The composites were prepared by modifying silicon carbide fiber with particles of zirconium carbide(ZrC)and boron carbide(B_(4)C)and incorporating them into a phenolic resin matrix.The influence of ZrC and B_(4)C on t...The composites were prepared by modifying silicon carbide fiber with particles of zirconium carbide(ZrC)and boron carbide(B_(4)C)and incorporating them into a phenolic resin matrix.The influence of ZrC and B_(4)C on the mechanical performance of SiCf/phenolic composites after high-temperature pyrolysis was studied through flexural performance test.The results show that the composite material has good thermal stability and high-temperature mechanical properties.After static ablation at 1400℃ for 15 minutes,the flexural strength of the composite material reaches 286 MPa,which is still 7.3%higher than at room temperature,indicating that the composite material still has good mechanical properties even after heat treatment at 1400℃.展开更多
In this paper,the influence of NaCl freeze-thaw(F-T)cycles and dry-wet(D-W)alternations on theflexural,com-pressive and bonding strengths of alkali-activatedfly ash(FA)and a blast furnace slag powder(BFS)is investi-gated...In this paper,the influence of NaCl freeze-thaw(F-T)cycles and dry-wet(D-W)alternations on theflexural,com-pressive and bonding strengths of alkali-activatedfly ash(FA)and a blast furnace slag powder(BFS)is investi-gated.The considered NaCl concentration is 3%.The effect of polypropylenefibers on the mechanical strengths is also examined.Scanning electron microscopy(SEM),thermogravimetry(TG)and X-ray diffraction(XRD)are selected to discern the mechanisms underpinning the NaCl-induced erosion.The obtained results indicate that the best results in terms of material resistance are obtained with admixtures containing 60%BFS and 40%FA in terms of mass ratio and 3%polypropylenefibers in terms of volume ratio.The maximum rates of decrease of theflexural,compressive and bonding strengths after 300 NaCl F-T cycles are 21.5%,20.3%and 22.6%,respec-tively.The corresponding rates of decrease due to NaCl D-W alternations are 28.1%,26.1%and 31.5%,respec-tively.The TG curves show that the alkali-activating activity of BFS is higher than that of FA.Moreover,in thefirst case,the microstructure of the hydration products is more compact.The results also show that NaCl F-T cycles lead to increasing cracks in the alkali-activated BFS.展开更多
In the induction heating of airport pavement to remove snow and ice,soft magnetic geopolymer composite(SMGC)can be used to gather the dissipated electromagnetic energy,thus enhancing the energy utilization efficiency....In the induction heating of airport pavement to remove snow and ice,soft magnetic geopolymer composite(SMGC)can be used to gather the dissipated electromagnetic energy,thus enhancing the energy utilization efficiency.The aim of this work is to analyze the influence mechanism of iron powder content on the electromagnetic and mechanical performance of SMGC,so as to provide theoretical guidance for the design of soft magnetic layer within airport pavement structure.The results show that the increase of iron powder content reduces the resistance and magnetoresistance of SMGC by decreasing the content of non-magnetic phases between iron powder.However,the reduction of iron powder spacing also provides a shorter transmission path for the inter-particle eddy currents in the SMGC specimen,which enhances the exchange coupling between iron powder,thus increasing the electromagnetic loss.Therefore,the compatibility between magnetic permeability and electromagnetic loss should be considered comprehensively in the mix design of SMGC.In addition,although iron powder can enhance the mechanical properties of SMGC by improving the density of geopolymer matrix,the excessive amount of iron powder can lead to a weak interfacial transition zone between geopolymer matrix and iron powder.According to the induction heating results,optimized SMGC can improve the energy transfer efficiency of induction heating by 24.03%.展开更多
Rare earth -containing PSBR sheet was prepared by reaction of rare earth alkoxide with quaternary ammonium salt of pyridine modified SBR (PSBR) latex, and then it was blended with natural rubber (NR) to produce rare e...Rare earth -containing PSBR sheet was prepared by reaction of rare earth alkoxide with quaternary ammonium salt of pyridine modified SBR (PSBR) latex, and then it was blended with natural rubber (NR) to produce rare earth - containing composite elastomer. It is found that mechanical performance can be improved remarkably. Analyzed by infrared spectrometry (IR), differential scanning calorimetry (DSC) and cross-linking densitometry, the relationship between structure and performance was discussed.展开更多
The aim of this study is to provide the quantificational change laws of strength,stiffness,and deformation capacity of frost-damaged concrete relating to a united index,the data were obtained by different researchers....The aim of this study is to provide the quantificational change laws of strength,stiffness,and deformation capacity of frost-damaged concrete relating to a united index,the data were obtained by different researchers.Then the index of relative compressive strength(RCS) was introduced as the indicator of frost damage and a large number of mechanical performance testing data of frost-damaged concrete were collected and analyzed.By curve fitting,the correlations between RCS and the initial elastic modulus,the strain at peak compressive stress,and biaxial compressive strength,and tensile strength,and the strain at peak tensile stress were established.Thereafter,the analytical stress-strain response of frost-damaged concrete under monotonic loading was presented using RCS and compared with that of the experimental data.Moreover,an isotropic elastoplastic damage model of frost-damaged concrete subjected to repeated loading was established.Finally,we can systematically estimate the effects of frost-damage on the mechanical performance of concrete,which can be provided for the numerical simulation of frost-damaged concrete structures.展开更多
Nitrogen doped diamond-like carbon (DLC:N) films were prepared by electron cyclotron resonance chemical vapor deposition (ECR-CVD) on polycrystalline Si chips. Film thickness is about 50 nm. Auger electron spectr...Nitrogen doped diamond-like carbon (DLC:N) films were prepared by electron cyclotron resonance chemical vapor deposition (ECR-CVD) on polycrystalline Si chips. Film thickness is about 50 nm. Auger electron spectroscopy (AES) was used to evaluate nitrogen content, and increasing N2 flow improved N content from 0 to 7.6%. Raman and X-ray photoelectron spectroscopy (XPS) analysis results reveal CN-sp^3C and N-sp^2C structure. With increasing the N2 flow, sp^3C decreases from 73.74% down to 42.66%, and so does N-sp^3C from 68.04% down to 20.23%. The hardness decreases from 29.18 GPa down to 19.74 GPa, and the Young's modulus from 193.03 GPa down to 144.52 GPa.展开更多
On the basis of test, nonlinear finite element analysis of reinforcedconcrete (R. C) short-limb shear walls under monotonic horizontal load are carried out by ANSYSprogram in order to understand the evolution of crack...On the basis of test, nonlinear finite element analysis of reinforcedconcrete (R. C) short-limb shear walls under monotonic horizontal load are carried out by ANSYSprogram in order to understand the evolution of cracking, deformation and failure course of thespecimens. At the same time, the results of numerical calculation are compared with the results oftest. The results indicate that, under monotonic horizontal load the failures of the specimens withflange wall and without flange wall all occur at the intersections of lintel bottom and limb ofwall, the failures also occur at the bottom of limb; the load-displacement curve of wall withoutflange is steeper than that of wall with flange, and the ductility is worse than that of wall withflange; the results, such as cracking, deformation, yield load and so on of finite element analysisagree well with the results of test. These results provide theoretical basis of study andapplication of R. C short-limb shear wall.展开更多
