A novel 3D hetero-nuclear framework,namely [K_2Cd_5（Hbptc）_4（H_2O）_（12）·12H_2O]_n（1,H4 bptc = biphenyl-2,3,3？,5？-tetracarboxylic acid）,was obtained by hydrothermal reaction. X-ray singlecrystal structur...A novel 3D hetero-nuclear framework,namely [K_2Cd_5（Hbptc）_4（H_2O）_（12）·12H_2O]_n（1,H4 bptc = biphenyl-2,3,3？,5？-tetracarboxylic acid）,was obtained by hydrothermal reaction. X-ray singlecrystal structure analysis reveals that polymer 1 crystallizes in orthorhombic,space group Pbcn with a = 26.6152（13）,b = 11.7449（5）,c = 29.5923（14） ？,V = 9250.3（7） ？~3,C_（64）H_（76）Cd_5K_2O_（56）,Mr = 2381.44,Dc = 1.710 g/cm^3,μ（MoK α） = 1.323 mm^（-1）,F（000） = 4744,Z = 4,the final R = 0.0668 and wR = 0.1135 for 10613 observed reflections（I 〉 2σ（I））. Polymer 1 displays a 3D network that is built on the unprecedented heterobimetallic [Cd_3Cd_2K] molecular building block with a（3,4）-connected（6·8·8）2（6·6·82·82·126·126） topology which represents a rare 2-fold interpenetrating 3D framework topology network. The luminescence analyses reveal that polymer 1 shows obvious emission at room temperature in the solid state. In addition,it was also characterized by elemental,IR spectra and TG analyses.展开更多
Purpose: Involuntary mental health admissions remain a highly contested area in law, policy and practice. There are growing concerns about the effectiveness and potential harms of using coercion to enable treatment. T...Purpose: Involuntary mental health admissions remain a highly contested area in law, policy and practice. There are growing concerns about the effectiveness and potential harms of using coercion to enable treatment. These concerns are heightened by the worldwide shift to recovery oriented care, which emphasizes the importance for mental health consumers experiencing self- sufficiency, control and having input into their own treatment. Involuntary treatment challenges these very principles. Methods: For this study we adapted Noblit and Hare Meta Ethnography methods and synthesized the themes of seven qualitative studies which focused on the experiences of involuntary mental health admission. Results: Seven overarching dimensions were identified as either hindering or facilitating recovery, namely: 1) having input into own treatment;2) shared humanity;3) power imbalance/ balance;4) freedom and control;5) ability/inability to incorporate the episode/experience;6) treatment factors;and 7) importance of relationships. Conclusions: The findings of this study indicate that the recovery framework, in particular the concepts of hope, relationships and control are very relevant in the context of involuntary settings.展开更多
基金supported by the National Natural Science Foundation of China(No.21273101 and 21302082)the Program for Science&Technology Innovation Talents in Universities of Henan Province(2014HASTIT014,14IRTSTHN008 and 164100510012)the Tackle Key Problem of Science and Technology Project of Henan Province(No.142102310483)
文摘A novel 3D hetero-nuclear framework,namely [K_2Cd_5（Hbptc）_4（H_2O）_（12）·12H_2O]_n（1,H4 bptc = biphenyl-2,3,3？,5？-tetracarboxylic acid）,was obtained by hydrothermal reaction. X-ray singlecrystal structure analysis reveals that polymer 1 crystallizes in orthorhombic,space group Pbcn with a = 26.6152（13）,b = 11.7449（5）,c = 29.5923（14） ？,V = 9250.3（7） ？~3,C_（64）H_（76）Cd_5K_2O_（56）,Mr = 2381.44,Dc = 1.710 g/cm^3,μ（MoK α） = 1.323 mm^（-1）,F（000） = 4744,Z = 4,the final R = 0.0668 and wR = 0.1135 for 10613 observed reflections（I 〉 2σ（I））. Polymer 1 displays a 3D network that is built on the unprecedented heterobimetallic [Cd_3Cd_2K] molecular building block with a（3,4）-connected（6·8·8）2（6·6·82·82·126·126） topology which represents a rare 2-fold interpenetrating 3D framework topology network. The luminescence analyses reveal that polymer 1 shows obvious emission at room temperature in the solid state. In addition,it was also characterized by elemental,IR spectra and TG analyses.
文摘Purpose: Involuntary mental health admissions remain a highly contested area in law, policy and practice. There are growing concerns about the effectiveness and potential harms of using coercion to enable treatment. These concerns are heightened by the worldwide shift to recovery oriented care, which emphasizes the importance for mental health consumers experiencing self- sufficiency, control and having input into their own treatment. Involuntary treatment challenges these very principles. Methods: For this study we adapted Noblit and Hare Meta Ethnography methods and synthesized the themes of seven qualitative studies which focused on the experiences of involuntary mental health admission. Results: Seven overarching dimensions were identified as either hindering or facilitating recovery, namely: 1) having input into own treatment;2) shared humanity;3) power imbalance/ balance;4) freedom and control;5) ability/inability to incorporate the episode/experience;6) treatment factors;and 7) importance of relationships. Conclusions: The findings of this study indicate that the recovery framework, in particular the concepts of hope, relationships and control are very relevant in the context of involuntary settings.
