In situ laser deposition of NiTi intermetallics for corrosion improvement of Ti-6Al-4V alloy

NiTi intermetallic coatings were fabricated on the surface of Ti-6Al-4V alloy by melting Ni and Ti powders using laser metal deposition（LMD） process.The effects of NiTi reinforcement content on the microstructure,hardness and corrosion properties of the coatings were examined.The results show that the deposited coatings are characterized by NiTi,NiTi2 and NiTi3 intermetallic phases.An appreciable increase in corrosion resistance is obtained for all the coatings,and Ti55Ni45 coating shows the highest corrosion resistance;while coatings Ti50Ni50 and Ti45Ni55 follow in that succession.The reinforcement materials are proven to be corrosion resistant in the tested environment,and the effect of Ti is more dominant.

Fluid Inclusion Geochemistry of Metallic Ore Deposits in the South- Central Sector of theDa Hinggan Mountains in China

Physicochemical parameters of mineralization such as temperature, pressure, salinity, density, composition and boiling of ore fluids as well as pH, Eh, fo2 and reducing parameter in theprocess of mineralization of major ore deposits in the study district have been obtained by the authors through systematic observation and determination of characteristics and phase changes of fluid inclusions at different temperatures and analysis of gaseous and liquid phase compositions of the inclusions, thus providing a scientific basis for the division of mineralization-alteration stages, types of mineral deposits and minerogenetic series and the deepening of the knowledge about the ore-forming processes and mechanisms of mineral deposits. It is indicated that the deposits of the same type have similar fluid inclusion geochemical features and physicochemical parameters though they belong to different minerogenetic series, while the compositions of inclusions are not conditioned by deposit types but closely related to the minerogenetic series of deposits.

The Evolutionary History of Ore-forming Processes of Metallic Ore Deposits in Northern Guangxi

The northern Guangxi region is an important rare metal, rare earth metal and polymetallic metallogenic province. In the region there exist five metallogenic series and two metallogenic subseries, whose metallogenesis shows features of polycyclic spiral evolution throughout the geological history. As far as various cycles are concerned, mantle-derived ore substances were reduced while crust-derived ore substances increased from early to late timesfin the whole geological evolutionary history, mantle-derived substances decreased gradually while crust-derived ones increased. Meanwhile ore element associations became more and more varied. In terms of space, mineralization migrated from the old basement outwards, i.e. from west to east during the Precambrian, and from north to south during the Phanerozoic, and again from east to west during the Yanshanian.

Effects of specific surface area of metallic nickel particles on carbon deposition kinetics

Carbon deposition on nickel powders in methane involves three stages in different reaction temperature ranges. Temperature programing oxidation test and Raman spectrum results indicated the formation of complex and ordered carbon structures at high deposition temperatures. The values of I（D）/I（G） of the deposited carbon reached 1.86, 1.30, and 1.22 in the first, second, and third stages, respectively. The structure of carbon in the second stage was similar to that in the third stage. Carbon deposited in the first stage rarely contained homogeneous pyrolytic deposit layers. A kinetic model was developed to analyze the carbon deposition behavior in the first stage. The rate-determining step of the first stage is supposed to be interfacial reaction. Based on the investigation of carbon deposition kinetics on nickel powders from different resources, carbon deposition rate is suggested to have a linear relation with the square of specific surface area of nickel particles.

Preparation and electrochemical lithium storage performance of porous silicon microsphere composite with metal modification and carbon coating

This work adopts a multi⁃step etching⁃heat treatment strategy to prepare porous silicon microsphere com⁃posite with Sb⁃Sn surface modification and carbon coating(pSi/Sb⁃Sn@C),using industrial grade SiAl alloy micro⁃spheres as a precursor.pSi/Sb⁃Sn@C had a 3D structure with bimetallic(Sb⁃Sn)modified porous silicon micro⁃spheres(pSi/Sb⁃Sn)as the core and carbon coating as the shell.Carbon shells can improve the electronic conductivi⁃ty and mechanical stability of porous silicon microspheres,which is beneficial for obtaining a stable solid electrolyte interface(SEI)film.The 3D porous core promotes the diffusion of lithium ions,increases the intercalation/delithia⁃tion active sites,and buffers the volume expansion during the intercalation process.The introduction of active met⁃als(Sb⁃Sn)can improve the conductivity of the composite and contribute to a certain amount of lithium storage ca⁃pacity.Due to its unique composition and microstructure,pSi/Sb⁃Sn@C showed a reversible capacity of 1247.4 mAh·g^(-1) after 300 charge/discharge cycles at a current density of 1.0 A·g^(-1),demonstrating excellent rate lithium storage performance and enhanced electrochemical cycling stability.