Motivated by the huge practical engineering demand for the fundamental understanding of mechanical characteristics of high-speed railway infrastructure,a fullscale multi-functional test platform for high-speed railway...Motivated by the huge practical engineering demand for the fundamental understanding of mechanical characteristics of high-speed railway infrastructure,a fullscale multi-functional test platform for high-speed railway track–subgrade system is developed in this paper,and its main functions for investigating the mechanical performance of track–subgrade systems are elaborated with three typical experimental examples.Comprising the full-scale subgrade structure and all the five types of track structures adopted in Chinese high-speed railways,namely the CRTS I,the CRTS II and the CRTS III ballastless tracks,the double-block ballastless track and the ballasted track,the test platform is established strictly according to the construction standard of Chinese high-speed railways.Three kinds of effective loading methods are employed,including the real bogie loading,multi-point loading and the impact loading.Various types of sensors are adopted in different components of the five types of track–subgrade systems to measure the displacement,acceleration,pressure,structural strain and deformation,etc.Utilizing this test platform,both dynamic characteristics and long-term performance evolution of high-speed railway track–subgrade systems can be investigated,being able to satisfy the actual demand for large-scale operation of Chinese high-speed railways.As examples,three typical experimental studies are presented to elucidate the comprehensive functionalities of the full-scale multi-functional test platform for exploring the dynamic performance and its long-term evolution of ballastless track systems and for studying the long-term accumulative settlement of the ballasted track–subgrade system in high-speed railways.Some interesting phenomena and meaningful results are captured by the developed test platform,which provide a useful guidance for the scientific operation and maintenance of high-speed railway infrastructure.展开更多
In order to explore the effect of high-temperature annealing on the mechanical performances and microstructures of different oxygen SiC fibers, two types of silicon carbide(SiC)-based fibers, specified as XD-SiC fib...In order to explore the effect of high-temperature annealing on the mechanical performances and microstructures of different oxygen SiC fibers, two types of silicon carbide(SiC)-based fibers, specified as XD-SiC fibers(low oxygen) and Nicalon-201 fibers(high oxygen), were annealed in Ar for 1 h at 800 ℃, 1 000 and 1 200 ℃, respectively. Mechanical properties of these fibers were characterized via a monofilament tensile method, with observation of the damaged monofilament by SEM. Also, the effects of annealing on the microstructure and chemical compositions of the fibers were studied. The experimental results indicated that the tensile strength decreased with the increase of annealing temperatures,after annealing-treatment at 1200℃, XD-SiC fibers remained 84% of its original strength, while Nicalon-201 fibers remained only 58% of its original strength. Crystallization and chemical composition of the fibers are the dominating factors for their mechanical performance at high temperatures. The microstructure changes of XD-SiC fibers are mainly composed of the growth of β-SiC, for Nicalon-201 fibers, evaporation of gases is the main change for microstructure.展开更多
Developing free-standing and mechanical robust membrane materials capable of superior enrichment of phosphopeptides for analyzing and identifying the specific phosphoproteome of cancer cells is significant in understa...Developing free-standing and mechanical robust membrane materials capable of superior enrichment of phosphopeptides for analyzing and identifying the specific phosphoproteome of cancer cells is significant in understanding the molecular mechanisms of cancer development and exploring new therapeutic approaches,but still a significant challenge in materials design.To this end,we firstly constructed highly flexible ZrTiO_(4) nanofibrous membranes(NFMs)with excellent mechanical stability through a cost-effective and scalable electrospinning and subsequent calcination technique.Then,to further increase the enrichment capacity of the phosphopeptide,the biomimetic TiO_(2)@ZrTiO_(4) NFMs with root hair or leaf like branch microstructure are developed by the hydrothermal post-synthetic modification of ZrTiO_(4) NFMs through growing unfurling TiO_(2) nanosheets onto the ZrTiO_(4) nanofibers.Importantly,remarkable flexibility and mechanical stability enable the resulting TiO_(2)@ZrTiO_(4) NFMs excellent practicability,while the biomimetic microstructure allows it outstanding enrichment ability of the phosphopeptide and identification ability of the specific phosphoproteins in the digest of cervical cancer cells.Specifically,6770 phosphopeptides can be enriched by TiO_(2)@ZrTiO_(4) NFMs(2205 corresponding phosphoproteins can be identified),and the value is much higher than that of ZrTiO_(4) NFMs(6399 phosphopeptides and 2132 identified phosphoproteins)and commercial high-performance TiO_(2) particles(4525 phosphopeptides and 1811 identified phosphoproteins).These results demonstrate the super ability of TiO_(2)@ZrTiO_(4) NFMs in phosphopeptide enrichment and great potential for exploring the pathogenesis of cancer.展开更多
Numerous studies showed that synthetic fibers are effective for reinforcing the mechanical performance of the asphalt mixture due to their high strength properties,ductility,and durability characteristics.In this pape...Numerous studies showed that synthetic fibers are effective for reinforcing the mechanical performance of the asphalt mixture due to their high strength properties,ductility,and durability characteristics.In this paper,the objective is to present a review of the reinforcement effect of synthetic fiber on the mechanical performance of the asphalt mixture.This paper reviews the relevant literature on the characterizations and applications of synthetic fibers to improve different mechanical properties of asphalt mixes,which can provide a reference for the applications and development of synthetic fibers in asphalt pavement.The characteristics of common synthetic fibers are introduced and the utilization of synthetic fibers in asphalt mixture is discussed.Different surface treatment methods for fiber are reviewed and it is found that surface treatment can improve the performance of the synthetic fibers in asphalt mixtures,especially the chemical surface treatment method.The influence of synthetic fiber addition on the mechanical properties of the asphalt concrete such as rutting resistance,tensile strength,water stability performance,and cracking resistance are then discussed.The research results show that aramid,glass,and polyester fibers improve the fatigue cracking resistance of asphalt mixture.Polyester fibers,polyamide fibers,and carbon fibers are used to improve resistance to the permanent deformation of asphalt pavement.展开更多
