Only two macroscopic parameters are needed to describe the mechanical properties of linear elastic solids, i.e. the Poisson's ratio and Young's modulus. Correspondingly, there should be two microscopic parameters to...Only two macroscopic parameters are needed to describe the mechanical properties of linear elastic solids, i.e. the Poisson's ratio and Young's modulus. Correspondingly, there should be two microscopic parameters to determine the mechanical properties of material if the macroscopic mechanical properties of linear elastic solids are derived from the microscopic level. Enlightened by this idea, a multiscale mechanical model for material, the virtual multi-dimensional internal bonds (VMIB) model, is proposed by incorporating a shear bond into the virtual internal bond (VIB) model. By this modification, the VMIB model associates the macro mechanical properties of material with the microscopic mechanical properties of discrete structure and the corresponding relationship between micro and macro parameters is derived. The tensor quality of the energy density function, which contains coordinate vector, is mathematically proved. From the point of view of VMIB, the macroscopic nonlinear behaviors of material could be attributed to the evolution of virtual bond distribution density induced by the imposed deformation. With this theoretical hypothesis, as an application example, a uniaxial compressive failure of brittle material is simulated. Good agreement between the experimental results and the simulated ones is found.展开更多
Statistical manipulation of material data was conducted for probabilistic life assessment or risk-based design and maintenance for high temperature components of power plants. To obtain the statistical distribution of...Statistical manipulation of material data was conducted for probabilistic life assessment or risk-based design and maintenance for high temperature components of power plants. To obtain the statistical distribution of material properties, dominant parameters affecting material properties are introduced into normalization of statistical variables. Those parameters are hardness, chemical composition, characteristic micro structural features and so on. Creep and fatigue properties are expressed by normalized parameters and the unified statistical distributions are obtained. These probability distribution functions show good coincidence statistically with the field database of steam turbine components. It was concluded that the unified statistical baseline approach is useful for the risk management of components in power plants.展开更多
The properties and tensile behaviors of polypropylene (PP) geogrids and geonets for reinforcement of soil structures are investigated.Mass per unit area of the geogrids and geonets was weighed using an electronic bala...The properties and tensile behaviors of polypropylene (PP) geogrids and geonets for reinforcement of soil structures are investigated.Mass per unit area of the geogrids and geonets was weighed using an electronic balance and aperture sizes of the geonets were exactly measured using a computer.Laboratory tests were performed using a small tensile machine capable of monitoring tensile force and displacement.Tensile failure behaviors were described,and tensile index properties such as tensile strength,maximum tensile strain,tensile forces corresponding to different strains in the geogrids and gronets were obtained.The characterization of these indexes is discussed.展开更多
This study aims at proposing a reasonable roughness parameter that can reflect the peak shear strength(PSS)of rock joints.Firstly,the contribution of the asperities with different apparent dip angles to shear strength...This study aims at proposing a reasonable roughness parameter that can reflect the peak shear strength(PSS)of rock joints.Firstly,the contribution of the asperities with different apparent dip angles to shear strength is studied.Then the shear strength of the entire joint asperities is derived.The results showed that the PSS of the entire joint asperities is proportional to a key parameter hs,which is related to the geometric character of the joint surface and the joint material properties.The parameter hsis taken as the new roughness parameter,and it is reasonable to associate the PSS with the geometric characteristics of the joint surface.Based on the new roughness parameter and shear test results of 20 sets of joint specimens,a new PSS model for rock joints is proposed.The new model is validated with the artificial joints in this paper and real rock joints in published studies.Results showed that it is suitable for different types of rock joints except for gneiss joints.The new model has the form of the Mohr-Coulomb model,which can directly reflect the relationship between the 3 D roughness parameters and the peak dilation angle.展开更多
Representative volume element (RVE) method and asymptotic homogenization (AH) method are two widely used methods in predicting effective properties of pe- riodic materials. This paper develops a novel implementa- ...Representative volume element (RVE) method and asymptotic homogenization (AH) method are two widely used methods in predicting effective properties of pe- riodic materials. This paper develops a novel implementa- tion of the AH method, which has rigorous mathematical foundation of the AH method, and also simplicity as the RVE method. This implementation can be easily realized using commercial software as a black box, and can use all kinds of elements available in commercial software to model unit cells with rather complicated microstructures, so the model may remain a fairly small scale. Several examples were car- fled out to demonstrate the simplicity and effectiveness of the new implementation.展开更多
