As the process of economic globalization continues to advance,China has undergone earth-shaking changes.High-quality products and promotional materials are crucial for Chinese companies to go global and build their br...As the process of economic globalization continues to advance,China has undergone earth-shaking changes.High-quality products and promotional materials are crucial for Chinese companies to go global and build their brands.The English translation of external promotional materials is crucial.However,some companies do not pay enough attention to their publicity,resulting in a low international status.This paper analyzes the Chinese-English translation of enterprise external publicity materials from the perspective of adaptation theory,thereby exploring the translation strategies adopted under the guidance of adaptation theory,hoping to provide some references for related translation practices in the future.展开更多
Discovery of materials using“bottom-up”or“top-down”approach is of great interest in materials science.Layered materials consisting of two-dimensional(2D)building blocks provide a good platform to explore new mater...Discovery of materials using“bottom-up”or“top-down”approach is of great interest in materials science.Layered materials consisting of two-dimensional(2D)building blocks provide a good platform to explore new materials in this respect.In van der Waals(vdW)layered materials,these building blocks are charge neutral and can be isolated from their bulk phase(top-down),but usually grow on substrate.In ionic layered materials,they are charged and usually cannot exist independently but can serve as motifs to construct new materials(bottom-up).In this paper,we introduce our recently constructed databases for 2D material-substrate interface(2DMSI),and 2D charged building blocks.For 2DMSI database,we systematically build a workflow to predict appropriate substrates and their geometries at substrates,and construct the 2DMSI database.For the 2D charged building block database,1208 entries from bulk material database are identified.Information of crystal structure,valence state,source,dimension and so on is provided for each entry with a json format.We also show its application in designing and searching for new functional layered materials.The 2DMSI database,building block database,and designed layered materials are available in Science Data Bank at https://doi.org/10.57760/sciencedb.j00113.00188.展开更多
This study presents an analytical solution of thermal and mechanical displacements, strains, and stresses for a thick-walled rotating spherical pressure vessel made of functionally graded materials (FGMs). The pressur...This study presents an analytical solution of thermal and mechanical displacements, strains, and stresses for a thick-walled rotating spherical pressure vessel made of functionally graded materials (FGMs). The pressure vessel is subject to axisymmetric mechanical and thermal loadings within a uniform magnetic field. The material properties of the FGM are considered as the power-law distribution along the thickness. Navier’s equation, which is a second-order ordinary differential equation, is derived from the mechanical equilibrium equation with the consideration of the thermal stresses and the Lorentz force resulting from the magnetic field. The distributions of the displacement, strains, and stresses are determined by the exact solution to Navier’s equation. Numerical results clarify the influence of the thermal loading, magnetic field, non-homogeneity constant, internal pressure, and angular velocity on the magneto-thermo-elastic response of the functionally graded spherical vessel. It is observed that these parameters have remarkable effects on the distributions of radial displacement, radial and circumferential strains, and radial and circumferential stresses.展开更多
Non-renewable fossil fuels have led to serious problems such as global warming,environmental pollution,etc.Oxygen electrocatalysis including oxygen reduction reaction(ORR)and oxygen evolution reaction(OER)plays a cent...Non-renewable fossil fuels have led to serious problems such as global warming,environmental pollution,etc.Oxygen electrocatalysis including oxygen reduction reaction(ORR)and oxygen evolution reaction(OER)plays a central role in clean energy conversion,enabling a number of sustainable processes for future air battery technologies.Fluorine,as the most electronegative element(4.0)not only can induce more efficient regulation for the electronic structure,but also can bring more abundant defects and other novel effects in materials selection and preparation for favorable catalysis with respect to the other nonmetal elements.However,an individual and comprehensive overview of fluorine-containing functional materials for oxygen electrocatalysis field is still blank.Therefore,it is very meaningful to review the recent progresses of fluorine-containing oxygen electrocatalysts.In this review,we first systematically summarize the controllable preparation methods and their possible development directions based on fluorine-containing materials from four preparation methods.Due to the strong electron-withdrawing properties of fluorine,its control of the electronic structure can effectively enhance the oxygen electrocatalytic activity of the materials.In addition,the catalytic enhancement effect of fluorine on carbonbased materials also includes the prevent oxidation and the layer peeling,and realizes the precise atomic control.And the catalytic improvement mechanism of fluorine containing metal-based compounds also includes the hydration of metal site,the crystal transformation,and the oxygen vacancy induction.Then,based on their various dimensions(0D–3D),we also have summarized the advantages of different morphologies on oxygen electrocatalytic performances.Finally,the prospects and possible future researching direction of F-containing oxygen electrocatalysts are presented(e.g.,novel pathways,advanced methods for measurement and simulation,field assistance and multi-functions).The review is considered valuable and helpful in exploring the novel designs and mechanism analyses of advanced fluorine-containing electrocatalysts.展开更多