Temporo-Spatial Distribution and Evolution of Ore Deposits in the West Sector of the Northern Qilian Mountains

The west sector of the northern Qilian Mountains is well-known for the Jingtieshan-type iron deposits. A new breakthrough has been made in prospecting for gold and copper in recent years. In this paper, the distribution characteristics of ore deposits in the study area are discussed from the viewpoint of tectonic evolution. It is suggested that there are 9 stages of mineralization from the Palaeoproterozoic to Indosinian. Four minerogenetic series and two minerogenetic subseries of ore deposits are recognized. Iron mineralization occurred in several stages, while most of the metals were accumulated in large amounts in the Caledonian. The enrichment and mineralization of gold is related to large-scale shear-strike-slip faults and the ascent and unloading of deep-seated fluids.

Microstructure transformations and improving wear resistance of austenitic stainless steel additively fabricated by arc-based DED process

In this study, austenitic stainless steel(ASS) was additively fabricated by an arc-based direct energy deposition(DED) technique. Macrostructure, microstructure, mechanical characteristics at different spatial orientations(0°, 90°, and 45°), and wear characteristics were evaluated at the deposited structure top, middle, and bottom regions. Results show that austenite(γ) and delta-ferrite(δ) phases make up most of the microstructure of additively fabricated SS316LSi steel. Within γ matrix, δ phase is dispersed both(within and along) grain boundaries, exhibiting a fine vermicular morphology. The bottom, middle,and top regions of WAAM deposited ASS exhibit similar values to those of wrought SS316L in the tensile and impact test findings. Notably, a drop in hardness values is observed as build height increases. During SEM examinations of fractured surfaces from tensile specimen, closed dimples were observed, indicating good ductility of as-built structure. Wear test findings show signs of mild oxidation and usual adhesive wear. By depositing a mechanically mixed composite layer, an increase in the oxidation percentage was discovered to facilitate healing of worn surfaces. The findings of this study will help in design, production and renovation of products/components that are prone to wear. WAAM-deposited ASS has remarkable strength and ability to withstand impacts;it can be used in the production of armour plates for defence applications, mainly military vehicles and aircraft.

The Ore-forming Mechanism of the Jiajika Pegmatite-Type Rare Metal Deposit in Western Sichuan Province:Evidence from Isotope Dating

Granitic pegmatites are commonly thought to form by fractional crystallization or by liquid immiscibility of granitic magma; however, these proposals are based mainly on analyses of fluid and melt inclusions. Here, we use the Jiajika pegmatite deposit, the largest spodumene deposit in Asia, as a case study to investigate ore forming processes using isotope dating. Dating of a single granite sample from the Jiajika deposit using multiple methods gave a zircon U-Pb SHRIMP age of 208.4 ~ 3.9 Ma, an 4~Ar/39Ar age for muscovite of 182.9 ~ 1.7 Ma, and an 4~Ar/39Ar age for biotite of 169.9 ＋ 1.6 Ma. Based on these dating results and the 4~Ar/39Ar age of muscovite from the Jiajika pegmatite, a temperature-time cooling track for the Jiajika granite was constructed using closure temperatures of the different isotope systems. This track indicates that the granite cooled over ^-40 m. y., with segregation of the pegmatite fluid from the granitic magma at a temperature of ~700~C. This result suggests that the Jiajika pegmatite formed not by fractional crystallization, but by segregation of an immiscible liquid from the granitic magma. When compared with fractional crystallization, the relatively early timing of segregation of an immiscible liquid from a granitic magma can prevent the precipitation of ore-forming elements during crystallization, and suggests that liquid immiscibility could be an important ore-forming process for rare metal pegmatities. We also conclude that isotope dating is a method that can potentially be used to determine the dominant ore-forming processes that occurred during the formation of granite-related ore deposits, and suggest that this method can be employed to determine the formation history of the W-Sn ore deposits found elsewhere within the Nanling Metallogenic Belt.