We compare the factors which affect the movement of Tibetan Plateau by building three types of finite element models: an elastic materials (M-EC), a continuous model composed by non-linear materials (M-PC), and a...We compare the factors which affect the movement of Tibetan Plateau by building three types of finite element models: an elastic materials (M-EC), a continuous model composed by non-linear materials (M-PC), and an elastic model with discontinuous fault movements (M-ET). Both in M-ET and M-EC, the materials in Qiangtang and Lhasa block are elastic, and in M-ET, discontinuous movement of faults is considered for evaluating the effects of strike-slip faults. In model M-PC Druker-Prager plastic materials are used in Qiangtang and Lhasa block. Comparisons of the numerical simulation and the GPS observations show following characteristics: (1) Under present tectonic environment, short-term deformation of Tibetan Plateau can be simulated well by elastic models; (2) Discontinuous fault activities increase the lateral extrusion of the eastern part of Tibetan Plateau, reduce the stress field level in Qiangtang, Tarim and Qaidam blocks and strengthen the E-W extensional force in the east and the west parts of Qiangtang block; (3) Properties of plastic materials reduce the total stress field and the E-W extensional force, thus, the normal fault earthquakes in southern Tibet is mainly owed to the effect of active fault movement. Based on the numerical simulations we speculate that faults movement may play a more important role on the kinematic pattern of Tibetan Plateau than bulk properties.展开更多
Hybrid materials incorporating Eu-(TTA)3·2H20 (hereafter designated as Eu-TTA, with TTA: thenoyltrifluoroacetone) in unmodified or modified MCM-41 by 3-aminopropyl-triethoxysilane (APTES) were prepared by impregn...Hybrid materials incorporating Eu-(TTA)3·2H20 (hereafter designated as Eu-TTA, with TTA: thenoyltrifluoroacetone) in unmodified or modified MCM-41 by 3-aminopropyl-triethoxysilane (APTES) were prepared by impregnation method. The obtained materials were characterized using X-ray diffraction (XRD), IR and diffuse reflectance spectroscopy and luminescence spectra. All the hybrid samples exhibited the characteristic emission bands of Eu3+ under UV light exci-tation at room temperature, and the excitation spectra showed significant blue-shifts compared to the pure rare-earth complex. Although the red emission intensity in the modified hybrid was almost the half of the red emission intensity in the pure Eu-TTA complex at room temperature, the hybrid showed a much higher thermal stability due to the shielding character of the MCM-41 host.展开更多
The physical modelanditsequivalentcircuitoftestapparatusissetup by meansofimpedanceanalysis method. The magnetostriction coefficient, magnetomechanicalcoupling coefficient,frequency and anti- frequency of TbxDy1 - xFe...The physical modelanditsequivalentcircuitoftestapparatusissetup by meansofimpedanceanalysis method. The magnetostriction coefficient, magnetomechanicalcoupling coefficient,frequency and anti- frequency of TbxDy1 - xFe2 - z(0 27 ≤x ≤0 3 ,0 ≤z ≤0 1) rod are measured. Somecoupling problems with mechanicalstress and electromagnetic field such as flux leakage in magnetic path are discussed. The comparing calculated with tested resultsshowsthe accuracyof measurementand thesimplification of model.展开更多
In this paper, we present a new united approach to formulate the equivalent micropolar constitutive relation of two-dimensional(2-D) periodic cellular material to capture its non-local properties and to explain the ...In this paper, we present a new united approach to formulate the equivalent micropolar constitutive relation of two-dimensional(2-D) periodic cellular material to capture its non-local properties and to explain the size effects in its structural analysis. The new united approach takes both the displacement compatibility and the equilibrium of forces and moments into consideration, where Taylor series expansion of the displacement and rotation fields and the extended averaging procedure with an explicit enforcement of equilibrium are adopted in the micromechanical analysis of a unit cell.In numerical examples, the effective micropolar constants obtained in this paper and others derived in the literature are used for the equivalent micropolar continuum simulation of cellular solids. The solutions from the equivalent analysis are compared with the discrete simulation solutions of the cellular solids. It is found that the micropolar constants developed in this paper give satisfying results of equivalent analysis for the periodic cellular material.展开更多
SiC reinforced graphite composites were prepared via introducing carbide silicon into the natural graphite flakes(NGF) by hot-pressing process. Their physical and mechanical properties, including density, open poros...SiC reinforced graphite composites were prepared via introducing carbide silicon into the natural graphite flakes(NGF) by hot-pressing process. Their physical and mechanical properties, including density, open porosity, flexural strength, and friction behavior were investigated. The addition of 30vol% Si C increased the bending strength of composites materials to 127 MPa, 2 times higher than 60 MPa of commercial pure graphite block. What was particularly interesting was that the as-obtained graphite composite with 30vol% Si C kept the same low friction coefficient of about 0.1 as pure graphite, and the wear resistance of composites increased.展开更多
Sensitive materials mainly composed of ZnO and their multi-functional properties were investigated. The temperature extent of linear resistance, non-linear deviation and endurance ability of surge energy were further ...Sensitive materials mainly composed of ZnO and their multi-functional properties were investigated. The temperature extent of linear resistance, non-linear deviation and endurance ability of surge energy were further discussed. The effect of Mg^2+, AI^3+ and Si^4+, which could be solid solutioned in ZnO grain and the function of Y^3+ ion segregated out in grain boundary were studied as well. The function of Ti was analyzed emphatically.展开更多