Acoustic wave propagation from surrounding medium into a soft material can generate acoustic radiation stress due to acoustic momentum transfer inside the medium and material, as well as at the interface between the t...Acoustic wave propagation from surrounding medium into a soft material can generate acoustic radiation stress due to acoustic momentum transfer inside the medium and material, as well as at the interface between the two. To analyze acoustic-induced deformation of soft materials, we establish an acoustomechanical constitutive theory by combining the acoustic radiation stress theory and the nonlinear elasticity theory for soft materials. The acoustic radiation stress tensor is formulated by time averaging the momentum equation of particle motion, which is then introduced into the nonlinear elasticity constitutive relation to construct the acoustomechanical constitutive theory for soft materials.Considering a specified case of soft material sheet subjected to two counter-propagating acoustic waves, we demonstrate the nonlinear large deformation of the soft material and analyze the interaction between acoustic waves and material deformation under the conditions of total reflection, acoustic transparency, and acoustic mismatch.展开更多
According to the basic idea of dual-complementarity, in a simple and unified way proposed by the author, various energy principles in theory of elastic materials with voids can be established systematically, In this p...According to the basic idea of dual-complementarity, in a simple and unified way proposed by the author, various energy principles in theory of elastic materials with voids can be established systematically, In this paper, an important integral relation is given, which can be considered essentially as the generalized pr- inciple of virtual work. Based on this relation, it is possible not only to obtain the principle of virtual work and the reciprocal theorem of work in theory of elastic materials with voids, but also to derive systematically the complementary functionals for the eight-field, six-field, four-field and two-field generalized variational principles, and the principle of minimum potential and complementary energies. Furthermore, with this appro ach, the intrinsic relationship among various principles can be explained clearly.展开更多
The dynamic behavior of a Griffith permeable crack under harmonic anti-plane shear waves in the piezoelectric materials is investigated by use of the non-local theory. To overcome the mathematical difficulties, a one-...The dynamic behavior of a Griffith permeable crack under harmonic anti-plane shear waves in the piezoelectric materials is investigated by use of the non-local theory. To overcome the mathematical difficulties, a one-dimensional non-local kernel is used instead of a two-dimensional one for the anti-plane dynamic problem to obtain the stress and the electric displacement near the crack tips. By means of Fourier transform, the problem can be solved with a pair of dual integral equations that the unknown variable is the jump of the displacement across the crack surfaces. These equations are solved with the Schmidt method and numerical examples are provided. Contrary to the previous results, it is found that no stress and electric displacement singularities are present at the crack tip. The finite hoop stress and the electric displacement depend on the crack length, the lattice parameter of the materials and the circle frequency of the incident waves. This enables us to employ the maximum stress hypothesis to deal with fracture problems in a natural way.展开更多
Free vibration response of functionally graded material (FGM) beams is studied based on the Levinson beam theory (LBT). Equations of motion of an FGM beam are derived by directly integrating the stress-form equati...Free vibration response of functionally graded material (FGM) beams is studied based on the Levinson beam theory (LBT). Equations of motion of an FGM beam are derived by directly integrating the stress-form equations of elasticity along the beam depth with the inertial resultant forces related to the included coupling and higherorder shear strain. Assuming harmonic response, governing equations of the free vibration of the FGM beam are reduced to a standard system of second-order ordinary differential equations associated with boundary conditions in terms of shape functions related to axial and transverse displacements and the rotational angle. By a shooting method to solve the two-point boundary value problem of the three coupled ordinary differential equations, free vibration response of thick FGM beams is obtained numerically. Particularly, for a beam with simply supported edges, the natural frequency of an FGM Levinson beam is analytically derived in terms of the natural frequency of a corresponding homogenous Euler-Bernoulli beam. As the material properties are assumed to vary through the depth according to the power-law functions, the numerical results of frequencies are presented to examine the effects of the material gradient parameter, the length-to-depth ratio, and the boundary conditions on the vibration response.展开更多
According to the basic idea of dual-complementarity,in a simple and unified way proposed by the author,some basic principles in dynamic theory of elastic materials with voids can be established sys- tematically.In thi...According to the basic idea of dual-complementarity,in a simple and unified way proposed by the author,some basic principles in dynamic theory of elastic materials with voids can be established sys- tematically.In this paper, an important integral relation in terms of convolutions is given,which can be con- sidered as the generalized principle of virtual work in mechanics.Based on this relation,it is possible not on- ly to obtain the principle of virtual work and the reciprocal theorem in dynamic theory of elastic materials with voids,but also to derive systematically the complementary functionals for the eight-field,six-field, four-field and two-field simplified Gurtin-type variational principles.Furthermore,with this approach,the in- trinsic relationship among various principles can be explained clearly.展开更多
