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Thermal and piezoelectric properties of Bi_(3.15)Nd_(0.85)Ti_3O_(12) thin film prepared by metal organic decomposition
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作者 胡和平 戴顺洪 +4 位作者 郑学军 周益春 冯雪 张大志 何林 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2010年第8期1424-1428,共5页
Bi3.15Nd0.85Ti3O12 (BNT) powder and thin film were prepared by metal organic decomposition (MOD) method. The heat flow curve of BNT powder was measured with a modulated temperature differential scanning calorimete... Bi3.15Nd0.85Ti3O12 (BNT) powder and thin film were prepared by metal organic decomposition (MOD) method. The heat flow curve of BNT powder was measured with a modulated temperature differential scanning calorimeter, and thermal physical parameters such as thermal conductivity coefficient and thermal diffusion coefficient were obtained from the heat flow curve. The phase identification, ferroelectric, and piezoelectric properties of BNT thin film annealed at 700℃ were investigated with X-ray diffractometer, ferroelectric analyzer, and scanning probe microscope. The results show that the thin films consisting of a single phase of bismuth-layered perovskite are polycrystalline, without a preferred orientation. Remnant polarization 2Pr is 63.2 μC/cm2 under 530 kV/cm applied field, and the effective piezoelectric coefficient d33 is 30 pm/V. 展开更多
关键词 bismuth-layered perovskite metal organic decomposition (MOD) thermal parameter remnant polarization effective piezoelectric coefficient
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Ethanol sensing properties of Bi_(3.15)Nd_(0.85)Ti_3O_(12) films at low operating temperatures
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作者 Hong JIANG Yong ZHANG 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2016年第12期3189-3195,共7页
Bi3.15Nd0.85Ti3O12 (BNdT) films were deposited on Pt/Ti/SiO2/Si(100) substrates by a metal organic decomposition (MOD)method, and annealed by a rapid thermal annealing process in oxygen atmosphere and in air, respecti... Bi3.15Nd0.85Ti3O12 (BNdT) films were deposited on Pt/Ti/SiO2/Si(100) substrates by a metal organic decomposition (MOD)method, and annealed by a rapid thermal annealing process in oxygen atmosphere and in air, respectively. The crystalline structuresand morphologies of BNdT films were characterized by X-ray diffraction and field-emission scanning electron microscopy, and thegas sensing properties were measured by monitoring its resistance at different gas concentrations. The results indicate that the BNdTfilms annealed in air are of porous microstructure and rough surface, and the annealing atmosphere has great influence on gas sensingproperties. At an operating temperature of 100 °C, the BNdT films annealed in air are of high response value to 1×10?6 gaseousethanol, and the detecting limit is as low as 0.1×10?6. The corresponding response and recovery time is about 10 and 6 s, respectively.The results can offer useful guidelines for fabricating high performance ethanol sensors. 展开更多
关键词 BNdT film ethanol sensing properties metal organic decomposition annealing atmosphere low operating temperature
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