The fabrication. microstructure and mechanical properties of ZrO2-Ni functionally gradient materials (FGM ) have been studied. FGM as well as non-FG M of ZrO2-Ni system was developed by powder metallurgical process. X...The fabrication. microstructure and mechanical properties of ZrO2-Ni functionally gradient materials (FGM ) have been studied. FGM as well as non-FG M of ZrO2-Ni system was developed by powder metallurgical process. X-ray diffractometer (XRD ). electron probe microanalyzer (EPMA), scanning electron microscope (SEM ) and optical microscope were employed to investigate the crystalline phases. chemical composition and microstructure Experimental results demonstrate that the composition and microstructure of ZrO2-Ni FGM have the expected gradient distribution. There are no distinct interfaces in the FGM due to the gradient change of components. that is, the constituents are continuous in microstructure everywhere. Moreover, Vickers hardness and flexural strength were measured for the common composites as a function of composition. It is made clear that the mechanical properties of the FGM vary corresponding to the constitutional changes as well展开更多
Influence of the gassing materials, such as PA6, PMMA, and POM on the dielectric properties of air are investigated. In this work, the fundamental electron collision cross section data were carefully selected and vali...Influence of the gassing materials, such as PA6, PMMA, and POM on the dielectric properties of air are investigated. In this work, the fundamental electron collision cross section data were carefully selected and validated. Then the species compositions of the air–organic vapor mixtures were calculated based on the Gibbs free energy minimization. Finally, the Townsend ionization coefficient, the Townsend electron attachment coefficient and the critical reduced electric field strength were derived from the calculated electron energy distribution function by solving the Boltzmann transport equation. The calculation results indicated that H;O with large attachment cross sections has a great impact on the critical reduced electric field strength of the air–organic vapor mixtures. On the other hand, the vaporization of gassing materials can help to increase the dielectric properties of air circuit breakers to some degree.展开更多
Mixing and heat transfer processes of the granular materials within rotary cylinders play a key role in industrial processes. The numerical simulation is carried out by using the discrete element method (DEM) to inv...Mixing and heat transfer processes of the granular materials within rotary cylinders play a key role in industrial processes. The numerical simulation is carried out by using the discrete element method (DEM) to investigate the influences of material properties on the bed mixing and heat transfer process, including heat conductivity, heat capacity, and shear modulus. Moreover, a new Prclet number is derived to determine the dominant mechanism of the heating rate within the particle bed, which is directly related to thermal and mechanical properties. The system exhibits a faster heating rate with the increase of ratio of thermal conductivity and heat capacity, or the decrease of shear modulus when inter-particle conduction dominates the heating rate; conversely, it shows a fast-mixing bed when particle convection governs the heating rate. The simulation results show good agreement with the theoretical predictions.展开更多
There are a large number of historic buildings which were mainly made of blue-brick masonry in today’s world.However,for the natural and man-made reasons,these historic buildings have been damaged in different degree...There are a large number of historic buildings which were mainly made of blue-brick masonry in today’s world.However,for the natural and man-made reasons,these historic buildings have been damaged in different degrees.In order to protect historic buildings more scientifically and learn about the preservation state of existing historic buildings,it is necessary to ascertain the material properties of blue brick in historic buildings.The article takes the blue bricks of historical buildings in Kaifeng area of the Central Plains as an example to study.Through the analysis of physical properties,X-ray fluorescence spectroscopy,X-ray diffraction and scanning electron microscopy of blue brick specimens,the physical properties such as the apparent density,moisture content,porosity,and material structure composition are understood.The results show that the apparent density of blue brick is 1.64 g/cm^(3),the moisture content is 10.23%,the 24 h atmospheric water absorption is 17.86%,and the porosity is 20.99%.The smaller the apparent density is,the larger the porosity is,and the water absorption performance is better.From the microscopic point of view,bonding ability between blue brick mineral particles is relatively weak.The pores between skeletons are large and the pore structure is obvious.From the perspective of material phase,the elements of blue brick are mainly O,Si,Al,Fe,and the composition of blue brick is mainly composed of quartz and feldspar.The softening coefficient of blue brick is 0.80,and the deformation and stability of the structure should be paid special attention in the rainy season or wet environment.Through the frost test,there are salt substances in the internal pores of the brick,and the surface of the blue brick is eroded and pulverized.In this paper,the experimental process and analysis methods for testing the material properties of blue brick can provide reference for the research on the material properties of the same kind of blue-brick masonry in historic buildings and masonry relics.The relevant material property parameters obtained in this paper can provide guidance for making protection schemes and scientific repairs for historic buildings in Central China,enrich the evaluation criteria for maintaining and reinforcing historic buildings,and provide theoretical support for studying the damage and health detection technology related to historic buildings.展开更多