The present article is aimed to detect material-intrinsic indices that can be used to supervise the mechanical performance of general solid matter.The novelty carried in this article can be summarised as follows.First...The present article is aimed to detect material-intrinsic indices that can be used to supervise the mechanical performance of general solid matter.The novelty carried in this article can be summarised as follows.Firstly,an inelastic deformation state of almost any solid matter can be treated as the combination of two fundamental modes due to different microscopic causation:Mode I inelastic distortion due to the movement of sliding types of defects and Mode II inelastic dilation due to the evolution of voids/bubbles.Secondly,each inelastic deformation mode is characterised by a single principal inelastic deformation descriptor(PIDD):Mode I by a newly introduced quantity of maximum distortional angle changeαand Mode II by the logarithm of dilating magnificationω.In particular,the concept of maximum distortional angle change gives rise to a geometrically intuitive yield criterion ofα>α_(c),which in situations of small deformation,is shown to asymptote von Mise's,and to become Tresca's in cases of plane stress.Thirdly,the deformation process of a solid matter under monotonic and ambient loads is formulated by means of trajectories of thermodynamic equilibria with respect to the PIDD pair.Then a pair of physical quantities which measure the stresses needed to change the local PIDD state are singled out.Being termed as inelastic deformation resistances(IDRs),these two quantities are shown to depend only on the onsite atomic configurations.It is also shown that key descriptive properties about the mechanical behaviours of materials,such as ductility,are encoded in IDRs as functions of PIDDs.Hence the IDR pair may serve as material performance indices that may be more intrinsic than conventional stress-strain relationships.展开更多
Magnesium(Mg)alloys are considered to be a new generation of revolutionary medical metals.Laser-beam powder bed fusion(PBF-LB)is suitable for fabricating metal implants withpersonalized and complicated structures.Howe...Magnesium(Mg)alloys are considered to be a new generation of revolutionary medical metals.Laser-beam powder bed fusion(PBF-LB)is suitable for fabricating metal implants withpersonalized and complicated structures.However,the as-built part usually exhibits undesirable microstructure and unsatisfactory performance.In this work,WE43 parts were firstly fabricated by PBF-LB and then subjected to heat treatment.Although a high densification rate of 99.91%was achieved using suitable processes,the as-built parts exhibited anisotropic and layeredmicrostructure with heterogeneously precipitated Nd-rich intermetallic.After heat treatment,fine and nano-scaled Mg24Y5particles were precipitated.Meanwhile,theα-Mg grainsunderwent recrystallization and turned coarsened slightly,which effectively weakened thetexture intensity and reduced the anisotropy.As a consequence,the yield strength and ultimate tensile strength were significantly improved to(250.2±3.5)MPa and(312±3.7)MPa,respectively,while the elongation was still maintained at a high level of 15.2%.Furthermore,the homogenized microstructure reduced the tendency of localized corrosion and favoredthe development of uniform passivation film.Thus,the degradation rate of WE43 parts was decreased by an order of magnitude.Besides,in-vitro cell experiments proved their favorable biocompatibility.展开更多
New research and development(R&D)institutions are an important part of the national innovation system,playing an important role in promoting the transformation of scientific and technological achievements.In recen...New research and development(R&D)institutions are an important part of the national innovation system,playing an important role in promoting the transformation of scientific and technological achievements.In recent years,new R&D institutions have gradually become the driving force of innovation-driven development in China.Taking new R&D institutions in Zhejiang Province as the research object,this paper studies the internal talent training path and performance evaluation mechanism of new R&D institutions in Zhejiang Province by using the literature research method,comparison method,case verification method,and other methods.The investigation results show that there are problems such as lack of material and spiritual support and neglect of the absorption of local talents in the internal talent training,and there are problems such as unclear standards,insufficient data,and opaque processes in the performance evaluation mechanism,which greatly affect the establishment and improvement of the performance evaluation mechanism.Given the above problems,this paper puts forward a forward-looking,oriented,flexible,and compatible talent training path and performance evaluation mechanism,hoping to optimize the effective internal talent training path of new R&D institutions,improve the evaluation performance,and promote healthy development of new R&D institutions in Zhejiang Province.展开更多
Solid-state diffusion bonding(DB)of TiAl alloy and Ti2 AlNb alloy was carried out using pure Ti as an interlayer at 1000℃under 20 MPa for 60-120 min.The effects of bonding times on the interfacial microstructure and ...Solid-state diffusion bonding(DB)of TiAl alloy and Ti2 AlNb alloy was carried out using pure Ti as an interlayer at 1000℃under 20 MPa for 60-120 min.The effects of bonding times on the interfacial microstructure and mechanical performance of the TiAl/Ti/Ti_(2)AlNb bonded joints at room temperature(RT)were investigated detailly.The results demonstrated that the diffusion layers(DLs)mainly consisted of four characteristic layers,(Ⅰ)single coarseα_(2)phase adjacent TiAl alloy,(Ⅱ)single refinedα_(2)phase at the bonding interface,(Ⅲ)equiaxed/acicularα_(2)phase embedded inβphase adjacent Ti_(2)AtNb alloy and(IV)both equiaxedα_(2)phase and acicular O phase embedded inβphase adj acent Ti_(2)AlNb alloy,respectively.The thickness of the four layers increased with the increasing of the bonding time.The growth of DLs is controlled by diffusion and the reaction rate constant k for regionⅠ,Ⅱ,ⅢandⅣare 1.22×10^(-6),1.27×10^(-6),2.6×10^(-7)and 7.7×10^(-7)m·s^(-1/2),respectively.Meanwhile,the interfaceα_(2)grain grows up without texture.The maximum tensile strength of 281 MPa was maintained at1000℃for 90 min under the pressure of 20 MPa.Consequently,the phase transformation and dynamic recrystallization behavior of the DLs were discussed.展开更多
Nature has achieved materials with properties and mechanisms that go far beyond the current know-how of the engineering-materials industry.The remarkable efficiency of biological materials,such as their exceptional pr...Nature has achieved materials with properties and mechanisms that go far beyond the current know-how of the engineering-materials industry.The remarkable efficiency of biological materials,such as their exceptional properties that rely on weak constituents,high performance per unit mass,and diverse functionalities in addition to mechanical properties,has been mostly attributed to their hierarchical structure.Key strategies for bioinspired materials include formulating the fundamental understanding of biological materials that act as inspiration,correlating this fundamental understanding to engineering needs/problems,and fabricating hierarchically structured materials with enhanced properties accordingly.The vast,existing literature on biological and bioinspired materials can be discussed in terms of functional and mechanical aspects.Through essential representative properties and materials,the development of bioinspired materials utilizes the design strategies from biological systems to innovatively augment material performance for various practical applications,such as marine,aerospace,medical,and civil engineering.Despite the current challenges,bioinspired materials have become an important part in promoting innovations and breakthroughs in the modern materials industry.展开更多
