Fatigue Life Evaluation Method for Foundry Crane Metal Structure Considering Load Dynamic Response and Crack Closure Effect

To compensate for the shortcomings of quasi-static law in anti-fatigue analysis of foundry crane metal structures,the fatigue life evaluation method of foundry crane metal structure considering load dynamic response and crack closure effect is proposed.In line with the theory of mechanical vibration,a dynamic model of crane structure during the working cycle is constructed,and dynamic coefficients under diverse actions are analysed.Calculation models of the internal force dynamic change process of dangerous cross-sections and a simulation model of first principal stress-time history are established by using the steel structure design criteria,which is utilised to extract the change of first principal stress of danger points over time.Then,the double-parameter stress spectrum is obtained by the rain flow counting method.The fatigue life calculation formula is corrected by introducing a crack closure parameter that can be calculated by the stress ratio and the effective stress ratio.Under the finite element model imported into Msc.Patran,crack propagation analysis is performed by the growth method in the fatigue integration module Msc.Fatigue.Taking the metal structure of a 100/40t-28.5m foundry crane with track offset as an example,the accuracy of calculation results and the feasibility and applicability of the proposed method are verified by theoretical calculation and finite element simulation,which provide a theoretical basis for improvement of the fatigue resistance design of foundry cranes.

Formation, Structure and Properties of Bulk Metallic Glasses

Bulk metallic glasses with up to 72 mm critical section thickness have been obtained by conventional casting techniques and the properties of these materials, particularly the mechanical and magnetic properties have been studied. These materials have been demonstrated to have novel properties which are fundamentally different from their crystalline counterparts. The recent status of research and development in formation, structure and properties of bulk metallic glasses is reviewed. The techniques to produce such bulk glasses are summarized and the glass forming ability and the critical cooling rate of these materials are discussed. Further consideration of the development and application of this new class of materiaIs will be proposed.

Structure Evolution of Bulk Metallic Glass Zr_(52.5)Ni_(14.6)Al_10Cu_(17.9)Ti_5 during Annealing

Bulk metallic glass Zr52.5Ni14.6Al10Cu17.9Ti5 was prepared by melt injection casting method. Its glass transition and crystallization temperatures were determined by differential scanning calorimetry （DSC） to be 631 K and 710 K respectively. By analysis of X-ray diffractometry （XRD） and transmission electron microscopy （TEM ）, the predominant crystallized phase of Zr2Ni0.67O0.33 distributed on glass state matrix was detected after annealing at 673 K for 600 s. The transformation to Zr2Ni0.67O0.33 and a small amount of ZrAl and Zr2Cu took place after annealing for 600 s at temperature from 703 K to 723 K. With increasing annealing temperature from 753 K to 823 K, the amounts of ZrAl and Zr2Cu increased, but the size of the crystals did not significantly change. The transformation to Zr2Ni0.67O0.33 is interface-controlled, but is diffusion-controlled to Zr2Cu and ZrAl. With increasing annealing temperature up to 200 K above Tx, the nanometer grains became very fine because of the increase of nucleation rate for Zr2Cu and ZrAl.

Investigation on Molecular and Crystal Structures of Metal Complexes with Aminopolycarboxylic Acids(Ⅰ)─Synthesis and Structure of Na_2[Fe~Ⅲ(ida)2]2·3H_2O

The crystal structure of the title complex salt has been determined by single-crystal X-ray structure analysis. The crystal data are as follows; Monoclinic, P21/c, a=15.6480(10)A,b=16.7870(10)A, c=10.347(2)A, β=90.790(10), V=2717.7(6)A3, Z=3, and R=0.0333 for 4789 unique reflections. The complex anion has a pseudo-octahedral structure distorted more than the CrⅢand CoⅢ analogs, in which cach iminodiacetato ligand (ida2-) is coordinated in a facial fashion with the two N atoms in a cis configuration, resulting in an unsyin-fac structure.