An artificially accelerated alternation of aging and seawater erosion test of rubber materials used in lead rubber bearing(LRB)was performed,mainly to study the time-varying laws of rubber materials mechanical propert...An artificially accelerated alternation of aging and seawater erosion test of rubber materials used in lead rubber bearing(LRB)was performed,mainly to study the time-varying laws of rubber materials mechanical properties.Time-varying laws of the Mooney–Rivlin and Neo-Hookean constitutive parameters of rubber materials under the alternation of aging and seawater erosion were also analyzed.Results indicate that the rubber material mechanical properties were significantly affected by alternation of aging and seawater erosion.Hardness and elongation stress increased exponentially with test time.And 120 days after the test,the hardness increased by 14%,the maximum percentage increase in stress of 124.76%occurred at 100%constant elongation and the minimum percentage increase in stress of 68.32%occurred at 300%constant elongation;Tensile strength and elongation at break decreased by 44.96%and 53.09%.Besides,constitutive parameters of Mooney–Rivlin and Neo-Hookean all changed greatly with test duration.Finally,time-varying laws of constitutive parameters were verified by comparing the simulated and experimental results of the lead rubber bearing’s stiffness.Research results are of great significance to the seismic performance research and life-cycle performance analysis of offshore traffic engineering such as cross-sea bridges and bridges in the marine environment.展开更多
The hot or cold processing would induce the change and the inhomogeneous of the material mechanical properties in the local processing region of the structure,and it is difficult to obtain the specific mechanical prop...The hot or cold processing would induce the change and the inhomogeneous of the material mechanical properties in the local processing region of the structure,and it is difficult to obtain the specific mechanical properties in these regions by using the traditional material tensile test.To accurately get actual material mechanical properties in the local region of structure,a micro-indentation test system incorporated by an electronic universal material test device has been established.An indenter displacement sensor and a group of special micro-indenter assemblies are estab-lished.A numerical indentation inversion analysis method by using ABAQUS software is also proposed in this study.Based on the above test system and analysis platform,an approach to obtaining material mechanical properties in the local region of structures is proposed and established.The ball indentation test is performed and combined with the energy method by using various changed mechanical properties of 316L austenitic stainless steel under differ-ent elongations.The investigated results indicate that the material mechanical properties and the micro-indentation morphological changes have evidently relevance.Compared with the tensile test results,the deviations of material mechanical parameters,such as hardness H,the hardening exponent n,the yield strength σy and others are within 5%obtained through the indentation test and the finite element analysis.It provides an effective and convenient method for obtaining the actual material mechanical properties in the local processing region of the structure.展开更多
In this paper,the functional polymeric active materials were prepared by the grafting copolymerization and their structure and properties were studied.The results show that the structure and properties of these ac- ti...In this paper,the functional polymeric active materials were prepared by the grafting copolymerization and their structure and properties were studied.The results show that the structure and properties of these ac- tive materials have the relative large effects on the properties of gadolinium ion selective electrodes.展开更多
Accurate representation of soft tissue material properties plays a crucial role in computational biomechanics. Several material models have been used for knee ligaments in finite element (FE) studies, including the ne...Accurate representation of soft tissue material properties plays a crucial role in computational biomechanics. Several material models have been used for knee ligaments in finite element (FE) studies, including the neo-Hookean model (widely used) and the Holzapfel-Gasser-Ogden (HGO) model (seldom used). While the coefficients of neo-Hookean models for the knee ligaments are available in the literature, limited data exists for the HGO model. Furthermore, no peer-reviewed comparison of these two material models for the knee ligaments while including the 3D representation of the ligaments for both material models is present in the literature. We used mechanical properties from the tensile test experiments in the literature for each ligament to obtain the HGO material coefficients while accounting for the ligaments’ viscoelastic behavior. Resultant coefficients were then used in an Abaqus/explicit knee model to simulate bipedal landing from a jump. The simulations were repeated with neo-Hookean values from the literature. Knee kinematics plus ACL and MCL strains were evaluated and compared for these two material models. The outputs from the simulations with HGO properties were predominantly within 1.5 standard deviations from the mean in-vitro data. When the material properties changed to Neo-Hookean, the outputs for kinematics and strain values were higher than the HGO case, and in most instances, they were outside the experimental range for ACL and MCL strains (by up to 11.35 SD) as well as some ITR angles (by up to 2.86 SD). Reported HGO material model with optimized coefficients produces a more realistic representation of the ligaments’ material properties, and will help improve the outcomes of FE models for more accurate predictions of knee behavior.展开更多
Energy transfer between the adjacent parts of rocks in underground mines is widely influenced by the thermal conductivity of rocks. The relationships between the thermal conductivity and some material properties of ro...Energy transfer between the adjacent parts of rocks in underground mines is widely influenced by the thermal conductivity of rocks. The relationships between the thermal conductivity and some material properties of rocks such as the uniaxial compressive strength, unit mass, tensile strength, cohesion, Young’s modulus, point load strength, Schmidt rebound hardness, Shore scleroscope hardness and toughness strength were investigated. The statistical analysis of the data obtained in laboratory tests shows that the thermal conductivity increases with increasing the uniaxial compressive strength, unit mass, tensile strength, cohesion, Young’s modulus, point load strength, Schmidt rebound hardness and Shore scleroscope hardness, and decreases with increasing the toughness strength.展开更多
基金Project supported by the National Basic Research Program of China (973 Project) (No. 2002CB412704).