Nature consists of various soft tissues with well-ordered hierarchical anisotropic structures, which play essential roles in biological systems to exhibit particular functions. Mimicking bio-tissues, synthetic hydroge...Nature consists of various soft tissues with well-ordered hierarchical anisotropic structures, which play essential roles in biological systems to exhibit particular functions. Mimicking bio-tissues, synthetic hydrogels with anisotropic structures have received considerable attention in recent years. However, existing approaches to fabricate anisotropic hydrogels often require complicated procedures, which are timeconsuming and labor-demanding. Inspired by the dry-induced crystallization phenomenon, we report a simple yet effective prestretching-drying-swelling method to afford anisotropic crystalline polyvinyl alcohol hydrogels. Owing to the distinct anisotropic microstructure, the hydrogels demonstrate excellent mechanical properties with noticeable directional distinction. It is revealed that both the enhancing of pre-orientation strain and the extending of heating time make the hydrogels with better mechanical properties and more remarkable anisotropicity. Owing to the anisotropically aligned structure, the hydrogels exhibit remarkably differential ionic conductivity: the difference between the parallel and vertical conductivity of the same sample can reach as high as 6.6 times, making the materials possible candidates as nano-conductive materials. We anticipate that this simple yet effective approach may become highly useful for fabricating oriented hydrogels and endow the materials with more promising application prospects in the future.展开更多
A new type of suspension bridge is proposed based on the gravity stiffness principle.Compared with a conventional suspension bridge,the proposed bridge adds rigid webs and cross braces.The rigid webs connect the main ...A new type of suspension bridge is proposed based on the gravity stiffness principle.Compared with a conventional suspension bridge,the proposed bridge adds rigid webs and cross braces.The rigid webs connect the main cable and main girder to form a truss that can improve the bending stiffness of the bridge.The cross braces connect the main cables to form a closed space truss structure that can improve the torsional stiffness of the bridge.The rigid webs and cross braces are installed after the construction of a conventional suspension bridge is completed to resist different loads with different structural forms.A new type of railway suspension bridge with a span of 340 m and a highway suspension bridge with a span of 1020 m were designed and analysed using the finite element method.The stress,deflection of the girders,unbalanced forces of the main towers,and natural frequencies were compared with those of conventional suspension bridges.A stiffness test was carried out on the new type of suspension bridge with a small span,and the results were compared with those for a conventional bridge.The results showed that the new suspension bridge had a better performance than the conventional suspension bridge.展开更多
The 5754 aluminum alloy has been widely used in the automotive industry to reduce the weight of vehicles.The weld-bonding(WB)process comprising resistance spot welding and adhesive bonding processes effectively improv...The 5754 aluminum alloy has been widely used in the automotive industry to reduce the weight of vehicles.The weld-bonding(WB)process comprising resistance spot welding and adhesive bonding processes effectively improves the mechanical properties of joints.However,it is still a great challenge in the WB process to obtain high-quality and defect-free nuggets of aluminum alloys.In this study,the parameters of the WB process are optimized and the mechanism of generation of defects during WB is analyzed.The results show that the welding parameters have a significant effect on the nugget sizes,among which the welding current plays the most important role.The residual adhesive can easily cause defects during welding,e.g.,expulsion and porosity in the nugget.This can be effectively avoided by optimizing the welding parameters.In addition,the gas in the joints is effectively reduced by adding an appropriate preheating pulse prior to welding,thus lowering the damage degree of the adhesive layer.As a result,welded joints with better weld nugget quality and more stable mechanical properties are obtained.展开更多
Although dielectric ceramic capacitors possess attractive properties for high-power energy storage,their pronounced electrostriction effect and high brittleness are conducive to easy initiation and propagation of crac...Although dielectric ceramic capacitors possess attractive properties for high-power energy storage,their pronounced electrostriction effect and high brittleness are conducive to easy initiation and propagation of cracks that significantly deteriorate electrical reliability and lifetime of capacitors in practical applications.Herein,a new strategy for designing relaxor ferroelectric ceramics with K_(0.5)Na_(0.5)NbO_(3)-core/SiO_(2)-shell structured grains was proposed to simultaneously reduce the electric-field-induced strain and enhance the mechanical strength of the ceramics.The simulation and experiment declared that the bending strength and compression strength of the core-shell structured ceramic were shown to increase by more than 50% over those of the uncoated sample.Meanwhile,the electric-field-induced strain was reduced by almost half after adding the SiO_(2) coating.The suppressed electrical deformation and enhanced mechanical strength could alleviate the probability of generation of cracks and prevent their propagation,thus remarkably improving breakdown strength and fatigue endurance of the ceramics.As a result,an ultra-high breakdown strength of 425 kV cm^(-1) and excellent recoverable energy storage density(Wrec~4.64 J cm^(-3))were achieved in the core-shell structured sample.More importantly,the unique structure could enhance the cycling stability of the ceramic(Wrec variation<±2% after 105 cycles).Thus,mechanical performance optimization via grain structure engineering offers a new paradigm for improving electrical breakdown strength and fatigue endurance of dielectric ceramic capacitors.展开更多
基金Funded by the Joint Fund of Ministry of Education for Equipment Pre-research(No.6141A02022250)the Fundamental Research Funds for the Central Universities,China(No.WUT:2021III003XZ)。
文摘The composites were prepared by modifying silicon carbide fiber with particles of zirconium carbide(ZrC)and boron carbide(B_(4)C)and incorporating them into a phenolic resin matrix.The influence of ZrC and B_(4)C on the mechanical performance of SiCf/phenolic composites after high-temperature pyrolysis was studied through flexural performance test.The results show that the composite material has good thermal stability and high-temperature mechanical properties.After static ablation at 1400℃ for 15 minutes,the flexural strength of the composite material reaches 286 MPa,which is still 7.3%higher than at room temperature,indicating that the composite material still has good mechanical properties even after heat treatment at 1400℃.