Sulfur-containing polymer(SCP)is considered as an outstanding cathode material for lithium-sulfur batteries.However,undesirable soluble polysulfides may shuttle in electrolyte,concluding long-chain Li_(2)S_(n)(n>4)...Sulfur-containing polymer(SCP)is considered as an outstanding cathode material for lithium-sulfur batteries.However,undesirable soluble polysulfides may shuttle in electrolyte,concluding long-chain Li_(2)S_(n)(n>4)and short-chain Li2Sn(n≤4),as well as the sluggish conversion kinetics are yet to be solved to enhance the performance of lithium-sulfur batteries.Here Se-doped sulfurized polyaniline with adjusted sulfur-chain-S_(x)-(x≤6)contribute to ensure the absence of long-chain polysulfides,and the skeleton with quinoid imine can endow strongly adsorption towards short-chain polysulfides by the reversible transition between deprotonated/protonated imine(-NH^(+)=and-N=),which offer double insurance against suppressing“shuttle effect”.Furthermore,Se atoms are doped into sulfurized polysulfides to accelerate the redox conversion and take a frontier orbital theory-oriented view into catalytic mechanism.Se-doped sulfurized polyaniline as active materials for lithium-organosulfur batteries delivers good electrochemical performance,including high rate,reversible specific capacity(680 mA h g^(-1)at 0.1 A g^(-1)),and lower capacity decay rate only of 0.15%with near 100%coulomb efficiency during long-term cycle.This work provides a valuable guiding ideology and promising solution for the chemistry-oriented structure design and practical application for lithium-organosulfur batteries.展开更多
Rechargeable ion batteries require anode materials with excellent performance,presenting a key challenge for researchers.This paper explores the potential of using two-dimensional dumbbell silicene as an anode materia...Rechargeable ion batteries require anode materials with excellent performance,presenting a key challenge for researchers.This paper explores the potential of using two-dimensional dumbbell silicene as an anode material for alkali metal ion batteries through density functional theory(DFT)calculations.Our findings demonstrate that alkali metal ions have negative adsorption energies on dumbbell silicene,and the energy barriers for Li/Na/K ion diffusion are as low as0.032 e V/0.055 e V/0.21 e V,indicating that metal ions can easily diffuse across the entire surface of dumbbell silicene.Additionally,the average open circuit voltages of dumbbell silicene as anode for Li-ion,Na-ion,and K-ion batteries are 0.42 V,0.41 V,and 0.60 V,respectively,with corresponding storage capacities of 716 m Ah/g,622 m Ah/g,and 716 m Ah/g.These results suggest that dumbbell silicene is an ideal anode material for Li-ion,Na-ion,and K-ion batteries,with high capacity,low open circuit voltage,and high ion diffusion kinetics.Moreover,our calculations show that the theoretical capacities obtained using DFT-D2 are higher than those obtained using DFT-D3,providing a valuable reference for subsequent theoretical calculations.展开更多
Hydrogen is considered one of the most ideal future energy carriers.The safe storage and convenient transportation of hydrogen are key factors for the utilization of hydrogen energy.In the current investigation,two-di...Hydrogen is considered one of the most ideal future energy carriers.The safe storage and convenient transportation of hydrogen are key factors for the utilization of hydrogen energy.In the current investigation,two-dimensional vanadium carbide(VC) was prepared by an etching method using V_(4)AlC_(3) as a precursor and then employed to enhance the hydrogen storage properties of MgH_(2).The studied results indicate that VC-doped MgH_(2) can absorb hydrogen at room temperature and release hydrogen at 170℃. Moreover,it absorbs 5.0 wt.%of H_(2) within 9.8 min at 100℃ and desorbs 5.0 wt.% of H_(2) within 3.2 min at 300℃.The dehydrogenation apparent activation energy of VC-doped MgH_(2) is 89.3 ± 2.8 kJ/mol,which is far lower than that of additive-free MgH_(2)(138.5 ± 2.4 kJ/mol),respectively.Ab-initio simulations showed that VC can stretch Mg-H bonds and make the Mg-H bonds easier to break,which is responsible for the decrease of dehydrogenation temperature and conducive to accelerating the diffusion rate of hydrogen atoms,thus,the hydrogen storage properties of MgH_(2) are remarkable improved through addition of VC.展开更多
The N-NO2 bond dissociation energies (BDEs) for 7 energetic materials were computed by means of accurate density functional theory (B3LYP, B3PW91 and B3P86) with 6-31G** and 6-311G** basis sets. By comparing t...The N-NO2 bond dissociation energies (BDEs) for 7 energetic materials were computed by means of accurate density functional theory (B3LYP, B3PW91 and B3P86) with 6-31G** and 6-311G** basis sets. By comparing the computed energies and experimental results, we find that the B3P86/6-311G** method can give good results of BDE, which has the mean absolute deviation of 1.30kcal/mol. In addition, substituent effects were also taken into account. It is noted that the Hammett constants of substituent groups are related to the BDEs of the N-NO2 bond and the bond dissociation energies of the energetic materials studied decrease when increasing the number of NO2 group.展开更多
Pure,pseudo and semi membrane theories may sound similar but totally different theories as well as its behavior.The differences are more significant when it comes to hybrid anisotropic materials,namely laminated shell...Pure,pseudo and semi membrane theories may sound similar but totally different theories as well as its behavior.The differences are more significant when it comes to hybrid anisotropic materials,namely laminated shell wall thickness.The nomenclatures and classifications have been existed centuries for isotropic material shells since Donnell and Vlasov era.The methods of formulation of the theories are unique and never been used by others except by the authors.Governing differential equations are uniquely formulated for each theory by use of asymptotic expansion method which has never been used by others for isotropic or anisotropic materials.Longitudinal(L)and circumferential(Πor l)length scale were introduced during the course of asymptotic expansion method and the different theories among membrane theory are apparently classified.Characteristic behaviors of each theory are shown.展开更多