文摘Only two macroscopic parameters are needed to describe the mechanical properties of linear elastic solids, i.e. the Poisson's ratio and Young's modulus. Correspondingly, there should be two microscopic parameters to determine the mechanical properties of material if the macroscopic mechanical properties of linear elastic solids are derived from the microscopic level. Enlightened by this idea, a multiscale mechanical model for material, the virtual multi-dimensional internal bonds (VMIB) model, is proposed by incorporating a shear bond into the virtual internal bond (VIB) model. By this modification, the VMIB model associates the macro mechanical properties of material with the microscopic mechanical properties of discrete structure and the corresponding relationship between micro and macro parameters is derived. The tensor quality of the energy density function, which contains coordinate vector, is mathematically proved. From the point of view of VMIB, the macroscopic nonlinear behaviors of material could be attributed to the evolution of virtual bond distribution density induced by the imposed deformation. With this theoretical hypothesis, as an application example, a uniaxial compressive failure of brittle material is simulated. Good agreement between the experimental results and the simulated ones is found.
文摘Statistical manipulation of material data was conducted for probabilistic life assessment or risk-based design and maintenance for high temperature components of power plants. To obtain the statistical distribution of material properties, dominant parameters affecting material properties are introduced into normalization of statistical variables. Those parameters are hardness, chemical composition, characteristic micro structural features and so on. Creep and fatigue properties are expressed by normalized parameters and the unified statistical distributions are obtained. These probability distribution functions show good coincidence statistically with the field database of steam turbine components. It was concluded that the unified statistical baseline approach is useful for the risk management of components in power plants.
文摘The properties and tensile behaviors of polypropylene (PP) geogrids and geonets for reinforcement of soil structures are investigated.Mass per unit area of the geogrids and geonets was weighed using an electronic balance and aperture sizes of the geonets were exactly measured using a computer.Laboratory tests were performed using a small tensile machine capable of monitoring tensile force and displacement.Tensile failure behaviors were described,and tensile index properties such as tensile strength,maximum tensile strain,tensile forces corresponding to different strains in the geogrids and gronets were obtained.The characterization of these indexes is discussed.
基金supported by China Postdoctoral Science Foundation(No.2020M680007)Beijing Postdoctoral Research Foundation(No.2020-zz-087)+1 种基金National Natural Science Foundation of China(Nos.51478027 and 51174012)Fundamental Research Funds for Beijing Civil Engineering and Architecture(No.X20031)。
文摘This study aims at proposing a reasonable roughness parameter that can reflect the peak shear strength(PSS)of rock joints.Firstly,the contribution of the asperities with different apparent dip angles to shear strength is studied.Then the shear strength of the entire joint asperities is derived.The results showed that the PSS of the entire joint asperities is proportional to a key parameter hs,which is related to the geometric character of the joint surface and the joint material properties.The parameter hsis taken as the new roughness parameter,and it is reasonable to associate the PSS with the geometric characteristics of the joint surface.Based on the new roughness parameter and shear test results of 20 sets of joint specimens,a new PSS model for rock joints is proposed.The new model is validated with the artificial joints in this paper and real rock joints in published studies.Results showed that it is suitable for different types of rock joints except for gneiss joints.The new model has the form of the Mohr-Coulomb model,which can directly reflect the relationship between the 3 D roughness parameters and the peak dilation angle.
基金supported by the National Natural Science Foundation of China(91216201)
文摘Representative volume element (RVE) method and asymptotic homogenization (AH) method are two widely used methods in predicting effective properties of pe- riodic materials. This paper develops a novel implementa- tion of the AH method, which has rigorous mathematical foundation of the AH method, and also simplicity as the RVE method. This implementation can be easily realized using commercial software as a black box, and can use all kinds of elements available in commercial software to model unit cells with rather complicated microstructures, so the model may remain a fairly small scale. Several examples were car- fled out to demonstrate the simplicity and effectiveness of the new implementation.