基金supported by 2023 University-Level Scientific Research Project of Ningbo Polytechnic(NZ23002)the First Batch of Ningbo Construction Scientific Research Projects in 2023(20230106).
文摘In this paper,the influence of NaCl freeze-thaw(F-T)cycles and dry-wet(D-W)alternations on theflexural,com-pressive and bonding strengths of alkali-activatedfly ash(FA)and a blast furnace slag powder(BFS)is investi-gated.The considered NaCl concentration is 3%.The effect of polypropylenefibers on the mechanical strengths is also examined.Scanning electron microscopy(SEM),thermogravimetry(TG)and X-ray diffraction(XRD)are selected to discern the mechanisms underpinning the NaCl-induced erosion.The obtained results indicate that the best results in terms of material resistance are obtained with admixtures containing 60%BFS and 40%FA in terms of mass ratio and 3%polypropylenefibers in terms of volume ratio.The maximum rates of decrease of theflexural,compressive and bonding strengths after 300 NaCl F-T cycles are 21.5%,20.3%and 22.6%,respec-tively.The corresponding rates of decrease due to NaCl D-W alternations are 28.1%,26.1%and 31.5%,respec-tively.The TG curves show that the alkali-activating activity of BFS is higher than that of FA.Moreover,in thefirst case,the microstructure of the hydration products is more compact.The results also show that NaCl F-T cycles lead to increasing cracks in the alkali-activated BFS.
基金This work was supported by National Key Research and Development Project(2020YFB1600102,2020YFA0714302)National Natural Science Foundation of China(51878164,51922030,52208430)+2 种基金Fundamental Research Funds for the Central Universities of China(2242022R10059)Natural Science Foundation of Jiangsu Province(SBK2021042206)Southeast University“Zhongying Young Scholars”Project,and Shuangchuang Program of Jiangsu Province(JSSCBS20210058).
文摘In the induction heating of airport pavement to remove snow and ice,soft magnetic geopolymer composite(SMGC)can be used to gather the dissipated electromagnetic energy,thus enhancing the energy utilization efficiency.The aim of this work is to analyze the influence mechanism of iron powder content on the electromagnetic and mechanical performance of SMGC,so as to provide theoretical guidance for the design of soft magnetic layer within airport pavement structure.The results show that the increase of iron powder content reduces the resistance and magnetoresistance of SMGC by decreasing the content of non-magnetic phases between iron powder.However,the reduction of iron powder spacing also provides a shorter transmission path for the inter-particle eddy currents in the SMGC specimen,which enhances the exchange coupling between iron powder,thus increasing the electromagnetic loss.Therefore,the compatibility between magnetic permeability and electromagnetic loss should be considered comprehensively in the mix design of SMGC.In addition,although iron powder can enhance the mechanical properties of SMGC by improving the density of geopolymer matrix,the excessive amount of iron powder can lead to a weak interfacial transition zone between geopolymer matrix and iron powder.According to the induction heating results,optimized SMGC can improve the energy transfer efficiency of induction heating by 24.03%.
文摘Rare earth -containing PSBR sheet was prepared by reaction of rare earth alkoxide with quaternary ammonium salt of pyridine modified SBR (PSBR) latex, and then it was blended with natural rubber (NR) to produce rare earth - containing composite elastomer. It is found that mechanical performance can be improved remarkably. Analyzed by infrared spectrometry (IR), differential scanning calorimetry (DSC) and cross-linking densitometry, the relationship between structure and performance was discussed.
基金Funded by the Program of Innovative Team of the Ministry of Education of China(No.IRT13089)the National Natural Science Foundation of China(No.51078307)
文摘The aim of this study is to provide the quantificational change laws of strength,stiffness,and deformation capacity of frost-damaged concrete relating to a united index,the data were obtained by different researchers.Then the index of relative compressive strength(RCS) was introduced as the indicator of frost damage and a large number of mechanical performance testing data of frost-damaged concrete were collected and analyzed.By curve fitting,the correlations between RCS and the initial elastic modulus,the strain at peak compressive stress,and biaxial compressive strength,and tensile strength,and the strain at peak tensile stress were established.Thereafter,the analytical stress-strain response of frost-damaged concrete under monotonic loading was presented using RCS and compared with that of the experimental data.Moreover,an isotropic elastoplastic damage model of frost-damaged concrete subjected to repeated loading was established.Finally,we can systematically estimate the effects of frost-damage on the mechanical performance of concrete,which can be provided for the numerical simulation of frost-damaged concrete structures.
文摘Nitrogen doped diamond-like carbon (DLC:N) films were prepared by electron cyclotron resonance chemical vapor deposition (ECR-CVD) on polycrystalline Si chips. Film thickness is about 50 nm. Auger electron spectroscopy (AES) was used to evaluate nitrogen content, and increasing N2 flow improved N content from 0 to 7.6%. Raman and X-ray photoelectron spectroscopy (XPS) analysis results reveal CN-sp^3C and N-sp^2C structure. With increasing the N2 flow, sp^3C decreases from 73.74% down to 42.66%, and so does N-sp^3C from 68.04% down to 20.23%. The hardness decreases from 29.18 GPa down to 19.74 GPa, and the Young's modulus from 193.03 GPa down to 144.52 GPa.
文摘On the basis of test, nonlinear finite element analysis of reinforcedconcrete (R. C) short-limb shear walls under monotonic horizontal load are carried out by ANSYSprogram in order to understand the evolution of cracking, deformation and failure course of thespecimens. At the same time, the results of numerical calculation are compared with the results oftest. The results indicate that, under monotonic horizontal load the failures of the specimens withflange wall and without flange wall all occur at the intersections of lintel bottom and limb ofwall, the failures also occur at the bottom of limb; the load-displacement curve of wall withoutflange is steeper than that of wall with flange, and the ductility is worse than that of wall withflange; the results, such as cracking, deformation, yield load and so on of finite element analysisagree well with the results of test. These results provide theoretical basis of study andapplication of R. C short-limb shear wall.