The signs of the electric field markers in Figs.2 and 4 of the paper[Chin.Phys.B 32104211(2023)]have been corrected.These modifications do not affect the results derived in the paper.
The multiple scattering theory has been a powerful tool in determining the effective properties of heterogeneous materials. In this paper , a simple relationship between the scattering theory and the micromechanics th...The multiple scattering theory has been a powerful tool in determining the effective properties of heterogeneous materials. In this paper , a simple relationship between the scattering theory and the micromechanics theory based on the Eshelby principle has been suggested. According to the relationship, a new and simple approximate solution to the exact multiple scattering theory has been given in terms of Eshelby' s S-tensor. The solution easily shows those known results for isotropic composites with spherical inclusions and for tracnsversely isotropic composites, and first gives non-setf-consistent (average t-matrix) and symmetric self-consistent (effective medium or coherent potential) approximate results for isotropic composites with spheroidal inclusions.展开更多
Three directions of development of kinetic indentation methods.Physical-energetic analysis of the indentation force diagram according to ISO 14577.Physical theory and universal criterion for the macrohardness of a mat...Three directions of development of kinetic indentation methods.Physical-energetic analysis of the indentation force diagram according to ISO 14577.Physical theory and universal criterion for the macrohardness of a material.Model of the physical process,thermomechanical potential,function of the state of the kinetic macroindentation process.Method for determining the physical function and unit of measurement of the kinetic macrohardness of a material.The ratio of the values of the empirical(standard)and physical macrohardness of the material.Physical reason for the appearance of the size effect in empirical indentation methods.The principle of determining the standard value of physical macrohardness.展开更多
A Donnell type theory is developed for finite deflection of closely stiffened truncated laminated composite conical shells under arbitrary loads by using the variational calculus and smeared-stiffener theory. The most...A Donnell type theory is developed for finite deflection of closely stiffened truncated laminated composite conical shells under arbitrary loads by using the variational calculus and smeared-stiffener theory. The most general bending-stretching coupling and the effect of eccentricity of stiffeners are considered. The equilibrium equations, boundary conditions and the equation of compatibility are derived. The new equations of the mixed-type of stiffened laminated composite conical shells are obtained in terms of the transverse deflection and stress function. The simplified equations are also given for some commonly encountered cases.展开更多
In this paper, the theory of materi als with elastic range by Lucchesi and Podio_Guidugli(1988) has been generalized . It has also shown that there are some difficulties on the definition of back s tress as the “cen...In this paper, the theory of materi als with elastic range by Lucchesi and Podio_Guidugli(1988) has been generalized . It has also shown that there are some difficulties on the definition of back s tress as the “center” of the yield surface in the Cauchy space. The back stres s tensor is Lagrangian,and must be defined in the Lagrangian stress space.展开更多
The theoretical calculation formulas for the plane strain fracture toughness of mode Ⅰand Ⅱcracks of ceramic materials are deduced in this paper by using the nonlocal elasticity theory and maximum tensile stress cri...The theoretical calculation formulas for the plane strain fracture toughness of mode Ⅰand Ⅱcracks of ceramic materials are deduced in this paper by using the nonlocal elasticity theory and maximum tensile stress criterion The deduced formulas, which are independent of crack geometry,bear a relation to material parameters.It is shown through experiment that the theoretical value of fracture toughness is the lower limit of testing value. The theoretical calculation formulas for fracture toughness relate the macro-mechanical performance of materials with the micro-structural parameters and,therefore, are beneficial to fully understanding the physical mechanism of material rupture.展开更多
文摘As the process of economic globalization continues to advance,China has undergone earth-shaking changes.High-quality products and promotional materials are crucial for Chinese companies to go global and build their brands.The English translation of external promotional materials is crucial.However,some companies do not pay enough attention to their publicity,resulting in a low international status.This paper analyzes the Chinese-English translation of enterprise external publicity materials from the perspective of adaptation theory,thereby exploring the translation strategies adopted under the guidance of adaptation theory,hoping to provide some references for related translation practices in the future.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.61888102,52272172,and 52102193)the Major Program of the National Natural Science Foundation of China(Grant No.92163206)+2 种基金the National Key Research and Development Program of China(Grant Nos.2021YFA1201501 and 2022YFA1204100)the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant No.XDB30000000)the Fundamental Research Funds for the Central Universities.