基金jointly supported by Chinese Academy of Sciences(Nos.KZCX2-YW-116 and KZCX2-YW-142)National Natural Science Foundation of China (Nos.40974034and 40064004)
文摘We compare the factors which affect the movement of Tibetan Plateau by building three types of finite element models: an elastic materials (M-EC), a continuous model composed by non-linear materials (M-PC), and an elastic model with discontinuous fault movements (M-ET). Both in M-ET and M-EC, the materials in Qiangtang and Lhasa block are elastic, and in M-ET, discontinuous movement of faults is considered for evaluating the effects of strike-slip faults. In model M-PC Druker-Prager plastic materials are used in Qiangtang and Lhasa block. Comparisons of the numerical simulation and the GPS observations show following characteristics: (1) Under present tectonic environment, short-term deformation of Tibetan Plateau can be simulated well by elastic models; (2) Discontinuous fault activities increase the lateral extrusion of the eastern part of Tibetan Plateau, reduce the stress field level in Qiangtang, Tarim and Qaidam blocks and strengthen the E-W extensional force in the east and the west parts of Qiangtang block; (3) Properties of plastic materials reduce the total stress field and the E-W extensional force, thus, the normal fault earthquakes in southern Tibet is mainly owed to the effect of active fault movement. Based on the numerical simulations we speculate that faults movement may play a more important role on the kinematic pattern of Tibetan Plateau than bulk properties.
基金financial supportfrom PRAMX 98-05 and helpful discussion with Dr.A.C.Franville.
文摘Hybrid materials incorporating Eu-(TTA)3·2H20 (hereafter designated as Eu-TTA, with TTA: thenoyltrifluoroacetone) in unmodified or modified MCM-41 by 3-aminopropyl-triethoxysilane (APTES) were prepared by impregnation method. The obtained materials were characterized using X-ray diffraction (XRD), IR and diffuse reflectance spectroscopy and luminescence spectra. All the hybrid samples exhibited the characteristic emission bands of Eu3+ under UV light exci-tation at room temperature, and the excitation spectra showed significant blue-shifts compared to the pure rare-earth complex. Although the red emission intensity in the modified hybrid was almost the half of the red emission intensity in the pure Eu-TTA complex at room temperature, the hybrid showed a much higher thermal stability due to the shielding character of the MCM-41 host.
文摘The physical modelanditsequivalentcircuitoftestapparatusissetup by meansofimpedanceanalysis method. The magnetostriction coefficient, magnetomechanicalcoupling coefficient,frequency and anti- frequency of TbxDy1 - xFe2 - z(0 27 ≤x ≤0 3 ,0 ≤z ≤0 1) rod are measured. Somecoupling problems with mechanicalstress and electromagnetic field such as flux leakage in magnetic path are discussed. The comparing calculated with tested resultsshowsthe accuracyof measurementand thesimplification of model.
文摘In this paper, we present a new united approach to formulate the equivalent micropolar constitutive relation of two-dimensional(2-D) periodic cellular material to capture its non-local properties and to explain the size effects in its structural analysis. The new united approach takes both the displacement compatibility and the equilibrium of forces and moments into consideration, where Taylor series expansion of the displacement and rotation fields and the extended averaging procedure with an explicit enforcement of equilibrium are adopted in the micromechanical analysis of a unit cell.In numerical examples, the effective micropolar constants obtained in this paper and others derived in the literature are used for the equivalent micropolar continuum simulation of cellular solids. The solutions from the equivalent analysis are compared with the discrete simulation solutions of the cellular solids. It is found that the micropolar constants developed in this paper give satisfying results of equivalent analysis for the periodic cellular material.
基金Funded by the National Natural Science Foundation of China(No.U1134102)
文摘SiC reinforced graphite composites were prepared via introducing carbide silicon into the natural graphite flakes(NGF) by hot-pressing process. Their physical and mechanical properties, including density, open porosity, flexural strength, and friction behavior were investigated. The addition of 30vol% Si C increased the bending strength of composites materials to 127 MPa, 2 times higher than 60 MPa of commercial pure graphite block. What was particularly interesting was that the as-obtained graphite composite with 30vol% Si C kept the same low friction coefficient of about 0.1 as pure graphite, and the wear resistance of composites increased.
基金National Natural Science Foundation of China!(No. 59972011).
文摘Sensitive materials mainly composed of ZnO and their multi-functional properties were investigated. The temperature extent of linear resistance, non-linear deviation and endurance ability of surge energy were further discussed. The effect of Mg^2+, AI^3+ and Si^4+, which could be solid solutioned in ZnO grain and the function of Y^3+ ion segregated out in grain boundary were studied as well. The function of Ti was analyzed emphatically.