An overview of laser-based multiple metallic material additive manufacturing: from macro- to micro-scales

Additive manufacturing(AM)is an emerging customized three-dimensional(3D)functional product fabrication technology.It provides a higher degree of design freedom,reduces manufacturing steps,cost and production cycles.However,existing metallic component 3D printing techniques are mainly for the manufacture of single material components.With the increasing commercial applications of AM technologies,the need for 3D printing of more than one type of dissimilar materials in a single component increases.Therefore,investigations on multi-material AM(MMAM)emerge over the past decade.Lasers are currently widely used for the AM of metallic components where high temperatures are involved.Here we report the progress and trend in laser-based macro-and micro-scale AM of multiple metallic components.The methods covered in this paper include laser powder bed fusion,laser powder directed energy deposition,and laser-induced forward transfer for MMAM applications.The principles and process/material characteristics are described.Potential applications and challenges are discussed.Finally,future research directions and prospects are proposed.

Laser metal deposition of refractory high-entropy alloys for high-throughput synthesis and structure-property characterization

Progress in materials development is often paced by the time required to produce and evaluate a large number of alloys with different chemical compositions.This applies especially to refractory high-entropy alloys(RHEAs),which are difficult to synthesize and process by conventional methods.To evaluate a possible way to accelerate the process,high-throughput laser metal deposition was used in this work to prepare a quinary RHEA,TiZrNbHfTa,as well as its quaternary and ternary subsystems by in-situ alloying of elemental powders.Compositionally graded variants of the quinary RHEA were also analyzed.Our results show that the influence of various parameters such as powder shape and purity,alloy composition,and especially the solidification range,on the processability,microstructure,porosity,and mechanical properties can be investigated rapidly.The strength of these alloys was mainly affected by the oxygen and nitrogen contents of the starting powders,while substitutional solid solution strengthening played a minor role.

A Super-Large Rb-Nb Rare Metal Deposit has been Discovered in Huashi Village of Xinglong County, Hebei Province

Objective The Huashi Village in Xinglong County of Hebei Province is located in the Yanshan subsidence zone in the central eastern North China Plate, which is 137 km away from Beijing City （Fig. la）. This area has undergone large -scale magmatic intrusion affected by the tectonic compression of the Pacific Plate in the Mesozoic （known as the Yanshanian movement） to form many alkaline rocks such as the Wulingshan rock mass. Previous studies have conducted petrological research and reconnaissance survey of rare metal ores in this area （Tian Shuzhang and Guo Zongshan, 1981; Xu Baoling et al., 1996）. In 2016, the Qinhuangdao Mineral and Hydrology Engineering Geological Brigade of Hebei Bureau of Geology and Mineral Resources Exploration implemented the project of Reconnaissance of Rare Metal Ores Including Rubidium in Huashi Village of Xinglong County, Hebei Province, and discovered super-large rare metal deposits of rubidium and biobium in the Madi alkali feldspar granite bodies in the Huashi Village to achieve great breakthrough of rare metal ore prospecting.

Effect of Al in Ti－microalloyed Mn－Ni－Mo welding wire on microstructure and toughness of deposited metal

The effect of Al in Ti-microalloyed welding wire on microstructure and toughness of deposited metals is studied.The results show that the deposited metal toughness worsens with increasing Al in wire' The mechanism of Al is as follows:(1) Al makes oxygen content in deposited metal increase.(2)Al restrains the formation of Ti-rich oxide inclusion, which causes granular bainite microstructure in deposited metal.(3)The content of solute Ti in deposited metal increases with Al content in welding wire,as a result,a part of carbonrich constitution in deposited metal is in the form of twin martensite.

