A new gas clean-up process called 'integrated sintered metal screen moving granular bed' (ISMSMGB) for the integrated gasification combined cycle (IGCC) and pressured fluidized bed combustion (PFBC) was develo...A new gas clean-up process called 'integrated sintered metal screen moving granular bed' (ISMSMGB) for the integrated gasification combined cycle (IGCC) and pressured fluidized bed combustion (PFBC) was developed on the basis of a sintered metal candle filter and a cross-flow moving granular bed filter. This is a combination of the surface and deep bed filtering processes. A set of facilities was established and a series of cold model tests were carried out. The dust removal efficiency and the pressure drop of the filter were measured and analyzed. The results show that this process features the advantages of the moving bed for high capacity as well as high inlet dust load and the surface filter for high efficiency. Meanwhile, the granules moving downward cleans the cake on the screen surface, so that the system is operated at steady state.展开更多
In oil drilling processes,sand production in the oil layer is a common issue,generally mitigated by means of sand control screens.To prevent or reduce the risk of damage of these screens and to improve the related ser...In oil drilling processes,sand production in the oil layer is a common issue,generally mitigated by means of sand control screens.To prevent or reduce the risk of damage of these screens and to improve the related service life,it is necessary to investigate the related erosion dynamics.In this study,a screen mesh model based on the flow field similarity theory is proposed to overcome the otherwise too complex geometric structure of this type of equipment.Such model is optimized using experimental data.The predicted results are in good agreement with the measured values,and the error is less than 15%.The results also show that the simplified geometric screen model and the optimized Zhang et al.erosion model have high reliability;therefore,they could effective be used to select underground screen meshes and improve the design of production process.展开更多
This paper, probing into heavy metal control in domestic rubbish by source screening and nutrient element analysis, revealed the feasibility of source control of heavy metals and the suitability of rubbish as turfgras...This paper, probing into heavy metal control in domestic rubbish by source screening and nutrient element analysis, revealed the feasibility of source control of heavy metals and the suitability of rubbish as turfgrass medium. Heavy metals in domestic rubbish were controlled by source screening before composting. The study consisted of a control with garden soil. The contents of main mineral elements and heavy metals in rubbish compost and control were determined by the method of ICP-AES. The results showed that heavy metal concentrations in rubbish were lower than those in garden soil, and little difference occurred between rubbish and garden soil in main mineral element concentrations. Based on this, it was concluded that rubbish compost was favorable for using as turfgrass medium and heavy metal control in rubbish by source screening was effective.展开更多
The coordination compounds of PdII, PtII, RhIII and IrIII metal ions with a Schiff base ligand (L) i.e. 2,6- diacetylpyridine bis(thiosemicarbazone) have been synthesized and characterized by elemental analyses, molar...The coordination compounds of PdII, PtII, RhIII and IrIII metal ions with a Schiff base ligand (L) i.e. 2,6- diacetylpyridine bis(thiosemicarbazone) have been synthesized and characterized by elemental analyses, molar conductance, magnetic susceptibility measurements, IR, NMR and electronic spectral studies. On the basis of molar conductance and elemental analyses the complexes were found to have composition [M(L)]Cl2 and [M’(L)Cl]Cl2, where M = Pd(II), Pt(II) and M’ = Rh(III), Ir(III). The spectral studies reveal that the complexes possess monomeric composition. Complexes of PdII and PtII were found to have four coordinated square planar geometry whereas the complexes of RhIII and IrIII posses six coordinated octahedral geometry. The ligand field parameters were calculated using various energy level diagrams. In vitro synthesized compounds and metal salts have been tested against some species of plant pathogenic fungi and bacteria in order to assess their antimicrobial properties.展开更多
The catalyst screening tests for carbon dioxide oxidative coupling of methane (CO2-OCM) have been investigated over ternary and binary metal oxide catalysts. The catalysts are prepared by doping MgO- and CeO2-based so...The catalyst screening tests for carbon dioxide oxidative coupling of methane (CO2-OCM) have been investigated over ternary and binary metal oxide catalysts. The catalysts are prepared by doping MgO- and CeO2-based solids with oxides from alkali (Li2O), alkaline earth (CaO), and transition metal groups (WO3 or MnO). The presence of the peroxide (O2-2) active sites on the Li2O2, revealed by Raman spectroscopy, may be the key factor in the enhanced performance of some of the Li2O/MgO catalysts. The high reducibility of the CeO2 catalyst, an important factor in the CO2-OCM catalyst activity, may be enhanced by the presence of manganese oxide species. The manganese oxide species increases oxygen mobility and oxygen vacancies in the CeO2 catalyst. Raman and Fourier Transform Infra Red (FT-IR) spectroscopies revealed the presence of lattice vibrations of metal-oxygen bondings and active sites in which the peaks corresponding to the bulk crystalline structures of Li2O, CaO, WO3 and MnO are detected. The performance of 5%MnO/15%CaO/CeO2 catalyst is the most potential among the CeO2-based catalysts, although lower than the 2%Li2O/MgO catalyst. The 2%Li2O/MgO catalyst showed the most promising C2+ hydrocarbons selectivity and yield at 98.0% and 5.7%, respectively.展开更多
基金Chinese Special Funds for Major State Basic Research Projects 973 (No. G1999022104).