文摘The fabrication. microstructure and mechanical properties of ZrO2-Ni functionally gradient materials (FGM ) have been studied. FGM as well as non-FG M of ZrO2-Ni system was developed by powder metallurgical process. X-ray diffractometer (XRD ). electron probe microanalyzer (EPMA), scanning electron microscope (SEM ) and optical microscope were employed to investigate the crystalline phases. chemical composition and microstructure Experimental results demonstrate that the composition and microstructure of ZrO2-Ni FGM have the expected gradient distribution. There are no distinct interfaces in the FGM due to the gradient change of components. that is, the constituents are continuous in microstructure everywhere. Moreover, Vickers hardness and flexural strength were measured for the common composites as a function of composition. It is made clear that the mechanical properties of the FGM vary corresponding to the constitutional changes as well
基金supported by the National Key Basic Research Program of China(973 Program)2015CB251002National Natural Science Foundation of China under Grant 51521065,51577145+1 种基金the Fundamental Research Funds for the Central UniversitiesShaanxi Province Natural Science Foundation 2013JM-7010
文摘Influence of the gassing materials, such as PA6, PMMA, and POM on the dielectric properties of air are investigated. In this work, the fundamental electron collision cross section data were carefully selected and validated. Then the species compositions of the air–organic vapor mixtures were calculated based on the Gibbs free energy minimization. Finally, the Townsend ionization coefficient, the Townsend electron attachment coefficient and the critical reduced electric field strength were derived from the calculated electron energy distribution function by solving the Boltzmann transport equation. The calculation results indicated that H;O with large attachment cross sections has a great impact on the critical reduced electric field strength of the air–organic vapor mixtures. On the other hand, the vaporization of gassing materials can help to increase the dielectric properties of air circuit breakers to some degree.
基金supported by the National High Technology Research and Development Program of China(Grant No.2007AA05Z215)the Fundamental Research Funds for the Central Universities(Grant No.FRF-AS-10-005B)
文摘Mixing and heat transfer processes of the granular materials within rotary cylinders play a key role in industrial processes. The numerical simulation is carried out by using the discrete element method (DEM) to investigate the influences of material properties on the bed mixing and heat transfer process, including heat conductivity, heat capacity, and shear modulus. Moreover, a new Prclet number is derived to determine the dominant mechanism of the heating rate within the particle bed, which is directly related to thermal and mechanical properties. The system exhibits a faster heating rate with the increase of ratio of thermal conductivity and heat capacity, or the decrease of shear modulus when inter-particle conduction dominates the heating rate; conversely, it shows a fast-mixing bed when particle convection governs the heating rate. The simulation results show good agreement with the theoretical predictions.
基金The authors would like to express heartfelt gratitude to the financial support by the Science Technology of the Ministry of Housing and Urban-Rural Development(No.2018-K9-065)China Postdoctoral Science Foundation Funded Project(No.2018M632805)+1 种基金Key Scientific and Technological Project of Henan Province(No.212102310932)Key Scientific and Technological Project of Kaifeng City(No.2001010).
文摘There are a large number of historic buildings which were mainly made of blue-brick masonry in today’s world.However,for the natural and man-made reasons,these historic buildings have been damaged in different degrees.In order to protect historic buildings more scientifically and learn about the preservation state of existing historic buildings,it is necessary to ascertain the material properties of blue brick in historic buildings.The article takes the blue bricks of historical buildings in Kaifeng area of the Central Plains as an example to study.Through the analysis of physical properties,X-ray fluorescence spectroscopy,X-ray diffraction and scanning electron microscopy of blue brick specimens,the physical properties such as the apparent density,moisture content,porosity,and material structure composition are understood.The results show that the apparent density of blue brick is 1.64 g/cm^(3),the moisture content is 10.23%,the 24 h atmospheric water absorption is 17.86%,and the porosity is 20.99%.The smaller the apparent density is,the larger the porosity is,and the water absorption performance is better.From the microscopic point of view,bonding ability between blue brick mineral particles is relatively weak.The pores between skeletons are large and the pore structure is obvious.From the perspective of material phase,the elements of blue brick are mainly O,Si,Al,Fe,and the composition of blue brick is mainly composed of quartz and feldspar.The softening coefficient of blue brick is 0.80,and the deformation and stability of the structure should be paid special attention in the rainy season or wet environment.Through the frost test,there are salt substances in the internal pores of the brick,and the surface of the blue brick is eroded and pulverized.In this paper,the experimental process and analysis methods for testing the material properties of blue brick can provide reference for the research on the material properties of the same kind of blue-brick masonry in historic buildings and masonry relics.The relevant material property parameters obtained in this paper can provide guidance for making protection schemes and scientific repairs for historic buildings in Central China,enrich the evaluation criteria for maintaining and reinforcing historic buildings,and provide theoretical support for studying the damage and health detection technology related to historic buildings.
基金This work was supported by the Programme for National Natural Science Foundation of China(52078150,51878196)National Key R&D Program of China(2019YFE0112500)2019 Guangzhou University Full-Time Graduate“Basic Innovation”Project(2019GDJC-D11).
