This work includes synthesis of 2,2＇-（5,5＇-（ethane-1,2-diyl）bis（1,3,4-oxadiazole-5,2diyl））bis（sulfanediyl）dibenzenamine （EOSBE） and 2,2＇-（5,5＇-methylenebis（1,3,4-oxadiazole-5,2-diyl）bis（sulfanediyl）...This work includes synthesis of 2,2＇-（5,5＇-（ethane-1,2-diyl）bis（1,3,4-oxadiazole-5,2diyl））bis（sulfanediyl）dibenzenamine （EOSBE） and 2,2＇-（5,5＇-methylenebis（1,3,4-oxadiazole-5,2-diyl）bis（sulfanediyl））dibenzenamine （MOSBE）. All synthesized ligands were characterized by IR, ^1H-NMR, ^13C-NMR, UV-visible spectroscopies and molar conductivity. A series of complexes with a general formula [M2LCl4]. Where M（Ⅱ） = Co, Ni, Cu and Zn; L = EOSBE and MOSBE were synthesized in basic media using KOH solution. In these complexes both ligands are bidentate ligands coordinated through sulfur and nitrogen. All complexes have been characterized by IR-spectra, UV-visiblc spectra, conductivity and magnetic susceptibility.展开更多
文摘This work includes synthesis of 2,2＇-（5,5＇-（ethane-1,2-diyl）bis（1,3,4-oxadiazole-5,2diyl））bis（sulfanediyl）dibenzenamine （EOSBE） and 2,2＇-（5,5＇-methylenebis（1,3,4-oxadiazole-5,2-diyl）bis（sulfanediyl））dibenzenamine （MOSBE）. All synthesized ligands were characterized by IR, ^1H-NMR, ^13C-NMR, UV-visible spectroscopies and molar conductivity. A series of complexes with a general formula [M2LCl4]. Where M（Ⅱ） = Co, Ni, Cu and Zn; L = EOSBE and MOSBE were synthesized in basic media using KOH solution. In these complexes both ligands are bidentate ligands coordinated through sulfur and nitrogen. All complexes have been characterized by IR-spectra, UV-visiblc spectra, conductivity and magnetic susceptibility.