文摘Discovery of materials using“bottom-up”or“top-down”approach is of great interest in materials science.Layered materials consisting of two-dimensional(2D)building blocks provide a good platform to explore new materials in this respect.In van der Waals(vdW)layered materials,these building blocks are charge neutral and can be isolated from their bulk phase(top-down),but usually grow on substrate.In ionic layered materials,they are charged and usually cannot exist independently but can serve as motifs to construct new materials(bottom-up).In this paper,we introduce our recently constructed databases for 2D material-substrate interface(2DMSI),and 2D charged building blocks.For 2DMSI database,we systematically build a workflow to predict appropriate substrates and their geometries at substrates,and construct the 2DMSI database.For the 2D charged building block database,1208 entries from bulk material database are identified.Information of crystal structure,valence state,source,dimension and so on is provided for each entry with a json format.We also show its application in designing and searching for new functional layered materials.The 2DMSI database,building block database,and designed layered materials are available in Science Data Bank at https://doi.org/10.57760/sciencedb.j00113.00188.
文摘This study presents an analytical solution of thermal and mechanical displacements, strains, and stresses for a thick-walled rotating spherical pressure vessel made of functionally graded materials (FGMs). The pressure vessel is subject to axisymmetric mechanical and thermal loadings within a uniform magnetic field. The material properties of the FGM are considered as the power-law distribution along the thickness. Navier’s equation, which is a second-order ordinary differential equation, is derived from the mechanical equilibrium equation with the consideration of the thermal stresses and the Lorentz force resulting from the magnetic field. The distributions of the displacement, strains, and stresses are determined by the exact solution to Navier’s equation. Numerical results clarify the influence of the thermal loading, magnetic field, non-homogeneity constant, internal pressure, and angular velocity on the magneto-thermo-elastic response of the functionally graded spherical vessel. It is observed that these parameters have remarkable effects on the distributions of radial displacement, radial and circumferential strains, and radial and circumferential stresses.
基金supported by the National Natural Science Foundation of China,China(52203066,51973157,51673148 and 51678411)the Science and Technology Plans of Tianjin,China(19PTSYJC00010)+3 种基金China Postdoctoral Science Foundation Grant,China(2019M651047)the Tianjin Research Innovation Project for Postgraduate Students,China(2020YJSB062)the Tianjin Municipal College Student’Innovation And Entrepreneurship Training Program,China(202110058052)the National Innovation and Entrepreneurship Training Program for College Students,China(202110058017)。
文摘Non-renewable fossil fuels have led to serious problems such as global warming,environmental pollution,etc.Oxygen electrocatalysis including oxygen reduction reaction(ORR)and oxygen evolution reaction(OER)plays a central role in clean energy conversion,enabling a number of sustainable processes for future air battery technologies.Fluorine,as the most electronegative element(4.0)not only can induce more efficient regulation for the electronic structure,but also can bring more abundant defects and other novel effects in materials selection and preparation for favorable catalysis with respect to the other nonmetal elements.However,an individual and comprehensive overview of fluorine-containing functional materials for oxygen electrocatalysis field is still blank.Therefore,it is very meaningful to review the recent progresses of fluorine-containing oxygen electrocatalysts.In this review,we first systematically summarize the controllable preparation methods and their possible development directions based on fluorine-containing materials from four preparation methods.Due to the strong electron-withdrawing properties of fluorine,its control of the electronic structure can effectively enhance the oxygen electrocatalytic activity of the materials.In addition,the catalytic enhancement effect of fluorine on carbonbased materials also includes the prevent oxidation and the layer peeling,and realizes the precise atomic control.And the catalytic improvement mechanism of fluorine containing metal-based compounds also includes the hydration of metal site,the crystal transformation,and the oxygen vacancy induction.Then,based on their various dimensions(0D–3D),we also have summarized the advantages of different morphologies on oxygen electrocatalytic performances.Finally,the prospects and possible future researching direction of F-containing oxygen electrocatalysts are presented(e.g.,novel pathways,advanced methods for measurement and simulation,field assistance and multi-functions).The review is considered valuable and helpful in exploring the novel designs and mechanism analyses of advanced fluorine-containing electrocatalysts.
