In this paper, the conditions of modified melamine formaldehyde resin (MF) used for a flocculent such as the ratio of reactant, reaction time, reaction temperature and the value of pH, were studied. The preferable syn...In this paper, the conditions of modified melamine formaldehyde resin (MF) used for a flocculent such as the ratio of reactant, reaction time, reaction temperature and the value of pH, were studied. The preferable synthetic conditions were melamine:formaldehyde:acrylamide (mole)=1:5:(2～3), reaction temperature 70 ℃, reaction time 4 h, pH 9.0.展开更多
In this work, melamine-formaldehyde resin was cationized by adding modifiers so that the fibers closely bonded to improve their usability and the wet strength of paper was greatly improved. Triethanolamine and dimethy...In this work, melamine-formaldehyde resin was cationized by adding modifiers so that the fibers closely bonded to improve their usability and the wet strength of paper was greatly improved. Triethanolamine and dimethylamine were added to modify the melamine-formaldehyde resin,respectively.The mechanism of the cationized resin was explored and the possible chemical reactions were deduced. It was concluded that,with the use of triethanolamine,the most optimum product was obtained by hydroxymethylation for 30 min with a temperature of 85℃ and p H of 9. 0 where n( melamine) ∶ n( formaldehyde) ∶ n( methanol) ∶ n( triethanolamine) was 100 ∶ 330 ∶ 450 ∶ 15. With the combined use of dimethylamine and methanol,the optimal product was acquired by condensation for 30 min at a temperature of 50℃ and p H of 2. 0 at melamine, formaldehyde, methanol, and dimethylamine molar ratio of100∶ 330∶ 350∶ 20. With the only use of dimethylamine,the optimal product was obtained by condensation at melamine,formaldehyde,dimethylamine molar ratio of 100∶ 330∶ 10. The wet tensile strength of fruit-bagging paper was improved by adding cationized melamine-formaldehyde resin. The zeta potential,charge density,and conductivity of the melamine-formaldehyde resin were also studied.展开更多
Melamine formaldehyde (MF) foam is kind of fire-retardant material and has great potential in acoustic and thermal insulation area. In this article, MF resin foam was prepared by microwave radiation. We discussed the ...Melamine formaldehyde (MF) foam is kind of fire-retardant material and has great potential in acoustic and thermal insulation area. In this article, MF resin foam was prepared by microwave radiation. We discussed the thermal stability of MF foam and the effect of different emulsifiers on its morphology, apparent density, fire-retardancy and mechanical property. The decomposition temperature of MF foam we prepared is nearly 400℃ and the constitution of residue after combustion is made up of carbon and graphite. Emulsifier influenced the apparent density of MF foam and using coemulsifiers can get flexible foam with uniform cell size, good morphology and low apparent density. When the fire-retardant MF foam’s apparent density is low of 5.53 kg/cm-3, its value of LOI can reach 32.4. The mechanical property of foam is consistent with apparent density.展开更多
A simple and convenient procedure for the synthesis of nitriles by dehydration of aldoxime using supported sulphuric acid on melamine-formaldehyde resin （MFR） under solvent-free condition has been developed. A varie...A simple and convenient procedure for the synthesis of nitriles by dehydration of aldoxime using supported sulphuric acid on melamine-formaldehyde resin （MFR） under solvent-free condition has been developed. A variety of aromatic and aliphatic aldoximes were converted to the corresponding nitriles. The resin was recovered and reused for subsequent reactions. ~ 2011 Ramin Rezaei. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.展开更多
The nitrogen and oxygen co-doped hollow carbon spheres（HCSs） were prepared via a simple pyrolysis of solid melamine-formaldhyde resin spheres. The carbonization temperature has an important influence on the specific...The nitrogen and oxygen co-doped hollow carbon spheres（HCSs） were prepared via a simple pyrolysis of solid melamine-formaldhyde resin spheres. The carbonization temperature has an important influence on the specific surface area, pore-size distribution and heteroatom contents of HCSs. The synergistic effects of those physical and chemical properties on supercapacitor performance were systematically investigated. Among the HCSs obtained at different temperatures, HCSs-800（co-doped HCSs at 800℃） exhibits the best reversible specific capacitance in 2 mol/L H2SO4 electrolyte and meanwhile maintains a high-class capacitance retention capability. The nitrogen heteroatoms were confirmed to play a crucial role in improving capacitance in an acid medium. This kind of nitrogen doved HCSs is a potential candidate for an efficient electrode material for supercapacitors.展开更多
Melamine-formaldehyde resin supported H~＋ is used as an efficient catalyst in the Pechmann condensation reaction of phenols withβ-ketoesters,in solvent-free media leading to the formation of coumarin derivatives usi...Melamine-formaldehyde resin supported H~＋ is used as an efficient catalyst in the Pechmann condensation reaction of phenols withβ-ketoesters,in solvent-free media leading to the formation of coumarin derivatives using conventional heating and microwave irradiation in excellent yields with good purity.展开更多
基金the financial support from the National Basic Research Program of China(No. 2009CB623200)the National Natural Science Foundation of China(No.50539040)the Scientific Research Foundation of Graduate School of Southeast University(No.YBJJ 0725).