基金This work was supported by the National Natural Science Foundation of China[Grant Nos.11790283,51978587,51708457]the Program of Introducing Talents of Discipline to Universities(111 Project)[Grant No.B16041].
文摘Motivated by the huge practical engineering demand for the fundamental understanding of mechanical characteristics of high-speed railway infrastructure,a fullscale multi-functional test platform for high-speed railway track–subgrade system is developed in this paper,and its main functions for investigating the mechanical performance of track–subgrade systems are elaborated with three typical experimental examples.Comprising the full-scale subgrade structure and all the five types of track structures adopted in Chinese high-speed railways,namely the CRTS I,the CRTS II and the CRTS III ballastless tracks,the double-block ballastless track and the ballasted track,the test platform is established strictly according to the construction standard of Chinese high-speed railways.Three kinds of effective loading methods are employed,including the real bogie loading,multi-point loading and the impact loading.Various types of sensors are adopted in different components of the five types of track–subgrade systems to measure the displacement,acceleration,pressure,structural strain and deformation,etc.Utilizing this test platform,both dynamic characteristics and long-term performance evolution of high-speed railway track–subgrade systems can be investigated,being able to satisfy the actual demand for large-scale operation of Chinese high-speed railways.As examples,three typical experimental studies are presented to elucidate the comprehensive functionalities of the full-scale multi-functional test platform for exploring the dynamic performance and its long-term evolution of ballastless track systems and for studying the long-term accumulative settlement of the ballasted track–subgrade system in high-speed railways.Some interesting phenomena and meaningful results are captured by the developed test platform,which provide a useful guidance for the scientific operation and maintenance of high-speed railway infrastructure.
文摘In order to explore the effect of high-temperature annealing on the mechanical performances and microstructures of different oxygen SiC fibers, two types of silicon carbide(SiC)-based fibers, specified as XD-SiC fibers(low oxygen) and Nicalon-201 fibers(high oxygen), were annealed in Ar for 1 h at 800 ℃, 1 000 and 1 200 ℃, respectively. Mechanical properties of these fibers were characterized via a monofilament tensile method, with observation of the damaged monofilament by SEM. Also, the effects of annealing on the microstructure and chemical compositions of the fibers were studied. The experimental results indicated that the tensile strength decreased with the increase of annealing temperatures,after annealing-treatment at 1200℃, XD-SiC fibers remained 84% of its original strength, while Nicalon-201 fibers remained only 58% of its original strength. Crystallization and chemical composition of the fibers are the dominating factors for their mechanical performance at high temperatures. The microstructure changes of XD-SiC fibers are mainly composed of the growth of β-SiC, for Nicalon-201 fibers, evaporation of gases is the main change for microstructure.
基金supported by the National Natural Science Foundation of China(Nos.52202110,22201167)the Natural Science Foundation of Science and Technology Agency of Shanxi Province(No.20210302124654)+6 种基金the Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi(No.2021L259)the Innovation and Entrepreneurship Training Program for College students in Shanxi Province(No.20220312)the Outstanding Young Talents of Shaanxi Universities(2019)the Scientific and Technological Plan Project of Xi’an(No.21XJZZ0012)the Key Research and Development Program of Shaanxi Province of China(No.2022SF-201)the Service Local Special Program of Education Department of Shaanxi Province(No.23JC029)the Scientific and Technological Plan Project of the Beilin District of Xi’an City(No.GX2206).
文摘Developing free-standing and mechanical robust membrane materials capable of superior enrichment of phosphopeptides for analyzing and identifying the specific phosphoproteome of cancer cells is significant in understanding the molecular mechanisms of cancer development and exploring new therapeutic approaches,but still a significant challenge in materials design.To this end,we firstly constructed highly flexible ZrTiO_(4) nanofibrous membranes(NFMs)with excellent mechanical stability through a cost-effective and scalable electrospinning and subsequent calcination technique.Then,to further increase the enrichment capacity of the phosphopeptide,the biomimetic TiO_(2)@ZrTiO_(4) NFMs with root hair or leaf like branch microstructure are developed by the hydrothermal post-synthetic modification of ZrTiO_(4) NFMs through growing unfurling TiO_(2) nanosheets onto the ZrTiO_(4) nanofibers.Importantly,remarkable flexibility and mechanical stability enable the resulting TiO_(2)@ZrTiO_(4) NFMs excellent practicability,while the biomimetic microstructure allows it outstanding enrichment ability of the phosphopeptide and identification ability of the specific phosphoproteins in the digest of cervical cancer cells.Specifically,6770 phosphopeptides can be enriched by TiO_(2)@ZrTiO_(4) NFMs(2205 corresponding phosphoproteins can be identified),and the value is much higher than that of ZrTiO_(4) NFMs(6399 phosphopeptides and 2132 identified phosphoproteins)and commercial high-performance TiO_(2) particles(4525 phosphopeptides and 1811 identified phosphoproteins).These results demonstrate the super ability of TiO_(2)@ZrTiO_(4) NFMs in phosphopeptide enrichment and great potential for exploring the pathogenesis of cancer.
基金This project was supported by Key Research and Development Project of Shaanxi Province(2022GY-427)The first author also gratefully acknowledges the financial support from China Scholarship Council(202006560071).
文摘Numerous studies showed that synthetic fibers are effective for reinforcing the mechanical performance of the asphalt mixture due to their high strength properties,ductility,and durability characteristics.In this paper,the objective is to present a review of the reinforcement effect of synthetic fiber on the mechanical performance of the asphalt mixture.This paper reviews the relevant literature on the characterizations and applications of synthetic fibers to improve different mechanical properties of asphalt mixes,which can provide a reference for the applications and development of synthetic fibers in asphalt pavement.The characteristics of common synthetic fibers are introduced and the utilization of synthetic fibers in asphalt mixture is discussed.Different surface treatment methods for fiber are reviewed and it is found that surface treatment can improve the performance of the synthetic fibers in asphalt mixtures,especially the chemical surface treatment method.The influence of synthetic fiber addition on the mechanical properties of the asphalt concrete such as rutting resistance,tensile strength,water stability performance,and cracking resistance are then discussed.The research results show that aramid,glass,and polyester fibers improve the fatigue cracking resistance of asphalt mixture.Polyester fibers,polyamide fibers,and carbon fibers are used to improve resistance to the permanent deformation of asphalt pavement.