基金supported by the National Natural Science Foundation of China (Grants 51528501, 11532009)the Fundamental Research Funds for Central Universities (Grant 2014qngz12)supported by China Scholarship Council as a visiting scholar to Harvard University
文摘Acoustic wave propagation from surrounding medium into a soft material can generate acoustic radiation stress due to acoustic momentum transfer inside the medium and material, as well as at the interface between the two. To analyze acoustic-induced deformation of soft materials, we establish an acoustomechanical constitutive theory by combining the acoustic radiation stress theory and the nonlinear elasticity theory for soft materials. The acoustic radiation stress tensor is formulated by time averaging the momentum equation of particle motion, which is then introduced into the nonlinear elasticity constitutive relation to construct the acoustomechanical constitutive theory for soft materials.Considering a specified case of soft material sheet subjected to two counter-propagating acoustic waves, we demonstrate the nonlinear large deformation of the soft material and analyze the interaction between acoustic waves and material deformation under the conditions of total reflection, acoustic transparency, and acoustic mismatch.
基金The project supported by the National Natural Science Foundation of China
文摘According to the basic idea of dual-complementarity, in a simple and unified way proposed by the author, various energy principles in theory of elastic materials with voids can be established systematically, In this paper, an important integral relation is given, which can be considered essentially as the generalized pr- inciple of virtual work. Based on this relation, it is possible not only to obtain the principle of virtual work and the reciprocal theorem of work in theory of elastic materials with voids, but also to derive systematically the complementary functionals for the eight-field, six-field, four-field and two-field generalized variational principles, and the principle of minimum potential and complementary energies. Furthermore, with this appro ach, the intrinsic relationship among various principles can be explained clearly.
文摘The dynamic behavior of a Griffith permeable crack under harmonic anti-plane shear waves in the piezoelectric materials is investigated by use of the non-local theory. To overcome the mathematical difficulties, a one-dimensional non-local kernel is used instead of a two-dimensional one for the anti-plane dynamic problem to obtain the stress and the electric displacement near the crack tips. By means of Fourier transform, the problem can be solved with a pair of dual integral equations that the unknown variable is the jump of the displacement across the crack surfaces. These equations are solved with the Schmidt method and numerical examples are provided. Contrary to the previous results, it is found that no stress and electric displacement singularities are present at the crack tip. The finite hoop stress and the electric displacement depend on the crack length, the lattice parameter of the materials and the circle frequency of the incident waves. This enables us to employ the maximum stress hypothesis to deal with fracture problems in a natural way.
基金supported by the National Natural Science Foundation of China(No.11272278)
文摘Free vibration response of functionally graded material (FGM) beams is studied based on the Levinson beam theory (LBT). Equations of motion of an FGM beam are derived by directly integrating the stress-form equations of elasticity along the beam depth with the inertial resultant forces related to the included coupling and higherorder shear strain. Assuming harmonic response, governing equations of the free vibration of the FGM beam are reduced to a standard system of second-order ordinary differential equations associated with boundary conditions in terms of shape functions related to axial and transverse displacements and the rotational angle. By a shooting method to solve the two-point boundary value problem of the three coupled ordinary differential equations, free vibration response of thick FGM beams is obtained numerically. Particularly, for a beam with simply supported edges, the natural frequency of an FGM Levinson beam is analytically derived in terms of the natural frequency of a corresponding homogenous Euler-Bernoulli beam. As the material properties are assumed to vary through the depth according to the power-law functions, the numerical results of frequencies are presented to examine the effects of the material gradient parameter, the length-to-depth ratio, and the boundary conditions on the vibration response.