文摘A new gas clean-up process called 'integrated sintered metal screen moving granular bed' (ISMSMGB) for the integrated gasification combined cycle (IGCC) and pressured fluidized bed combustion (PFBC) was developed on the basis of a sintered metal candle filter and a cross-flow moving granular bed filter. This is a combination of the surface and deep bed filtering processes. A set of facilities was established and a series of cold model tests were carried out. The dust removal efficiency and the pressure drop of the filter were measured and analyzed. The results show that this process features the advantages of the moving bed for high capacity as well as high inlet dust load and the surface filter for high efficiency. Meanwhile, the granules moving downward cleans the cake on the screen surface, so that the system is operated at steady state.
基金the Foundation of the National Natural Science Foundation of China(No.51974033)Educational Commission of Hubei Province of China(Q20191310,D20171305).
文摘In oil drilling processes,sand production in the oil layer is a common issue,generally mitigated by means of sand control screens.To prevent or reduce the risk of damage of these screens and to improve the related service life,it is necessary to investigate the related erosion dynamics.In this study,a screen mesh model based on the flow field similarity theory is proposed to overcome the otherwise too complex geometric structure of this type of equipment.Such model is optimized using experimental data.The predicted results are in good agreement with the measured values,and the error is less than 15%.The results also show that the simplified geometric screen model and the optimized Zhang et al.erosion model have high reliability;therefore,they could effective be used to select underground screen meshes and improve the design of production process.
基金NationalNaturalScienceFoundation (59878033)Tianjin Science and Technology Developm entProgram (043100611).
文摘This paper, probing into heavy metal control in domestic rubbish by source screening and nutrient element analysis, revealed the feasibility of source control of heavy metals and the suitability of rubbish as turfgrass medium. Heavy metals in domestic rubbish were controlled by source screening before composting. The study consisted of a control with garden soil. The contents of main mineral elements and heavy metals in rubbish compost and control were determined by the method of ICP-AES. The results showed that heavy metal concentrations in rubbish were lower than those in garden soil, and little difference occurred between rubbish and garden soil in main mineral element concentrations. Based on this, it was concluded that rubbish compost was favorable for using as turfgrass medium and heavy metal control in rubbish by source screening was effective.
文摘The coordination compounds of PdII, PtII, RhIII and IrIII metal ions with a Schiff base ligand (L) i.e. 2,6- diacetylpyridine bis(thiosemicarbazone) have been synthesized and characterized by elemental analyses, molar conductance, magnetic susceptibility measurements, IR, NMR and electronic spectral studies. On the basis of molar conductance and elemental analyses the complexes were found to have composition [M(L)]Cl2 and [M’(L)Cl]Cl2, where M = Pd(II), Pt(II) and M’ = Rh(III), Ir(III). The spectral studies reveal that the complexes possess monomeric composition. Complexes of PdII and PtII were found to have four coordinated square planar geometry whereas the complexes of RhIII and IrIII posses six coordinated octahedral geometry. The ligand field parameters were calculated using various energy level diagrams. In vitro synthesized compounds and metal salts have been tested against some species of plant pathogenic fungi and bacteria in order to assess their antimicrobial properties.
文摘The catalyst screening tests for carbon dioxide oxidative coupling of methane (CO2-OCM) have been investigated over ternary and binary metal oxide catalysts. The catalysts are prepared by doping MgO- and CeO2-based solids with oxides from alkali (Li2O), alkaline earth (CaO), and transition metal groups (WO3 or MnO). The presence of the peroxide (O2-2) active sites on the Li2O2, revealed by Raman spectroscopy, may be the key factor in the enhanced performance of some of the Li2O/MgO catalysts. The high reducibility of the CeO2 catalyst, an important factor in the CO2-OCM catalyst activity, may be enhanced by the presence of manganese oxide species. The manganese oxide species increases oxygen mobility and oxygen vacancies in the CeO2 catalyst. Raman and Fourier Transform Infra Red (FT-IR) spectroscopies revealed the presence of lattice vibrations of metal-oxygen bondings and active sites in which the peaks corresponding to the bulk crystalline structures of Li2O, CaO, WO3 and MnO are detected. The performance of 5%MnO/15%CaO/CeO2 catalyst is the most potential among the CeO2-based catalysts, although lower than the 2%Li2O/MgO catalyst. The 2%Li2O/MgO catalyst showed the most promising C2+ hydrocarbons selectivity and yield at 98.0% and 5.7%, respectively.
