Mixed matrix hollow fiber membranes（MMHFMs）filled with metal-organic frameworks（MOFs）have great potential for energy-efficient gas separation processes,but the major hurdle is polymer/MOFs interfacial defects and ...Mixed matrix hollow fiber membranes（MMHFMs）filled with metal-organic frameworks（MOFs）have great potential for energy-efficient gas separation processes,but the major hurdle is polymer/MOFs interfacial defects and membrane plasticization.Herein,lab-synthesized MIL-53 was post-functionalized by aminosilane grafting and subsequently incorporated into Ultem-1000 polymer matrix to fabricate high performance MMHFMs.SEM,DLS,XRD and TGA were performed to characterize silane-modified MIL-53（S-MIL-53）and prepared MMHFMs.Moreover,the effect of MOFs loading was systematically investigated first;then gas separation performance of MMHFMs for pure and mixed gas was evaluated under different pressures.MMHFMs containing post-functionalized S-MIL-53 achieved remarkable gas permeation properties which was better than model predictions.Compared to pure HFMs,CO2permeance of MMHFM loaded with 15%S-MIL-53 increased by 157%accompanying with 40%increase for CO2/N2selectivity,which outperformed the MMHFM filled with naked MIL-53.The pure and mixed gas permeation measurements with elevated feed pressure indicated that incorporation of S-MIL-53 also increased the resistance against CO2plasticization.This work reveals that post-modified MOFs embedded in MMHFMs facilitate the improvement of gas separation performance and suppression of membrane plasticization.展开更多
This article presents a new method to obtain local reinforcement in near-surface layers of channels in castings made of a particle-reinforced metal matrix composite in the alternating electromagnetic field generated b...This article presents a new method to obtain local reinforcement in near-surface layers of channels in castings made of a particle-reinforced metal matrix composite in the alternating electromagnetic field generated by an inductor placed inside the channel. In centrifugal casting, the centrifugal force on the particles leads to the formation of composite structures, while in the proposed method, the electromag- netic force field on the particles results in the designed structure of the composite casting. The article reports the experimental verification of this method using an aluminium sleeve reinforced locally with SiC particles at the inner wall.展开更多
基金the financial support from the National Natural Science Foundation of China(No.21436009)
文摘Mixed matrix hollow fiber membranes（MMHFMs）filled with metal-organic frameworks（MOFs）have great potential for energy-efficient gas separation processes,but the major hurdle is polymer/MOFs interfacial defects and membrane plasticization.Herein,lab-synthesized MIL-53 was post-functionalized by aminosilane grafting and subsequently incorporated into Ultem-1000 polymer matrix to fabricate high performance MMHFMs.SEM,DLS,XRD and TGA were performed to characterize silane-modified MIL-53（S-MIL-53）and prepared MMHFMs.Moreover,the effect of MOFs loading was systematically investigated first;then gas separation performance of MMHFMs for pure and mixed gas was evaluated under different pressures.MMHFMs containing post-functionalized S-MIL-53 achieved remarkable gas permeation properties which was better than model predictions.Compared to pure HFMs,CO2permeance of MMHFM loaded with 15%S-MIL-53 increased by 157%accompanying with 40%increase for CO2/N2selectivity,which outperformed the MMHFM filled with naked MIL-53.The pure and mixed gas permeation measurements with elevated feed pressure indicated that incorporation of S-MIL-53 also increased the resistance against CO2plasticization.This work reveals that post-modified MOFs embedded in MMHFMs facilitate the improvement of gas separation performance and suppression of membrane plasticization.
基金supported by the National Science Centre of Poland (Grant No. N508 620940)
文摘This article presents a new method to obtain local reinforcement in near-surface layers of channels in castings made of a particle-reinforced metal matrix composite in the alternating electromagnetic field generated by an inductor placed inside the channel. In centrifugal casting, the centrifugal force on the particles leads to the formation of composite structures, while in the proposed method, the electromag- netic force field on the particles results in the designed structure of the composite casting. The article reports the experimental verification of this method using an aluminium sleeve reinforced locally with SiC particles at the inner wall.