基金partly supported by the National Natural Science Foundation of China(Grant No.12172074)partly supported by the National Natural Science Foundation of China(Grant Nos.12150001,and 11832019)the Fundamental Research Funds for the Central Chinese Universities(Grant No.DUT16RC(3)091)。
文摘The present article is aimed to detect material-intrinsic indices that can be used to supervise the mechanical performance of general solid matter.The novelty carried in this article can be summarised as follows.Firstly,an inelastic deformation state of almost any solid matter can be treated as the combination of two fundamental modes due to different microscopic causation:Mode I inelastic distortion due to the movement of sliding types of defects and Mode II inelastic dilation due to the evolution of voids/bubbles.Secondly,each inelastic deformation mode is characterised by a single principal inelastic deformation descriptor(PIDD):Mode I by a newly introduced quantity of maximum distortional angle changeαand Mode II by the logarithm of dilating magnificationω.In particular,the concept of maximum distortional angle change gives rise to a geometrically intuitive yield criterion ofα>α_(c),which in situations of small deformation,is shown to asymptote von Mise's,and to become Tresca's in cases of plane stress.Thirdly,the deformation process of a solid matter under monotonic and ambient loads is formulated by means of trajectories of thermodynamic equilibria with respect to the PIDD pair.Then a pair of physical quantities which measure the stresses needed to change the local PIDD state are singled out.Being termed as inelastic deformation resistances(IDRs),these two quantities are shown to depend only on the onsite atomic configurations.It is also shown that key descriptive properties about the mechanical behaviours of materials,such as ductility,are encoded in IDRs as functions of PIDDs.Hence the IDR pair may serve as material performance indices that may be more intrinsic than conventional stress-strain relationships.
基金supported by the following funds:National Natural Science Foundation of China(51935014,52165043)Jiangxi Provincial Cultivation Program for Academic and Technical Leaders of Major Subjects(20225BCJ23008)+1 种基金Jiangxi Provincial Natural Science Foundation(20224ACB204013,20224ACB214008)Scientific Research Project of Anhui Universities(KJ2021A1106)。
文摘Magnesium(Mg)alloys are considered to be a new generation of revolutionary medical metals.Laser-beam powder bed fusion(PBF-LB)is suitable for fabricating metal implants withpersonalized and complicated structures.However,the as-built part usually exhibits undesirable microstructure and unsatisfactory performance.In this work,WE43 parts were firstly fabricated by PBF-LB and then subjected to heat treatment.Although a high densification rate of 99.91%was achieved using suitable processes,the as-built parts exhibited anisotropic and layeredmicrostructure with heterogeneously precipitated Nd-rich intermetallic.After heat treatment,fine and nano-scaled Mg24Y5particles were precipitated.Meanwhile,theα-Mg grainsunderwent recrystallization and turned coarsened slightly,which effectively weakened thetexture intensity and reduced the anisotropy.As a consequence,the yield strength and ultimate tensile strength were significantly improved to(250.2±3.5)MPa and(312±3.7)MPa,respectively,while the elongation was still maintained at a high level of 15.2%.Furthermore,the homogenized microstructure reduced the tendency of localized corrosion and favoredthe development of uniform passivation film.Thus,the degradation rate of WE43 parts was decreased by an order of magnitude.Besides,in-vitro cell experiments proved their favorable biocompatibility.
文摘New research and development(R&D)institutions are an important part of the national innovation system,playing an important role in promoting the transformation of scientific and technological achievements.In recent years,new R&D institutions have gradually become the driving force of innovation-driven development in China.Taking new R&D institutions in Zhejiang Province as the research object,this paper studies the internal talent training path and performance evaluation mechanism of new R&D institutions in Zhejiang Province by using the literature research method,comparison method,case verification method,and other methods.The investigation results show that there are problems such as lack of material and spiritual support and neglect of the absorption of local talents in the internal talent training,and there are problems such as unclear standards,insufficient data,and opaque processes in the performance evaluation mechanism,which greatly affect the establishment and improvement of the performance evaluation mechanism.Given the above problems,this paper puts forward a forward-looking,oriented,flexible,and compatible talent training path and performance evaluation mechanism,hoping to optimize the effective internal talent training path of new R&D institutions,improve the evaluation performance,and promote healthy development of new R&D institutions in Zhejiang Province.
基金the National Natural Science Foundation of China(No.51771150)the National Key Research and Development Program of China(No.2016YFB0701303)+1 种基金the Aeronautical Science Foundation of China(No.201936053001)the Research Fund of the State Key Laboratory of Solidification(NWPU),China(No.2019-TS-07)。
文摘Solid-state diffusion bonding(DB)of TiAl alloy and Ti2 AlNb alloy was carried out using pure Ti as an interlayer at 1000℃under 20 MPa for 60-120 min.The effects of bonding times on the interfacial microstructure and mechanical performance of the TiAl/Ti/Ti_(2)AlNb bonded joints at room temperature(RT)were investigated detailly.The results demonstrated that the diffusion layers(DLs)mainly consisted of four characteristic layers,(Ⅰ)single coarseα_(2)phase adjacent TiAl alloy,(Ⅱ)single refinedα_(2)phase at the bonding interface,(Ⅲ)equiaxed/acicularα_(2)phase embedded inβphase adjacent Ti_(2)AtNb alloy and(IV)both equiaxedα_(2)phase and acicular O phase embedded inβphase adj acent Ti_(2)AlNb alloy,respectively.The thickness of the four layers increased with the increasing of the bonding time.The growth of DLs is controlled by diffusion and the reaction rate constant k for regionⅠ,Ⅱ,ⅢandⅣare 1.22×10^(-6),1.27×10^(-6),2.6×10^(-7)and 7.7×10^(-7)m·s^(-1/2),respectively.Meanwhile,the interfaceα_(2)grain grows up without texture.The maximum tensile strength of 281 MPa was maintained at1000℃for 90 min under the pressure of 20 MPa.Consequently,the phase transformation and dynamic recrystallization behavior of the DLs were discussed.
