Study on full-length recoverable resin-metal bolts

The paper introduces a kind of full length recoverable resin metal bolts, expounds its structural principle and stress features, and gives some instances in laboratory tests and underground tests. The results show that full length recoverable resin metal bolts can be used for supporting the walls of class Ⅰ～Ⅲ mining gateways, that the anchoring force is 50 kN or so, and that the recoverability rate is more than 80%, thus the supporting effect is better than that of split set bolts.

Preparation of Low Cost Activated Carbon from Deactivated Resin Catalyst for Methyl Tert-Butyl Ether Synthesis and Its Application in Dimethyl Sulfide Adsorption with Transition Metal Impregnation

In this paper, a low-cost activated carbon(AC) was prepared from deactivated resin catalyst(DRC) for methyl tert-butyl ether(MTBE) synthesis through carbonization and subsequent steam activation treatment. The activated carbon was characterized in detail. After loading various transition metals, including Cu^(2+), Ag+, Co^(2+), Ni^(2+), Zn^(2+), and Fe^(3+) via the ultrasonic-assisted impregnation method, a series of metal-loaded adsorbents(xM-AC) were obtained and their dimethyl sulfide(DMS) adsorption performance was investigated in a batch system. Among these adsorbents, 15Cu-AC presented a superior DMS adsorption capacity equating to 58.986 mg/g due to the formation of S-M(σ) bonds between Cu^(2+) and sulfur atoms of DMS as confirmed by the Raman spectra and kinetic study.

ADSORPTION SELECTIVITY FOR Cu^(2+),Ni^(2+),Co^(2+)IONS USING CROSSLINKING CHITOSAN RESINS IMPRINTED BY METAL IONS

Metal ion-imprintedly crosslinked chitosan resin 1 and resin 2 were prepared by theuse of Cu2+ and Ni2+ as template ions and glutaraldehyde as crosslinking agent, respectively.Through investigation on the adsorption capacities and binding constants for Cu2+, Ni2+andCo2+ ions on chitosan resins, resin 1 and resin 2 exhibit the adsorption selectivity for themixture solution of 1:1 Cu2+ and Ni2+ ions. The adsorption selectivity of metal ion-imprintedresins for their template ions is much higher than that of uncrosslinked chitosan resin.

SYNTHESIS, CHARACTERIZATION, METAL-UPTAKE BEHAVIOR OF BIS(BENZIMIDAZOLE) RESIN SUPPORTED ON EPOXIDE POLYMER

The new chelate resins, abbreviated as PNBMZs and PBBMZs based on epoxide polymer, were synthesized by polycondensation of N,N-diglycidyl-4-glycidyloxyaniline or 1,4-bis（2,3-epoxypropyl）benzene with the primary amine group of 1,3-bis（benzimidazol-2yl）propylamine （BBPAH）. The ion exchangers contain 2.71-3.23 mmol of the ligand contents per gram of the resin. Batch extraction capacities were determined for the metal chloride salts in buffer solutions in the pH range from -1 to 6.0. The chelate resins were very selective for Cu^2＋, Zn^2＋, Cd^2＋ in the presence of other divalent transition metal ions. The maximum uptake capacities of PNBMZ （synthetic molar ratio = 1：1.5） under non-competitive condition were found to be 0.94 mmol/g for Cu^2＋ at pH = 2, 1.3 mmol/g for Cd^2＋ at pH = 1 and 1.75 mmol/g for Zn^2＋ at pH = -1 respectively. While in the case of PBBMZ, it was 1.39 mmol/g for Cd〉 at pH = 1. The metal-uptake behaviors for both of them showed strong pH dependence, and their extraction capacities increase with decreasing pH. The uptake of Cu^2＋ by the resin PNBMZs at pH = 1 was found to be rather fast with t1/2 = 18 min. Metal-uptake experiments under competitive conditions also confirm that the chelate resins have a high selectivity for Cu^2＋, Zn^2＋, Cd^2＋ and the contrary pH dependence.

