Fe Ni合金与无铅焊料反应速率低,生成的金属间化合物(IMC)较薄,有望作为圆片级封装(WLP)凸点下金属(UBM)层材料。对两种Fe Ni UBM以及一种Cu UBM圆片级封装样品进行回流、湿热以及预处理实验,并通过推球的方法,对其焊点进行剪切测试。...Fe Ni合金与无铅焊料反应速率低,生成的金属间化合物(IMC)较薄,有望作为圆片级封装(WLP)凸点下金属(UBM)层材料。对两种Fe Ni UBM以及一种Cu UBM圆片级封装样品进行回流、湿热以及预处理实验,并通过推球的方法,对其焊点进行剪切测试。通过断面与截面分析,研究其在不同处理条件下的金属间化合物生长情况,分析其断裂模式。结果表明,Fe Ni UBM焊点剪切力高于Cu UBM。Fe47Ni UBM与焊料反应生成的金属间化合物较薄,对于剪切力影响较小,而Fe64Ni UBM与焊料反应生成离散的Cu Ni Sn金属间化合物,对于其焊点强度有提高作用,Cu UBM与焊料反应生成较厚的金属间化合物,会明显降低焊点的剪切力。断面分析表明,Cu UBM会随焊球发生断裂,其强度明显小于Fe Ni UBM。展开更多
Because Fe has a more negative standard reduction potential than Ni, the simultaneous electroless deposition of Fe and Ni is difficult. In this study, Fe-42Ni（P） electroless deposit was prepared by using disodium et...Because Fe has a more negative standard reduction potential than Ni, the simultaneous electroless deposition of Fe and Ni is difficult. In this study, Fe-42Ni（P） electroless deposit was prepared by using disodium ethylene diarnine tetraacetate （ETDA-2Na） as complexing agent to reduce the difference in the electrode potential between Ni2＋ and Fe2＋o The solderability and the interfacial reaction between Fe-42Ni（P） alloy and Sn were investigated. It was found that the electroless Fe-42Ni（P） alloy has excellent wettability with Sn. Moreover, the interfacial reaction rate between Fe-42Ni（P） and Sn is very slow. These results suggest that Fe-42Ni（P） alloy may become an attractive under-bump metallization （UBM）.展开更多
文摘Fe Ni合金与无铅焊料反应速率低,生成的金属间化合物(IMC)较薄,有望作为圆片级封装(WLP)凸点下金属(UBM)层材料。对两种Fe Ni UBM以及一种Cu UBM圆片级封装样品进行回流、湿热以及预处理实验,并通过推球的方法,对其焊点进行剪切测试。通过断面与截面分析,研究其在不同处理条件下的金属间化合物生长情况,分析其断裂模式。结果表明,Fe Ni UBM焊点剪切力高于Cu UBM。Fe47Ni UBM与焊料反应生成的金属间化合物较薄,对于剪切力影响较小,而Fe64Ni UBM与焊料反应生成离散的Cu Ni Sn金属间化合物,对于其焊点强度有提高作用,Cu UBM与焊料反应生成较厚的金属间化合物,会明显降低焊点的剪切力。断面分析表明,Cu UBM会随焊球发生断裂,其强度明显小于Fe Ni UBM。
基金supported by the National Basic Research Program of China (No. 2004CB619306)the National Natural Science Foundation of China (Nos. 51171191 and 51101161)the Major National Science and Technology Program of China (No. 2011ZX02602)
文摘Because Fe has a more negative standard reduction potential than Ni, the simultaneous electroless deposition of Fe and Ni is difficult. In this study, Fe-42Ni（P） electroless deposit was prepared by using disodium ethylene diarnine tetraacetate （ETDA-2Na） as complexing agent to reduce the difference in the electrode potential between Ni2＋ and Fe2＋o The solderability and the interfacial reaction between Fe-42Ni（P） alloy and Sn were investigated. It was found that the electroless Fe-42Ni（P） alloy has excellent wettability with Sn. Moreover, the interfacial reaction rate between Fe-42Ni（P） and Sn is very slow. These results suggest that Fe-42Ni（P） alloy may become an attractive under-bump metallization （UBM）.