基金supports from the National Natural Science Foundation of China(No.51703240),Guangdong Basic and Applied Basic Research Foundation(2019A1515012093)Shenzhen Peacock Technology Innovation Fund(KQJSCX2018033017043010)Pearl-River Talent Scheme(2017GC010135)。
文摘Nature has achieved materials with properties and mechanisms that go far beyond the current know-how of the engineering-materials industry.The remarkable efficiency of biological materials,such as their exceptional properties that rely on weak constituents,high performance per unit mass,and diverse functionalities in addition to mechanical properties,has been mostly attributed to their hierarchical structure.Key strategies for bioinspired materials include formulating the fundamental understanding of biological materials that act as inspiration,correlating this fundamental understanding to engineering needs/problems,and fabricating hierarchically structured materials with enhanced properties accordingly.The vast,existing literature on biological and bioinspired materials can be discussed in terms of functional and mechanical aspects.Through essential representative properties and materials,the development of bioinspired materials utilizes the design strategies from biological systems to innovatively augment material performance for various practical applications,such as marine,aerospace,medical,and civil engineering.Despite the current challenges,bioinspired materials have become an important part in promoting innovations and breakthroughs in the modern materials industry.
基金financial support from the National Key Research and Development Program of China (No.2019YFE0111000)the National Natural Science Foundation of China (NSFC,Nos.51903253,51903257)+2 种基金Natural Science Foundation of Guangdong Province of China (Nos.2019A1515011150,2019A1515011258)Macao University of Science and Technology Foundation (No.FRG-19-003-SP)the Science and Technology Development Fund of Macao (Nos.FDCT 0009/2019/A,0083/2019/A2,0007/2019/AKP)。
文摘Nature consists of various soft tissues with well-ordered hierarchical anisotropic structures, which play essential roles in biological systems to exhibit particular functions. Mimicking bio-tissues, synthetic hydrogels with anisotropic structures have received considerable attention in recent years. However, existing approaches to fabricate anisotropic hydrogels often require complicated procedures, which are timeconsuming and labor-demanding. Inspired by the dry-induced crystallization phenomenon, we report a simple yet effective prestretching-drying-swelling method to afford anisotropic crystalline polyvinyl alcohol hydrogels. Owing to the distinct anisotropic microstructure, the hydrogels demonstrate excellent mechanical properties with noticeable directional distinction. It is revealed that both the enhancing of pre-orientation strain and the extending of heating time make the hydrogels with better mechanical properties and more remarkable anisotropicity. Owing to the anisotropically aligned structure, the hydrogels exhibit remarkably differential ionic conductivity: the difference between the parallel and vertical conductivity of the same sample can reach as high as 6.6 times, making the materials possible candidates as nano-conductive materials. We anticipate that this simple yet effective approach may become highly useful for fabricating oriented hydrogels and endow the materials with more promising application prospects in the future.
基金The work described in this paper has been supported by the grants awarded by the Guangxi Major Science and Technology Project(No.AB18126047).
文摘A new type of suspension bridge is proposed based on the gravity stiffness principle.Compared with a conventional suspension bridge,the proposed bridge adds rigid webs and cross braces.The rigid webs connect the main cable and main girder to form a truss that can improve the bending stiffness of the bridge.The cross braces connect the main cables to form a closed space truss structure that can improve the torsional stiffness of the bridge.The rigid webs and cross braces are installed after the construction of a conventional suspension bridge is completed to resist different loads with different structural forms.A new type of railway suspension bridge with a span of 340 m and a highway suspension bridge with a span of 1020 m were designed and analysed using the finite element method.The stress,deflection of the girders,unbalanced forces of the main towers,and natural frequencies were compared with those of conventional suspension bridges.A stiffness test was carried out on the new type of suspension bridge with a small span,and the results were compared with those for a conventional bridge.The results showed that the new suspension bridge had a better performance than the conventional suspension bridge.
基金The authors gratefully thank the financial support from Excellent CAS Talents(NO.292017312D1100301)Excellent Technology Leader(NO.19XD1433500)Strengthen Industrial Base(GYQJ-2019-1-33)programs,which are from Chinese Academy of Sciences,Science and Technology Commission Shanghai Municipality,and Shanghai Municipal Commission of Economy and Information,respectively.
文摘The 5754 aluminum alloy has been widely used in the automotive industry to reduce the weight of vehicles.The weld-bonding(WB)process comprising resistance spot welding and adhesive bonding processes effectively improves the mechanical properties of joints.However,it is still a great challenge in the WB process to obtain high-quality and defect-free nuggets of aluminum alloys.In this study,the parameters of the WB process are optimized and the mechanism of generation of defects during WB is analyzed.The results show that the welding parameters have a significant effect on the nugget sizes,among which the welding current plays the most important role.The residual adhesive can easily cause defects during welding,e.g.,expulsion and porosity in the nugget.This can be effectively avoided by optimizing the welding parameters.In addition,the gas in the joints is effectively reduced by adding an appropriate preheating pulse prior to welding,thus lowering the damage degree of the adhesive layer.As a result,welded joints with better weld nugget quality and more stable mechanical properties are obtained.
基金This work was supported by the National Natural Science Foundation of China(grants nos.52072150,51972146,and 51772175)the China Association for Science and Technology(Young Elite Scientists Sponsorship Program)the State Key Laboratory of New Ceramic and Fine Processing Tsinghua University(project no.KF202002).
文摘Although dielectric ceramic capacitors possess attractive properties for high-power energy storage,their pronounced electrostriction effect and high brittleness are conducive to easy initiation and propagation of cracks that significantly deteriorate electrical reliability and lifetime of capacitors in practical applications.Herein,a new strategy for designing relaxor ferroelectric ceramics with K_(0.5)Na_(0.5)NbO_(3)-core/SiO_(2)-shell structured grains was proposed to simultaneously reduce the electric-field-induced strain and enhance the mechanical strength of the ceramics.The simulation and experiment declared that the bending strength and compression strength of the core-shell structured ceramic were shown to increase by more than 50% over those of the uncoated sample.Meanwhile,the electric-field-induced strain was reduced by almost half after adding the SiO_(2) coating.The suppressed electrical deformation and enhanced mechanical strength could alleviate the probability of generation of cracks and prevent their propagation,thus remarkably improving breakdown strength and fatigue endurance of the ceramics.As a result,an ultra-high breakdown strength of 425 kV cm^(-1) and excellent recoverable energy storage density(Wrec~4.64 J cm^(-3))were achieved in the core-shell structured sample.More importantly,the unique structure could enhance the cycling stability of the ceramic(Wrec variation<±2% after 105 cycles).Thus,mechanical performance optimization via grain structure engineering offers a new paradigm for improving electrical breakdown strength and fatigue endurance of dielectric ceramic capacitors.