SYNTHESIS OF 1－（2－AMINOETHYL） PIPERAZINE RESIN AND ITS ADSORBABILITYFOR NOBLE METALLIC IONS

ＳＹＮＴＨＥＳＩＳＯＦ１－（２－ＡＭＩＮＯＥＴＨＹＬ）ＰＩＰＥＲＡＺＩＮＥＲＥＳＩＮＡＮＤＩＴＳＡＤＳＯＲＢＡＢＩＬＩＴＹＦＯＲ ＮＯＢＬＥＭＥＴＡＬＬＩＣＩＯＮＳＹｕａｎ；Ｘｉｎｇｚｈｏｎｇ（ＩｎｓｔｉｔｕｔｅｏｆＥｎｖｉｒｏｍｅｎｔａｌＰｒｏｔｅ...

Metal-organic-framework-derived formation of Co–N-doped carbon materials for efficient oxygen reduction reaction

Non-precious metal nitrogen-doped carbonaceous materials have attracted tremendous attention in the field of electrochemical energy storage and conversion.Herein,we report the designed synthesis of a novel series of Co-N-C nanocomposites and their evaluation of electrochemical properties.Novel yolkshell structured Co nanoparticles@polymer materials are fabricated from the facile coating polymer strategy on the surface of ZIF-67.After calcination in nitrogen atmosphere,the Co–N–C nanocomposites in which cobalt metal nanoparticles are embedded in the highly porous and graphitic carbon matrix are successfully achieved.The cobalt nanoparticles containing cobalt metal crystallites with an oxidized shell and/or smaller(or amorphous)cobalt-oxide deposits appear on the surface of graphitic carbons.The prepared Co–N–C nanoparticles showed favorable electrocatalytic activity for oxygen reduction reactions,which is attributed to its high graphitic degree,large surface area and the large amount existence of Co–N active sites.

ADSORPTION STUDIES OF TANNIC ACID BY COMMERCIAL ESTER RESIN XAD-7

Tannic acid and its related compounds are known as refractory organic pollutants, and it can create serious problems for the environment. The adsorption and desorption studies of tannic acid on commercial resins XAD-7 and D-201 are performed, and all data indicates resin XAD-7 can be used as an effective adsorbent for removing tannic acid during water/wastewater treatment. Furthermore, adsorption thermodynamics studies indicate different adsorption mechanisms for TA on XAD-7 and D-201. FT-IR and solid state 13C-NMR spectroscopy are used to explain the adsorption force between XAD-7 and TA. It suggests that hydrogen bonding is the main adsorption force for TA. Finally, XAD-7＇s adsorption capacity in the presence of different metal ions is investigated, which indicates that heavy metal ions in solutions can decrease the adsorption capacity for TA on ester resin XAD-7.

Adsorption properties of Ag(Ⅰ),Au(Ⅲ),Pd(Ⅱ)and Pt(Ⅳ)ions on commercial 717 anion-exchange resin

The adsorption properties of the four precious metal ions(Ag(Ⅰ),Au(Ⅲ),Pd(Ⅱ)and Pt(Ⅳ))on the commercial Cl--form 717 strongly basic anion-exchange resin were studied in detail.The effects of the contact time,solution acidity,and concentrations of Cl - and Pb 2+ ions on the adsorption properties were studied by the batch method.Then,the column method was conducted under the optimized adsorption conditions(pH=3.0).The effects of the sample loading flow rate and the length-to-diameter ratios of the columns were investigated.The precious metal ions adsorbed could not be eluted completely after the saturated adsorption because the precious metal ions were found to be reduced to their metallic states during the adsorption process.So,it is recommended that the commercial Cl--form 717 strongly basic anion-exchange resin should be decomposed directly to recovery the precious metals after the saturated adsorption.