基金The project supported by the Foundation of Zhongshan University Advanced Research Center
文摘According to the basic idea of dual-complementarity,in a simple and unified way proposed by the author,some basic principles in dynamic theory of elastic materials with voids can be established sys- tematically.In this paper, an important integral relation in terms of convolutions is given,which can be con- sidered as the generalized principle of virtual work in mechanics.Based on this relation,it is possible not on- ly to obtain the principle of virtual work and the reciprocal theorem in dynamic theory of elastic materials with voids,but also to derive systematically the complementary functionals for the eight-field,six-field, four-field and two-field simplified Gurtin-type variational principles.Furthermore,with this approach,the in- trinsic relationship among various principles can be explained clearly.
基金partly supported by the National Natural Science Foundation of China(51763014 and 52073133)the Key Talent Project Foundation of Gansu Province+3 种基金Joint fund between Shenyang National Laboratory for Materials Science and State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals(18LHPY002)the Incubation Program of Excellent Doctoral Dissertation-Lanzhou University of Technologyexcellent doctoral Program of Gansu Province(22JR5RA240)the Program for Hongliu Distinguished Young Scholars in Lanzhou University of Technology。
文摘Sulfur-containing polymer(SCP)is considered as an outstanding cathode material for lithium-sulfur batteries.However,undesirable soluble polysulfides may shuttle in electrolyte,concluding long-chain Li_(2)S_(n)(n>4)and short-chain Li2Sn(n≤4),as well as the sluggish conversion kinetics are yet to be solved to enhance the performance of lithium-sulfur batteries.Here Se-doped sulfurized polyaniline with adjusted sulfur-chain-S_(x)-(x≤6)contribute to ensure the absence of long-chain polysulfides,and the skeleton with quinoid imine can endow strongly adsorption towards short-chain polysulfides by the reversible transition between deprotonated/protonated imine(-NH^(+)=and-N=),which offer double insurance against suppressing“shuttle effect”.Furthermore,Se atoms are doped into sulfurized polysulfides to accelerate the redox conversion and take a frontier orbital theory-oriented view into catalytic mechanism.Se-doped sulfurized polyaniline as active materials for lithium-organosulfur batteries delivers good electrochemical performance,including high rate,reversible specific capacity(680 mA h g^(-1)at 0.1 A g^(-1)),and lower capacity decay rate only of 0.15%with near 100%coulomb efficiency during long-term cycle.This work provides a valuable guiding ideology and promising solution for the chemistry-oriented structure design and practical application for lithium-organosulfur batteries.
基金the National Natural Science Foundation of China(Grant No.12274112)the Overseas Scientists Sponsorship Program of Hebei Province of China(Grant No.C20210330)the State Key Laboratory of Reliability and Intelligence of Electrical Equipment of Hebei University of Technology(Grant No.EERI PI2020009)。
文摘Rechargeable ion batteries require anode materials with excellent performance,presenting a key challenge for researchers.This paper explores the potential of using two-dimensional dumbbell silicene as an anode material for alkali metal ion batteries through density functional theory(DFT)calculations.Our findings demonstrate that alkali metal ions have negative adsorption energies on dumbbell silicene,and the energy barriers for Li/Na/K ion diffusion are as low as0.032 e V/0.055 e V/0.21 e V,indicating that metal ions can easily diffuse across the entire surface of dumbbell silicene.Additionally,the average open circuit voltages of dumbbell silicene as anode for Li-ion,Na-ion,and K-ion batteries are 0.42 V,0.41 V,and 0.60 V,respectively,with corresponding storage capacities of 716 m Ah/g,622 m Ah/g,and 716 m Ah/g.These results suggest that dumbbell silicene is an ideal anode material for Li-ion,Na-ion,and K-ion batteries,with high capacity,low open circuit voltage,and high ion diffusion kinetics.Moreover,our calculations show that the theoretical capacities obtained using DFT-D2 are higher than those obtained using DFT-D3,providing a valuable reference for subsequent theoretical calculations.
基金supported by the National Natural Science Foundation of China (Grant Nos.52261038 and 51861002)the Natural Science Foundation of Guangxi Province (Grant No.2018GXNSFAA294125)+1 种基金the Innovation-driven Development Foundation of Guangxi Province (Grant No.AA17204063)support by the Ministry of Science and Higher Education of the Russian Federation in the framework of the Increase Competitiveness Program of NUST "MISiS" (grant number K2-2020-046)。
文摘Hydrogen is considered one of the most ideal future energy carriers.The safe storage and convenient transportation of hydrogen are key factors for the utilization of hydrogen energy.In the current investigation,two-dimensional vanadium carbide(VC) was prepared by an etching method using V_(4)AlC_(3) as a precursor and then employed to enhance the hydrogen storage properties of MgH_(2).The studied results indicate that VC-doped MgH_(2) can absorb hydrogen at room temperature and release hydrogen at 170℃. Moreover,it absorbs 5.0 wt.%of H_(2) within 9.8 min at 100℃ and desorbs 5.0 wt.% of H_(2) within 3.2 min at 300℃.The dehydrogenation apparent activation energy of VC-doped MgH_(2) is 89.3 ± 2.8 kJ/mol,which is far lower than that of additive-free MgH_(2)(138.5 ± 2.4 kJ/mol),respectively.Ab-initio simulations showed that VC can stretch Mg-H bonds and make the Mg-H bonds easier to break,which is responsible for the decrease of dehydrogenation temperature and conducive to accelerating the diffusion rate of hydrogen atoms,thus,the hydrogen storage properties of MgH_(2) are remarkable improved through addition of VC.
