In this paper , by means of SHPB(Split Hopkinson Pressure Bar),the impact tests have been carried out on every parts of welded joint with different strain rate. Relevant dynamic mechanical diagrams of curves have been...In this paper , by means of SHPB(Split Hopkinson Pressure Bar),the impact tests have been carried out on every parts of welded joint with different strain rate. Relevant dynamic mechanical diagrams of curves have been obtained. The result shows that the dynamic mechanical heterogeneity of welded joint has its special behaviors and a higher sensibility with high strain rate.展开更多
In this study, 20 mm thick AA7075-T6 alloy plates were joined by friction stir welding. The microstructure and mechanical properties of the nugget zone along the thickness direction from the top to the bottom was inve...In this study, 20 mm thick AA7075-T6 alloy plates were joined by friction stir welding. The microstructure and mechanical properties of the nugget zone along the thickness direction from the top to the bottom was investigated. The results showed that the microstructure including the grain size, the degree of dynamic recrystallization, the misorientation angle distribution and the precipitation phase containing its size, type and content exhibited a gradient distribution along the thickness direction. The testing results of mechanical properties of the slices showed that the nugget was gradually weakened along the depth from the top to the bottom. The maximum ultimate tensile strength, yield strength and elongation of the slice in the nugget top-middle are obtained, which are 415 MPa, 255 MPa and 8.1%, respectively.展开更多
The heterogeneous Fenton reaction can generate highly reactive hydroxyl radicals（·OH）from reactions between recyclable solid catalysts and H2O2 at acidic or even circumneutral pH.Hence,it can effectively oxidiz...The heterogeneous Fenton reaction can generate highly reactive hydroxyl radicals（·OH）from reactions between recyclable solid catalysts and H2O2 at acidic or even circumneutral pH.Hence,it can effectively oxidize refractory organics in water or soils and has become a promising environmentally friendly treatment technology.Due to the complex reaction system,the mechanism behind heterogeneous Fenton reactions remains unresolved but fascinating,and is crucial for understanding Fenton chemistry and the development and application of efficient heterogeneous Fenton technologies.Iron-based materials usually possess high catalytic activity,low cost,negligible toxicity and easy recovery,and are a superior type of heterogeneous Fenton catalysts.Therefore,this article reviews the fundamental but important interfacial mechanisms of heterogeneous Fenton reactions catalyzed by iron-based materials..OH,hydroperoxyl radicals/superoxide anions（HO2./O2^-.）and high-valent iron are the three main types of reactive oxygen species（ROS）,with different oxidation reactivity and selectivity.Based on the mechanisms of ROS generation,the interfacial mechanisms of heterogeneous Fenton systems can be classified as the homogeneous Fenton mechanism induced by surface-leached iron,the heterogeneous catalysis mechanism,and the heterogeneous reaction-induced homogeneous mechanism.Different heterogeneous Fenton systems catalyzed by characteristic iron-based materials are comprehensively reviewed.Finally,related future research directions are also suggested.展开更多
文摘In this paper , by means of SHPB(Split Hopkinson Pressure Bar),the impact tests have been carried out on every parts of welded joint with different strain rate. Relevant dynamic mechanical diagrams of curves have been obtained. The result shows that the dynamic mechanical heterogeneity of welded joint has its special behaviors and a higher sensibility with high strain rate.
基金supported by the National Natural Science Foundation of China(NSFC)(No.51265043 and 51265042)the Special Construction Project of Advanced Science and Technology Innovation Team of Jiangxi Province(No.20171BCB24007)
文摘In this study, 20 mm thick AA7075-T6 alloy plates were joined by friction stir welding. The microstructure and mechanical properties of the nugget zone along the thickness direction from the top to the bottom was investigated. The results showed that the microstructure including the grain size, the degree of dynamic recrystallization, the misorientation angle distribution and the precipitation phase containing its size, type and content exhibited a gradient distribution along the thickness direction. The testing results of mechanical properties of the slices showed that the nugget was gradually weakened along the depth from the top to the bottom. The maximum ultimate tensile strength, yield strength and elongation of the slice in the nugget top-middle are obtained, which are 415 MPa, 255 MPa and 8.1%, respectively.
基金supported by the National Natural Science Foundation of China (Nos. 21107125, 21577160, 51221892, 51290282 and 41201498)
文摘The heterogeneous Fenton reaction can generate highly reactive hydroxyl radicals（·OH）from reactions between recyclable solid catalysts and H2O2 at acidic or even circumneutral pH.Hence,it can effectively oxidize refractory organics in water or soils and has become a promising environmentally friendly treatment technology.Due to the complex reaction system,the mechanism behind heterogeneous Fenton reactions remains unresolved but fascinating,and is crucial for understanding Fenton chemistry and the development and application of efficient heterogeneous Fenton technologies.Iron-based materials usually possess high catalytic activity,low cost,negligible toxicity and easy recovery,and are a superior type of heterogeneous Fenton catalysts.Therefore,this article reviews the fundamental but important interfacial mechanisms of heterogeneous Fenton reactions catalyzed by iron-based materials..OH,hydroperoxyl radicals/superoxide anions（HO2./O2^-.）and high-valent iron are the three main types of reactive oxygen species（ROS）,with different oxidation reactivity and selectivity.Based on the mechanisms of ROS generation,the interfacial mechanisms of heterogeneous Fenton systems can be classified as the homogeneous Fenton mechanism induced by surface-leached iron,the heterogeneous catalysis mechanism,and the heterogeneous reaction-induced homogeneous mechanism.Different heterogeneous Fenton systems catalyzed by characteristic iron-based materials are comprehensively reviewed.Finally,related future research directions are also suggested.
