Formation of mesophase microbeads from bulk mesophase pitch induced by fullerene

A transformation of naphthalene-based coalescenced mesophase pitch(NMP)to mesophase microbeads was achieved by heating a mixture of NMP and fullerene(C_(60)).This is different from the conventional process of the liquid-phase carbonization of isotropic pitch to the emergence of carbon microbeads in the matrix and finally their growth to form a 100%anisotropic bulk meso-phase,but rather a reverse transformation.The effects of C_(60) loading and reaction temperature on the morphological transformation of mesophase were investigated by polarizing optical and scanning electron microscopies.The physical changes in the NMP induced by C_(60) were characterized by thermogravimetric analysis,Fourier transform infrared spectroscopy,X-ray diffractometry and Raman spectroscopy.The results show that the coalesced NMP can be converted to a spherical type at 300-320℃ with the addition of 5%C_(60),and the size of the mesophase microbeads increases with increasing temperature.Furthermore,a model is established to ex-plain the unique induction effect of C_(60) in the transformation process.This work makes the morphological transformation of MP con-trollable,and provides a new idea for the understanding and research of mesophase pitch.

Mechanism of colluvial landslide induction by rainfall and slope construction:A case study

The landslide hazards occurring in the complex geological genesis accumulation body are usually controlled by the coupling action of many internal and external factors.Therefore,this paper takes the dam-front Danbo accumulation body landslide of Yangfanggou hydropower station on the Yalong River as the geological prototype,and discusses the process and mechanism of slope stability degradation under the combined action of rainfall and slope construction.Based on the detailed understanding of the basic characteristics of the accumulation body,the development characteristics of the landslide and the construction situation of the slope engineering,the study conducted correlation analysis between rainfall and landslide displacement,the physical and mechanical tests of all types of rocksoil masses,and the numerical simulation testing of seepage field variation of the landslide section.It is found that the special slope structure and material composition of the old landslide accumulation layer on the upper part of the Danbo accumulation body are the internal factors for the occurrence of thrust loadinduced landslide,and the construction of the slope engineering not only creates free space conditions for sliding,but also provides channels for the infiltration of rainfall into the slope after confluence,which is an external factor that caused the mechanical properties of the sliding zone soil to gradually weaken from the trailing edge to the leading edge.The geomechanical model of such landslide is that the active section of the trailing edge produces the"source of force",the transition section of the middle section affects the occurrence of sliding,and the anti-sliding section of the leading edge controls the occurrence of landslide hazards.The results of this research provide not only a useful supplement to the theory of landslide formation mechanisms but also a scientific basis for guiding the prevention and control of similar hazards.

MOLECULAR POLARIZATION INDUCTION IN CONCERTED MECHANISM OF ALKOXY MIGRATION

The rearrangement of α-substituted phenyl-α, α′-dimethoxypropanones (R1) was recently proved to he an [1, 3] siqmatropic migration of methoxy group by study of LFER, solvent effect, crossover experiment, and by other means. The rearrangement catalysed by trace of totuenesulfonic acid gave a negligible value of the Hammett reaction constant. Further experimental results show that the electronic effect of substituent on the aromatic ring for the rearrangement in neutral medium is much greater (Table 1). We propose sigmatropic migration

Global Solar Radiation Maps of Saudi Arabia

This paper uses Abductive network to predict global solar radiation in any location in the Kingdom of Saudi Arabia （KSA） based on sunshine duration, month number, latitude, longitude, and altitude of the location. Results indicate good agreement between measured and predicted GSR values for each of the 35 locations with known GSR values. Finally, the data from all available stations are used to train an abductive network to estimate the GSR values anywhere in the Kingdom based on latitude and longitude. GSR values are estimated using the developed method at 25 additional locations throughout the kingdom and used with the measured data from the 35 available measurement stations to draw a comprehensive contour map of GSR values for KSA.

Effects of liquid feed rate and impeller rotation speed on heat transfer in a mechanically fluidized reactor

A mechanically fluidized reactor （MFR） is a novel and compact reactor used for biomass pyrolysis. Endothermic biomass pyrolysis requires heat provided from the wall of the MFR. Meanwhile, mixing with a vertical stirrer helps achieve effective heat transfer from the wall to the bed. Here, the heat trans- fer characteristics between the wall of a 1.0-L MFR and its bed of mechanically fluidized sand particles were studied. An induction heating system was used to heat the wall, while a vertical blade stirrer was used for mixing. Heat transfer measurements were carried out using silica sand particles, having three average Sauter mean diameters： 190, 300, and 600 p.m. The overall wall-to-bed heat transfer coeffi- cients were estimated using temperature measurements taken during continuous injection of water onto the fluidized bed. The overall heat transfer coefficient for bed temperatures of 500-700℃ increased as particle size increased or superficial velocity of the vaporized liquid increased. Effect of impeller rotation speed also was investigated. Typically, the overall heat transfer coefficient increased as rotation speed increased. The wall-to-bed heat transfer coefficients obtained in this study are comparable to estimates from traditional bubbling fluidized beds, even at vapor velocities below the minimum fluidization veloccity.