Active metal bismuth is produced in situ via Sin/BiCl_3, system in aqueous media. Promoted by this active species. β-aminoesters and α-selenoesters are synthesized via reaction of α-bromoesters with 1 -(α-aminoalk...Active metal bismuth is produced in situ via Sin/BiCl_3, system in aqueous media. Promoted by this active species. β-aminoesters and α-selenoesters are synthesized via reaction of α-bromoesters with 1 -(α-aminoalkyl ) benzotriazole and diselenides in moderate to good yields.展开更多
In the presence of active metal bismuth (Bi) which was prepared from the combination of bismuth trichloride and sodium borohydride,aldehydes have been found to react with allyl bromide in aqueous media,and the corresp...In the presence of active metal bismuth (Bi) which was prepared from the combination of bismuth trichloride and sodium borohydride,aldehydes have been found to react with allyl bromide in aqueous media,and the corresponding homoallylic alcohols were obtained in excellent yields with high chemo-and stereoselectivity.展开更多
A Phase-change thermal control unit( PTCU) filled with metallic phase change material( PCM) Bismuth alloy for electric devices thermal protection was developed and investigated experimentally. The PTCU filled with PCM...A Phase-change thermal control unit( PTCU) filled with metallic phase change material( PCM) Bismuth alloy for electric devices thermal protection was developed and investigated experimentally. The PTCU filled with PCM was designed and manufactured. Resistance heating components( RCHs) produced 1 W,3 W, 5 W,7W,and 10 W for simulating heat generation of electronic devices. At various heating power levels,the performance of PTCU were tested during heating period and one duty cycle period. The experimental results show that the PTCU delays RCH reaching the maximum operating temperature. Also,a numerical model was developed to enable interpretation of experimental results and to perform parametric studies. The results confirmed that the PTCU is suitable for electric devices thermal control.展开更多
The conventional p-n heterojunction photocatalysts suffer from the incompatibility between the interfacial charge transfer efficiency and the redox ability of charge carriers.To optimize the interfacial charge transfe...The conventional p-n heterojunction photocatalysts suffer from the incompatibility between the interfacial charge transfer efficiency and the redox ability of charge carriers.To optimize the interfacial charge transfer of the conventional BiOI/TiO_(2) p-n photocatalyst,we synthesized the BiOI/Bi/TiO_(2) ternary photocatalyst with sandwiched metallic bismuth(Bi~0)by the oxygen-vacancy assisted method.The DFT calculation and structural characterizations confirmed the reaction of the electron-rich oxygen vacancies in the 2D-TiO_(2) nanosheets(TiO_(2)-NS)with the adsorbed BiO~+species.This reaction broke the Bi-O bonds to form Bi^(0) nanoparticles in-situ at the interface but still maintained the p-n heterojunction well.The NO-TPD and XRD analyses for samples correlated the Bi~0 formation with the oxygen vacancy concentrations well.The sandwiched Bi~0 functioned as an electronic transfer mediator like that in the Z-scheme heterostructure.Comparing with 0.20 BiOI/TiO_(2)-NP(NP,Nanoparticles),0.20 BiOI/Bi/TiO_(2)-NS-a(NS,Nanosheet)showed a much improved catalytic performance,i.e.,duplicated apparent quantum yield(AQY)and triplicated reaction rate constant(k).Also,the formation mechanism and the reaction mechanism were investigated in detail.This work provides a new strategy for the improving of the conventional p-n photocatalysts and new insights into the nature of the photocatalysis.展开更多
Metallic bismuth crystal is one important and interesting semimetal that has attracted great attention owing to its unique thermal and electrical properties. Herein, we report a facile, green, cost-effective and susta...Metallic bismuth crystal is one important and interesting semimetal that has attracted great attention owing to its unique thermal and electrical properties. Herein, we report a facile, green, cost-effective and sustainable solvothermal process using ethanol, glycol, isopropanol, phenylcarbinol as solvent and commercial Bi_2O_3 as the starting material to produce high-purity metallic Bi with tunable morphologies on large scale. It is found that all alcohols are capable of reducing Bi_2O_3 to Bi and the reducibility of glycol is proved to be the strongest. The highest purity of the resultant Bi is calculated to be 99.74%. What's more, the morphology of final Bi particles is controllable by adding various types and concentrations of additives. As a consequence, our work lays the root for the large scale solvothermal production of high-purity Bi particles with various regular morphologies.展开更多
New design solutions have been proposed for a BRS-GPG type reactor circuit, which are different from transport and stationary low and medium-powered reactor installations cooled with heavy liquid-metal coolants, and w...New design solutions have been proposed for a BRS-GPG type reactor circuit, which are different from transport and stationary low and medium-powered reactor installations cooled with heavy liquid-metal coolants, and which correspond to the evolutionary development of such installations. While developing these solutions, the available experience in creating and operating So</span><span>viet pilot and commercial power plants cooled with lead-bismuth coolants</span><span> was used, including investigations, primarily experimental ones, carried out by team of authors in justification of a capacity range (50</span></span><span> </span><span>-</span><span> </span><span>250 MW) of low and medium-powered reactor plants with horizontal steam generators (BRS-</span><span> </span><span>GPG) proposed and elaborated at the NNSTU.展开更多
基金the National Natural Science Foundation of China ! 29872010,294938004NSF of Zhe-hang province, China and the Laboratory of O
文摘Active metal bismuth is produced in situ via Sin/BiCl_3, system in aqueous media. Promoted by this active species. β-aminoesters and α-selenoesters are synthesized via reaction of α-bromoesters with 1 -(α-aminoalkyl ) benzotriazole and diselenides in moderate to good yields.