Effects of rare earth elements on sulphur and phosphorus impurities in deposited metal

In order to reduce sulphur （ S ） and phosphorus （ P ） impurities in deposited metal, a small amount of rare earth （RE） lanthanum （ La） and yttrium （Y） were added into the coating ofE4303 electrode, a low carbon steel electrode. The microstructures of deposited metal were analyzed with metalloscope, and then the content of S and P was examined by energy dispenive X-ray spectrometer （ EDXS ）, and by wavelength dispersive X-ray fluorescence （XRF） spectrometer for further examination. The results show that the proper addition of La and Y can be beneficial to the desulfurization and dephosphorization of the deposited metal. Certainly, difference in the addition amount of La and Y could lead to various desulfurization and dephosphorization efficiency, in which the former is more obvious than the latter. With the proper amount of La attd Y, there is finer microstructure in deposited metal, and mechanical properties are improved as well. The S content in deposited metal with added La and Y decreases by 44. 44 wt. % , while the P content 6. 67 wt. %, compared with that in deposited metal without La and II.

In-situ wafer bowing measurements of GaN grown on Si(111) substrate by reflectivity mapping in metal organic chemical vapor deposition system

In this work, the wafer bowing during growth can be in-situ measured by a reflectivity mapping method in the 3×2 Thomas Swan close coupled showerhead metal organic chemical vapor deposition（MOCVD） system. The reflectivity mapping method is usually used to measure the film thickness and growth rate. The wafer bowing caused by stresses（tensile and compressive） during the epitaxial growth leads to a temperature variation at different positions on the wafer, and the lower growth temperature leads to a faster growth rate and vice versa. Therefore, the wafer bowing can be measured by analyzing the discrepancy of growth rates at different positions on the wafer. Furthermore, the wafer bowings were confirmed by the ex-situ wafer bowing measurement. High-resistivity and low-resistivity Si substrates were used for epitaxial growth. In comparison with low-resistivity Si substrate, Ga N grown on high-resistivity substrate shows a larger wafer bowing caused by the highly compressive stress introduced by compositionally graded Al Ga N buffer layer. This transition of wafer bowing can be clearly in-situ measured by using the reflectivity mapping method.

Low-leakage-current AlGaN/GaN HEMTs on Si substrates with partially Mg-doped GaN buffer layer by metal organic chemical vapor deposition

High-performance low-leakage-current A1GaN/GaN high electron mobility transistors （HEMTs） on silicon （111） sub- strates grown by metal organic chemical vapor deposition （MOCVD） with a novel partially Magnesium （Mg）-doped GaN buffer scheme have been fabricated successfully. The growth and DC results were compared between Mg-doped GaN buffer layer and a unintentionally onμe. A 1μ m gate-length transistor with Mg-doped buffer layer exhibited an OFF-state drain leakage current of 8.3 × 10-8 A/mm, to our best knowledge, which is the lowest value reported for MOCVD-grown A1GaN/GaN HEMTs on Si featuring the same dimension and structure. The RF characteristics of 0.25-μ m gate length T-shaped gate HEMTs were also investigated.

Selective Area Growth and Characterization of GaN Nanorods Fabricated by Adjusting the Hydrogen Flow Rate and Growth Temperature with Metal Organic Chemical Vapor Deposition

CaN nanorods are successfully fabricated by adjusting the flow rate ratio of hydrogen （H2）/nitrogen （N2） and growth temperature of the selective area growth （SAG） method with metal organic chemical vapor deposition （MOCVD）. The SAG template is obtained by nanospherical-lens photolithography. It is found that increasing the flow rate of 1-12 will change the CaN crystal shape from pyramid to vertical rod, while increasing the growth temperature will reduce the diameters of GaN rods to nanometer scale. Finally the CaN nanorods with smooth lateral surface and relatively good quality are obtained under the condition that the H2：N2 ratio is 1：1 and the growth temperature is 1030℃. The good crystal quality and orientation of GaN nanorods are confirmed by high resolution transmission electron microscopy. The cathodoluminescence spectrum suggests that the crystal and optical quality is also improved with increasing the temperature.