基金Supported by the Science Foundation of Shanghai MunicipalCommission of Education!( 97A2 6 )
文摘In this paper, the conditions of modified melamine formaldehyde resin (MF) used for a flocculent such as the ratio of reactant, reaction time, reaction temperature and the value of pH, were studied. The preferable synthetic conditions were melamine:formaldehyde:acrylamide (mole)=1:5:(2～3), reaction temperature 70 ℃, reaction time 4 h, pH 9.0.
文摘In this work, melamine-formaldehyde resin was cationized by adding modifiers so that the fibers closely bonded to improve their usability and the wet strength of paper was greatly improved. Triethanolamine and dimethylamine were added to modify the melamine-formaldehyde resin,respectively.The mechanism of the cationized resin was explored and the possible chemical reactions were deduced. It was concluded that,with the use of triethanolamine,the most optimum product was obtained by hydroxymethylation for 30 min with a temperature of 85℃ and p H of 9. 0 where n( melamine) ∶ n( formaldehyde) ∶ n( methanol) ∶ n( triethanolamine) was 100 ∶ 330 ∶ 450 ∶ 15. With the combined use of dimethylamine and methanol,the optimal product was acquired by condensation for 30 min at a temperature of 50℃ and p H of 2. 0 at melamine, formaldehyde, methanol, and dimethylamine molar ratio of100∶ 330∶ 350∶ 20. With the only use of dimethylamine,the optimal product was obtained by condensation at melamine,formaldehyde,dimethylamine molar ratio of 100∶ 330∶ 10. The wet tensile strength of fruit-bagging paper was improved by adding cationized melamine-formaldehyde resin. The zeta potential,charge density,and conductivity of the melamine-formaldehyde resin were also studied.
文摘Melamine formaldehyde (MF) foam is kind of fire-retardant material and has great potential in acoustic and thermal insulation area. In this article, MF resin foam was prepared by microwave radiation. We discussed the thermal stability of MF foam and the effect of different emulsifiers on its morphology, apparent density, fire-retardancy and mechanical property. The decomposition temperature of MF foam we prepared is nearly 400℃ and the constitution of residue after combustion is made up of carbon and graphite. Emulsifier influenced the apparent density of MF foam and using coemulsifiers can get flexible foam with uniform cell size, good morphology and low apparent density. When the fire-retardant MF foam’s apparent density is low of 5.53 kg/cm-3, its value of LOI can reach 32.4. The mechanical property of foam is consistent with apparent density.
文摘A simple and convenient procedure for the synthesis of nitriles by dehydration of aldoxime using supported sulphuric acid on melamine-formaldehyde resin （MFR） under solvent-free condition has been developed. A variety of aromatic and aliphatic aldoximes were converted to the corresponding nitriles. The resin was recovered and reused for subsequent reactions. ~ 2011 Ramin Rezaei. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.
基金Supported by the National Natural Science Foundation of China（Nos.51072048, 51102083）, the Natural Science Foundation of Heilongjiang Province, China（Nos.JC201211, B201107） and the Program for Science and Technology Project of Heilong：jiang Province, China（No.WB 10A204）.
文摘The nitrogen and oxygen co-doped hollow carbon spheres（HCSs） were prepared via a simple pyrolysis of solid melamine-formaldhyde resin spheres. The carbonization temperature has an important influence on the specific surface area, pore-size distribution and heteroatom contents of HCSs. The synergistic effects of those physical and chemical properties on supercapacitor performance were systematically investigated. Among the HCSs obtained at different temperatures, HCSs-800（co-doped HCSs at 800℃） exhibits the best reversible specific capacitance in 2 mol/L H2SO4 electrolyte and meanwhile maintains a high-class capacitance retention capability. The nitrogen heteroatoms were confirmed to play a crucial role in improving capacitance in an acid medium. This kind of nitrogen doved HCSs is a potential candidate for an efficient electrode material for supercapacitors.
文摘Melamine-formaldehyde resin supported H~＋ is used as an efficient catalyst in the Pechmann condensation reaction of phenols withβ-ketoesters,in solvent-free media leading to the formation of coumarin derivatives using conventional heating and microwave irradiation in excellent yields with good purity.