SYNTHESES AND ADSORPTION PROPERTIES OF PHENOL-FORMALDEHYDE-TYPE CHELATING RESINS BEARING THE FUNCTIONAL GROUP OFTAR TARIC ACID

Several kinds of novel chelating resins bearing the functional group of tartaric acid (TTA-FQ-12, TTA-FQ-23, and TTA-FQ-34) were synthesized by reacting epoxy maleic anhydride, which was prepared through the oxidization reaction of maleic anhydride by hydrogen peroxide, with phenol-formaldehyde resin containing polyamine (FQ resins series). The effects of such factors as reaction time, reaction temperature and pH value on the loading capacity of TTA in resins were investigated. The results showed that the optimum reaction conditions are as follows: time 9-12 h; temperature 90-105'C; pH value 6-10. The loading capacities of TTA can reach 0.15, 0.14, and 0.11 mmol/g-1 when the functional group of FQ resin was - OCH2CH2NHC2H4NH2, - O(CH2CH2NH)2C2H4NH2 and - O(CH2CH2NH)3C2H4NH2), respectively. The structures of resins were characterized by FTIR spectra. The primary study on the adsorption properties of the resins for metal ions showed that there are two kinds of adsorption mechanisms i.e. ion exchange and chelate in the adsorption process. TTA-FQ resins have much higher adsorption selectivity for Pb2+and Zn2+ than for Cu2+ and Ni2+. These resins can probably be used for separating Pb2+ or Zn2+ in the mixture of metal ions or for treating wastewater containing heavy metal ions.

ADSORPTION OF HUMIC SUBSTANCES BY MACRO WEAKLY BASIC IONEXCHANGE RESIN AND THEIR EFFECTS ON REMOVAL OF Cu^(2+) AND Pb^(2+)

Adsorption of humic, tannic and gallic acids by a macro weakly basic ion-exchange resin JN-01 was studied. The adsorption capacity of this resin for gallic and tannic acids is much higher than that for humic acid, which can be explained on the basis of both their molecular size and ionization degree. Furthermore, humic acid is separated into different components with molecular weight in the range from 2000 Da to 100000 Da by ultra-filter, and their adsorption isotherms on resin JN-01 indicate that humic acid＇s molecular weight is an important factor which makes significant influence on adsorption. Finally, changes in the amount of Cu^2＋ and Pb^2＋ adsorbed on resin JN-01 as a function of the concentration of each of these three acids were studied. A large increase in the heavy metal ions uptake is observed in the presence of humic substance, such advantages are due to the interactions between the heavy metal ions and the unbound functional groups of the adsorbed organic acids.

Heavy metal extraction by a counter-flow moving bed reactor

In the current study, the extraction of heavy metal ions (Zn2+, Cu2+ and Cd2+) is suggested to be achieved by a counter-flow moving bed reactor. The studies are made at high (1 × 10-2 M) and low (1 × 10-4 M) initial concentrations of the heavy metal ions. Theoretical and experimental studies are made on the extraction of the metal ions with impregnated Amberlite resins, prepared by sorption of an organic extractant into the resin. The study suggests structural, kinetic and hydrodynamic parameters that shall be investigated prior to the design of a moving bed reactor. The effect of these parameters on the adsorption extent is theoretically investigated through the proposed model. Analyses of the experimentally estimated external, internal and chemical rate parameters show that the process is controlled by chemical reaction in both concentrations as the chemical reaction rate parameter is significantly smaller than both the internal and the external diffusion rate parameters.

ON THE SYNTHESES OF BENZIDINE CHELATE RESINS CONSISTING OF POLYETHER BACKBONE AND THEIR ADSORPTION PROPERTIES

Three new resins are synthesized by the reaction of polyepichlorohydrin with benzidine, O-tolidine and O-dianisidine, respecti v,ely. Their adsorption properties for Au(III), Pd(II), Pt(IV), Hg(II), Cu(II), Pb(II) and Zn(II) are investigated. The resin containing O-dianisidine group selectively sorbed Au(III) in the presence of transition metal ions. The results show that synergistic effect of anchor groups plays an important role in the adsorption of metal ions.