Studies of Atomic Structure and Physical Properties of Metal Clusters in MgO by HREM and Nano-probe Methods

Nanometer-sized metal clusters were prepared inside single crystalline MgO films by vacuum co-deposition of metals and MgO. The atomic structure was studied by high-resolution electron microscopy (HREM) and nm-area electron diffraction. The size of the clusters is ranging from 1 nm to 3 nm without those larger than 5 nm, and most of them have definite epitaxial orientations with the MgO matrix films. The character of the composite films is very much useful for the studies of various kinds of physical properties with anisotroPy. The physical properties such as electric transport, magnetic, optical absorption, sintering and catalytic ones were thus measured on the same samples analyzed by HREM by using high sensitivity apparatus with interest of clarifying the retationship between the atomic structure and physical

Heterogeneous catalytic partial oxidation of lower alkanes(C_1–C_6) on mixed metal oxides

This review paper aims at analysing the state of the art for partial oxidation and oxidative dehydrogenation(ODH) reactions of lower alkanes C_1–C_6into olefins and oxygenated products(aldehydes, anhydrides,carboxylic acids) on metal oxide catalysts with cations of variable oxidation state, such as Mo and V in particular. Key parameters to be met by the catalysts, such as their redox properties, their structural aspects, active sites composed of ensembles of atoms isolated one from the others, mechanisms of reactions, are discussed. Main features of the different reactions of C_1–C_6alkanes and catalysts are analysed and their generalisation for determining more active and more selective catalysts is attempted. Prospective views for the future of the domain are proposed.

Recent Developments of Transition Metal Compounds-Carbon Hybrid Electrodes for High Energy/Power Supercapacitors

Due to their rapid power delivery,fast charging,and long cycle life,supercapacitors have become an important energy storage technology recently.However,to meet the continuously increasing demands in the fields of portable electronics,transportation,and future robotic technologies,supercapacitors with higher energy densities without sacrificing high power densities and cycle stabilities are still challenged.Transition metal compounds(TMCs)possessing high theoretical capacitance are always used as electrode materials to improve the energy densities of supercapacitors.However,the power densities and cycle lives of such TMCs-based electrodes are still inferior due to their low intrinsic conductivity and large volume expansion during the charge/discharge process,which greatly impede their large-scale applications.Most recently,the ideal integrating of TMCs and conductive carbon skeletons is considered as an effective solution to solve the above challenges.Herein,we summarize the recent developments of TMCs/carbon hybrid electrodes which exhibit both high energy/power densities from the aspects of structural design strategies,including conductive carbon skeleton,interface engineering,and electronic structure.Furthermore,the remaining challenges and future perspectives are also highlighted so as to provide strategies for the high energy/power TMCs/carbon-based supercapacitors.

A Universal Principle to Accurately Synthesize Atomically Dispersed Metal–N_4 Sites for CO_2 Electroreduction

Atomically dispersed metal-nitrogen sites-anchored carbon materials have been developed as effective catalysts for CO2 electroreduction(CO2 ER),but they still suffer from the imprecisely control of type and coordination number of N atoms bonded with central metal.Herein,we develop a family of single metal atom bonded by N atoms anchored on carbons(SAs-M-N-C,M=Fe,Co,Ni,Cu)for CO2 ER,which composed of accurate pyrrole-type M-N4 structures with isolated metal atom coordinated by four pyrrolic N atoms.Benefitting from atomically coordinated environment and specific selectivity of M-N4 centers,SAs-Ni-N-C exhibits superior CO2 ER performance with onset potential of-0.3 V,CO Faradaic efficiency(F.E.) of 98.5%at-0.7 V,along with low Tafel slope of 115 mV dec-1 and superior stability of 50 h,exceeding all the previously reported M-N-C electrocatalysts for CO2-to-CO conversion.Experimental results manifest that the different intrinsic activities of M-N4 structures in SAs-M-N-C result in the corresponding sequence of Ni> Fe> Cu> Co for CO2 ER performance.An integrated Zn-CO2 battery with Zn foil and SAs-Ni-N-C is constructed to simultaneously achieve CO2-to-CO conversion and electric energy output,which delivers a peak power density of 1.4 mW cm-2 and maximum CO F.E.of 93.3%.