文摘In the presence of active metal bismuth (Bi) which was prepared from the combination of bismuth trichloride and sodium borohydride,aldehydes have been found to react with allyl bromide in aqueous media,and the corresponding homoallylic alcohols were obtained in excellent yields with high chemo-and stereoselectivity.
文摘A Phase-change thermal control unit( PTCU) filled with metallic phase change material( PCM) Bismuth alloy for electric devices thermal protection was developed and investigated experimentally. The PTCU filled with PCM was designed and manufactured. Resistance heating components( RCHs) produced 1 W,3 W, 5 W,7W,and 10 W for simulating heat generation of electronic devices. At various heating power levels,the performance of PTCU were tested during heating period and one duty cycle period. The experimental results show that the PTCU delays RCH reaching the maximum operating temperature. Also,a numerical model was developed to enable interpretation of experimental results and to perform parametric studies. The results confirmed that the PTCU is suitable for electric devices thermal control.
基金financially supported by the National Natural Science Foundation of China(No.21043006 and 51702205)the Education Department of Guangdong Province(No.2018KTSCX063 and 2013KJCX0081)+2 种基金the Science and Technology Planning Project of Guangdong Province(No.2014A020216045)the 2020 Li Ka Shing Foundation Cross-Disciplinary Research Grant(2020LKSFG09A)the Guangdong Key Discipline Fund at GTIIT。
文摘The conventional p-n heterojunction photocatalysts suffer from the incompatibility between the interfacial charge transfer efficiency and the redox ability of charge carriers.To optimize the interfacial charge transfer of the conventional BiOI/TiO_(2) p-n photocatalyst,we synthesized the BiOI/Bi/TiO_(2) ternary photocatalyst with sandwiched metallic bismuth(Bi~0)by the oxygen-vacancy assisted method.The DFT calculation and structural characterizations confirmed the reaction of the electron-rich oxygen vacancies in the 2D-TiO_(2) nanosheets(TiO_(2)-NS)with the adsorbed BiO~+species.This reaction broke the Bi-O bonds to form Bi^(0) nanoparticles in-situ at the interface but still maintained the p-n heterojunction well.The NO-TPD and XRD analyses for samples correlated the Bi~0 formation with the oxygen vacancy concentrations well.The sandwiched Bi~0 functioned as an electronic transfer mediator like that in the Z-scheme heterostructure.Comparing with 0.20 BiOI/TiO_(2)-NP(NP,Nanoparticles),0.20 BiOI/Bi/TiO_(2)-NS-a(NS,Nanosheet)showed a much improved catalytic performance,i.e.,duplicated apparent quantum yield(AQY)and triplicated reaction rate constant(k).Also,the formation mechanism and the reaction mechanism were investigated in detail.This work provides a new strategy for the improving of the conventional p-n photocatalysts and new insights into the nature of the photocatalysis.
基金Supported by the Natural Science Foundation of China(51373096,11304198)
文摘Metallic bismuth crystal is one important and interesting semimetal that has attracted great attention owing to its unique thermal and electrical properties. Herein, we report a facile, green, cost-effective and sustainable solvothermal process using ethanol, glycol, isopropanol, phenylcarbinol as solvent and commercial Bi_2O_3 as the starting material to produce high-purity metallic Bi with tunable morphologies on large scale. It is found that all alcohols are capable of reducing Bi_2O_3 to Bi and the reducibility of glycol is proved to be the strongest. The highest purity of the resultant Bi is calculated to be 99.74%. What's more, the morphology of final Bi particles is controllable by adding various types and concentrations of additives. As a consequence, our work lays the root for the large scale solvothermal production of high-purity Bi particles with various regular morphologies.
文摘New design solutions have been proposed for a BRS-GPG type reactor circuit, which are different from transport and stationary low and medium-powered reactor installations cooled with heavy liquid-metal coolants, and which correspond to the evolutionary development of such installations. While developing these solutions, the available experience in creating and operating So</span><span>viet pilot and commercial power plants cooled with lead-bismuth coolants</span><span> was used, including investigations, primarily experimental ones, carried out by team of authors in justification of a capacity range (50</span></span><span> </span><span>-</span><span> </span><span>250 MW) of low and medium-powered reactor plants with horizontal steam generators (BRS-</span><span> </span><span>GPG) proposed and elaborated at the NNSTU.