文摘An artificially accelerated alternation of aging and seawater erosion test of rubber materials used in lead rubber bearing(LRB)was performed,mainly to study the time-varying laws of rubber materials mechanical properties.Time-varying laws of the Mooney–Rivlin and Neo-Hookean constitutive parameters of rubber materials under the alternation of aging and seawater erosion were also analyzed.Results indicate that the rubber material mechanical properties were significantly affected by alternation of aging and seawater erosion.Hardness and elongation stress increased exponentially with test time.And 120 days after the test,the hardness increased by 14%,the maximum percentage increase in stress of 124.76%occurred at 100%constant elongation and the minimum percentage increase in stress of 68.32%occurred at 300%constant elongation;Tensile strength and elongation at break decreased by 44.96%and 53.09%.Besides,constitutive parameters of Mooney–Rivlin and Neo-Hookean all changed greatly with test duration.Finally,time-varying laws of constitutive parameters were verified by comparing the simulated and experimental results of the lead rubber bearing’s stiffness.Research results are of great significance to the seismic performance research and life-cycle performance analysis of offshore traffic engineering such as cross-sea bridges and bridges in the marine environment.
基金Supported by National Natural Science Foundation of China(Grant No.52075434)Key R&D Projects in Shaanxi Province(Grant No.2021KW-36).
文摘The hot or cold processing would induce the change and the inhomogeneous of the material mechanical properties in the local processing region of the structure,and it is difficult to obtain the specific mechanical properties in these regions by using the traditional material tensile test.To accurately get actual material mechanical properties in the local region of structure,a micro-indentation test system incorporated by an electronic universal material test device has been established.An indenter displacement sensor and a group of special micro-indenter assemblies are estab-lished.A numerical indentation inversion analysis method by using ABAQUS software is also proposed in this study.Based on the above test system and analysis platform,an approach to obtaining material mechanical properties in the local region of structures is proposed and established.The ball indentation test is performed and combined with the energy method by using various changed mechanical properties of 316L austenitic stainless steel under differ-ent elongations.The investigated results indicate that the material mechanical properties and the micro-indentation morphological changes have evidently relevance.Compared with the tensile test results,the deviations of material mechanical parameters,such as hardness H,the hardening exponent n,the yield strength σy and others are within 5%obtained through the indentation test and the finite element analysis.It provides an effective and convenient method for obtaining the actual material mechanical properties in the local processing region of the structure.
文摘In this paper,the functional polymeric active materials were prepared by the grafting copolymerization and their structure and properties were studied.The results show that the structure and properties of these ac- tive materials have the relative large effects on the properties of gadolinium ion selective electrodes.
文摘Accurate representation of soft tissue material properties plays a crucial role in computational biomechanics. Several material models have been used for knee ligaments in finite element (FE) studies, including the neo-Hookean model (widely used) and the Holzapfel-Gasser-Ogden (HGO) model (seldom used). While the coefficients of neo-Hookean models for the knee ligaments are available in the literature, limited data exists for the HGO model. Furthermore, no peer-reviewed comparison of these two material models for the knee ligaments while including the 3D representation of the ligaments for both material models is present in the literature. We used mechanical properties from the tensile test experiments in the literature for each ligament to obtain the HGO material coefficients while accounting for the ligaments’ viscoelastic behavior. Resultant coefficients were then used in an Abaqus/explicit knee model to simulate bipedal landing from a jump. The simulations were repeated with neo-Hookean values from the literature. Knee kinematics plus ACL and MCL strains were evaluated and compared for these two material models. The outputs from the simulations with HGO properties were predominantly within 1.5 standard deviations from the mean in-vitro data. When the material properties changed to Neo-Hookean, the outputs for kinematics and strain values were higher than the HGO case, and in most instances, they were outside the experimental range for ACL and MCL strains (by up to 11.35 SD) as well as some ITR angles (by up to 2.86 SD). Reported HGO material model with optimized coefficients produces a more realistic representation of the ligaments’ material properties, and will help improve the outcomes of FE models for more accurate predictions of knee behavior.
文摘Energy transfer between the adjacent parts of rocks in underground mines is widely influenced by the thermal conductivity of rocks. The relationships between the thermal conductivity and some material properties of rocks such as the uniaxial compressive strength, unit mass, tensile strength, cohesion, Young’s modulus, point load strength, Schmidt rebound hardness, Shore scleroscope hardness and toughness strength were investigated. The statistical analysis of the data obtained in laboratory tests shows that the thermal conductivity increases with increasing the uniaxial compressive strength, unit mass, tensile strength, cohesion, Young’s modulus, point load strength, Schmidt rebound hardness and Shore scleroscope hardness, and decreases with increasing the toughness strength.