Intrusion-related Gold Deposits in Egypt

Intrusion-related gold deposits(IRGDs)occur in the Eastern Desert(ED)of Egypt within magmatic districts that are exploited for tungsten and tin mineralization.IRGDs and intrusion-related rare metal deposits(IRRMDs)are almost invariably linked with the late to post collisional Younger Granites(YGs)that have three successive phases(Ⅰ,ⅡandⅢ).At~635–630 Ma,the ED underwent a transition in deformation style from compressional to extensional and a switch from subduction with crustal thickening to delamination with crustal thinning.This transition was concurrent with the emplacement of a short magmatic pulse(~635–630 Ma)that represents a transition between orogenic gold deposits and IRGDs.K-rich calc alkaline granites(phaseⅠandⅡof the YGs)hosting IRGDs like the Hangalia deposit were emplaced during the time span 630–610 Ma.Alkaline magmatism began at 610 Ma,coexisting with the K-rich calc-alkaline magmatism over the 610–590 Ma time span,where the Fawakhir(598±3 Ma)and Um Had(596±2 Ma)granites that host the IRGDs were emplaced.In time,the alkaline magmatism became more alkaline giving rise to phaseⅢof the YGs that hosts IRRMDs.A distinct metallogenic epoch comprising both IRGDs and IRRMDs,was undergoing extreme growth at~600 Ma.

Influence of processing parameters on laser metal deposited copper and titanium alloy composites

The laser metal deposition （LMD） was conducted on copper by varying the processing parameters in order to achieve the best possible settings. Two sets of experiments were conducted. The deposited composites were characterized through the evolving microstructure, microhardness profiling and mechanical properties. It was found that the evolving microstructures of the deposited composites were characterized with primary, secondary and tertiary arms dendrites, acicular microstructure as well as the alpha and beta eutectic structures. From the two sets of experiments performed, it was found that Sample E produced at a laser power of 1200 W and a scanning speed of 1.2 m/min has the highest hardness of HV （190±42） but exhibits some lateral cracks due to its brittle nature, while Sample B produced at laser power of 1200 W and a scanning speed of 0.3 m/min shows no crack and a good microstructure with an increase in dendrites. The strain hardening coefficient of the deposited copper composite obtained in this experiment is 3.35.

Effect of electropulsing on anisotropy in strength of laser metal deposited Ti-6Al-4V alloy

The effect of electropulsing treatment on microstructure and mechanical strength of laser metal deposited Ti−6Al−4V alloy was investigated in order to eliminate the anisotropy in strength of laser metal deposited Ti−6Al−4V alloy by tensile tests,optical microscopy,scanning electron microscopy,electron back-scattered diffraction analyses and transmission electron microscopy.With increasing applied voltages from 0 to 130 V,the evolution of microstructure within columnarβgrains followed the sequence ofα′martensite→colonyαstructure→basket-weaveαstructure.The electropulsing treated at 130 V weakened the texture of martensite withinβgrains.The as-built Ti−6Al−4V alloy showed an anisotropy in yield strength(6.2%).After processing at 130 V,the anisotropy in yield strength was reduced to 0.6%,which was attributed to the almost equivalent distribution of Schmid factor in the samples deformed along different orientations.

Growth and Characterization of Doped CeO_2 Buffers on Ni-W Substrates for Coated Conductors Using Metal Organic Deposition Method

CeO2 and Ce0.8M0.2O2-d films （M = Mn, Y, Gd, Sm, Nd and La） with （00l） preferred orientation have been prepared on biaxially textured Ni-W substrates by metal organic decomposition （MOD） method. The factors influencing the formation of cracks on the surface of these CeO2 and doped CeO2 films on Ni-W substrates were explored by X-ray diffraction （XRD）, scanning electron microscopy （SEM） analysis, atomic force microscopy （AFM） and differential scanning calorimetry （DSC）. The results indicate that many factors, such as the change of the ionic radii of doping cations, the transformation of crystal structure and the formation of oxygen vacancies in lattices at high annealing temperature, may be related to the formation of cracks on the surface of these films. However, the crack formation shows no dependence on the crystal lattice mismatch degree of the films with Ni-W substrates. Moreover, the suppression of surface cracks is related to the change of intrinsic elasticity of CeO2 film with doping of cations with a larger radius. SEM and AFM investigations of Ce0.8M0.2O2-d （M = Y, Gd, Sm, Nd and La） films reveal the dense, smooth and crack-free microstructure, and their lattice parameters match well with that of YBCO, illuminating that they are potentially suitable to be as buffer layer, especially as cap layer in multi-layer architecture of buffer layer for coated conductors.