SYNTHESES AND PROPERTIES OF A CHELATING RESIN WITH MERCAPTO GROUPS

Chelating resins with thiol as functional group were synthesized from poly (β-chloroethyl gly-cidyl ether) . and adsorption of Au ( Ⅲ) , Pd (Ⅱ) , Pt (Ⅳ ), IIg ( Ⅱ ), Cu ( Ⅱ ) and Pb (Ⅱ) on the resins was also inrestigated. Both resins show high affinity for Au ( Ⅲ ),Pd( Ⅱ ) , Pt ( Ⅳ ) and Hg ( Ⅱ ) withina broad range of hydrochloric acid. Results of static and dynamic tests indicate the possibility of separation of Au ( Ⅲ ) , Pd ( Ⅱ ) , Pt ( Ⅳ ) and IIg (Ⅱ) from high concentrations of acid and neutral salt from high concentrations of acid and neutral salt solution.

Synthesis and Adsorption Properties of Polystyrene-supported Chelating Resins Containing Heterocyclic Functional Groups

A series of new chelating resins with incorporating heterocyclic functional groups： pyridine, thiadizole, benzothizole into macroporous chloromethylated polystyrene were synthesized via hydrophilic spacer arm of polyethylene glycol containing sulfur. These chelating resins were found to show high adsorption capacities for Ag^＋, Hg^2＋, Au^3＋ and Pd^2＋, and the presence of spacer arm can enhance adsorption ability due to increase the hydrophilicity of the chelating resins.

电子级IPA微量金属离子吸附分离及其模拟

研究了树脂对异丙醇(IPA)中微量Na^(+)和K^(+)的静态吸附和动态吸附过程,其等温吸附符合Langmuir吸附模型,动力学吸附符合拟一级动力学模型。利用Aspen Adsorption模拟了树脂对IPA中Na^(+)和K^(+)的动态吸附过程,模拟结果和实验测得的穿透曲线吻合良好。通过离子交换树脂去除IPA中的金属离子,最终金属离子质量浓度均低于5.00μg/L。这些结果为IPA中微量金属离子吸附装置的设计提供了依据。

Synthesis and Adsorption Properties of Chelating Resins Containing Sulfoxide and Heterocyclic Functional Groups

Several of new chelating resins containing sulfoxide and heterocyclic functional groups （3-aminopyridine and 2-mercaptobenzothiazole） based on macroporous chloromethylated polystyrene were synthesized and characterized by elemental analysis and infrared spectra. Their adsorption capacities towards Zn^2＋, Cu^2＋, Pb^2＋, Hg^2＋ and Ag^＋ at pH 3.0 and 6.0 were investigated in detail. It was found that the adsorption capacities of the resins containing bis[（3-pyridylaminoethyl）sulfoxide or （2-benzothiazolylthioethyl）sulfoxide for the above ions were higher than that on ones containing single above-mentioned groups.

改性纳米氮化硼对纤维金属层板的性能影响

纤维金属层板是一种由金属薄板与纤维层依次交替铺叠而成,在一定的温度与压力下粘结固化形成的一种混合复合材料。因为其中有金属与纤维两种材料,因此它既有金属的富延展性、韧性强与导热性好等优点,又具有复合材料纤维的抗疲劳、耐高强度与低密度等特点。文章以提升环氧复合材料基体的拉伸与断裂韧性性能和改善FMLs的性能,尤其是冲击与弯曲性能为主要目的,采用向FMLs环氧树脂基体中添加纳米氮化硼(h-BN)的方法,来提升纤维金属层板的力学性能。先对氮化硼材料进行一系列的球磨改性处理,分成不同含量的组分依次加入环氧树脂基体中,确定用量最好的四组,再将这四组环氧树脂复合材料基体用湿法铺层的方法铺在铝薄板与碳纤维布之间,使用硫化机固化的方式制备FMLs试件,利用水切割技术切割成标准试样,并进行冲击与弯曲测试。实验结果表明,向FMLs的环氧树脂基体中添加一定量的纳米氮化硼对FMLs的性能有着积极的影响。

Study on Chelating Resins XXXI Syntheses and Adsorption Properties of a New Type of Bead Resins Containing S and N

A new type of bead crosslinked chelating resins containing coordinate atoms N and S were synthesized by the reaction of polyethyleneimine with chlorometbylthiirane in suitable sovent at temperature of 2080C. These chelating resins exhibited excellent adsorption properties for precious metal ions.