基金The project was supported by the National Natural Science Foundation of China (No. 10774039)
文摘The N-NO2 bond dissociation energies (BDEs) for 7 energetic materials were computed by means of accurate density functional theory (B3LYP, B3PW91 and B3P86) with 6-31G** and 6-311G** basis sets. By comparing the computed energies and experimental results, we find that the B3P86/6-311G** method can give good results of BDE, which has the mean absolute deviation of 1.30kcal/mol. In addition, substituent effects were also taken into account. It is noted that the Hammett constants of substituent groups are related to the BDEs of the N-NO2 bond and the bond dissociation energies of the energetic materials studied decrease when increasing the number of NO2 group.
文摘Pure,pseudo and semi membrane theories may sound similar but totally different theories as well as its behavior.The differences are more significant when it comes to hybrid anisotropic materials,namely laminated shell wall thickness.The nomenclatures and classifications have been existed centuries for isotropic material shells since Donnell and Vlasov era.The methods of formulation of the theories are unique and never been used by others except by the authors.Governing differential equations are uniquely formulated for each theory by use of asymptotic expansion method which has never been used by others for isotropic or anisotropic materials.Longitudinal(L)and circumferential(Πor l)length scale were introduced during the course of asymptotic expansion method and the different theories among membrane theory are apparently classified.Characteristic behaviors of each theory are shown.
文摘The signs of the electric field markers in Figs.2 and 4 of the paper[Chin.Phys.B 32104211(2023)]have been corrected.These modifications do not affect the results derived in the paper.
基金This work was supported by the National H-Tech Program under contract No.863-7152101
文摘The multiple scattering theory has been a powerful tool in determining the effective properties of heterogeneous materials. In this paper , a simple relationship between the scattering theory and the micromechanics theory based on the Eshelby principle has been suggested. According to the relationship, a new and simple approximate solution to the exact multiple scattering theory has been given in terms of Eshelby' s S-tensor. The solution easily shows those known results for isotropic composites with spherical inclusions and for tracnsversely isotropic composites, and first gives non-setf-consistent (average t-matrix) and symmetric self-consistent (effective medium or coherent potential) approximate results for isotropic composites with spheroidal inclusions.
文摘Three directions of development of kinetic indentation methods.Physical-energetic analysis of the indentation force diagram according to ISO 14577.Physical theory and universal criterion for the macrohardness of a material.Model of the physical process,thermomechanical potential,function of the state of the kinetic macroindentation process.Method for determining the physical function and unit of measurement of the kinetic macrohardness of a material.The ratio of the values of the empirical(standard)and physical macrohardness of the material.Physical reason for the appearance of the size effect in empirical indentation methods.The principle of determining the standard value of physical macrohardness.
文摘A Donnell type theory is developed for finite deflection of closely stiffened truncated laminated composite conical shells under arbitrary loads by using the variational calculus and smeared-stiffener theory. The most general bending-stretching coupling and the effect of eccentricity of stiffeners are considered. The equilibrium equations, boundary conditions and the equation of compatibility are derived. The new equations of the mixed-type of stiffened laminated composite conical shells are obtained in terms of the transverse deflection and stress function. The simplified equations are also given for some commonly encountered cases.
文摘In this paper, the theory of materi als with elastic range by Lucchesi and Podio_Guidugli(1988) has been generalized . It has also shown that there are some difficulties on the definition of back s tress as the “center” of the yield surface in the Cauchy space. The back stres s tensor is Lagrangian,and must be defined in the Lagrangian stress space.
文摘The theoretical calculation formulas for the plane strain fracture toughness of mode Ⅰand Ⅱcracks of ceramic materials are deduced in this paper by using the nonlocal elasticity theory and maximum tensile stress criterion The deduced formulas, which are independent of crack geometry,bear a relation to material parameters.It is shown through experiment that the theoretical value of fracture toughness is the lower limit of testing value. The theoretical calculation formulas for fracture toughness relate the macro-mechanical performance of materials with the micro-structural parameters and,therefore, are beneficial to fully understanding the physical mechanism of material rupture.