Recent Progress in Ferroelectric Diodes: Explorations in Switchable Diode Effect

Switchable diode effect in ferroelectric diodes has attracted much attention for its potential applications in novel nonvolatile memories. We briefly review recent investigations on the switchable diode effect in ferroelectric diodes both experimentally and theoretically. Many recent studies demonstrate that the interfacial barrier between the metal-ferroelectrics could be modulated by the polarization charges, and the ferroelectric polarization that can be reversed by an external electric field plays a dominant role in the switchable diode effect. Moreover, we review a self-consistent numerical model, which can well describe the switchable diode effect in ferroelectric diodes. Based on this model, it can be predicted that it is a better choice to select metals with a smaller permittivity, such as noble metals, to obtain a more pronounced switchable diode effect in ferroelectric diodes.

Non Ideal Schottky Barrier Diode’s Parameters Extraction and Materials Identification from Dark I-V-T Characteristics

Several parameters of a commercial Si-based Schottky barrier diode (SBD) with unknown metal material and semiconductor-type have been investigated in this work from dark forward and reverse I-V characteristics in the temperature (T) range of [274.5 K - 366.5 K]. Those parameters include the reverse saturation current (Is), the ideality factor (n), the series and the shunt resistances (Rs and Rsh), the effective and the zero bias barrier heights (ΦB and ΦB0), the product of the electrical active area (A) and the effective Richardson constant (A**), the built-in potential (Vbi), together with the semiconductor doping concentration (NA or ND). Some of them have been extracted by using two or three different methods. The main features of each approach have been clearly stated. From one parameter to another, results have been discussed in terms of structure performance, comparison on one another when extracted from different methods, accordance or discordance with data from other works, and parameter’s temperature or voltage dependence. A comparison of results on ΦB, ΦB0, n and NA or ND parameters with some available data in literature for the same parameters, has especially led to clear propositions on the identity of the analyzed SBD’s metal and semiconductor-type.

Sustainability of steel structures:towards an integrated approach to life-time engineering design

Nowadays,the construction sector is more and more oriented toward the promotion of sustainability in all its activities.The goal to achieve is the optimization of performances,over the whole life-cycle,with respect to environmental,economic and social requirements.According to the latest advances,the concept of sustainability applied to constructions covers a number of branches such as life-cycle costing,ecology,durability and even structural design.Several procedures and design tools have been implemented in the framework of international research.Indeed the current trend in civil engineering research is moving towards life-time engineering,with the aim to implement integrated methodologies to consider as a whole all the sustainability requirements according to time-dependent multi-performance-based design approaches.Following a general introduction of the concept of sustainability applied to constructions,this paper presents an overview of life-time engineering methodologies according to the current state-of-the-art.In particular the methods currently received by International Standards are discussed.A special focus is devoted to the durability design of metal structures with respect to the degradation phenomena able to impair the structural capacity over time.Finally a proposal towards an integrated approach to life-time engineering design of steel structures and needs for further advances are presented.

Optical trapping using transverse electromagnetic(TEM)-like mode in a coaxial nanowaveguide

Optical traps have emerged as powerful tools for immobilizing and manipulating small particles in three dimensions.Fiber-based optical traps(FOTs)significantly simplify optical setup by creating trapping centers with single or multiple pieces of optical fibers.In addition,they inherit the flexibility and robustness of fiber-optic systems.However,trapping 10-nm-diameter nanoparticles(NPs)using FOTs remains challenging.In this study,we model a coaxial waveguide that works in the optical regime and supports a transverse electromagnetic(TEM)-like mode for NP trapping.Single NPs at waveguide front-end break the symmetry of TEM-like guided mode and lead to high transmission efficiency at far-field,thereby strongly altering light momentum and inducing a large-scale back-action on the particle.We demonstrate,via finite-difference time-domain(FDTD)simulations,that this FOT allows for trapping single 10-nm-diameter NPs at low power.