat capacity factor （HCF） was used to analyze the thermal properties of the materials. The heat storage property of PCMs, containing the same content of stearic acid （23~ by mass） in the starting materials but synthesized by different technical processes, was investigated by using HCE It was found that there were vast influences of different dispersants on the heat capacity. The samples orelaared with chloroform provided the best heat storage ability in all samples tested.展开更多
Low temperature calorimetry is an experimental method of heat capacity measurements, and heatcapacity is one of the most important and fundamental thermodynamic properties of substances. Theheat capacity can provide a...Low temperature calorimetry is an experimental method of heat capacity measurements, and heatcapacity is one of the most important and fundamental thermodynamic properties of substances. Theheat capacity can provide an average evaluation of the thermal property of a sample since it is a bull（property of substances. In the other hand, the condensed states of substances could be mainly controlledby the molecular motions, intermolecular interactions, and interplay among molecular structures. Thephysical property reflected in a material may be closely related to the energy changes in these threefactors, which can be directly observed in a heat capacity curve. Therefore, low temperature calorimetryhas been used not only to obtain heat capacity, entropy, enthalpy and Gibbs free energy, but also toinvestigate and understand lattice vibrations, metals, superconductivity, electronic and nuclearmagnetism, dilute magnetic systems and structural transitions. In this review, we have presented theconcept of low temperature calorimetry and its applications in the related field of material researches,such as nano-materials, magnetic materials, ferroelectric materials, phase change materials and othermaterials.展开更多
文摘ZrO2 nanopowders based stearic acid phase change materials （PCMS） were prepareo oy mgn-energy milling. The concept of heat capacity factor （HCF） was used to analyze the thermal properties of the materials. The heat storage property of PCMs, containing the same content of stearic acid （23~ by mass） in the starting materials but synthesized by different technical processes, was investigated by using HCE It was found that there were vast influences of different dispersants on the heat capacity. The samples orelaared with chloroform provided the best heat storage ability in all samples tested.
基金financially supported by the National Natural Science Foundation of China(Nos.21473198,11775226)Natural Science Foundation of Liaoning Provincial(No.201602741)Hundred-Talent Program founded by Chinese Academy of Sciences
文摘Low temperature calorimetry is an experimental method of heat capacity measurements, and heatcapacity is one of the most important and fundamental thermodynamic properties of substances. Theheat capacity can provide an average evaluation of the thermal property of a sample since it is a bull（property of substances. In the other hand, the condensed states of substances could be mainly controlledby the molecular motions, intermolecular interactions, and interplay among molecular structures. Thephysical property reflected in a material may be closely related to the energy changes in these threefactors, which can be directly observed in a heat capacity curve. Therefore, low temperature calorimetryhas been used not only to obtain heat capacity, entropy, enthalpy and Gibbs free energy, but also toinvestigate and understand lattice vibrations, metals, superconductivity, electronic and nuclearmagnetism, dilute magnetic systems and structural transitions. In this review, we have presented theconcept of low temperature calorimetry and its applications in the related field of material researches,such as nano-materials, magnetic materials, ferroelectric materials, phase change materials and othermaterials.
