The chelate complex of Cu2+ with 2-hydroxy-(4-methylthio)butanoate(MHA-H, the anion derived from the so-called methionine hydroxy-analogue, largely used in animal nutrition as a source of methionine, MHA) is an e...The chelate complex of Cu2+ with 2-hydroxy-(4-methylthio)butanoate(MHA-H, the anion derived from the so-called methionine hydroxy-analogue, largely used in animal nutrition as a source of methionine, MHA) is an efficient, bioavailable trace mineral additive for animal feeding. The structure of MHA-H copper chelate was investigated by single-crystal X-ray diffraction. The crystal structure(C10H18Cu O6S2, 1, monoclinic, space group P21/c, Z = 2, a = 16.158(4), b = 4.9733(12), c = 9.159(2) ?, β = 104.786(4)°) exhibits that two MHA-H ligands coordinate with a CuII ion to form a square-planar environment completed to an octahedron through interaction with carbonyl oxygens of neighboring molecules, which expand to constitute a two-dimensional sheet coordination network. And a separation between the hydrophilic and lipophilic moieties like micelles was found in the packing structure. X-ray powder diffraction and thermogravimetric analysis were used to study the phase purity of the bulk sample and thermostability of complex 1, respectively.展开更多
欧盟是中国食品接触材料及制品的主要出口地区之一,且出口数量近年来呈现逐年上升的趋势。本文通过分析2012~2016年欧盟食品和饲料快速预警系统(Rapid Alert System for Food and Feed,RASFF)对华食品接触材料及制品通报情况,总结其涉...欧盟是中国食品接触材料及制品的主要出口地区之一,且出口数量近年来呈现逐年上升的趋势。本文通过分析2012~2016年欧盟食品和饲料快速预警系统(Rapid Alert System for Food and Feed,RASFF)对华食品接触材料及制品通报情况,总结其涉及的材质情况、风险项目等,发现食品接触用金属材料及制品是中国输欧食品接触材料及制品中的高风险产品,食品接触用金属材料及制品通报数量占通报总量的35.60%。重金属超标是通报中最主要的风险项目,其中重金属铬、锰、镍超标最为突出,并探讨了这些情况对我国食品接触材料及制品安全监管的启示。展开更多
重金属一直是我国食品污染的主要原因之一。本文通过总结2011~2015年欧盟食品和饲料快速通报系统(rapid alert system for food and feed,RASFF)通报我国出口食品重金属问题,并分别对通报类型、食品种类、各类重金属分布情况及通报国...重金属一直是我国食品污染的主要原因之一。本文通过总结2011~2015年欧盟食品和饲料快速通报系统(rapid alert system for food and feed,RASFF)通报我国出口食品重金属问题,并分别对通报类型、食品种类、各类重金属分布情况及通报国家等进行统计分析,研究欧盟在重金属方面的技术壁垒措施,从而为出口企业提高产品质量和我国行政管理部门制定政策、标准提供参考,以便采取有效措施积极应对,推动和扩大输欧贸易。展开更多
The wetting of galvanized steel by molten Al alloys was studied in the cold metal transfer process by the sessile drop method using a high speed video camera.The wetting behavior can be divided into two typical cases,...The wetting of galvanized steel by molten Al alloys was studied in the cold metal transfer process by the sessile drop method using a high speed video camera.The wetting behavior can be divided into two typical cases,trending of non-wetting by using small wire feeding speed and wetting by using large wire feeding speed.The Leidenfrost effect is caused by the volatilization of Zn,which is responsible for the former case.The enhanced wettability of steel by Al and the weakening of the Leidenfrost effect are responsible for the latter case.Zn is the destabilizing factor for Al-steel joining that needs to be avoided by a reasonable design of process.展开更多
基金supported by the National Natural Science Foundation of China (No. 21301139,21373158,21103135,51304158)Scientific Research Program Funded by Shaanxi Provincial Education Department (No. 2013JK0651)+1 种基金the Scientific Research Cultivating Fund (No. 201221)the Doctoral Starting Fund (No. 2014QDJ004) from Xi'an University of Science and Technology
文摘The chelate complex of Cu2+ with 2-hydroxy-(4-methylthio)butanoate(MHA-H, the anion derived from the so-called methionine hydroxy-analogue, largely used in animal nutrition as a source of methionine, MHA) is an efficient, bioavailable trace mineral additive for animal feeding. The structure of MHA-H copper chelate was investigated by single-crystal X-ray diffraction. The crystal structure(C10H18Cu O6S2, 1, monoclinic, space group P21/c, Z = 2, a = 16.158(4), b = 4.9733(12), c = 9.159(2) ?, β = 104.786(4)°) exhibits that two MHA-H ligands coordinate with a CuII ion to form a square-planar environment completed to an octahedron through interaction with carbonyl oxygens of neighboring molecules, which expand to constitute a two-dimensional sheet coordination network. And a separation between the hydrophilic and lipophilic moieties like micelles was found in the packing structure. X-ray powder diffraction and thermogravimetric analysis were used to study the phase purity of the bulk sample and thermostability of complex 1, respectively.
文摘欧盟是中国食品接触材料及制品的主要出口地区之一,且出口数量近年来呈现逐年上升的趋势。本文通过分析2012~2016年欧盟食品和饲料快速预警系统(Rapid Alert System for Food and Feed,RASFF)对华食品接触材料及制品通报情况,总结其涉及的材质情况、风险项目等,发现食品接触用金属材料及制品是中国输欧食品接触材料及制品中的高风险产品,食品接触用金属材料及制品通报数量占通报总量的35.60%。重金属超标是通报中最主要的风险项目,其中重金属铬、锰、镍超标最为突出,并探讨了这些情况对我国食品接触材料及制品安全监管的启示。
文摘重金属一直是我国食品污染的主要原因之一。本文通过总结2011~2015年欧盟食品和饲料快速通报系统(rapid alert system for food and feed,RASFF)通报我国出口食品重金属问题,并分别对通报类型、食品种类、各类重金属分布情况及通报国家等进行统计分析,研究欧盟在重金属方面的技术壁垒措施,从而为出口企业提高产品质量和我国行政管理部门制定政策、标准提供参考,以便采取有效措施积极应对,推动和扩大输欧贸易。
基金Item Sponsored by National Natural Science Foundation of China(51301083,51265028)Provincial Fund for Distinguished Young Scientists of Gansu of China(1506RJDA087)
文摘The wetting of galvanized steel by molten Al alloys was studied in the cold metal transfer process by the sessile drop method using a high speed video camera.The wetting behavior can be divided into two typical cases,trending of non-wetting by using small wire feeding speed and wetting by using large wire feeding speed.The Leidenfrost effect is caused by the volatilization of Zn,which is responsible for the former case.The enhanced wettability of steel by Al and the weakening of the Leidenfrost effect are responsible for the latter case.Zn is the destabilizing factor for Al-steel joining that needs to be avoided by a reasonable design of process.